This invention relates to the field of piezoelectric ceramics technology, specifically to a high-electrostrain
bismuth sodium titanate-based lead-free piezoelectric
ceramic material and its preparation method. The general
chemical formula of the
ceramic material is: (Bi 0.5 Na 0.5 ) (1‑x) (Ca 0.5 Sr 0.5 ) x Ti 0.98 (Sn 0.5 Sb 0.4 ) 0.02 O3, in which x =0.03~0.4. Its preparation method includes: weighing raw materials according to stoichiometric ratio, ball milling and mixing, pre-
calcination synthesis, secondary ball milling,
granulation and molding, and debinding
sintering. This invention introduces Ca at the A-site. 2+ and Sr 2+ Constructing quasi-isomorphic phase boundaries to lower the polarization energy barrier; introducing Sn through the B site. 4+ and Sb 3+ The formation of defect dipoles pins domain walls and enhances the random field. These two factors work synergistically to significantly improve the electrostrain properties of the material; the prepared
ceramic exhibits a maximum strain of [value missing] under an
electric field of 100 kV / cm. S max The inverse
piezoelectric coefficient is 2.18%, the inverse
piezoelectric coefficient is 2572 pm / V, and the memory strain is 2.18%. S r With a lead content of 1.19%, and a simple,
environmentally friendly process, it is suitable for
mass production and has broad application prospects in the field of high-performance lead-free actuators.