2917results about "Cement production" patented technology

The invention describes an activated supersulphated aluminosilicate binder containing aluminosilicates, calcium sulphate and an activator containing alkali metal salts, wherein the aluminosilicates are selected from the group consisting of blast furnace slag, clay, marl and industrial by-products such as fly ash with the proviso that the Al2O3 content is greater than 5% by weight, wherein blast furnace slag is present in an amount exceeding 35% by weight and clay, marl and/or fly ash is present in an amount exceeding 5% per weight and wherein cement kiln dust in an amount of from 3 to 10% by weight is added to the mixture as an activator and calcium sulphate is used in an amount exceeding 5% by weight.

The invention provides geopolymeric compositions, which have controllable thickening and setting times for a wide range of temperatures and a large range of geopolymer slurry densities. The geopolymer slurry compositions have good mixability and pumpability, whilst the set materials develop good compressive strength and permeability. The invention discloses a method for preparing geopolymer for oilfield cementing applications. The geopolymeric compositions according to the invention comprises a suspension comprising an aluminosilicate source, a metal silicate, an alkali activator, lightweight or heavyweight fillers and a carrier fluid wherein the suspension of said geopolymeric composition is pumped in a well and allowed to set.

Processes and compositions are provided for decreasing emissions of mercury upon combustion of fuels such as coal. Various sorbent compositions are provided that contain components that reduce the level of mercury and/or sulfur emitted into the atmosphere upon burning of coal. In various embodiments, the sorbent compositions are added directly to the fuel before combustion; are added partially to the fuel before combustion and partially into the flue gas post combustion zone; or are added completely into the flue gas post combustion zone. In preferred embodiments, the sorbent compositions comprise a source of halogen and preferably a source of calcium. Among the halogens, iodine and bromine are preferred. In various embodiments, inorganic bromides make up a part of the sorbent compositions.

Methods and compositions for wellbore treating fluids, especially remedial compositions such as pills, that include zeolite and at least one carrier fluid.

A geopolymer composite ultra high performance concrete (GUHPC), and methods of making the same, are provided herein, the GUHPC comprising: (a) a binder comprising one or more selected from the group consisting of reactive aluminosilicate and reactive alkali-earth aluminosilicate; (b) an alkali activator comprising an aqueous solution of metal hydroxide and metal silicate; and (c) one or more aggregate.

The invention discloses a light isolated material and a preparation method thereof, including an aluminates polymer, the molar ratio of silicon (Si) and aluminum (Al) in which is more than or equal to one and less than or equal to three and which includes solid raw materials containing silicon and aluminum of 50-85 weight percent of fly ash, kaolin, coal gangue, coal slag, etc.; 14.5-48 percent of liquid alkaline activator; 0.5-2 percent of foaming agent. The liquid alkaline activator includes caustic solution and water glass, which are mixed and stirred with the solid raw materials and the foaming agent to produce a roof heat insulation plate, which is applied to both the direct pouring and the die molding prefabrication and can be used both for the heat insulation or the cold insulation of cold or heat equipment and for making large size building wallboards for heat insulation, deafening and fireproofing.

A process for making a pervious concrete comprising a geopolymerized pozzolanic ash. Generally, the process includes mixing a solid aggregate and a geopolymerized pozzolanic ash binder together to form a pervious concrete mixture. Some examples of suitable aggregates comprise recycled carpet, recycled cement, and aggregates of coal-combustion byproducts. The geopolymerized pozzolanic ash binder is made by combining a pozzolanic ash, such as fly ash, with a sufficient amount of an alkaline activator and water to initiate a geopolymerization reaction. The activator solution may contain an alkali metal hydroxide, carbonate, silicate, aluminate, or mixtures thereof. In some aspects, the final concrete forms a solid mass in the form of pavement or a pre-cast concrete shape. The solid mass of concrete may have a void content of between about 5% and about 35%.

The invention belongs to the technical field of mining engineering and building materials and particularly relates to a mine filling cementing material slurry and a preparation method thereof. The preparation method comprises the following steps of: with steel slag, mineral slag and industrial byproduct gypsum as cementing agents and tailing sand as a filling aggregate, adding water, mixing and stirring uniformly to prepare mine filling cementing material slurry, wherein a dry basis of raw materials comprises the following components in percentage by weight: 1-7% of steel slag, 5-12% of mineral slag, 2-10% of industrial byproduct gypsum and 75-90% of tailing sand, and the sum of the weight percentage of the dry basis of all the raw materials is 100%; adding water to regulate the mass concentration of the filling cementing material slurry to be between 65-75%. The mine filling cementing material slurry has the beneficial effects of higher strength, simple process, high flowability and suitablity for self-flowing filling; no cement or cement clinker or additives are added in the components of the filling cementing material slurry which is completely made of solid wastes, so that the utilization rate of the tailing sand is high, and the production cost is very low.

A hydraulic cement for biomedical applications. The cement sets in-situ, hardening when exposed to water to produce nano-dispersed composite of calcium-silicate-hydrate gel mixed with hydroxyapatite. In comparison with prior cements, the composition provides high biocompatibility, high bioactivity and high biomechanical strength, due to the composite structure of the calcium silicate hydrate reinforced with co-precipitated particles of hydroxyapatite. Biocompatibility is also increased due to an absence of aluminum and magnesium in the composition. The cement is suitable for variety of applications, including dental implants, bone fixation, and bone repair.

The invention discloses a fibre reinforced coal ash based geopolymer foam material and a preparation method thereof. The fibre reinforced coal ash based geopolymer foam material disclosed by the invention comprises the following components in percentage by weight: 50-70% of aluminium silicon raw material, 5-15% of slag, 3-8% of inorganic fibre, 15-30% of liquid alkaline exciting agent, 0.2-2% of foaming agent, and 2.5-3.5% of foam stabilizer. The preparation method disclosed by the invention comprises the step of also adding the foam stabilizer while adding the foaming agent by adopting the liquid alkaline exciting agent by taking the inorganic fibre as the reinforcing agent, the slag as the Ca adjusting agent and other solid raw materials (such as coal ash, metakaolin and silica fume) as powder for providing aluminium silicon. The light foam material prepared by the invention has the characteristics of being high in intensity, small in size change rate, low in water absorption and the like in the event of having same volume weight and heat conductivity of the similar materials, and is applied to various applications.

A cement composition of an environmental impact reducing type, used in the field of civil engineering and construction, which provides initial strength-development equal to that of ordinary Portland cement and which can reduce the clinker calcination amount, is provided. A cement composition containing Portland cement having a 3CaO.SiO₂ content of at least 60% and a slowly cooled blast furnace slag powder, wherein the content of the slowly cooled blast furnace slag powder is from 10 to 50 parts per 100 parts of the cement composition.

The invention aims at providing a low-cost multipurpose base mortar which comprises the following ingredients in proportions: 15-50 percent of cement, 50-85 percent of sand, 1-20 percent of inorganic composite material, 0.05-10 percent of organic composite material and 0.1-5 percent of fibrous material. The invention generates a super-composition effect by utilizing a multi-compositing design thinking and adding a plurality of inorganic and organic functional materials and enables that the mortar performance is greatly prompted, different types of prepared mortars satisfy the rigorous requirement for the mortar performance from various corresponding novel materials, the cost is not increased remarkably, and factory-produced dry-mixed mortar can be used in engineering construction actually.

This invention discloses a method for extracting SiO2 and Al2O3 from fly ashes. The method comprises: activating fly ashes, leaching with more than 40 wt. % NaOH solution so that Si is stripped out in the form of sodium cilicate, introducing CO2 to prepare SiO2, adding CaO or CaCO3 into the leaching residue, calcining to obtain a clinker, preparing Al2O3 by Bayer method, and preparing cement from the waste residue. The method extracts Si at first, thus increasing the Al/Si ratio in the leaching residue. Treated leaching residue can be directly subjected to Bayer method to extract Al2O3, which largely simplify Al2O3 extraction process and increase Al2O3 utility. The method has such advantages as simple process, low investment, and high product added value.

A modified alkali silicate composition for forming an inorganic network matrix. The modified alkali silicate matrix is made by reacting an alkali silicate (or its precursors such as an alkali hydroxide, a SiO₂ source and water), an acidic inorganic composition, such as a reactive glass, water and optional fillers, additives and processing aids. An inorganic matrix composite can be prepared by applying a slurry of the modified aqueous alkali silicate composition to a reinforcing medium and applying the temperature and pressure necessary to consolidate the desired form. The composite can be shaped by compression molding as well as other known fabrication methods. A notable aspect of the invention is that, although composite and neat resin components prepared from the invention can exhibit excellent dimensional stability to 1000° C. and higher, they can be prepared at the lower temperatures and pressures typical to organic polymer processing.

Process for production of acid and high temperature resistant cement composites, where the matrix is alkali activated F fly ash alone, F Fly ash combined with ground slag or ground slag alone. F-fly ash produces lower quality alkali activated cement systems. On the other hand the lack of calcium oxide results in very high resistance to medium and highly concentrated inorganic or organic acids. The high strength and low permeability of pure F-fly ash cement systems is achieved by using in the composition un-densified silica fume, the amorphous silicone dioxide obtained as by products in production of ferro-silicones. Precipitated nano-particle silica made from soluble silicates and nano-particle silica fume produced by burning silicon tetra chloride in the hydrogen stream.

The invention discloses a nano additive modified high strength wall self heat preservation brick and a preparation method thereof. The method comprises the following steps: according to mass portion, 1 to 20 portions of bonding agent, 0.1 to 5 portions of admixture and 0.5 to 5 portions of nano additive are evenly mixed and added with admixtures, the weight of which is 0.001 to 0.1 times against the weight of the mixture, and evenly mixed again; and the mixture obtained is added with water and shaped. For the wall self heat preservation brick prepared by the method of the invention, the pressive strength is between 5 and 14MPa, the coefficient of thermal conductivity is between 0.1 and 0.2w/m.k, so that the brick is a highly efficient energy saving building material with superior performance.

The invention provides a geopolymer gel material for rush repairs and rush constructions, which is prepared by adding water to 13-17 percent by weight of exciting agent and 82-87 percent by weight of slag containing aluminosilicate. The slag comprises one or the combination of more of blast furnace slag, steel slag, coal ash and coal gangue, and the exciting agent comprises the following components in percentage by weight: 35-75 percent of SiO2, 0-55 percent of Na2O, 0-65 percent of K2O, 0-1 percent of CaO and 0-1 percent of SO3. The geopolymer gel material which has the characteristic of quick setting and hardening is prepared by using the industrial waste slag as a main raw material and matching the exciting agent, and the geopolymer gel material has excellent mechanical property and controllable setting time and can replace gel materials such as fast setting and hardening cement, and the like in the processes of rush repairs and rush constructions. The industrial solid wastes such as the blast furnace slag, the steel slag, the coal ash, the coal gangue, and the like containing the aluminosilicate series are used as main raw materials, metakaolin is not added and the raw materials do not need to be calcined, thus the invention has low energy consumption, less pollution, simple process, low cost, environmental protection and energy saving.

The invention discloses a technological method for producing high-purity low-iron aluminum sulfate by using coal ash and comprehensively utilizing the coal ash, comprising the following steps of: carrying out mechanical activation, flotation decarburization, magnetic separation for deferrization, aluminum extraction with sulfuric acid, solid-liquid separation, concentration of aluminum sulfate crude liquor, organic alcohol alcoholization for acid rinse, organic alcohol alcoholization for deferrization and aluminum sulfate dewatering and drying on the coal ash to obtain the high-purity low-iron aluminum sulfate with low Fe content. The invention solves the problems on impurity removal and purification of the aluminum sulfate in the recycling process of the coal ash, simplifies the process flow, reduces the energy consumption, solves the technical problem of overlarge accumulation of secondary residue quantity, achieves high extraction ratio of aluminum contained in the coal ash, and realizes the recycling of organic alcohol and sulfuric acid and the comprehensive utilization of side products including unburnt black, magnetic iron powder, iron-containing aluminum sulfate crystals, high-silicon-dust active mineral blending materials or novel silicon-magnesium cement, and the like. The technological method has the advantages of simple process, short flow, easiness for control of a production process, high aluminum extraction ratio, low impurity content of products and stable quality.

The invention relates to an alkali-activated cementing material prepared from siliceous iron tailings and a preparation method of the alkali-activated cementing material. The preparation method comprises the following steps: 1) proportionally and evenly mixing siliceous iron tailing powder, coal ash and slag powder together to obtain iron tailing powder-coal ash-slag powder compound powder; 2) mixing liquid water glass with water to obtain an alkali activating agent solution; 3) adding the alkali activating agent solution to the compound powder and stirring evenly to obtain an alkali-activated cementing material paste; 4) injecting the alkali-activated cementing material paste into a die for vibrating molding and maintaining under a normal temperature condition until knockout, thereby obtaining an alkali-activated cementing material net paste test piece; and 5) performing steam curing on the alkali-activated cementing material net paste test piece. The alkali-activated cementing material has the beneficial effects that the alkali-activated cementing material hardened paste has excellent mechanical properties, the 3d compressive strength of the optimal proportion of the hardened paste is greater than 60MPa and the 28d compressive strength of the hardened paste is greater than 80MPa.

Disclosed is a comprehensive recovery method for a complex material containing arsenic and valuable metal slags, comprising passing the materials containing arsenic through a primary rotating kiln to volatilize the arsenic, and through a secondary rotating kiln to purify the arsenic, so that an arsenic product containing 99.5% As 2 O 3 is produced; reduction smelting slags from the primary and secondary rotating kilns in a blowing volatilization furnace, with the resultant highly arsenious dust being returned to the primary rotating kiln for treatment, and the slags being used as a raw material in a cement manufactory and a raw material for zinc after undergoing strongly reductive dearsenization and volatilization of zinc in a fuming furnace; the resultant alloy containing arsenic being subjected to basic oxidizing refinement, and the oxidized/refined alloy after dearsenizations containing Pb > 72%, Sb > 12%, As 2 O 3 <0.02%, being sold as a lead-antimony alloy; the basic slags from the refinement, containing As 2 O 3 10%-20%, being subjected to crushing, dissolution in base, and filtration, with the slags thereof being returned to a blowing volatilization furnace for treatment; precipitating tin from the basic solution containing tin and arsenic by blowing in CO 2 , with the filtered tin oxide being sold as a raw material for tin; adding Ca(OH) 2 into the basic filtrate containing arsenic to precipitate arsenic, returning the filtered slags of calcium arsenate to the primary rotating kiln for treatment, and evaporating the remaining basic solution to concentrate and recover the base.

The invention relates to a burning-free geology polymer material of red mud coal ash and a preparation method thereof, belonging to the technical field of recycling inorganic nonmetal material and industrial solid waste. Kawazu mud powder and coal ash are taken as main substrate raw materials, building fine sands and building crushed stones are taken as aggregate, solid water glass powder is taken as alkali activator to prepare the burning-free geology polymer material of red mud coal ash. The raw materials comprise the following components based on parts by weight percent: 5-98% of the kawazu mud powder, 1-65% of the coal ash, 1-96% of the building fine sands and the building crushed stones, and 1-20% of the solid water glass powder. Counting the red mud+the coal ash+the building fine sands and the building crushed stones as 100%, the raw materials further comprise the following components based on parts by weight percent: 5-45% of water and 0.1-10% of calcium lignosulphonate. The preparation method comprises the steps of: dosing, mixing, aging, shaping, maintaining and drying, etc. The invention has the advantages of the high use ratio of industrial solid waste, the less pollution, the low energy composition and the simple operation of the preparation technology, and embodies the important meanings of environment protection, energy conservation and emission reduction.

Compositions and methods for increasing grinding efficiency of cement, cement clinker, raw materials for cement, and other inorganic particles. Use of biomass-derived polyols such as diols, triols, or mixtures thereof, optionally with a conventional grinding aid, cement quality improver, and/or hexavalent chromium reducer, are believed to provide less risk of sludging when compared to glycerides obtained from fossil fuel sources.

A dry mix cement composition including an alkaline multi-phase aluminosilicate material, wherein the alkaline multi-phase aluminosilicate material provides a source of alkaline and soluble silicate to the cement composition.

The invention relates to a cement reinforced grinding aid, containing polycarboxylic acid type composite activated cement reinforced grinding aid, which contains esterification catalyst, inhibitor, initiator, grinding aid, activator, strengthening agent, blending agent and chain transfer agent and contains no chlorine ion. The polycarboxylic acid type composite activated cement reinforced grinding aid is a neutral efficient composite cement additive, which is synthesized through the highly efficient magnetized, activated and composite technology. The invention is made though synthesizing inorganic reinforced components with optimized surfactant and antistatic agent and has the advantages of toxin-free, hazard-free, nonirritant, chlorine-free, flame retardant and non-corrosive. The product belongs to green produce. The used amount is 0.015-0.025 weight portions of cement, and the mill output per hour can be improved by 10-25 percent. The twenty eighth day strength of the cement can be increased by 4-8MPa. The strength is increased by 2-4MPa in three days.

The invention discloses a chlorine-free powdery cement grinding aid suitable for fly ash, which comprises the following components in parts by weight: 0-5 parts of alkanolamine, 2-5 parts of polylol,15-75 parts of sulfate, 5-20 parts of acetate, 0-5 parts of lignosulphonate, 2-6 parts of carbohydrate organic matter, 5-25 parts of miltonite, 0-25 parts of carbamide and 5-50 parts of inorganic carrier material. The invention also discloses a preparation method of the chlorine-free powdery cement grinding aid suitable for the fly ash. A compound grinding aid can lower the cement cost and uses the fly ash for replacing partial clinker to save the clinker dosage by 10-15 percent on the premise of keeping the cement strength unchanged, and uses extra 10-15 parts of fly ash without increasing the required water amount of cement standard consistency; the cost of the cement per ton is lowered by more than 10 Yuan.

The invention discloses inorganic artificial combining stone and a preparation method thereof. The artificial combining stone uses silicon acid-base solution to arouse metakaolin to react and generate geopolymer to serve as an inorganic cementing agent, and the artificial combining stone mainly contains the metakaolin, the silicon acid-base solution, natural stone aggregate, decoration aggregate, a thickening time control agent, inorganic pigment and fibers. The preparation method is firstly enabling the thickening time control agent and the inorganic pigment to be dissolved in the silicon acid-base solution to obtain mixed serous fluid, evenly blending the metakaolin, the natural stone aggregate, the decoration aggregate, the fibers and the mixed serous fluid, preparing the artificial combining stone through model entering or material distribution, vibration under the vacuum condition, molding in a pressing mode, maintaining, cutting, polishing, burnishing and surface protection. The artificial combining stone not only has decoration features which can be equal to that of resin artificial stone, but also is non-toxic, environment-friendly, low in cost, resisting in corrosion of most majority of acid-base salts, durable in high temperature and excellent in durable performance, obviously avoids whiting and saltpetering phenomena after a long time use, and is strong in pollution resisting capability.

The invention relates to anti-cracking alkali exciting ecological cement, which consists of A, B and C, and solid-phase mass ratio of the A to the B to the C is 5-10:75-90:5-15. The A is exciting agent, which comprises the following components by mass percentage: more than or equal to 80 percent of water glass of which modulus is 0.7 to 1.4, and less than or equal to 20 percent of one or a plurality of sodium sulfate, sodium phosphate, sodium carbonate, sodium chloride and magnesium chloride; and the A is prepared into solution containing more than or equal to 40 percent of solid for use. The B is a mineral additive, which comprises the following components by mass percentage: 30 to 70 percent of slag powder, and 30 to 70 percent of other additives, wherein the other additives comprise one or a plurality of siliceous dust, coal ash, metakaolin, red mud, burnt shale, colliery waste, steel slag and alloy slag, and is grinded to powder of which specific surface is 350 to 800m<2>/g. The C is active magnesium oxide, wherein mass content of MgO is more than or equal to 70 percent. The active magnesium oxide is calcined at a temperature of between 700 and 1,000 DEG C and then mixed and grinded with the B to become powder. The cement is the low-carbon discharge ecological cement with the advantages of high-early strength, durability, permeability resistance, corrosion resistance, freezing and thawing resistance, low heat of hydration, good cracking resistance, economy and environmental protection, and is used for civil construction, water conservancy, national defense, and oil well and mine passage support engineering.

Geopolymer composite materials having low coefficient of thermal expansion are disclosed. The materials are useful in high temperature applications due to their low coefficient of thermal expansion and high strength. Also disclosed is a boron modified water glass geopolymer composition that is compatible with ceramic particulate material such as cordierite and fused silica. The geopolymer composite may be extruded to form structures such as honeycomb monoliths, flow filters or used as a plugging or skinning cement and may be fired at temperatures at or below 1100° C. Both the structures and the cement have high green and fired strength, a low coefficient of thermal expansion, and good acid durability. The cost of manufacturing objects using the material of the present invention is substantially reduced, in comparison with typically production methods of cordierite based bodies, due to the substantially shortened firing times.

The present invention generally relates to a geopolymer precursor dry mixture, geopolymer precursor package, a process of preparing a geopolymer composition, and a method of providing a geopolymer composition to a geopolymer composition preparation site.

The invention discloses active belite-sulphate aluminum cement clinker, which comprises the following mineral compositions in weight percentage: 25-30 percent of beta-type C2S, 25-30 percent of a-type C2S, 28-40 percent of C4A3S`, 4-12 percent of C4AF and 4-8 percent of amorphous-phase substance. The control of different forms and the change of number of the C2S in the clinker are controlled mainly through special setting on clinker ingredient rate values. The invention also discloses a preparation method for the active belite-sulphate aluminum cement clinker. Compared with traditional common silicate cement clinker, the active belite-sulphate aluminum cement clinker has the advantages that more industrial solid waste residues are used in raw materials by the active belite-sulphate aluminum cement clinker, and thereby, the production cost is reduced, the use proportion of limestone is greatly reduced, and the carbon dioxide emission in clinker production is obviously reduced. Under the condition that the water demand and the setting time of the obtained clinker are basically the same as that of the common silicate cement clinker, the strength of the obtained clinker is superior to that of the common silicate cement clinker.