The application relates to a
phosphorus-
sulfur co-doped hard carbon material, a preparation method and a
sodium ion battery, and belongs to the technical field of secondary batteries. In the material, the
carbon layer crystal face parameter satisfies d 002 = 0.36-0.39 nm, L c = 1.20-1.40 nm, L a = 6.00-6.40 nm; the
phosphorus and
sulfur doped heteroatoms are in a locally enriched and overall uniform distribution mode; in the material, the content of
phosphorus is 0.367%-0.457%, and the content of
sulfur is 0.949%-1.183%. A three-step special process of "
solvent low-speed
dilution-winding reinforcement crosslinking-gradual temperature increase directional
carbonization" is adopted, and the
heteroatom doping and the construction of the dense
carbon skeleton are realized by relying on the winding characteristics of the high-
viscosity precursor molecules. The material has excellent electrochemical performance, specifically good cycle stability, high volume specific capacity and excellent rate performance.