The invention provides a preparation method of
silicon dioxide nano-tubes, which includes the following steps. (1) The
ethanol solution of
tartrate is in preparation. The ultrasonic is implemented until the
tartrate is dissolved completely, so that a the first solution can be obtained, wherein the concentration of
tartrate is 0.01 to 0.04mol / L. (2) The
ammonia solution with the weight percentage concentration of 24% to 28% is added to the first solution obtained from the first step, thus a the second solution is obtained, wherein the volume ratio of the
ammonia solution and the first solution is 0.2 to 0.6. (3) In a state of agitation, the
silicon ester is dropped into the second solution obtained from the second step within 0 to 2 hours, which then stands for 0 to 24 hours after the dropping is completed. Thereby a white gel is obtained, wherein the volume ratio of the
silicon ester and the second solution is 0.05 to 0.2. (4) The white gel obtained from the third step is repeatedly washed with the deionized water ultrasonic. Afterwards, the white floc obtained from the washing is dried, so that the
silicon dioxide nano-tubes are obtained. Therefore, the method of the invention has the advantages of high
yield ratio,
large aspect ratio,
uniform size and so on.