The invention discloses a nano-composite adsorbent preparation method directly processing waste water containing chrome tanning. Low-concentration heavy metal waste water is commonly processed by an adsorption method, an ion exchange method and the like currently, and the methods selectively adsorb chrome. According to the nano-composite adsorbent preparation method direct processing the waste water containing chrome tanning, diallyl dimethyl ammonium chloride, methacrylic acid, acrylamide, hydroxyethyl acrylate and nanometer titania are used as raw materials, and aqueous solution free radicals are polymerized to prepare vinyl-based polymer / nanometer titania P (DMDACC-MAA-AM-HEA) / TiO2 nano composite adsorbent. According to the nano-composite adsorbent preparation method directly processing the waste water containing chrome tanning, the adsorbent can directly process low-concentration chrome tanning waste water, chrome removal rate can be 98.6 %, the adsorbent has wide pH value adaptability, has highly-selective adsorbability to Cr, is not prone to being polluted by other pollutant in the waste water, and is large in adsorption capacity, high in processing efficiency, and particularly suitable for processing acidic low-concentration chrome tanning waste water.