536 results about "Polyphosphate" patented technology

The present invention discloses a self-assembled monolayer hole transport material based on an alkyl polyphosphate anchoring group, a synthesis method thereof, and an application in an inverted perovskite solar cell. The present invention uses carbazole or 3,6-diphenylcarbazole with good hole transport properties as a parent core, and achieves complete coverage and stable self-assembly of the material on the substrate surface by improving the anchoring group from traditional alkyl monophosphate to alkyl diphosphate and triphosphate. The synthesis method of the present invention is simple and the synthesis cost is low. The prepared material can achieve the dual functions of hole transport and perovskite interface passivation, while enhancing the self-assembly strength and stability. When the material is used as a hole transport layer in an inverted perovskite solar cell, a photoelectric conversion efficiency of >20% can be obtained without doping, and the material has broad application prospects.

The invention belongs to the technical field of flame retardants, and particularly relates to a high-thermal-stability polyphosphate flame retardant and a preparation method thereof. The DOPO is modified through the polyethylene glycol acrylate, methyl methacrylate and dicumyl peroxide composite solution, double bonds of the polyethylene glycol acrylate and P-H bonds of the DOPO can be subjected to nucleophilic addition to form stable C-P bonds, and thermal migration of the DOPO is hindered; dOPO has polymerization double bonds of methyl methacrylate and long carbon chains of polyethylene glycol acrylate, so that the compatibility of the polyphosphate flame retardant and a polymer substrate is improved, and phase separation is avoided; maleic anhydride grafted silicone oil is connected to the surface of an amino modified gamma-cyclodextrin-modified DOPO inclusion compound, so that the polyphosphate flame retardant has high thermal stability and high compatibility after long-chain alkyl modification; amino groups in the modified gamma-cyclodextrin react with maleic anhydride grafted silicone oil to generate an amido bond cross-linked network, so that the thermal migration of DOPO is reduced together, and the high thermal stability of the polyphosphate flame retardant is improved.

The invention relates to the technical field of land improvement, in particular to an alginic acid type multifunctional long-acting soil conditioner and a preparation method and application of the alginic acid type multifunctional long-acting soil conditioner. The core particle layer comprises an organic material, nano silicon, calcium magnesium polyphosphate, magnesium hydride, ammonium borate, rhamnose and an adhesive, and the slow release layer comprises clay minerals and alginate; the mass ratio of the clay mineral to the alginate to the organic material to the calcium magnesium polyphosphate to the nano silicon to the magnesium hydride to the ammonium borate to the rhamnose to the binder is controlled within a certain range. The soil conditioner provided by the invention is good in slow release performance, can release effective components durably and slowly, and has multiple effects of improving soil quality, providing nutrition, promoting crop growth, improving resistance and the like; the problems of soil acidification, heavy metal pollution, micro-plastic pollution, pesticide pollution, antibiotic pollution and the like in agricultural production can be effectively solved.

The invention belongs to the field of modified self-repairing calcium aluminate cement 3D printing, and particularly relates to a phosphate modified self-repairing calcium aluminate cement 3D printing material and a preparation method thereof. The phosphate modified self-repairing calcium aluminate cement 3D printing material prepared by the invention is prepared from the following raw materials in parts by mass: 60 to 70 parts of calcium aluminate cement, 3 to 7 parts of silica fume, 2 to 4 parts of metakaolin, 0.5 to 3.5 parts of double-template modified calcium bentonite, 0.8 to 1.5 parts of amino modified sodium polyphosphate and 0.15 to 0.8 part of basalt fiber. The invention relates to a concrete anti-microbial agent, which is prepared from the following raw materials in parts by weight: 20-30 parts of water, 20-30 parts of water, 20-30 parts of water, 20-30 parts of nano calcium carbonate, 20-30 parts of nano calcium carbonate, 20-30 parts of magnesium phosphate cement coated bacteria-loaded porous microspheres, 20-30 parts of a polycarboxylate superplasticizer, 20-30 parts of an organic silicon defoaming agent and 25-35 parts of mixing water. The technical-economic cooperation requirement of building 3D printing under complex working conditions is met, and various indexes of phosphate modified calcium aluminate cement applied to the 3D printing technology are met.

The invention relates to the technical field of surface coating materials, in particular to a multifunctional surface coating which comprises the following raw materials: organic silicon modified acrylic resin, an intumescent flame retardant, hollow glass beads, nano titanium dioxide, an auxiliary agent, graphene, silver nanoparticles and flaky zinc powder. The intumescent flame retardant is formed by compounding melamine polyphosphate and pentaerythritol, and the auxiliary agent comprises a dispersing agent, a flatting agent and a plasticizer. By integrating multiple functions of fire prevention, water prevention, heat insulation, self-cleaning and the like into a whole, the complex requirements of different fields of buildings, industry, traffic and the like on material performance can be comprehensively met. In the application of building exterior walls, the fireproof safety, the waterproof sealing performance and the heat insulation performance of buildings can be effectively improved, and energy consumption is reduced; in the aspect of industrial equipment protection, equipment can be protected from being damaged by environmental factors such as high temperature, moisture and corrosion, and the service life of the equipment is prolonged.

The invention is suitable for the technical field of solid hydrogen storage, and provides a preparation method and application of a PCN-doped MOF derived nano-porous hydrogen storage composite material. The preparation method comprises the following steps: firstly, synthesizing a cobalt-nickel bimetallic MOF material, and introducing melamine polyphosphate and pentaerythritol ester in the synthesis process; introducing metal vanadium ions to obtain an MOF derivative, and calcining the MOF derivative to obtain the PCN-doped MOF derivative nano-porous hydrogen storage material. And compounding with magnesium hydride to obtain the V-Ni-Co / PCN + MgH2 hydrogen storage composite material. The hydrogen storage capacity of the prepared material reaches 7.0 wt% or above, rapid hydrogen absorption can be started at 40 DEG C, the dehydrogenation starting temperature is reduced to about 150 DEG C, rapid hydrogen absorption / hydrogen desorption is completed within 30 min and 45 min respectively, and excellent hydrogen storage thermal / dynamic performance is shown; after 100 times of hydrogen absorption and desorption cycles, the hydrogen storage capacity retention rate of the material is as high as 97%, and the material shows excellent cycle stability.

The invention discloses a flame-retardant ABS (Acrylonitrile Butadiene Styrene) composition as well as a preparation method and application thereof, and relates to the technical field of high polymer materials. The flame-retardant ABS composition provided by the invention comprises the following components in parts by mass: 50-80 parts of ABS resin; 8 to 12 parts of styrene-acrylonitrile copolymer; 3 to 5 parts of styrene-acrylonitrile-maleic anhydride terpolymer; 2 to 6 parts of a fluorine-containing maleimide copolymer; 5 to 15 parts of graphite nanosheet modified high rubber powder; 12 to 18 parts of brominated flame retardant; 3-7 parts of a phosphorus-based flame retardant; 0.1-1 part of a processing aid; the phosphorus-based flame retardant is prepared from the following components in parts by mass: 80 to 95 parts of diethyl phosphinate; 0.3 to 3 parts of ethyl butyl phosphinate; 0.1 to 2 parts of ethyl phosphonate; and 5 to 20 parts of melamine polyphosphate. The flame-retardant ABS composition prepared by the invention is good in flame retardant property, good in welding strength and low in cost.

The invention provides a self-repairing hydrated salt phase change microcapsule as well as a preparation method and application thereof, and belongs to the field of phase change materials. The preparation method comprises the following steps: preparing a hydrated salt phase change material and sorbitol into eutectic melt by adopting a melting method; strontium carbonate, sorbitol grafted nano titanium dioxide, SiO2-coated silicone rubber microspheres, hollow Al2O3 microspheres, tannic acid microcapsules, alpha-zirconium phosphate, melamine polyphosphate, diethyl aluminum hypophosphite, carboxylated multi-walled carbon nanotubes, polydopamine modified boron nitride nanosheets and hydrophilic fumed silica are added into the eutectic melt, and blending is performed to obtain a core material; The preparation method comprises the following steps: adding strontium carbonate, sorbitol grafted nano titanium dioxide, SiO2-coated silicone rubber microspheres, hollow Al2O3 microspheres, tannic acid microcapsules, alpha-zirconium phosphate, melamine polyphosphate, diethyl aluminum hypophosphite, carboxylated multi-walled carbon nanotubes, polydopamine modified boron nitride nanosheets and hydrophilic fumed silica into the eutectic melt; bio-based polyurethane-polyurea is used as a shell material, the core material is coated in the shell to prepare the microcapsule, and the temperature of the coating operation is not higher than the phase change temperature of the hydrated salt phase change material; the surface is coated with a super-hydrophobic coating. According to the invention, a solid filler system is constructed, and a low-temperature preparation process is combined, so that the phase-change microcapsule with high performance, high reliability and high safety is developed.

The invention relates to the technical field of flame-retardant materials, in particular to a halogen-free flame-retardant glass fiber modified polypropylene material and a preparation method thereof. The material comprises the following components in parts by mass: 60-80 parts of polypropylene, 15-30 parts of long glass fiber, 8-15 parts of a halogen-free intumescent flame retardant, 2-5 parts of a synergist, 3-8 parts of a compatilizer, 2-3 parts of an interface modifier, 2-4 parts of a dynamic cross-linking agent and 1-3 parts of a functional additive. According to the halogen-free flame-retardant glass fiber modified polypropylene material and the preparation method thereof, an intumescent halogen-free flame retardant melamine polyphosphate is compounded with organic montmorillonite, nano zinc borate and MXene, so that the flame-retardant efficiency is improved through a synergistic effect, and the release of smoke and toxic gas in a combustion process is inhibited; the halogen-free flame-retardant glass fiber modified polypropylene material has a good flame-retardant effect by introducing the halogen-free flame-retardant glass fiber, and maleic anhydride grafted polypropylene is introduced as a compatilizer to modify the surface of the long glass fiber and enhance the interface bonding force between the long glass fiber and a matrix.

The invention relates to the technical field of high polymer materials, in particular to a resin composite material with flame-retardant and insulating properties and a preparation method thereof. The problems that in the prior art, a resin composite material is poor in flame retardance and insufficient in insulating property are solved. The preparation method comprises the following steps: modifying epoxy resin with maleic anhydride and carboxyl modified nitrile rubber to obtain modified epoxy resin; a modified flame-retardant system is obtained by processing the carbon nanotube loaded melamine polyphosphate, the triphenyl phosphate and the magnesium hydroxide; the preparation method comprises the following steps: mixing modified epoxy resin and a modified flame-retardant system, adding modified nano silicon dioxide through a supercritical fluid technology and ultrasonic dispersion, and performing staged curing through a curing agent to obtain a resin composite material; the flame retardant property of the composite material is improved through the synergistic effect of the flame retardant and loading of the carbon nanotubes; and through the synergistic effect of the modified nano silicon dioxide and the carbon nanotubes, the insulating property of the composite material is improved.

The invention discloses a comb-type polyphosphate polymeric dispersant and a preparation method thereof, the dispersant is prepared by preparing a phosphate monomer from acrylate and phosphorus pentoxide, then copolymerizing the phosphate monomer with phenyl alkene or alkyl alkene, and finally adding alkali liquor for neutralization. A phosphate-polyether bifunctional side chain is introduced to a main chain, a phosphate group provides electrostatic repulsion, and a polyether group enhances steric hindrance, so that the dispersing agent can meet the requirements of strong adsorption and long-range stability at the same time, and a more durable and effective stabilizing effect is provided for a dispersion system.

The invention relates to the technical field of fireproof materials, and discloses a flame retardant for fireproof paint and a preparation method of the flame retardant. The flame retardant is prepared from modified aluminum polyphosphate, a borate-phosphate composite acid source, a silica modified carbon forming agent, chitosan modified nano carbon, melamine cyanurate, bicarbonate, graphene oxide, nano titanium dioxide and an interface reinforcing agent. Through the multi-stage catalysis of the composite acid source, the efficient charring of the modified charring agent, the multi-stage gas source release and the synergistic effect of the nano additive, a compact and uniform expansion layer is formed, and the high-temperature stability, the heat insulation performance and the thickness retention rate in a dynamic environment of the expansion layer are remarkably improved. According to the preparation method, by optimizing the steps of mixing, dispersing, drying and curing the components, the high-efficiency exertion of the performance of the flame retardant is ensured. The flame retardant is widely applicable to fireproof coatings for buildings, steel structures, wood and the like, has the characteristics of high expansion efficiency, lasting heat insulation and excellent mechanical properties, and effectively overcomes the defects in the prior art.

A lubricating oil composition is described. The composition includes a major amount of a base oil of lubricating viscosity and a polyphosphate-based dispersion. The dispersion includes an ammonium polyphosphate and a dispersing agent.

The method for preparing D-mannose through catalysis can effectively reduce the amount of by-products glucose and fructose, and greatly improves the conversion rate of D-mannose. Specifically, engineering bacteria for expressing isoamylase genes and engineering bacteria for expressing alpha-glucan phosphorylase genes, glucophosphate mutase genes, difunctional enzyme glucophosphate isomerase / mannose 6-phosphate isomerase genes and mannose 6-phosphate phosphatase genes are utilized, starch or starch derivatives are used as substrates, and the starch or starch derivatives are used as substrates. A phosphate buffer solution and Mg < 2 + > are added, a preliminary catalysis system is constructed, after the reaction is completed, an incompletely-reacted substrate and maltodisaccharide exist in the reaction system, the incompletely-reacted substrate and maltodisaccharide can be hydrolyzed into glucose by glucoamylase, and the polyphosphoglucokinase can be used for catalyzing the reaction of the polyphosphoglucokinase under the assistance of sodium hexametaphosphate. All glucose is converted into phosphorylated glucose, then D-mannose is generated, and by-products in a system are removed while the yield is increased.

A sheet molding compound (SMC) composition formulation including a curable resin, such as unsaturated polyester of vinyl ester, in an ethylenically unsaturated monomer; a low profile additive, in a curable solvent; and an intumescent additive, such as melamine polyphosphate or ethylene diamine phosphate. An article formed of the SMC composition formulation experiences no more than a 100% increase in thickness as compared to an initial thickness of the article after exposure to a flame. The low profile additive is present in the composition and the intumescent additive is present in the composition. The resulting article has a char strength at 3 mm thickness of between 100 and 1,000 Newtons.

The invention relates to the technical field of sewage treatment, in particular to a biological phosphorus removal method for wastewater by adopting anoxic starvation treatment. The method comprises the following steps: carrying out sludge domestication on a mixture of activated sludge and wastewater to be treated, and then carrying out anoxic starvation treatment; wherein the activated sludge contains fermentation type phosphorus-accumulating bacteria, the initial abundance of the fermentation type phosphorus-accumulating bacteria is 0.5%-1.5% before the sludge domestication, and a mixture of the activated sludge and to-be-treated wastewater is soaked in a solution containing nitrite nitrogen during the anoxic starvation treatment. According to the method, the abundance of the fermentation type phosphorus-accumulating bacteria is increased and proliferation of filamentous bacteria is inhibited through anoxic starvation treatment, so that sludge bulking is effectively inhibited, and the high-abundance fermentation type phosphorus-accumulating bacteria can promote the performance of a biological phosphorus removal system and improve the sewage treatment effect.

The invention relates to the field of biomedical materials, in particular to a nasal cavity hemostatic sponge and a preparation method thereof. According to the preparation method of the nasal cavity hemostatic sponge provided by the invention, the hyaluronic acid is grafted and modified by using the amino alcohol, and the gelatin is modified by using the hydrazide; dissolving the oxidized hyaluronate grafted and modified by amino alcohol in a buffer solution, and adding a calcium ion donor to form a first solution; dissolving hydrazide modified gelatin in a buffer solution, and adding polyphosphate to form a second solution; the first solution and the second solution are mixed to react to form hydrogel, and the hemostatic sponge is obtained after the formed hydrogel is subjected to a low-temperature gel freezing process. The nasal cavity hemostatic sponge prepared by the invention can effectively stop bleeding, and has excellent wet adhesion property, mechanical property and biocompatibility.

This application relates to the field of metal surface treatment materials, specifically disclosing a silicon-integrated inorganic supercrystalline thermal energy powder and its preparation and application methods. The silicon-integrated inorganic supercrystalline thermal energy powder comprises raw material A and raw material B. Raw material A includes the following: magnesium oxide, sodium fluoroaluminate, sodium polyphosphate, zinc oxide, crystalline tin tetrachloride, silicon dioxide, and boric acid. Raw material B includes the following raw materials in parts by weight: spodumene, lithium carbonate, titanium dioxide, zinc silicate, sodium carbonate, antimony trioxide, albite, fluorite, boric acid, sodium hydroxide, and yttrium oxide. The inorganic supercrystalline thermal energy powder of this application has advantages such as corrosion resistance and oxidation resistance, good thermal stability, no damage from thermal cycling, high hardness, wear resistance and high temperature resistance, energy saving, water scale reduction, and the ability to replace organosilicon high-temperature resistant special coatings, baking paints, enamel paints, and ceramic floor glazes.

The invention belongs to the technical field of polymer additives, and provides an additive composition and application thereof, the additive composition comprises the following components by mass: 65-84 parts of aluminum diethylphosphinate, 7-16 parts of melamine polyphosphate, 7.5-16 parts of a flame retardant synergist, and 0.1-1 part of aluminum alkyl phosphite; the mass percentage content of water in the additive composition is 0.4%-0.6%. Through design and mutual cooperation of the components and control of the water content, the additive composition has excellent flame retardance, stability and precipitation resistance. The additive composition is used for flame retardance of a polymer system, especially enables the polyamide composition containing the additive composition to have excellent flame retardance, flame retardance stability and high-temperature and high-humidity resistance, still keeps excellent flame retardance after high-temperature and high-humidity aging, inhibits or avoids the problem of additive precipitation, and is suitable for industrial production. The comprehensive performance of the flame-retardant polyamide is greatly improved.

The invention relates to a flame-retardant polypropylene wire rod and a preparation method and application thereof, the flame-retardant polypropylene wire rod has a core-shell structure, and the shell structure comprises polypropylene, MCA, tetrapod-like zinc oxide, an antioxidant and a lubricant; the core layer structure is prepared from polypropylene, piperazine pyrophosphate, melamine polyphosphate, tetrapod-like zinc oxide, an antioxidant and a lubricant. According to the invention, by controlling the type and content of the flame retardant in the shell layer of the wire rod, the interlayer binding force is not influenced during high-temperature fused deposition printing, a workpiece with relatively high mechanical property can be prepared, and the core layer material of the wire rod has relatively high flame retardant property, so that the prepared workpiece has relatively good flame retardant property. The preparation method of the flame-retardant polypropylene wire rod is simple, electronic and electric appliance structural parts which are complex in structure, difficult to design mold parting surface injection molding, high in mechanical property requirement and high in flame retardant property requirement can be prepared through 3D printing forming, and the flame-retardant polypropylene wire rod has wide application prospects.

The invention belongs to the technical field of preparation of phosphorus removal agents, and particularly relates to a composite phosphorus removal agent and a preparation method and application thereof. The composite phosphorus removal agent comprises a honeycomb carrier and microspheres, the microspheres are loaded on the honeycomb carrier; the microspheres are prepared from the following raw materials: polyvinylidene fluoride particles, graphene oxide, ZrOCl2 and phosphorus-accumulating bacteria. The composite phosphorus removal agent comprises a honeycomb carrier, microspheres and microcapsules, wherein the microspheres and the microcapsules are loaded on the honeycomb carrier; capturing phosphate radicals in a water body by the microspheres and carrying out biological phosphorus removal and adsorption phosphorus removal; the honeycomb carrier also has the effect of adsorbing phosphate; and the two synergistically remove phosphate in the water body, so that the phosphorus removal effect of the phosphorus removal agent is improved, and the burden of the water body is not increased.

This invention discloses a gypsum-based lightweight flame-retardant board and its preparation method, relating to the field of building materials technology. The gypsum-based lightweight flame-retardant board prepared by this invention is made by foaming a gypsum substrate with a foaming agent and a composite stabilizer, then introducing a self-made flame retardant and other raw materials, casting it between two layers of facing paper, and drying it. The composite stabilizer includes a modified acrylamide copolymer and acrylamide hydrogel. The modified acrylamide copolymer is obtained by copolymerizing N-isopropylacrylamide with silane acrylic acid and then reacting it with hyperbranched polyphosphate. The acrylamide hydrogel is obtained by polymerizing acrylic acid and acrylamide through an aqueous solution. The self-made flame retardant is obtained by reacting ammonium polyphosphate with a hydroxy heterocyclic amino alcohol. The hydroxy heterocyclic amino alcohol is obtained by reacting a heterocyclic amino alcohol with a double-terminated hydroxyl polyphenylene ether. This process gives the gypsum-based lightweight flame-retardant board excellent flame retardancy, mechanical properties, and flame-retardant stability.

The invention relates to high-elasticity high-adhesive-force UV curing flexible printing ink and a preparation method thereof, and relates to the technical field of printing ink, the high-elasticity high-adhesive-force UV curing flexible printing ink comprises aliphatic polyurethane acrylate, a polyphosphate acrylate oligomer, core-shell structure polyurethane-acrylate microspheres, hexanediol diacrylate, isobornyl acrylate, a photoinitiator and a pigment, and a functional auxiliary agent. The polyphosphate acrylate oligomer realizes strong anchoring of a base material through a phosphate group, and meanwhile, a flexible chain segment of the polyphosphate acrylate oligomer interacts with the aliphatic polyurethane acrylate resin to form a continuous phase; the acrylate shells of the core-shell structure microspheres are covalently bonded with the matrix resin, and the elastic cores of the core-shell structure microspheres are uniformly dispersed in the resin as stress dissipation units. Through the synergistic effect, firm adhesion of a cured film layer can be achieved through interface chemical bonds, stress can be effectively dispersed through deformation of the microspheres when the cured film layer is subjected to external force, and therefore excellent adhesive force and outstanding flexibility are obtained.

The invention relates to the technical field of photo-anodes, in particular to a composite photo-anode with transition metal ions embedded into phosphoric acid small organic molecules and a preparation method of the composite photo-anode. The preparation method comprises the following steps: S1, soaking a bismuth vanadate photo-anode in a phosphoric acid small organic molecule solution, and then performing annealing treatment to obtain a phosphoric acid small organic molecule / photo-anode; and S2, soaking the phosphoric acid small organic molecule / photo-anode in a transition metal salt solution to obtain the composite photo-anode. According to the invention, hole storage and transmission functions of polyphosphoric acid small organic molecules and surface rapid water oxidation reaction kinetics of metal ions are synergistically utilized, on one hand, the electron-hole separation efficiency of bismuth vanadate is improved through hole storage, and on the other hand, surface hydroxyl groups of the polyphosphoric acid small organic molecules and transition metal ions are anchored; bismuth vanadate surface electron-hole separation and water oxidation kinetics are synergistically enhanced, charge recombination is synergistically inhibited, charge transfer power is promoted, and the photocurrent density and the water decomposition hydrogen production capacity of the photoanode are improved.

The invention provides an electrolyte additive for synergistically regulating and controlling activity and stability of an all-vanadium redox flow battery and application of the electrolyte additive, the electrolyte additive is a composite additive of an organic amino acid compound and inorganic phosphate, the organic amino acid compound is one of aspartic acid, glycine and cysteine, and the inorganic phosphate is one of amino acid, glycine and cysteine. The inorganic phosphate is one or two or more of phosphate, dihydric phosphate, dihydric phosphate, polyphosphate and pyrophosphate, and cations of the inorganic phosphate are one or two or more of potassium, sodium and ammonium salt. The composite additive is used as an electrolyte additive to be added into an all-vanadium redox flow battery electrolyte, so that the vanadium electrolyte can be effectively prevented from generating precipitates at high temperature, the capacity fading in the battery operation process is avoided, and the stable operation of the battery is realized. The preparation process is simple to operate, energy-saving, environment-friendly and low in cost, and stable operation of the electrolyte in the battery can be realized.

The invention belongs to the technical field of polyurethane thermal insulation materials, and particularly relates to a high-flame-retardant polyurethane thermal insulation material and a preparation method thereof. The polyurethane thermal insulation material is prepared from the following raw materials in parts by weight: 20-25 parts of polyisocyanate; 15 to 20 parts of polyol; 2-4 parts of a foaming agent; 0.6 to 0.8 part of a foam stabilizer; 0.3 to 0.5 part of a catalyst; 2-3 parts of a modified additive; through the synergistic effect of polyphosphate-diol containing a polyphosphate group and a nitrogen element and the modified additive containing a polyphosphate group, a nitrogen element and a silicon element, the multiple flame-retardant effect is achieved, and the polyurethane thermal insulation material with high flame-retardant property is obtained; the prepared polyurethane thermal insulation material also has good dimensional stability, thermal insulation performance and strength, and can better meet market requirements.

The invention relates to the field of chemical synthesis, in particular to a preparation method of chlorinated alkyl polyphosphate, which comprises the following steps: mixing diethylene glycol and gamma-valerolactone, slowly adding phosphorus oxychloride, and reacting at 20-50 DEG C to generate a reaction solution containing an intermediate; adding gamma-valerolactone and an IL (at) MOFs-P catalyst into the reaction solution, slowly adding epoxypropane, and reacting at 130-150 DEG C in a nitrogen atmosphere to generate a target product mixed solution; and recovering gamma-valerolactone through distillation, centrifugally separating the catalyst, regenerating and recycling, and purifying a crude product to obtain a final product. The green solvent gamma-valerolactone is adopted and recycled, the IL-coated MOFs-P catalyst is high in activity and can be recycled, side reactions are reduced by accurately controlling reaction conditions, the product yield reaches 90% or above, the purity exceeds 98%, and the method has the advantages of being green, environmentally friendly, economical and efficient.

The invention relates to the technical field of flame-retardant high polymer materials, in particular to a high-temperature-resistant and high-humidity-resistant flame-retardant polypropylene composite material and a preparation method thereof. The invention provides a high-temperature-resistant and high-humidity-resistant flame-retardant polypropylene composite material. The high-temperature-resistant and high-humidity-resistant flame-retardant polypropylene composite material consists of polypropylene, a mixed silane modified intumescent flame retardant, a flame-retardant aid NOR 116 and a compatilizer According to the invention, bis [3-(trimethoxysilyl) propyl] amine / triacetoxyvinyl silane is mixed to modify an intumescent flame retardant, which is composed of piperazine pyrophosphate as a main flame retardant and melamine polyphosphate, aluminum hypophosphite or aluminum diethylphosphinate as a secondary flame retardant; a plurality of active silicon hydroxyl sites after silane hydrolysis are mixed, and single flame retardants are connected together to form a macromolecular intumescent flame retardant, so that the modified intumescent flame retardant is still difficult to migrate or separate out from a polypropylene matrix even under high-temperature and high-humidity conditions, and the weather resistance of flame-retardant polypropylene is greatly improved.

The invention provides a PVC (polyvinyl chloride) plate for a refrigerator back plate, which is prepared from the following raw materials: 50 to 75 parts of PVC resin, 5 to 20 parts of chlorinated polyvinyl chloride, 5 to 15 parts of phosphorus-nitrogen flame retardant, 5 to 20 parts of inorganic flame retardant, 3 to 10 parts of mica powder, 3 to 10 parts of plasticizer, 0.2 to 3 parts of heat stabilizer, 0.2 to 3 parts of lubricant, 0.2 to 3 parts of coupling agent, 0.3 to 3 parts of nucleating agent, 0.5 to 1 part of antioxidant and 2 to 10 parts of processing aid. The phosphorus-nitrogen flame retardant is one or a combination of melamine polyphosphate, ammonium polyphosphate and phosphazene flame retardants; the inorganic flame retardant is one or a combination of aluminum hydroxide, magnesium hydroxide and antimony trioxide. The composition of the flame retardant in the PVC board is regulated and controlled, and the flame retardant property of the refrigerator back board can be greatly improved by compounding the phosphorus-nitrogen intumescent flame retardant and the inorganic flame retardant, so that the flame retardant property of the refrigerator back board reaches the 5VA grade and meets the industrial standard.

The invention discloses a water-based metal anticorrosive paint and a preparation method thereof, and belongs to the technical field of water-based paints. The hyperbranched polyphosphate and the water-based alkyd resin can be subjected to a cross-linking reaction to form a compact network structure, the hyperbranched polyphosphate and a metal interface also have good bonding performance, the adhesiveness of a coating is improved, the water-based alkyd resin has good flexibility, the integrity of the coating is kept, and the water-based alkyd resin has good adhesion to the metal interface. Corrosion media are prevented from permeating, and the purpose of protecting metal for a long time is achieved; by adding the glass flakes, a complex and zigzag path can be formed in the coating, corrosion media are further prevented from permeating into metal, and therefore the corrosion resistance of the coating is improved; the organosilane-modified nano cerium oxide particles can be directionally distributed in the coating, oxygen diffusion is blocked, a rare earth conversion film can be formed on the surface of a metal base material, and a stable passivation layer is generated through hydrolysis, so that electrochemical corrosion is inhibited.