1008results about "Cement production" patented technology

The invention discloses a sulfuric acid erosion resistant self-repairing geopolymer system and a self-repairing method thereof, and relates to the technical field of composite materials and artificial intelligence. At least one self-repairing unit optimized for sulfuric acid erosion embedded within the geopolymer matrix; the in-situ multipoint pH sensing network is integrated in the geopolymer matrix and is used for monitoring spatio-temporal evolution data of a pH field in a sulfuric acid erosion process in real time; the edge calculation module is used for identifying a preliminary erosion indication according to the received spatio-temporal evolution data of the pH field; and the central AI decision module is used for evaluating an erosion state and predicting a development trend by utilizing an AI model optimized aiming at sulfuric acid erosion according to the identified preliminary erosion indication and the pH field spatio-temporal evolution data, and generating an optimal repair strategy to control the self-repair unit to perform self-repair. According to the invention, intelligent, active and refined protection and life management of the geopolymer in the sulfuric acid erosion process can be realized.

The invention provides a geopolymer preparation and optimization method and system based on machine learning. The method is applied to the technical field of material science and machine learning. The method comprises the following steps: acquiring geopolymer preparation experimental data and preprocessing the data; performing nonlinear regression modeling on the geopolymer performance based on four machine learning regression algorithms, and constructing a geopolymer performance prediction model; calculating and distributing weights according to the mean square error of each machine learning model on the verification set, and performing weighted fusion to obtain a performance prediction result; receiving target performance parameters input by a user and an initial raw material ratio range, performing performance prediction by using the trained geopolymer performance prediction model, and reversely searching an optimal ratio combination meeting target performance constraints through an optimization algorithm; and preparing a geopolymer according to the optimal ratio combination to prepare the coal gangue-slag-fly ash geopolymer grouting material. According to the method, the prediction precision and the model generalization ability are effectively improved, and intelligent recommendation and accurate performance prediction of the raw material ratio are realized.

The invention relates to the technical field of cement materials, in particular to a red-mud-containing steel slag composite cementing material and a preparation method thereof.The method comprises the steps that red mud, slag, steel slag, desulfurized gypsum and sulphoaluminate cement clinker are subjected to dry mixing to obtain an initial mixture; determining whether the excitation capability of the potential hydration activity reaches the standard or not based on the alkaline matching index, and adjusting the weight part of the sulphoaluminate cement clinker; adding a composite exciting agent to obtain activated slurry; determining whether the dispersion effect of the flocculation structure of the initial mixture is qualified or not based on the dispersion index of the flocculation structure, and adjusting the ball milling rotating speed; adding a polymer emulsion to obtain an initial composite cementing material; determining whether the synergistic enhancement effect of the polymer emulsion and the activated slurry is qualified or not based on the synergistic enhancement index, and adjusting the dripping rate of the polymer emulsion; the steel slag composite cementing material containing the red mud is obtained. The preparation stability of the red mud-containing steel slag composite cementing material is improved.

The invention relates to hybrid fiber reinforced ultrahigh-performance geopolymer concrete as well as a preparation method and application thereof. Slag, metakaolin and silica fume are used as precursor materials of geopolymer concrete, a sodium hydroxide-water glass solution is adopted to compound an alkali activator, and steel fibers, polyvinyl alcohol fibers and modified glass chopped fibers of different sizes are mixed and doped, so that the brittleness of the geopolymer concrete is remarkably improved, and the service life of the geopolymer concrete is prolonged. The early strength and the high temperature resistance are improved. The hybrid fiber reinforced ultrahigh-performance geopolymer concrete has the characteristics of low carbon emission, ultrahigh strength, high temperature resistance, high durability and the like, and can meet the use of the geopolymer concrete in actual engineering. According to the ultrahigh-performance geopolymer concrete, solid waste resources are utilized at the same time, carbon emission in the concrete production process is reduced, and the ultrahigh-performance geopolymer concrete is environmentally friendly, low in carbon, ultrahigh in strength, easy to prepare and capable of being suitable for complex environmental engineering structures such as tunnels, bridges and high-rise buildings.

The invention discloses a layered pore structure geopolymer based on combination of multi-stage low-temperature in-situ polymerization and an ice template method and a preparation method of the layered pore structure geopolymer. The preparation method comprises the following steps: preparing geopolymer slurry; performing one-way freezing on the slurry to form a frozen green body containing a directionally arranged ice crystal template; before the frozen green body is subjected to freeze drying to remove an ice crystal template, specific multi-stage low-temperature in-situ polymerization treatment is carried out, and the treatment comprises at least two different low-temperature heat preservation stages which are sequentially carried out within the temperature range of-10 DEG C to + 5 DEG C, and the temperature of the low-temperature heat preservation stages is gradually increased; and then the treated green body is subjected to freeze drying and maintenance. According to the method, the multi-stage low-temperature in-situ polymerization step aiming at the reaction characteristics of the geopolymer is introduced before the ice crystal template is removed, so that the problems of low mechanical property and unstable pore structure of the geopolymer prepared by a traditional ice template method are solved, and the mechanical strength and structural integrity of the product are remarkably improved; meanwhile, a good layered pore structure and pore channel connectivity are kept.

The invention relates to the technical field of solid waste treatment and recycling, and discloses a waste incineration fly ash geopolymer composite material and a preparation method thereof, and the composite material is prepared from waste incineration fly ash, apatite minerals, zero-valent iron powder, persulfate and an alkali activator. The preparation method comprises the following steps: mixing the waste incineration fly ash, apatite minerals, zero-valent iron powder and persulfate to obtain composite powder; performing frequency conversion mechanochemical synergistic activation on the composite powder, wherein the activation process comprises a low-temperature activation stage and a high-energy pulse activation stage; and finally, mixing the activated powder with an alkali activator, pouring, molding and curing. According to the method, the reduction reaction and the oxidation reaction are driven step by step in the same system by regulating and controlling the mechanical energy input time sequence, the compatibility problem of a reducing agent and an oxidizing agent is solved, different types of persistent organic pollutants are synergistically degraded, meanwhile, heavy metal is stabilized, and the treatment effect is good. And the fly ash is recycled to prepare a geopolymer material with mechanical properties.

The invention discloses a high belite iron aluminate cement clinker, which is prepared from the following raw materials in parts by weight: 39 to 73 parts of carbide slag, 8 to 37 parts of low-grade bauxite, 10 to 16 parts of ardealite, 1 to 31 parts of fly ash and 3 to 9 parts of steel slag. According to the cement clinker, the resource utilization rate of industrial solid waste in cement preparation can be remarkably increased, and dependence on natural raw materials and high-grade raw materials is reduced; impurities in various solid wastes can be used as in-situ mineralizing agents and activating agents, and on the basis of realizing high-added-value resource utilization of various industrial solid wastes and low-grade bauxite, efficient synthesis of target minerals at a relatively low temperature is promoted; and gradient temperature control calcination and gradient cooling processes are further combined, so that sufficient crystallization and development of a target mineral phase can be effectively promoted, a clinker microstructure is optimized, excellent early strength and continuously increased later strength of the cement are ensured, and the common problems of strength shrinkage and the like of the traditional solid waste-based cement can be effectively avoided.

The invention discloses a composite system geopolymer grouting material and a preparation method thereof. The composite system geopolymer grouting material comprises the following raw materials in percentage by mass: 50-70% of coal gangue, 10-30% of fly ash and 10-30% of cement. Functional additives: 5%-20% of desulfurized gypsum and 5%-15% of bentonite; the composite exciting agent is formed by compounding carbide slag and sodium silicate according to the mass ratio of 1: 1-1: 2. The geopolymer is excellent in mechanical property, meets engineering requirements, is remarkable in environmental protection benefit, conforms to double-carbon target low-carbon process innovation: a calcination-free process: traditional high-temperature calcination is abandoned (the temperature needs to be 550-900 DEG C), carbon emission is reduced by more than 30% (compared with a contrast, the carbon emission of a traditional process is increased by 35%), and the geopolymer conforms to the green positioning of low energy consumption and low three wastes of geopolymers. The cost advantage is prominent, the economic value is remarkable, the raw material cost is reduced, specifically, the coal gangue (low-cost solid waste) is used for replacing 30%-50% of cement, and the comprehensive raw material cost is reduced by 40% (compared with a traditional cement-based grouting material).

The invention discloses a grading grinding vertical mill and a using method thereof, and relates to the technical field of vertical mills.The grading grinding vertical mill comprises a mill shell, a millstone grading rotor and an eddy current restraining flow guide cover assembly, the grading rotor is fixedly installed on the upper portion of the inner wall of the mill shell, and a millstone is fixed below the grading rotor; and a vortex suppression flow guide cover assembly is fixedly mounted on the inner wall of the mill shell and located on the periphery of the grading rotor, and the vortex suppression flow guide cover assembly is used for guiding airflow to uniformly and stably flow to a blade area of the grading rotor. According to the invention, the eddy current suppression flow guide cover assembly is mounted, so that active suppression of three-dimensional turbulence in a classification area is realized, the problems of over-grinding of fine powder and running of coarse particles caused by airflow turbulence induced by a high-speed rotor are solved, the classification precision is improved, and the classification power consumption is reduced.

The invention relates to the technical field of building materials, in particular to a cementing material for a fabricated wall prepared from multi-element solid waste and a preparation method of the cementing material. The preparation method comprises the following steps: 25-55 parts of fly ash, 25-65 parts of blast furnace slag, 8-10 parts of lime, 1-5 parts of desulfurized gypsum, 3-6 parts of a first mixture, 2-5 parts of a second mixture and 5-8 parts of an alkali activator; the mass ratio of the metakaolin to the bentonite to the superfine calcium carbonate in the first mixture is 3: 2: 1; the mass ratio of the vermiculite to the expanded perlite to the glass beads in the second mixture is 2: 2: 1. Through the synergistic excitation effect of Ca < 2 + > and Na < + > and the addition of the first mixture and the second mixture, the cementing material forms a more stable microstructure. A hydration product SEM figure shows that C-S-H and C (N)-A-S-H gel are symbiotic to form a three-dimensional network, pores are filled with needle-like ettringite crystals, and in combination with the brucite phase anchoring effect, the mechanical properties, such as strength and durability, of the material are remarkably improved.

The invention relates to a modified silicon carbide fiber and a preparation method and application thereof, the modified silicon carbide fiber endows magnetic loss, and combines high strength and corrosion resistance of a geopolymer matrix to realize double improvement of mechanical properties and wave absorbing efficiency of concrete. Carbon fibers in conventional wave-absorbing concrete are replaced by modified silicon carbide fibers, so that on one hand, the wave-absorbing concrete has good oxidation resistance at high temperature, carbon emission is greatly reduced, and the wave-absorbing concrete has the advantages of energy conservation and environmental protection; and on the other hand, the defect that the performance is reduced at high temperature is overcome, and the modified silicon carbide fiber enables the magnetic loss of metal and the dielectric loss of a matrix to form a synergistic effect, so that the wave absorbing performance is greatly improved. The invention is suitable for green communication infrastructures, and has the characteristics of environmental protection, high durability and broadband wave absorption.

The invention discloses sulfate-erosion-resistant metakaolin-slag-based geopolymer concrete, belongs to the technical field of concrete, and aims to solve the problems that the corrosion resistance of traditional silicate concrete is ineffective and the adaptability of conventional alkali-activated concrete is insufficient in a special environment. The concrete comprises the following components in parts by weight: 60-90 parts of a cementing material, 120-170 parts of aggregate, 15-30 parts of a composite activator, 2-8 parts of a function regulator and the like, the cementing material is prepared from nano TiO2 / KH-550 composite modified metakaolin, slag and silica fume-coal gangue powder-HAP composite powder; the aggregate comprises modified limestone macadam (soaked and dried by a sodium dihydrogen phosphate solution) and river sand; the composite exciting agent comprises water glass, sodium hydroxide, sodium pyrophosphate, propylene glycol and the like; the function regulator comprises superfine fly ash, a naphthalene water reducer, HPMC (Hydroxy Propyl Methyl Cellulose) and boric acid. Through the synergistic effect of the components, the sulfate corrosion resistance, the mechanical property and the environmental adaptation performance of the concrete are improved, and the concrete is suitable for engineering construction under the service environment of high-concentration sulfate and the like.

This invention relates to the field of novel low-carbon composite cement and solid waste resource utilization technology, specifically to a red mud-based low-carbon composite cement and its preparation method. The raw materials for this red mud-based low-carbon composite cement include red mud, auxiliary cementitious materials, gypsum-based solid waste, alkali activator, retarder, and interface reinforcing agent. It possesses compressive strength comparable to or even higher than 425 or 525 cement, with a red mud content ≥30wt% and an alkali activator content as low as 3wt%–8wt%. This not only achieves large-scale resource utilization of red mud but also significantly reduces production costs. Simultaneously, the cement hydration products have a good shielding effect against radioactivity, ensuring that the radioactivity of the hardened cement still meets national standards even with the large-scale incorporation of red mud. Moreover, the preparation method of this cement is simple, requiring neither red mud dealkalization nor high-temperature calcination, truly achieving low-carbon, low-energy-consumption, and low-cost green and environmentally friendly cement production.

The invention relates to the technical field of geopolymer concrete preparation, in particular to a geopolymer concrete material as well as a preparation method and application thereof. The geopolymer concrete material comprises modified metakaolin, slag, modified glass beads, an exciting agent solution and a mixed modifier. The preparation method of the modified glass beads comprises the following steps: soaking glass beads in a composite acid solution, washing the glass beads with water until the glass beads are neutral, drying the glass beads, and soaking the glass beads in an ethanol solution of 3-aminopropyltriethoxysilane with the concentration of 5wt% to obtain pretreated glass beads; dispersing the pretreated microbeads in a 1 wt% dopamine hydrochloride solution, carrying out an oscillating reaction for 1.5-2 h, carrying out centrifugation, then carrying out cleaning with ethanol, and carrying out vacuum drying so as to obtain dried microbeads; molybdenum disulfide and the dried microbeads are mixed and then added into absolute ethyl alcohol, precipitate is collected after ultrasonic dispersion, the precipitate is dried, and the modified glass microbeads are obtained.

The invention provides a geopolymer alkali activator based on a red mud raw material and a preparation method of the geopolymer alkali activator, and belongs to the technical field of geopolymer materials. The method comprises the following steps that under the stirring and heating conditions, red mud and plant ash are gradually added into a sodium chloride solution to form a mixed solution, the mass ratio of the red mud to the plant ash is (3-6): 1, and the solid-liquid mass ratio of the red mud to the sodium chloride solution is 1: (3-6); the pH value of the system and the Na2O release amount are continuously detected, when the pH value of the system is larger than or equal to 12.0 and the change amount within 30 min is smaller than 0.1, steel slag micro powder is added, the adding amount is 1-5% of the total mass of the mixed solution, and stirring continues to be conducted for 20-60 min; and when the pH value of the system is stable and no longer increased within 2 hours or the release amount of Na2O is balanced, carrying out solid-liquid separation to obtain filtrate, namely the geopolymer alkali activator. According to the method, the dependence on traditional high-alkalinity chemical substances can be reduced, and a new way is provided for resource utilization of the red mud.

The application discloses a method for preparing low-carbon clinker by electrolytic manganese residue and phosphogypsum, and the method comprises the following steps: obtaining phosphogypsum, electrolytic manganese residue and carbonaceous raw materials, drying and crushing, and then mixing and grinding according to the modified C:S, KH value and total CaO:SiO2 mass ratio; the obtained mixture is added with water to form material balls, and then the material balls are dried; the dried material balls are calcined in an oxygen-deficient or oxygen-free environment, and then the low-carbon clinker is obtained after cooling; and the reduction components in the electrolytic manganese residue are used for decomposing the phosphogypsum, so that the industrial solid wastes, i.e., the electrolytic manganese residue and the phosphogypsum, are effectively and cooperatively utilized, and energy is saved; except for the carbonaceous raw materials, the total utilization rate of the electrolytic manganese residue and the phosphogypsum in the batching reaches 100%, the industrial solid wastes, i.e., the electrolytic manganese residue and the phosphogypsum, are effectively and cooperatively utilized, the amount of the carbonaceous raw materials required for decomposing the phosphogypsum is reduced, the cost and carbon emission are reduced, and the low-carbon clinker is synchronously prepared.

The invention discloses a mixing design-based ratio optimization method for a multi-source solid waste cementing material containing alkaline residues, which is used for optimizing to obtain an optimal ratio of five solid waste components according to a preset cementing material performance target, the alkaline residues are used as an alkaline excitation component, a D optimal mixing design method is adopted to determine a test point, a three-order normative polynomial model is established, and the optimal ratio of the five solid waste components is obtained. Setting constraint conditions of each solid waste component, testing the three-day compressive strength and 28-day compressive strength of the neat paste for each test point, obtaining a first fitting model based on compressive strength response and a second fitting model based on response according to test data, and according to a preset performance target, the first fitting model and the second fitting model, calculating the compressive strength of the neat paste according to the first fitting model and the second fitting model. Solving through a multi-objective optimization algorithm to obtain an optimal proportion of five solid waste components; according to the method, the problems of low efficiency and high cost of a traditional trial and error method are solved, and scientization and standardization of the proportion design of the multi-source solid waste cementing material are realized.

The invention discloses a preparation method of low-cost solid-waste-based sulphoaluminate cement, and relates to the technical field of cement preparation.The preparation method comprises the steps of solid waste pretreatment, ingredient design, raw material preparation, low-temperature calcination, clinker quenching and cement powdering.By means of the scheme design, high-aluminum / sulfur-rich solid waste such as red mud, desulfurized gypsum and fly ash is used for replacing 70% or above of natural raw materials, and the low-cost solid-waste-based sulphoaluminate cement is obtained; for example, expensive alumina, natural gypsum and the like, the cost of the raw materials can be directly reduced by more than 40%. Wherein the red mud is used as the waste residue of the aluminum oxide industry, the original treatment cost is very high, and the red mud is converted into an effective aluminum source nowadays, so that negative-cost raw material utilization is realized, and the waste residue treatment cost is also saved; the desulfurized gypsum is used as a power plant waste material to completely replace natural gypsum, so that the sulfur source cost is reduced by 60%. Through comprehensive calculation, the production cost of the clinker is reduced by 30-35% compared with that of the traditional sulphoaluminate cement.

The application provides a coal-based solid waste flotation-metallurgy-material resource comprehensive utilization process method and application, and belongs to the technical field of coal-based solid waste comprehensive utilization.The coal-based solid waste is first separated by flotation to obtain residual carbon and tail ash; then the tail ash is dried and alkali melted to become active material; then the active material is leached and filtered to obtain leaching liquid and leaching residue, and Li and Ga in the leaching liquid are adsorbed and enriched; the adsorbed leaching liquid is adjusted in silicon-aluminum ratio, hydrothermally crystallized, filtered and high-temperature calcined to obtain mesoporous molecular sieve; the filtered silicon-containing alkali liquor is carbonized and calcined to obtain white carbon black; the tail ash and the leaching residue are mixed, and through moisture adjustment and curing process, a geopolymer product is obtained.The method in the application does not produce waste residue and waste water in the implementation process, finally obtains four products of Li and Ga enrichment product, geopolymer product, mesoporous molecular sieve and white carbon black, realizes full and comprehensive utilization of the coal-based solid waste, and has good environmental benefits and great significance.

The invention discloses a self-repairing geopolymer grouting material as well as a preparation method and application thereof, and belongs to the technical field of underground engineering structures and rock mass grouting, leaking stoppage and reinforcement materials. The self-repairing geopolymer grouting material is prepared from the following components in parts by mass: 1 part of grouting powder base material, 0.01 to 0.1 part of self-repairing microcapsule and 0.5 to 1.5 parts of water, the self-repairing microcapsule comprises a geopolymer microcapsule and a microbial microcapsule in a mass ratio of (0.5-1.5): 1. The obtained grouting material has high impermeability, dynamic deformation adaptability and multi-scale self-repairing capability. In the elastic stage, the shell of the geopolymer microcapsule absorbs deformation energy and delays the cracking of the matrix; in the damage stage, the geopolymer microcapsules are broken to release the repairing agent, and crack diffusion energy is dissipated through chemical bond recombination; and in the repairing stage, the calcium carbonate / geopolymer composite phase forms a new energy loss interface, so that the material still has relatively low permeability after strain cyclic loading, and the repairing effect is improved.

The invention discloses geopolymer cement based on coal gangue activation reaction as well as a preparation method and application thereof, and relates to the technical field of building materials. The invention relates to a coal gangue concrete, which is prepared from the following raw materials in percentage by mass: 50 to 70 percent of activated coal gangue powder, 5 to 15 percent of alkali activator, 10 to 30 percent of auxiliary cementing material and water, wherein the water accounts for 30 to 40 percent of the total mass of the activated coal gangue powder, the alkali activator and the auxiliary cementing material. Through a composite activation process of medium-temperature calcination decarburization and superfine grinding, the activity of silicon-aluminum components in the coal gangue is effectively excited, the reaction efficiency is remarkably improved, the mixing amount of the coal gangue reaches 50%-70%, the resource utilization rate of solid waste is greatly increased, and efficient activation and resource utilization of the coal gangue are achieved. By adopting the methyl sodium silicate and sodium silicate composite activator, the reaction rate and the product structure are regulated and controlled, and the workability and the setting and hardening behaviors of slurry are improved, so that the obtained geopolymer cement has relatively high early and later strength and excellent durability.

The invention relates to the technical field of gelling materials, in particular to a gelling material based on high-doping-amount shield muck and a preparation method and application thereof.The preparation method comprises the following steps that after original shield muck is sequentially subjected to mechanical crushing, forced homogenization and drying to constant weight, gradient heating calcination is conducted, then rapid cooling is conducted immediately, and the high-doping-amount shield muck is obtained; carrying out two-stage ball milling and sieving to obtain active shield muck powder; preparing a solid dry blend; preparing a composite alkali activator solution; and mixing the composite alkali activator solution with the solid dry blend, primarily stirring and infiltrating, adding the residual mixing water, stirring to obtain uniform geopolymer slurry, and compacting and molding to obtain the cementing material. The problems that in the prior art, a high-performance geopolymer cementing material based on shield muck is low in activity, insufficient in strength, small in shield muck mixing amount, single in performance and poor in volume stability are solved.

The invention discloses a diabase tailing geopolymer cementing material and a preparation method thereof, and belongs to the technical field of building materials. The diabase tailing geopolymer cementing material provided by the invention is prepared from the following components in parts by mass: 80 to 120 parts of diabase tailings, 10 to 20 parts of sodium hydroxide, 80 to 120 parts of water glass, 10 to 20 parts of aluminum hydroxide, 1 to 3 parts of a water reducing agent and 2 to 11 parts of a stabilizing material, the geopolymer cementing material is prepared from the solid waste diabase tailings, harmful solvents, heavy metals and radioactive substances are not added, waste can be turned into wealth, the preparation process is simple, the cost is low, the energy consumption is small, and an effective way is provided for comprehensive utilization of the diabase tailings.

This invention discloses a high-early-strength, low-shrinkage composite silicate cement and its preparation method, comprising: low-shrinkage silicate cement clinker, early-strength component, and gypsum component; the low-shrinkage silicate cement clinker is prepared from calcareous raw materials, siliceous-aluminous raw materials, ferrous raw materials, a first activator, and a mineralizer; its mineral composition includes: C3S 30-50 parts, C2S 20-40 parts, C3A 0.5-5 parts, and C4AF 10-25 parts; its particle size distribution characteristics are D10≥5μm, D90≤45μm, uniformity index of 1.2-1.6, and characteristic particle size of 25-30μm; the early-strength component is prepared from F-type fly ash or C-type fly ash, limestone, magnesium oxide, and a second activator; its mineral composition includes: C 20 A 13 M3S 350-65 parts, C2S 35-50 parts. The cement prepared by this invention not only has high early strength, but also has a small drying shrinkage rate.

The utility model relates to the technical field of flour mills, in particular to an efficient flour mill which comprises a flour mill main body used for grinding cement raw materials, a feed port and a discharge device, one end of the cylindrical flour mill main body is communicated with the feed port, and the other end of the cylindrical flour mill main body is communicated with the discharge device. The other end of the pulverizer main body is communicated with a discharging device composed of a supporting seat and a discharging port, a coarse grinding bin and a fine grinding bin are formed in the pulverizer main body, a first lining plate is arranged on the inner wall of the coarse grinding bin formed in the pulverizer main body, a second lining plate is arranged on the inner wall of the fine grinding bin formed in the pulverizer main body, and the second lining plate is arranged on the inner wall of the fine grinding bin. The outer side of a supporting seat of the discharging device is fixedly connected with a support, one side of the support is fixedly connected with a transverse rod, and the bottom of the transverse rod is fixedly connected with an electric telescopic rod. And maintenance or replacement after disassembly is facilitated.

The invention provides a coal-based solid waste acid-activated cementing material and a preparation method thereof, and the preparation method comprises the following steps: fully crushing, calcining and ball-milling coal gangue, coal series kaolin and kaolin tailing slag to obtain a ball-milled material; grinding and sieving the sludge incineration ash to obtain screen underflow, and adding an extracting solution into the screen underflow to prepare an acid activator; mixing and stirring an acid activator and the ball-milled material to obtain neat paste; and carrying out pouring molding on the neat paste, and carrying out sealing maintenance to obtain the coal-based solid waste acid-activated gel material. The coal-based solid waste acid-activated cementing material prepared by the preparation method provided by the invention has good cementing property and mechanical property, and the preparation process is low in energy consumption, less in carbon dioxide emission, easily available in raw materials and low in price, so that the resource utilization of solid wastes is effectively realized; an engineering application foundation is laid for replacing cement on a large scale or preparing concrete for buildings, and the method can also be applied to soil remediation of contaminated sites.

The invention discloses a geopolymer concrete dry blend as well as a preparation method and application thereof, and belongs to the technical field of building materials. The geopolymer concrete dry blend comprises the following components in parts by weight: 20-85 parts of mineral powder; 10 to 35 parts of fly ash; 5 to 30 parts of silica fume; and 5-20 parts of a solid alkali activator A. In addition, the invention also provides a preparation method of the geopolymer concrete dry blend, which comprises the following steps: mixing mineral powder, fly ash and silica fume to obtain a powder mixture N1; mixing a solid alkali activator and a water reducing agent to obtain a powder mixture N2; and mixing the powder mixture N1, the powder mixture N2 and quartz sand to obtain the geopolymer concrete dry blend. In addition, the invention also provides an application of the geopolymer concrete dry blend in preparation of concrete members. A concrete member prepared from the geopolymer concrete dry blend provided by the invention is long in initial setting time and high in strength.

The present application belongs to the technical field of underground filling of metal mines, and particularly relates to an iron tailings powder-based cementitious material for mine full tailings cemented filling, a preparation method and application thereof. The geopolymer-based anti-cracking mortar is made of iron tailings ultrafine powder, ore powder, sulphoaluminate clinker, Portland cement clinker, desulfurization gypsum and methyl cellulose ether. The iron tailings powder-based cementitious material can completely replace ordinary Portland cement in full tailings filling and achieve better cementing effect than cement, thereby greatly reducing the consumption of cement and other cementitious materials, lowering the filling cost, reducing carbon emissions and increasing the utilization rate of tailings. The rheological properties, mechanical properties and durability of the full tailings cemented filling material made of the iron tailings powder-based cementitious material can meet the requirements of mine filling, and the material can achieve the effect of expansion and roof contact without adding external additives, thereby solving the shrinkage problem of cement-based filling materials.

The invention discloses a geopolymer-based recycled fine aggregate shield synchronous grouting material and a preparation method thereof. The grouting material is composed of a cementing material, an alkali activator, aggregate, a water reducing agent, a retarder and water, and the cementing material is a geopolymer precursor and is composed of fly ash, slag and metakaolin; the aggregate is composed of river sand and recycled fine aggregate. By optimizing the proportion and the preparation process, the material has the characteristics of excellent flowability, controllable setting time, high early strength, good impermeability, good durability and the like, and is suitable for synchronous grouting of shield tunnels in water-rich sand layers, high-water-pressure stratums or corrosion stratums. The invention also provides two optimization methods which are respectively based on a response surface method and a BP neural network combined genetic algorithm to realize multi-objective optimization of slurry performance. According to the material, dependence on traditional cement and gravel resources is remarkably reduced, energy consumption and carbon emission are reduced, high-added-value resource utilization of industrial solid waste and construction waste is achieved, and the material conforms to the development direction of green low-carbon building materials.

The application discloses a high-value resource utilization system and method of waste concrete, and the system comprises a preheating subsystem, a calcining subsystem, a cooling subsystem, a separating subsystem, a crushing subsystem, a dust collecting subsystem and a conveying subsystem. Waste concrete which is coarsely separated and pre-homogenized is mixed into cement raw materials to produce silicate cement clinker, and the test block after coarse crushing, screening, fine crushing and screening is directly stripped, and the separated powder can be used as a mixing material; the test block after stripping is preheated and calcined in a rotary kiln, the obtained material is cooled and stripped, and then sent into a V-type powder separator to separate coarse aggregates, and the fine aggregates and recycled waste concrete micro powder are separated through the powder separator and a dust collector. The application realizes the synergistic effect of pollution reduction and carbon reduction by combining with a cement production line, separates fine aggregates, coarse aggregates and hardened cement paste in the waste concrete, and realizes the high-value resource utilization of the waste in multiple ways according to the characteristics of each component.