5713 results about "Lithium iron phosphate" patented technology

The invention relates to a method for preparing a lithium iron phosphate / carbon composite material of a lithium ion battery, which belongs to the technical field of lithium ion batteries. The method for preparing the lithium iron phosphate / carbon composite material of the lithium ion battery comprises the following steps of: 1) preparing a suspending graphene-dispersed aqueous solution system, namely, crushing graphite to 1 to 5 microns, adding the crushed graphite into distilled water or purified water, adding 0.1 to 5 percent of surfactant, heating with stirring the mixed solution to 180 to 250 DEG C in a sealing way, performing stirring for 2 to 6 hours and reducing the temperature; 2) crushing lithium iron phosphate to the particle size of 1 to 5 microns, adding the crushed lithium iron phosphate into the distilled water or the purified water, adding with stirring 0.01 to 1 percent of coupling agent, performing uniform stirring, adding the graphene-dispersed aqueous solution, and performing stirring and filtration; and 3) vacuum-drying solid powder obtained by the filtration, and calcinating the dried solid powder for 2 to 12 hours to obtain the graphene-coated lithium iron phosphate cathode material. The method has the advantages of simple process, high material performance, high conductivity, high bulk density, high compacted density and the like.

Systems, methods, and articles for a portable power case are disclosed. The portable power case is comprised of at least one battery and at least one PCB. The portable power case has at least one USB port and at least two access ports, at least two leads, or at least one access port and at least one lead. The portable power case is operable to supply power to an amplifier, a radio, a wearable battery, a mobile phone, and a tablet. The portable power case is operable to be charged using solar panels, vehicle batteries, AC adapters, non-rechargeable batteries, and generators. The portable power case provides for modularity that allows the user to disassemble and selectively remove the batteries installed within the portable power case housing.

Systems, methods, and articles for a portable power case are disclosed. The portable power case is comprised of at least one battery and at least one PCB. The portable power case has at least one USB port and at least two access ports, at least two leads, or at least one access port and at least one lead. The portable power case is operable to supply power to an amplifier, a radio, a wearable battery, a mobile phone, and a tablet. The portable power case is operable to be charged using solar panels, vehicle batteries, AC adapters, non-rechargeable batteries, and generators. The portable power case provides for modularity that allows the user to disassemble and selectively remove the batteries installed within the portable power case housing.

The invention discloses a lithium iron phosphate positive electrode material, a preparation method thereof and a lithium battery, and relates to the technical field of lithium ion batteries. According to the method, the pressing index of the lithium iron phosphate positive electrode material is tested by adopting a specific method, so that the pressing index meets a specific range, meanwhile, the average circularity of larger particles in a Dv50-Dv100 range meets a proper range, the lithium iron phosphate positive electrode material has better particle movement capability, and the particles can move at a higher speed to be rearranged during pressing, so that the particle size of the lithium iron phosphate positive electrode material is reduced, and the quality of the lithium iron phosphate positive electrode material is improved. Therefore, the positive pole piece with high compaction density can be obtained, the charge-discharge capacity of the battery can be improved, and meanwhile, the particles can be prevented from being broken when being pressed, so that the positive pole piece has good anti-pressure capability. By adopting the lithium iron phosphate positive electrode material provided by the invention, the lithium battery has relatively high energy density and capacity retention ratio.

The invention provides a battery monomer, a secondary battery and an electric device, and belongs to the field of batteries. The battery monomer comprises a positive electrode plate, the positive electrode plate comprises a positive electrode active material layer, the positive electrode active material layer comprises a positive electrode active material, and the volume particle size distribution Dv50 of the positive electrode active material is 0.3 [mu] m-3 [mu] m; the volume particle size distribution Dv10 is 100-800 nm, the volume particle size distribution Dv99 is less than 20 [mu] m, the positive electrode active material comprises M-doped lithium iron phosphate, M comprises Al and / or at least one transition metal element except Fe, and the mass content of M in the M-doped lithium iron phosphate is 200-1500 ppm. According to the present invention, the particle size of the positive electrode active material, the type of the doping element and the doping amount are simultaneously regulated and controlled in the above range, and the parameters are matched and co-act so as to provide the good cycle performance on the basis of the high power performance of the battery monomer.

The invention discloses a preparation method of a high-compaction-density lithium iron phosphate material, through grading of large and small particle lithium iron phosphate, optimization of a sintering process and reasonable selection of a carbon source and a titanium dopant, the compaction density and the electrochemical performance of the material are remarkably improved, and the preparation method specifically comprises the following steps: mixing iron phosphate, lithium carbonate, the carbon source and auxiliary materials; the preparation method comprises the following steps: carrying out coarse grinding and fine grinding, respectively preparing large-particle lithium iron phosphate and small-particle lithium iron phosphate (a material A and a material B) by adopting spray drying and high-temperature calcination processes, mixing the material A and the material B according to a ratio, adding auxiliary materials, grinding, further carrying out spray drying, calcining and crushing to obtain a final lithium iron phosphate product, and the maximum compaction density of the prepared material can reach 2.712 g / cm < 3 >. According to the present invention, the maximum 1C discharge specific capacity can achieve 140.5 mAh / g, the maximum 1C 3.2 V discharge platform retention rate is 91.4%, and the prepared lithium ion battery negative electrode material has characteristics of excellent conductivity, high discharge capacity and good cycle stability, and is suitable for power batteries and energy storage batteries.

The invention relates to a waste lithium iron phosphate battery recycling method, in particular to a graded recycling method for lithium, iron, phosphorus and graphite in a waste lithium iron phosphate battery, and belongs to the technical field of lithium ion batteries and resource recycling of the lithium ion batteries. According to the method, the mode that oxidizing roasting and selective leaching are combined is adopted, the leaching rate and selectivity of lithium are effectively improved, the leaching rate of the lithium element is close to 100% under the optimized condition, and limit recovery of the lithium element is achieved; meanwhile, aiming at the problem that iron and phosphorus in the leaching residues are difficult to utilize, a wet ball milling and secondary acid leaching method is combined, phosphorus and iron elements are separated from negative electrode graphite firstly, and graded recovery of iron, phosphorus and graphite is achieved. According to the method, the high recovery rate of lithium is realized, and meanwhile, high-added-value products such as ferric oxide and sodium phosphate are prepared by efficiently recovering ferric phosphate.

The invention provides a battery monomer, a battery device and a power utilization device. The battery monomer comprises a positive pole piece, an isolating membrane, a negative pole piece and electrolyte, and the positive pole piece, the isolating membrane and the negative pole piece are arranged in a laminated manner; the positive pole piece comprises a positive current collector and a positive active layer arranged on at least one side of the positive current collector, the negative pole piece comprises a negative current collector and a negative active layer arranged on at least one side of the negative current collector, and the positive active layer comprises lithium iron phosphate primary particles; the isolating membrane comprises a base membrane and a bonding layer, the bonding layer is of a porous continuous structure, and the bonding layer is at least arranged on one side, facing the positive electrode active layer, of the base membrane; the electrolyte comprises a first solvent, and the first solvent comprises one or more of dimethyl carbonate and linear carboxylic ester. The battery monomer has relatively good cycle performance.

The invention discloses a wide-temperature-range high-rate lithium iron phosphate positive electrode material, a preparation method and a lithium ion battery, and the preparation method comprises the following steps: S1, uniformly mixing an iron source, a phosphorus source, a lithium source, a first carbon source, a transition metal-containing dopant and a dispersant, and carrying out first grinding; s2, performing spray drying on the slurry subjected to primary grinding to obtain a first precursor; s3, sintering the first precursor for the first time under the protection of an inert gas atmosphere; s4, mixing a material obtained after primary sintering, a second carbon source and a dispersing agent, and then performing secondary grinding; s5, performing spray drying on the slurry obtained by secondary grinding to obtain a second precursor; and S6, sintering the second precursor for the second time under the protection of the inert gas atmosphere to obtain the lithium iron phosphate positive electrode material. After the positive electrode material provided by the invention is assembled into a battery, the side reaction of lithium iron phosphate and electrolyte can be effectively reduced, and the positive electrode material not only has low-temperature high-rate performance, but also has excellent high-temperature cycle performance.

The invention discloses a composite positive electrode material and a preparation method thereof, a positive plate and a lithium ion battery. The composite positive electrode material comprises lithium iron phosphate and a carbon coating layer coating the surface of the lithium iron phosphate, wherein the integral intensity ratio ID / IG of a D peak to a G peak of the carbon coating layer in a Raman spectrum is 0.2-0.9, and the resistivity of the composite positive electrode material is 0.1-10 omega.cm. According to the preparation method, the graphitization degree of the carbon coating layer is controlled within a proper range (ID / IG is 0.2-0.9), so that good conductivity is ensured, and structural instability caused by excessive graphitization is avoided. The moderate graphitization degree is beneficial to formation of an ordered carbon layer structure, provides more electron transport channels and reduces the potential barrier of electron migration, so that the conductivity of the composite material is greatly improved, and the resistivity is reduced to an excellent level of 0.1-10 omega.cm.

The invention discloses a lithium iron phosphate battery pack SOE dynamic prediction and life evaluation method and system fused with a P2D model, and relates to the technical field of battery management, and the method comprises the steps: collecting operation data, building a multi-physical field coupled P2D model, carrying out the SOE dynamic prediction based on the P2D model, building a life evaluation model in combination with a performance attenuation mechanism, and optimizing an operation strategy. According to the method, on the basis of historical operation data and real-time state parameters, an SOE dynamic prediction result of the battery pack is generated by using an electrochemical-thermal-mechanical multi-physics field coupled P2D model; and analyzing the prediction result in combination with a long-term performance attenuation mechanism, evaluating the residual life of the battery pack, and outputting an evaluation result. The SOE prediction precision is improved, the performance change rule is comprehensively reflected by using the life evaluation model, and the operation efficiency is remarkably improved and the service life is prolonged through real-time monitoring and optimization. According to the invention, efficient and reliable battery management requirements under complex working conditions can be met.

The invention discloses a waste lithium iron phosphate positive electrode material regenerated by a low-temperature normal-pressure liquid phase method and a preparation method, repair of waste lithium iron phosphate is realized through a low-temperature liquid phase, compared with a traditional hydrothermal method, the requirement for equipment in the repair process can be effectively reduced, the structure of regenerated lithium iron phosphate is stabilized through an annealing process, and the recovery rate of lithium iron phosphate is improved. Meanwhile, the added organic carbon source can repair a damaged carbon layer of the waste lithium iron phosphate, and the electrochemical performance of the regenerated lithium iron phosphate is improved. The invention aims to provide the regeneration method of the waste lithium iron phosphate positive electrode material, which is green, efficient and low in energy consumption and has an industrial application prospect.

The invention discloses a waste lithium iron phosphate positive electrode material recycling method and a lithium iron phosphate material, and the method comprises the following steps: calcining a waste lithium iron phosphate positive electrode material to obtain a lithium iron phosphate / carbon powder material; the element content of the lithium iron phosphate / carbon powder is obtained, and the amount of lithium, iron and phosphorus needing to be supplemented is determined; lithium, iron and phosphorus are supplemented to the lithium iron phosphate / carbon powder, then a reducing agent is added and mixed, a mixture is obtained, and the reducing agent comprises at least one of a non-amino acid reducing agent and an amino acid reducing agent; and calcining the mixture to obtain the recycled and regenerated lithium iron phosphate material. According to the method, elements missing in the waste lithium iron phosphate material are analyzed and supplemented, and the type of the reducing agent is adjusted, so that efficient repair of the waste lithium iron phosphate material is realized. The repairing efficiency of the waste lithium iron phosphate material is high, and the battery assembled by the repaired lithium iron phosphate material has excellent rate capability and cycle performance.

Disclosed are a lithium iron phosphate precursor, a lithium iron phosphate material, a preparation method therefor, and a use thereof. The lithium iron phosphate material comprises a flower cluster structure, the flower cluster structure comprises secondary particles, and the secondary particles are formed by agglomerating primary particles by means of a coating layer; the material of the primary particles is lithium iron phosphate. The lithium iron phosphate material of the present invention has good electrochemical properties and processing properties when used in batteries.

The present invention relates to the technical field of lithium battery state estimation, and in particular to a fuzzy EKF-AH algorithm-based state of charge (SOC) estimation and correction method for a lithium iron phosphate battery. The method comprises: by taking a certain startup of an energy storage device as a start, a BMS reading an SOC and a state of health (SOH) at the previous shutdown, and on the basis of a standby time, selecting an open circuit voltage (OCV) or an EKF algorithm to correct the SOC; using an EKF-AH algorithm to estimate the SOC, establishing, on the basis of fuzzy control, a fuzzy rule library associated with the SOC and the SOH, and dynamically adjusting a weight and a measurement noise deviation of the EKF-AH algorithm; and calculating estimation differences between the EKF algorithm and an ampere-hour integration method, and if the sum of the estimation differences is greater than a corresponding threshold, issuing an SOH correction warning. The present invention improves the estimation accuracy of the entire life cycle of the lithium iron phosphate battery, and assists the correction of the SOH.

The invention discloses a lithium iron phosphate positive electrode material and a preparation method and application thereof, and belongs to the technical field of lithium iron phosphate positive electrode materials. The lithium iron phosphate positive electrode material comprises a lithium iron phosphate matrix and a carbon coating layer coating the surface of the lithium iron phosphate matrix, the average standard deviation of the thickness of a carbon coating layer in the lithium iron phosphate positive electrode material is # imgabs0 #, and sigma (d) is more than or equal to 0.05 nm and less than or equal to 0.35 nm; the average standard deviation of the carbon content in the lithium iron phosphate positive electrode material is sigma (Cwt%), and sigma (Cwt%) is larger than or equal to 0.02 wt% and smaller than or equal to 0.35 wt%. The lithium iron phosphate positive electrode material has a uniform carbon coating layer, and the thickness of the carbon coating layer and the carbon content at each position are relatively consistent, so that the improvement of the carrier mobility of the lithium iron phosphate positive electrode material is facilitated, and the further improvement of the electrochemical performance of a battery prepared from the lithium iron phosphate positive electrode material is facilitated.

The invention provides a method for preferentially extracting lithium from battery black powder, and relates to the field of battery recovery. The method comprises the following steps: mixing battery black powder with water and acid liquor, carrying out lithium extraction reaction on the battery black powder under the conditions of pressurization and heating to obtain reacted slurry, and carrying out solid-liquid separation to obtain a lithium-rich solution and residues; the battery black powder comprises at least one of waste ternary lithium ion battery positive electrode powder, waste ternary lithium ion battery positive and negative electrode mixed powder and waste lithium iron phosphate battery black powder. According to the method for preferentially extracting the lithium from the battery black powder, operation steps are simplified, energy consumption is reduced, efficient and preferential recovery of the lithium is achieved, the recovery rate of the lithium and the separation efficiency of the lithium and nickel / cobalt / manganese are remarkably improved, the lithium leaching rate can reach 96.5% or above, and the nickel-cobalt-manganese leaching rate is lt; and 0.5%.

The invention relates to the technical field of lithium iron phosphate production, and discloses a carbon-coated titanium-doped lithium iron phosphate positive electrode material and a preparation method thereof.The preparation method comprises the following steps that 1, a ferrous solution and a phosphorus source solution are mixed in proportion, dopamine hydrochloride is added, a pH regulator is dropwise added in the stirring state, the pH of the solution is adjusted to 4.0-5.5, a reaction is conducted, a titanium source solution is added, and a reaction solution is obtained; after uniformly stirring, continuously dropwise adding a pH regulator to regulate the pH value of the solution to 5.5-6.5; the iron phosphate octahydrate coated with the titanium-embedded polydopamine is obtained; 2) calcining the titanium-embedded polydopamine-coated ferrous phosphate octahydrate in an inert gas atmosphere to obtain carbon-coated titanium-doped anhydrous ferrous phosphate; 3) mixing the carbon-coated titanium-doped anhydrous ferrous phosphate with lithium phosphate and a carbon source, ball-milling, mixing, spray-drying and calcining to obtain a carbon-coated titanium-doped lithium iron phosphate positive electrode material; the synthesis process is simple, and energy consumption is reduced.

The invention discloses a lithium iron phosphate battery. The lithium iron phosphate battery comprises a positive electrode, a negative electrode, an isolating membrane and an electrolyte, a main material of the positive electrode comprises lithium iron phosphate, and a main material of the negative electrode comprises graphite and a silicon-based material; the surface density of the positive electrode is greater than or equal to 23mg / cm < 2 >, and the surface density of the negative electrode is greater than or equal to 7.8 mg The electrolyte comprises a lithium salt, a solvent and an additive, the solvent mainly comprises ethylene carbonate and a micromolecular linear solvent, the additive comprises FEC and a negative electrode film-forming additive, and a negative electrode film-forming agent comprises vinylene carbonate and a lithium salt additive; the mass fraction of the micromolecular linear solvent is 35%-60%, the mass fraction of the fluoroethylene carbonate is M, the mass fraction of the silicon element in the negative electrode layer is W1, M is greater than or equal to 2% and less than or equal to 2 * W1, and the mass fraction of the negative electrode film-forming agent is 4%-6%. The energy density of the battery cell can be improved and the cycle life and the quick charge capacity of the battery cell are both considered by doping a silicon-based material into the negative electrode, designing a thick electrode and adjusting an electrolyte formula.

The invention discloses a carbon-coated lithium iron phosphate active material and a preparation method thereof, a positive pole piece and a lithium battery, and relates to the technical field of lithium batteries. According to the method, the structure of the carbon coating layer of the carbon-coated lithium iron phosphate active material is comprehensively evaluated through the carbon coating factor beta, # imgabs0 can evaluate the amount of graphitized carbon on the unit surface area of the carbon-coated lithium iron phosphate active material, and compared with amorphous carbon, the graphitized carbon has more excellent conductivity and can better improve the conductivity of a lithium iron phosphate matrix. By regulating and controlling a carbon coating layer structure of the carbon-coated lithium iron phosphate active material, a carbon coating factor beta meets a specific value range, so that the uniform conductivity of the carbon-coated lithium iron phosphate active material is improved; the lithium ion battery prepared from the lithium ion battery positive electrode material is small in internal resistance growth rate, charge transfer impedance Rct sample standard deviation and Warburg coefficient sample standard deviation, and the overall electrical performance of the lithium ion battery is improved.

The invention discloses a lithium iron phosphate positive electrode material and a preparation method thereof, a positive electrode plate and a lithium battery, and relates to the technical field of lithium batteries. The agglomeration strength of the lithium iron phosphate positive electrode material provided by the invention is in a proper range, the lithium iron phosphate positive electrode material is easy to disperse in a slurry preparation process, the prepared positive electrode slurry has no obvious granular sensation and good fluidity, and the surface density of a positive electrode piece obtained by coating is uniform, so that the resistivity of the pole piece is relatively low.

The invention provides a lithium iron phosphate material and a preparation method thereof, a positive pole piece and a secondary battery, and relates to the field of positive pole materials. The lithium iron phosphate material meets the condition that sigma b / sigma f is larger than or equal to 1.10 and smaller than or equal to 5.00, sigma b is the sample standard deviation of the circularity C of large-particle lithium iron phosphate, sigma f is the sample standard deviation of the circularity C of small-particle lithium iron phosphate, and the large-particle lithium iron phosphate and the small-particle lithium iron phosphate with different morphologies are matched with each other through the difference of the sample standard deviation of the circularity of the large-particle lithium iron phosphate and the sample standard deviation of the circularity of the small-particle lithium iron phosphate. Therefore, the lithium iron phosphate material has good tap density and specific surface area. According to the preparation method of the lithium iron phosphate material, the large-particle-size iron phosphate seed crystal partially coated with polydopamine is subjected to vacuum dehydration to obtain the modified iron phosphate seed crystal with the dehydrated surface layer, the morphology of the large-particle iron phosphate prepared by precipitation reaction is influenced, and the iron phosphate material is obtained by utilizing the large and small seed crystals through a coprecipitation method. And finally, the lithium iron phosphate material with good tap density and specific surface area is prepared.

The invention discloses a waste battery lithium iron phosphate positive electrode black powder recovery method which comprises the following steps: S1, activating and roasting positive electrode black powder to obtain pretreated black powder, and mixing and ball-milling the pretreated black powder, an oxidizing agent and an activating solvent to obtain pre-oxidized black powder; s3, the pre-oxidized black powder and an inorganic solvent are mixed for a leaching reaction, and mother liquor A and iron phosphate slag are obtained; s4, adding a pH regulator into the mother liquor A to remove impurities so as to obtain mother liquor B; s5, mixing and purifying the iron phosphate slag and phosphoric acid to obtain crude iron phosphate, washing the crude iron phosphate with water, and adding a complexing agent for further purification to obtain high-purity iron phosphate; and S6, concentrating the mother liquor B to obtain concentrated mother liquor C, and introducing carbon dioxide into the concentrated mother liquor C to precipitate lithium to obtain the battery-grade lithium carbonate. According to the process, iron, lithium, phosphorus and other elements in the positive electrode black powder are efficiently separated and recycled, low-acid or acid-free green leaching of lithium is achieved, the lithium leaching rate is larger than or equal to 98.0%, and the purity of obtained iron phosphate is larger than or equal to 99.3%; the purity of lithium carbonate is greater than or equal to 99.0%.

The invention discloses a solid-phase sintering repair method of a waste lithium iron phosphate battery material, and relates to the related field of battery recovery and repair, and the method comprises the following steps: disassembling the waste lithium iron phosphate battery material, taking out a battery positive plate, cleaning, drying and separating a positive material; a spectrograph is adopted for component analysis, the element component content is determined, and raw material adding and supplementing are conducted based on the deviation value of the theoretical element proportion; based on the characteristic information, sectional type sintering scheme analysis is conducted, and solid-phase sintering repair scheme parameters are obtained; the mixed lithium iron phosphate powder is pressed into a sheet shape and placed in sintering equipment for solid-phase sintering repairing treatment, and a repairing sample is obtained; and obtaining test performance parameters according to a battery application detection standard, and performing repair compensation control on the repair scheme parameters. The technical problem that the repairing effect is uncontrollable due to lack of precise analysis and targeted optimization in existing solid-phase sintering repairing is solved, and the technical effects of efficient repairing and performance improvement are achieved.

The invention relates to a comprehensive recovery method of lithium iron phosphate black powder, and belongs to the technical field of lithium iron phosphate battery recovery. The technical problem to be solved by the invention is to provide the lithium iron phosphate black powder comprehensive recovery method. The method comprises the following steps: mixing lithium iron phosphate black powder with acid, and adding an oxidizing agent for reaction to obtain iron phosphorus slag; the iron phosphorus slag is subjected to acid pickling and then acid leaching to obtain secondary acid leaching liquid; and dropwise adding the secondary acid leaching solution into bottom water to generate a precipitate, and adjusting the molar ratio of phosphorus to iron or the molar ratio of phosphorus to (iron and manganese) to obtain battery-grade iron phosphate or ferromanganese phosphate. According to the method, alkali is not adopted as a precipitator, iron powder is not introduced, iron phosphate or the ferromanganese phosphate precursor is obtained through a normal-pressure one-step method, the problems that mixing is not uniform when the ferromanganese phosphate precursor is prepared through a solid-phase method, and alkali is needed as the precipitator or organic matter is introduced in a liquid-phase method are solved, use of alkaline chemical reagents and generation treatment of by-products are reduced, and the method is suitable for industrial production. The method has the advantages of simple process, low equipment use requirements, battery grade and high purity of the prepared product, improves the utilization rate of the phosphorus source, and has high yield.

The invention provides a lithium ion battery and electric equipment, the lithium ion battery comprises a positive pole piece and an electrolyte, active substances in the positive pole piece comprise a phosphate lithium positive pole material and nickel cobalt manganese lithium oxide, and the electrolyte comprises a positive pole film-forming agent, a negative pole film-forming agent and a lithium salt, the lithium salt comprises lithium hexafluorophosphate and lithium bis (fluorosulfonyl) imide, the lithium ion battery meets the following formula: # imgabs0 #, NL is the mass ratio of the lithium nickel cobalt manganese oxide to the lithium phosphate positive electrode material, Salt is the sum of the molar concentrations of the lithium hexafluorophosphate and the lithium bis (fluorosulfonyl) imide in the electrolyte by taking mol / L as the unit, and the sum of the molar concentrations of the lithium hexafluorophosphate and the lithium bis (fluorosulfonyl) imide in the electrolyte is the sum of the molar concentrations of the lithium hexafluorophosphate and the lithium bis (fluorosulfonyl) imide. Add is the mass ratio of the positive electrode film-forming agent to the negative electrode film-forming agent. When the ternary material is doped in the lithium manganese iron phosphate or the lithium iron phosphate, the proportion of the positive and negative electrode film-forming agents and the proportion of the heat-resistant high-lithium salt can be adjusted according to the mixing proportion of the lithium manganese iron phosphate and the lithium iron phosphate, so that the cycle performance of the battery is improved.

The invention provides a preparation method for regenerating waste lithium iron phosphate into sodium ferric pyrophosphate, and belongs to the technical field of battery material production.The recovery process comprises the steps that a high-grade oxide serves as an oxidizing agent, a waste lithium iron phosphate positive electrode material and a current collector are stripped under the acid or strong alkaline condition, and lithium iron phosphate is oxidized; recovering to obtain iron phosphate containing impurities and a solution containing lithium ions; in the regeneration process, recycling slag obtained in the recycling process is uniformly mixed with a sodium source and a phosphorus source, sintering regeneration is performed to prepare ferric sodium pyrophosphate, conductive carbon in waste lithium iron phosphate is used as a reducing agent, and a high-performance ferric sodium pyrophosphate positive electrode material is obtained without an additional reducing agent; recycled slag obtained in the recycling process mainly comprises high-purity iron phosphate, and the content of impurities can be controlled to be 0.1% or below by controlling the solid-to-liquid ratio, the temperature and the reaction time in the recycling process.

The invention belongs to the technical field of lithium ion battery materials, and provides a lithium iron phosphate material preparation method, which comprises: (1) carrying out primary mixing on precursors with different titanium element contents, sintering, and crushing to obtain lithium iron phosphate; the precursor comprises a phosphorus source, an iron source, a lithium source, a primary carbon source and a titanium source; and (2) adding the lithium iron phosphate into a mixture of a connecting agent and a secondary carbon source, carrying out secondary mixing, drying, sintering, and crushing to obtain the lithium iron phosphate material. The lithium iron phosphate material prepared by the method has a certain particle size distribution width, and the compaction density of the lithium iron phosphate material can be improved.

The invention discloses a lithium manganese iron phosphate composite material, a preparation method thereof and a lithium ion battery containing the lithium manganese iron phosphate composite material. The preparation method comprises the following steps: grinding, sintering and crushing a mixture of the lithium iron manganese phosphate, the lithium iron phosphate precursor and water to form the lithium iron manganese phosphate composite material, the sintering temperature is 650 DEG C to 750 DEG C; wherein the lithium manganese iron phosphate forms an inner core of the lithium manganese iron phosphate composite material, and the average particle size of the inner core is 600 nm to 1200 nm; the lithium iron phosphate precursor forms a lithium iron phosphate coating layer and a carbon coating layer of the lithium manganese iron phosphate composite material. The lithium manganese iron phosphate composite material provided by the invention can effectively improve the ginger-Taylor effect of the lithium manganese iron phosphate and improve the electrochemical cycle performance of the material at the same time.

Systems, methods, and articles for a portable power case are disclosed. The portable power case is comprised of at least one battery and at least one PCB. The portable power case has at least one USB port and at least two access ports, at least two leads, or at least one access port and at least one lead. The portable power case is operable to supply power to an amplifier, a radio, a wearable battery, a mobile phone, and a tablet. The portable power case is operable to be charged using solar panels, vehicle batteries, AC adapters, non-rechargeable batteries, and generators. The portable power case provides for modularity that allows the user to disassemble and selectively remove the batteries installed within the portable power case housing.