The invention discloses a sandwich core-shell structured
lithium-rich
manganese base,
spinel and
graphene flexible composite positive
electrode and a production method thereof, and belongs to the field of
material synthesis. The
chemical formula of a
lithium-rich
manganese base positive
electrode material is aLi2MnO3.(1-a)LiMO2, and the
chemical formula of a
spinel material is LiMn2-xMxO4, wherein x is not less than 0.1 and is less than 1, M = Mn1-x-yNixCoy, x is not less than 0 and not more than 0.5, and y is not less than 0 and not more than 0.5. The production method comprises the following steps: carrying out a
coprecipitation technology to obtain a
manganese nickel cobalt carbonate spherical precursor, uniformly mixing the precursor with a
lithium salt compound, calcining the obtained mixture to obtain the spherical lithium-rich manganese base positive
electrode material, mixing the positive
electrode material with a
graphene oxide dispersion, carrying out a vacuum suction
filtration technology to produce a sandwich structured lithium-rich manganese base and
graphene oxide composite film, and carrying out high-temperature in-situ carbothermal reduction to produce the sandwich core-shell structured lithium-rich manganese base,
spinel and graphene flexible composite positive electrode. The production method has the advantages of simple process and low production cost; and the sandwich core-shell structured lithium-rich manganese base, spinel and graphene flexible composite positive electrode has the advantages of obviously improved and reliable performances, large specific capacity, excellent rate and excellent cycle performances.