929 results about "Titanate" patented technology

The invention provides a high-stability lithium-rich manganese-based positive electrode material and a preparation method thereof, and relates to the technical field of lithium-rich manganese-based positive electrode materials, and the method comprises three steps of preparation of a homogeneous precursor, solid-state mechanical fusion doping and coating, and high-temperature sintering; a lithium-rich manganese-based precursor is prepared by adopting a homogeneous coprecipitation process, uniform distribution of metal ions is ensured, then an aluminum source, a zirconium source and a fluorine source are introduced as doping agents, phosphate and a titanate coating agent are combined, doping and coating integrated treatment is realized through mechanical ball milling, and the lithium-rich manganese-based composite material is obtained. And finally, mixing with a lithium source in an argon atmosphere, and carrying out high-temperature sintering of temperature programming and staged heat preservation to form a stable composite coating layer in situ. Therefore, manganese ion migration is effectively inhibited through lattice doping, a layered structure is prevented from being converted into spinel or rock salt phase, meanwhile, a nanoscale ion / electron transmission channel is constructed, interface impedance is reduced, and the charging and discharging efficiency under high voltage is improved.

The invention relates to a high-temperature-resistant light stealth coating material and a preparation method thereof, and belongs to the technical field of functional materials, the high-temperature-resistant light stealth coating material comprises the following raw materials: boride, silicide, a titanate fluxing agent, metal coated carbide, a zinc oxide coated nano carbon material and a sintering aid; according to the prepared high-temperature-resistant light stealth coating material, the infrared emissivity at the wavelength of 3-5 [mu] m is 0.231-0.245, the infrared emissivity at the wavelength of 8-14 [mu] m is 0.424-0.441, the tensile bonding strength is 40.8-46.4 MPa, and the thermal shock resistance frequency is 153-167.

The invention provides a preparation method of prismatic titanium diboride powder, and belongs to the technical field of titanium diboride powder. The preparation method comprises the steps of titanium source preparation, boron source preparation, material mixing, cold isostatic pressing and carbon thermal reduction reaction. The step of preparing the titanium source comprises the following steps: heating TiO2 powder body liquid, raising the temperature to 52-55 DEG C, adding a tetrabutyl titanate solution, uniformly stirring, adding an ammonia water solution to adjust the pH value to 7.0, and carrying out heat preservation stirring for 2.7-3.2 hours to obtain the titanium source; the step of preparing the boron source comprises the following steps: adding B4C powder into absolute ethyl alcohol, carrying out ultrasonic dispersion, then adding a mixed solution, controlling the adding rate of the mixed solution to be 0.8-1.2 g / min, heating to 34-37 DEG C, and carrying out heat preservation and stirring for 3.8-4.2 hours to obtain the boron source; the titanium diboride powder obtained through the method is in a prism shape and is uniform in particle, high in density and purity and poor in high-temperature oxidation resistance.

The invention provides a photo-thermal evaporation material based on black titanium dioxide as well as a preparation method and application of the photo-thermal evaporation material. The preparation method comprises the following steps: mixing urea, absolute ethyl alcohol and tetrabutyl titanate into a solution A, mixing absolute ethyl alcohol, ultrapure water and hydrochloric acid into a solution B, dropwise adding the solution B into the solution A, mixing to form a white colloid, heating in a water bath, drying, and calcining in a nitrogen atmosphere to obtain black titanium dioxide powder; the preparation method comprises the following steps: fully mixing a certain amount of black titanium dioxide, sodium alginate and ultrapure water to form a uniform dispersion liquid, dipping the pretreated polyurethane sponge in the dispersion liquid, and crosslinking with a calcium chloride solution to prepare the photo-thermal evaporation material of the black titanium dioxide-calcium alginate composite hydrogel. The photo-thermal evaporation material breaks through the photo-thermal application bottleneck of traditional titanium dioxide, has excellent evaporation rate and seawater desalination performance, and can effectively remove various printing and dyeing wastewater to obtain clean water.

The invention belongs to the technical field of glass materials, and discloses thermal shock resistant transparent high borosilicate glass which comprises the following components in percentage by weight: 60-70% of silicon dioxide, 18-22% of diboron trioxide, 4-7% of aluminum oxide, 3-5% of magnesium oxide, 2-4% of alkali metal oxide, 0.5-1.5% of nano silicon nitride and 0.5-1% of nano aluminum titanate. The thermal shock temperature difference of the glass within the temperature change range of 20-200 DEG C is larger than or equal to 180 DEG C, the light transmittance within the visible light range of 400-760 nm is larger than or equal to 85%, the alkali metal oxide is composed of sodium oxide and potassium oxide, the weight ratio of the sodium oxide to the potassium oxide is 1: 1-3: 1, the average particle size of the nanometer silicon nitride is smaller than or equal to 100 nm, and the nanometer silicon nitride is evenly dispersed in the glass matrix; according to the thermal-shock-resistant transparent high borosilicate glass and the preparation method thereof, the thermal shock resistance and light transmittance of the glass are improved by optimizing the chemical components of the glass and adding the special nanoparticles in cooperation with a specific preparation process, and the thermal shock resistance of the glass is improved. The problems that existing high borosilicate glass is insufficient in thermal shock resistance and low in light transmittance in a high-temperature environment are solved.

In accordance with some embodiments of the present disclosure, a memory device is provided. The memory device may include a first electrode, a ferroelectric layer fabricated on the first electrode, and a second electrode fabricated on the ferroelectric layer. The ferroelectric layer includes a plurality of ferroelectric films and a plurality of interface layers stacked alternately. Each of the ferroelectric films comprises at least one ferroelectric material, such as hafnium oxide (HfO2), zirconium oxide (ZrO2), zirconium-doped hafnium oxide (Hf1-xZrxO2), scandium-doped aluminum nitride (Al1-xScxN), titanates (BaTiO3), niobates (LiNbO3), tantalates (NaTaO3), etc. Each of the interface layers comprises at least one dielectric material that is more chemically stable than the ferroelectric material, such as aluminum oxide.

The invention provides a photocatalytic porous composite material for sewage treatment and a preparation method and application thereof, and the preparation method comprises the following steps: dropwise adding an organic ligand solution into a precursor solution composed of a nano cellulose solution and a cobalt source solution, mixing a reaction solution with polyvinyl alcohol, injecting the mixture into a mold, and carrying out directional freezing to obtain an aerogel matrix; carrying out hydrophobic modification on the aerogel matrix to obtain a modified aerogel matrix; the preparation method comprises the following steps: dissolving tetrabutyl titanate and cetyltrimethylammonium bromide in absolute ethyl alcohol, stirring and heating to obtain precursor sol, adding a ferric nitrate solution into the precursor sol for hydrothermal reaction, and filtering and calcining after the reaction is finished to obtain doped titanium dioxide particles; and dispersing the doped titanium dioxide particles in deionized water to obtain a dispersion liquid, and dipping the modified aerogel matrix. According to the invention, a composite material composed of a nanocellulose / ZIF-67 composite aerogel matrix and doped titanium dioxide particles is constructed, and efficient sewage treatment of adsorption-catalysis-regeneration cycle is realized.

The invention relates to the technical field of optical coating materials, and particularly discloses a trititanium pentoxide optical coating material and a preparation process thereof. The invention relates to a preparation process of a trititanium pentoxide optical coating material, which comprises the following specific steps: mixing titanium dioxide and titanium powder by using a dry method, then carrying out hydraulic pressure, then carrying out vacuum sintering, cooling, then taking out trititanium pentoxide sintered crystals, then carrying out surface modification on the trititanium pentoxide sintered crystals and a titanate coupling agent, and finally carrying out vacuum sintering to obtain the trititanium pentoxide optical coating material. Drying and crushing to obtain a trititanium pentoxide finished product; and mixing the trititanium pentoxide finished product with silicon dioxide and aluminum oxide, and sintering to form the trititanium pentoxide optical coating material. Under the synergistic effect of all processes and raw materials, prepared trititanium pentoxide finished product particles are promoted to form a more compact sintered body, a uniform and stable interface is formed in the coating process, and the bonding strength and wear-resistant stability of the coating material are improved.

The invention relates to the field of coatings, and discloses a wear-resistant and corrosion-resistant high-entropy alloy composite coating and a preparation method thereof.The wear-resistant and corrosion-resistant high-entropy alloy composite coating is prepared by depositing functional high-entropy alloy composite powder on the surface of a base body in a laser cladding mode, the functional high-entropy alloy composite powder comprises high-entropy alloy powder, a modified additive and composite ceramic powder, the modified additive is prepared by using urea and titanium tetrachloride as raw materials, growing nano titanium nitride particles on the surface of a silicon carbide nanowire in situ to prepare a nano titanium nitride / silicon carbide nanowire composite material, and then coating a layer of nano titanium dioxide particles on the surface of the nano titanium nitride / silicon carbide nanowire composite material by using tetrabutyl titanate; and the composite ceramic powder is prepared by compounding zirconium carbide, niobium carbide, hafnium carbide and tantalum disilicide. The hardness, wear resistance and corrosion resistance of the high-entropy alloy coating are enhanced by adding the modified additive and the composite ceramic powder.

The invention provides a novel underwater wet welding flux-cored wire and a preparation method thereof. The flux-cored wire comprises a metal sheath and a flux core, the flux core is prepared by sintering a flux core base material and a flux core additive; the flux core base material comprises the following raw materials in percentage by mass: 20-40% of rutile, 15-35% of fluoride, 2-7% of titanate, 3-10% of aluminum powder, 5-15% of manganese powder and 10-15% of composite nano metal oxide; the composite nano metal oxide at least comprises the following raw materials: nano aluminum oxide, nano zirconium dioxide, nano yttrium oxide, nano cerium oxide and nano lanthanum oxide; and the flux-cored additive is linear aliphatic epoxy resin. The specific mixed nano metal oxide powder is added into the flux-cored wire, grain refinement is achieved, a quenched martensite structure is reduced, the mechanical property of a weld joint is improved, meanwhile, the specific epoxy resin and the flux-cored base material are mixed, filled and sintered, a proper amount of carbon element is introduced while all raw material components of the flux-cored wire are dispersed uniformly and stably, and the welding quality of the flux-cored wire is improved. And metal is prevented from being oxidized in the welding process.

The invention relates to a continuous production method of high-purity tetraethoxysilane, and belongs to the technical field of tetraethoxysilane preparation. The method comprises a raw material pretreatment stage and a purification and rectification stage: in the pretreatment stage, silicon tetrachloride and ethanol are subjected to an esterification reaction in a molar ratio of 1: (3-4) under the protection of nitrogen, the pH is adjusted to be neutral through triethylamine, and triethylamine hydrochloride is removed through reduced pressure distillation; then, a cerium oxide-molecular sieve composite adsorbent with the specific surface area larger than or equal to 800 m / g and the pore diameter of 2-5 nm is adopted for dehydration under the pressure of 0.8-1.2 MPa till the water content is smaller than or equal to 5 ppm, and volatile impurities are removed through high-purity nitrogen purging; in the purification stage, metal ions and Cl are synergistically removed through a titanate modified resin layer and a nano TiOtube layer, and then step-by-step separation is performed through a four-stage differential pressure rectifying tower. Through collaborative optimization of structural design of the composite adsorbent, construction of an organic-inorganic hybrid interface of the resin layer and pressure gradient rectification, 72-hour continuous production is achieved, the single-pass yield of the product is 92%, and the total amount of metal impurities is smaller than or equal to 5 ppb.

The invention discloses a chromium-free fingerprint-resistant coating agent for a galvanized steel sheet and a preparation method of the chromium-free fingerprint-resistant coating agent. The chromium-free fingerprint-resistant coating agent is prepared from the following elements in percentage by mass: 1%-5% of sodium molybdate or / and sodium tungstate, 0.5%-2% of a phytic acid-chitosan compound, 0.3%-1.0% of a chelating titanate coupling agent, 2%-5% of fluorosilane modified nano SiO2, 30%-55% of waterborne hyperbranched polyurethane resin, 0.5%-2% of oxidized polyethlene wax and the balance of deionized water. The chromium-free fingerprint-resistant coating agent disclosed by the invention has excellent fingerprint resistance, high adhesive force and environmental protection property, is free of white rust in neutral salt mist for 150 hours and red rust in neutral salt mist for 360 hours, the white rust area is less than 5%, the industrial requirements of galvanized steel sheet surface treatment are met, and the problem of environmental risk in the prior art is avoided by adopting the combination of bio-based corrosion inhibitors.

The invention belongs to the technical field of conductive silver paste, and particularly relates to composite conductive silver paste and a preparation method and application thereof. The raw materials comprise modified silver powder, glass powder and an additive; wherein the raw materials of the modified silver powder comprise micron-scale silver powder and nano-scale silver powder; the organic carrier comprises the following raw materials: polyimide resin, simethicone and a dispersing agent; the additives comprise carbon nanotubes, a titanate coupling agent, fumed silica, a defoaming agent and an organic carrier. The method comprises the following steps: adding the modified silver powder, the glass powder, the carbon nano tube, the titanate coupling agent, the fumed silica and the defoaming agent into the organic carrier, and stirring to obtain primary mixed slurry; and grinding the preliminary mixed paste until the fineness of the paste is less than or equal to 5 microns, and then defoaming to obtain the composite conductive silver paste. The composite conductive silver paste is applied to preparation of a flexible circuit board. The printing forming process is adopted, waste water and waste gas are avoided, safety is high, and production efficiency is high.

The invention relates to the technical field of refractory materials, in particular to an antioxidant and application thereof in steel ladle slag line bricks, and the antioxidant comprises a Si / SiC multiphase material, modified nano Al2O3 and CaF2; the ladle slag line brick comprises an antioxidant, fused magnesite, crystalline flake graphite and phenolic resin. Si-SiC compound waste is subjected to magnetic separation and acid pickling, then a SiO2 passivation layer is formed through pre-oxidation, moisture and air in the storage period are isolated, and a titanate coupling agent is introduced to improve the wettability and compatibility with phenolic resin. P2O5 released by phosphate on the surface of the modified nano Al2O3 at a high temperature reacts with alkali (earth) metal migrated to a SiO2 oxide layer to prevent the alkali (earth) metal from forming a low-melting-point eutectic substance, CaF2 reacts with SiO2 along with temperature rise, a passivation layer is broken, internal Si and SiC are directly exposed, and boron oxide of the modified nano Al2O3 remarkably reduces activation energy and a temperature threshold value of the reaction of CaF2 and SiO2.

A magnetic nanoparticle composite microcapsule, and a preparation method therefor and the use thereof. The preparation method comprises: diluting concentrated ammonia water with absolute ethanol in which nano-Fe3O4 is dispersed, stirring same and adding ethyl orthosilicate, centrifuging same, and then performing washing to obtain Fe3O4 / SiO2 particles; dispersing same in anhydrous ethanol, then adding isopropanol containing tetrabutyl titanate, and performing a treatment to obtain Fe3O4 / SiO2 / TiO2 nanoparticles; adding polyurethane TDI prepolymer to the Fe3O4 / SiO2 / TiO2 nanoparticles, adding same to a core material, then dripping an emulsifier, and stirring same to obtain a core material emulsion; and heating same in a water bath, dropwise adding butanediol, and performing heating, stirring and vacuum filtration to obtain a magnetic nanoparticle composite microcapsule. By means of the loading with a core material having a repair function, the prepared magnetic microcapsule can actively repair damage to an insulating material caused by electrical and mechanical stress, thereby improving the reliability of a device.

The invention discloses a preparation method of a lignite resin drilling fluid filtrate reducer, and relates to the technical field of petroleum and natural gas drilling engineering. The method comprises the following steps: carrying out superfine grinding on lignite, carrying out alkaline hydrolysis pretreatment on waste nylon PA66, alkalizing lignite powder, carrying out sulfonation reaction on the alkalized lignite powder and phosphorous acid to introduce phosphonic acid groups, carrying out cross-linking with tetrabutyl titanate to form a three-dimensional network structure, and adding a nano-montmorillonite suspension to realize physical enhancement. A reaction product is subjected to freeze-drying, a porous structure is reserved, and then the product and polyethylene glycol 400 are mixed and granulated. By utilizing humic acid functional group grafting, inorganic-organic composite cross-linking and waste raw material recycling technologies, the product still keeps excellent filtration loss control capability at the high temperature of 200 DEG C and in a saturated salt solution, the high-temperature and high-pressure filtration loss is less than or equal to 6.50 mL, the viscosity retention rate is greater than or equal to 92.8%, the lubricating coefficient reduction rate is greater than or equal to 48.5%, and the product has the advantages of temperature resistance, salt resistance, environmental protection and low cost, and is suitable for industrial production. And the method is suitable for deep oil-gas drilling engineering.

The invention relates to the technical field of printed electronic materials, in particular to conductive copper ink for a printed circuit and a preparation method of the conductive copper ink. The conductive mica powder-graphene composite material comprises conductive mica powder, a nano-copper-graphene filler, flaky copper powder, spherical copper powder, an organic carrier, a dispersing agent, a coupling agent, an antioxidant and an auxiliary agent, a layer-point composite conductive structure is constructed through conductive mica powder and nano-copper-graphene filler, a close packing system is formed by combining particle size grading of copper powder with different morphologies, and the conductivity is guaranteed; by means of a chemical bonding interface formed by the coupling agent, the copper powder and the organic carrier, the integrity of the coating is enhanced, and stress cracking during welding is reduced; microencapsulated rosin in the auxiliary agent promotes wetting and spreading of the welding flux, titanate modified nano titanium dioxide constructs a three-dimensional cross-linked network to improve the bending resistance and thermal shock resistance of the coating, the falling phenomenon of components after welding is reduced, and the stability of the conductive copper ink in actual printed circuit production is improved.

The invention provides a preparation method of a metal-based ceramic composite membrane with a catalytic ozone function. The preparation method comprises the following steps: preparing functional powder by taking tetrabutyl titanate as a titanium source and silver nitrate or ferric nitrate as a catalytic active metal source and adopting a sol-gel method; a porous metal pipe is used as a supporting body, metal powder and functional powder which are made of the same material as the supporting body are mixed to prepare functional slurry, the functional slurry is evenly deposited on the inner wall of the supporting body through vacuum filtration, and powder particles which are not firmly combined are removed through back flushing; and finally, the binding force between the functional film layer and the metal matrix is improved through high-temperature heat treatment. Wherein the thermal expansion coefficient difference between the metal supporting body and the functional film layer can be reduced by adding the metal powder, the metal powder is melted and diffused in the high-temperature heat treatment stage, and metallurgical bonding is formed between the functional powder and the metal substrate. The method is simple in process, and the prepared metal-based ceramic composite membrane has the advantages of being high in membrane layer binding force, not prone to falling off, high in catalytic activity, high in anti-pollution capacity, stable in operation and the like.

The present application provides a solid-state hydrogen storage material and a preparation method and application thereof. Specifically, the preparation method comprises the following steps: (1) ball-milling a magnesium-based alloy powder, a light metal hydride, a nano-carbon material, a composite catalyst powder and an interface modifier to obtain a mixed powder; and (2) sintering the mixed powder under vacuum at 200-350 DEG C for 2-5 hours to obtain a sintered body, wherein: the magnesium-based alloy powder is a Mg-Mn-Al alloy powder; the light metal hydride is a mixture of LiAlH4 and NaBH4; the nano-carbon material is selected from one or more of graphene and carbon nanotubes; the composite catalyst powder is a mixture of TiO2, Fe3O4, CeO2 and La2O3; and the interface modifier is selected from one or more of a silane coupling agent and a titanate coupling agent. The solid-state hydrogen storage material has high hydrogen storage capacity, fast hydrogen absorption and desorption rate and good cycle stability.

The invention discloses a closed-cell heat-conducting flame-retardant foamed silica gel material and a preparation method thereof in the field of organic silicon functional materials. The closed-cell heat-conducting flame-retardant foamed silica gel material is prepared from the following raw materials: basic silica gel, silane modified boron nitride, titanate modified aluminum hydroxide, a foaming agent, a cross-linking agent, a catalyst, an inhibitor and absolute ethyl alcohol. The raw materials are mixed according to a certain mass ratio. Wherein the silane modified boron nitride is prepared by heating, refluxing and reacting boron nitride powder and a silane coupling agent in an ethanol solvent and then drying; the titanate modified aluminum hydroxide is prepared by ultrasonically dispersing aluminum hydroxide powder and a titanate coupling agent in deionized water, adjusting the pH value, reacting and drying. The preparation method comprises the following steps: mixing the basic silica gel with the two modified fillers at a high speed, sequentially adding other raw materials, continuously mixing, transferring into a mold, pressurizing at a certain temperature to complete vulcanization foaming, taking out, washing with water, and drying in vacuum. According to the material, the interface bonding force is improved through the modified filler, and the material has the characteristics of high heat conductivity, high flame retardance and stable closed-cell structure.

The invention discloses a strontium-doped bismuth titanate-based ferroelectric film and a preparation method thereof, and belongs to the technical field of dielectric energy storage materials. The chemical composition of the film is Ba < 1-x > Sr < x > Bi < 4 > Ti < 4 > O < 15 >, wherein x ranges from 0.025 to 0.1. The preparation method comprises the following steps: mixing ethylene glycol monomethyl ether and ethylene glycol, adding bismuth nitrate, barium acetate, strontium acetate and butyl titanate, fully stirring and filtering to obtain a precursor solution, aging, dripping to the center of a substrate for spin coating, heating a spin-coated sample to obtain a dry film, and annealing to obtain the ferroelectric film. The method is low in technological condition requirement, and the thin film obtains the optimal energy storage density by changing the doping proportion of Sr. According to the ferroelectric film, when x is equal to 0.075, the leakage current density of Ba0. 925Sr0. 075Bi4Ti4O15 (BBST75) is only 1.59 * 10 <-7 > A / cm < 2 >, the breakdown field strength is as high as 3.22 MV / cm, and at the moment, the film has the energy storage density of 28.2 J / cm < 3 > and the energy storage efficiency of 80.36%.

The invention belongs to the technical field of composite polyurethane materials, and discloses a groutable high-bonding-strength composite polyurethane material and a preparation method thereof. The composite polyurethane material is prepared from the following raw materials in parts by mass: 15 to 20 parts of hydrophilic polyurethane grouting liquid, 15 to 20 parts of cement, 5 to 8 parts of silica powder, 8 to 10 parts of polyurethane diluent, 2 to 3 parts of titanate coupling agent, 0.5 to 1 part of fumed silica, 1 to 2 parts of rubber powder, 0.2 to 0.4 part of water reducing agent and 0.5 to 0.8 part of catalyst. According to the composite polyurethane material, the waterborne polyurethane-cement-silica powder is taken as main materials and matched with the functional auxiliaries, and through the synergistic effect of the multiple components, the composite polyurethane material has high permeability, rapid curing, strong adhesion and long-acting durability at the same time, and shows remarkable advantages in leakage treatment of underground engineering, tunnels and building foundations.

The invention discloses a low-dielectric-constant polyamide material, and relates to the technical field of high polymer materials. The invention discloses a low-dielectric-constant polyamide material. The composite material is prepared from the following raw materials in parts by weight: 35 to 45 parts of polyamide 66, 5 to 10 parts of polytetrafluoroethylene micro powder, 8 to 12 parts of modified porous siloxane microspheres, 3 to 7 parts of modified nano zinc oxide, 10 to 15 parts of glass fibers, 4 to 8 parts of polyether-ether-ketone, 1 to 3 parts of graphene nanosheets, 3 to 5 parts of fluororubber, 1 to 2 parts of a titanate coupling agent, 0.3 to 0.7 part of an antioxidant 1010, 0.5 to 1.0 part of ethylene bis stearamide and 0.1 to 0.3 part of an ultraviolet absorbent UV-531. The low-dielectric-constant polyamide material has the remarkable advantages that the raw materials are scientifically proportioned, and various modified components are contained to enhance the performance; all the components are subjected to special treatment, so that the compatibility is good; the preparation process is rigorous, and the material has excellent dielectric properties; and the material also has good heat resistance and weather resistance and strong mechanical properties, and is suitable for various scenes with high dielectric constant requirements.

The invention relates to the technical field of nano titanium oxide preparation processes, and discloses a nano titanium oxide preparation method which comprises the following steps: dissolving cerium nitrate in deionized water to obtain a solution A; dissolving tetrabutyl titanate in absolute ethyl alcohol, adding the solution A, and uniformly stirring to obtain a solution B; dissolving glycerol and hydroxybenzophenone in deionized water, and uniformly stirring to obtain a solution C; slowly dropwise adding the solution B into the solution C, adding citric acid at the same time, and violently stirring to form a mixed solution; adjusting the pH value of the mixed solution to 9.0-10.0 to form a suspension; and carrying out reaction on the suspension at 160-200 DEG C for 6-10 hours. According to the nano titanium oxide prepared by the preparation method disclosed by the invention, the skin feeling of the nano titanium oxide can be remarkably improved, the problems of dryness, thickness, whitening and the like are reduced, and the use satisfaction of consumers is improved.

The invention relates to a composite phase change cold storage material and a preparation method thereof. According to the technical scheme, 60-90 wt% of deionized water, 4-34 wt% of anhydrous sodium formate, 2-5 wt% of anhydrous potassium sulfate and 1-4 wt% of xanthan gum are evenly mixed and dispersed, and a phase change cold storage medium is prepared; the preparation method comprises the following steps: mixing 64-75wt% of absolute ethyl alcohol, 15-20wt% of deionized water, 9-12wt% of nitric acid solution and 1-4wt% of expanded graphite, and standing to obtain dispersion liquid I; uniformly mixing 60 to 70 weight percent of tetrabutyl titanate and 30 to 40 weight percent of absolute ethyl alcohol, so as to obtain dispersion liquid II; uniformly mixing 30-40wt% of the dispersion liquid II and 60-70wt% of the dispersion liquid I under the condition of 70-100 DEG C, filtering and drying to prepare the nano titanium dioxide coated expanded graphite; 30-40 wt% of expanded graphite wrapped by nanometer titanium dioxide and 60-70 wt% of a phase change cold storage medium are subjected to vacuum impregnation and compression molding, and the composite phase change cold storage material is prepared. The prepared product is high in heat conductivity, large in phase change latent heat value, small in supercooling degree and good in cycling stability.

The present invention provides a VD furnace cover castable lining and a preparation method thereof, which belongs to the technical field of high-temperature refractory materials, comprising the steps of: mixing an emulsion of hydrogenated silicone oil, aminopropyltriethoxysilane, and pearl sand, heating and soaking, and drying to obtain modified pearl sand; mixing graphite, acetic acid, tetrabutyl titanate, and nano silicon powder, dropping an ethanol aqueous solution, adjusting the pH value to acidic, aging, drying, heating at a high temperature under an inert gas environment, and cooling to obtain TiC-Ti3SiC2 composite coating graphite; mixing brown corundum, silicon carbide, α-Al2O3 powder, calcium aluminate cement, TiC-Ti3SiC2 composite coating graphite, and modified pearl sand, drying, adding distilled water, stirring, putting into a mold, casting and molding, standing, taking out, drying, spraying silicon powder on the surface, and performing heat treatment under a nitrogen atmosphere to obtain a VD furnace cover castable lining. The present invention can improve the thermal insulation performance of the VD furnace cover while improving the thermal shock stability of the VD furnace cover castable lining.

The invention provides a modified high-temperature-resistant heat-insulating anticorrosive coating and a preparation method thereof. The modified high-temperature-resistant heat-insulating anticorrosive paint comprises a component A and a component B, the component A comprises organic silicon resin, epoxy resin, a polyaniline-nano metal oxide-graphene oxide composite material, hollow glass beads and hexagonal boron nitride; the component B comprises an organic silicon modified amine curing agent, an anhydride curing agent, a titanate catalyst and an accelerant. The modified high-temperature-resistant heat-insulating anticorrosive paint has excellent corrosion resistance, high-temperature-resistant heat-insulating performance and high-temperature cracking resistance, and also has the advantages of strong adhesive force and short surface drying time. The modified high-temperature-resistant heat-insulating anticorrosive paint provided by the invention is suitable for corrosion protection of metal components exposed in high-temperature and complex corrosive environments for a long time.

This invention discloses a method for preparing a nitrogen-doped titanium dioxide and carbon hollow sphere heterojunction photocatalyst, comprising the following steps: 1) preparing a carbon hollow sphere core-shell structure sample based on melamine-formaldehyde nanospheres; 2) preparing a TiO2@carbon core-shell structure sample using the carbon hollow sphere core-shell structure and tetrabutyl titanate as the reaction system; 3) using a one-step method to simultaneously dope nitrogen into the TiO2@carbon core-shell structure to form an N-TiO2@N-doped carbon hollow sphere heterojunction. This invention provides a method for preparing a nitrogen-doped titanium dioxide@carbon hollow sphere heterojunction photocatalyst and its application. This method achieves uniform nitrogen doping and effective composite of TiO2 and carbon hollow spheres through specific steps, and the prepared photocatalyst exhibits excellent photocatalytic performance under both visible and ultraviolet light.

The invention discloses a graphene aerogel modified elastic graphite material and a preparation method thereof, and the graphene aerogel modified elastic graphite material comprises the following components by mass: 50-80 parts of crystalline flake graphite; 8 to 15 parts of graphene aerogel; 3 to 8 parts of aminated modified boron-doped carbon nanotubes; 2 to 6 parts of hydroxyapatite-cerium oxide composite nano particles; 1 to 4 parts of a polyimide-montmorillonite nano composite material; 0.5 to 3 parts of titanate coupling agent modified nano silicon dioxide; 1-3 parts of a dispersant; 2-5 parts of a binder; the amination modified boron-doped carbon nanotubes can enhance the electrical conductivity and interface bonding force of the material, the hydroxyapatite-cerium oxide composite nanoparticles improve the high-temperature stability and mechanical toughness of the material, and the polyimide-montmorillonite nanocomposite improves the corrosion resistance and resilience durability of the material. And the titanate coupling agent modified nano silicon dioxide further optimizes the dispersion uniformity of all the components, and the comprehensive performance of the material is remarkably improved.

The invention provides an electroplating strengthening method for an aluminum alloy wheel. The electroplating strengthening method comprises the following steps: forming a periodic microstructure on the surface of the aluminum alloy wheel by utilizing a laser micro-etching technology; immersing the wheel into a supercritical carbon dioxide cleaning system to clean oil stains and oxidation films; after cleaning, spraying an active coating containing nano titanate; a high-compactness plating layer is formed in a pulse current electroplating mode; a chemical nickel-phosphorus plating layer and a hard chromium plating layer containing nano metal particles are sequentially formed on the surface of the wheel; performing hole sealing treatment on the electroplated layer by using low-temperature plasma; and coating and curing a flexible UV coating containing an ultraviolet light absorber on the surface of the electroplated layer to form the anti-aging protective film. According to the invention, a novel double cleaning-activating step is adopted in the pretreatment process, and special pre-plating passivation treatment is combined, so that tight combination of an electroplated layer and an aluminum alloy substrate is ensured, and the adhesive force grade reaches 5B, which is obviously superior to that of a traditional process.