852 results about "ALUMINUM PHOSPHATE" patented technology

The invention belongs to the technical field of battery materials, and particularly relates to a method for preparing a porous carbon structure containing a sub-nanoscale ionic conduction improvement layer by utilizing atomic layer deposition and application. The invention discloses a porous carbon-silicon negative electrode structure, which is characterized in that a sub-nano-scale ion conduction improvement layer is added between a porous carbon substrate and silicon particles, and the sub-nano-scale ion conduction improvement layer comprises silicon carbide, aluminum phosphide, aluminum nitride, aluminum oxide, lithium phosphate, aluminum phosphate and lithium aluminum phosphate. Meanwhile, the invention also discloses a preparation method of the porous carbon-silicon negative electrode structure, namely, a sub-nano-scale ion conduction improvement layer is deposited on the porous carbon substrate through an atomic layer deposition method, so that the binding force between the sub-nano-scale ion conduction improvement layer and silicon particles and an ion transport channel are increased, and the ion conduction of a vapor deposition silicon-carbon negative electrode material is improved; the polarization of the material is effectively reduced, so that the rate capability of the battery is improved, and the cycling stability of the porous carbon structure battery is improved.

The invention relates to the field of lithium ion batteries, and discloses a positive electrode lithium supplement additive, a preparation method thereof, a positive plate and a lithium ion battery. The lithium supplement additive for the positive electrode comprises a lithium-containing compound, and a first coating layer and a second coating layer which sequentially coat the surface of the lithium-containing compound, wherein the first coating layer comprises at least one of lithium aluminum titanium phosphate, lithium lanthanum zirconium oxide and lithium lanthanum titanium oxide; the second coating layer includes at least one of a Ga-containing compound, a Sm-containing compound, a Si-containing compound, an Al-containing compound, a V-containing compound, a Nb-containing compound, a Mg-containing compound, a Zr-containing compound, and a Zn-containing compound. The first coating layer improves the stability in the processing process, prevents side reaction, ensures the structural stability of the positive electrode lithium supplement additive, and improves the cycle performance of the battery; and the second coating layer provides an effective smooth channel for lithium ions, so that the impedance of the battery can be effectively reduced, and the capacity and the cycle performance of the battery are improved.

The invention discloses an ablation-resistant long-fiber reinforced nylon material for a battery pack, and relates to the technical field of nylon materials, the ablation-resistant long-fiber reinforced nylon material comprises the following raw material components by weight: 60-80 parts of nylon resin powder, 30-50 parts of a long-fiber reinforced material, 10-18 parts of aluminum diethylhypophosphite master batch, 8-15 parts of bromine-antimony composite master batch, 3-7 parts of montmorillonite, 12-20 parts of aluminum hydroxide, and 2-6 parts of nano-silica. The composite material is prepared from the following components in parts by weight: 1-4 parts of carbon nanotubes, 0.5-1.2 parts of an antioxidant I, 0.3-0.8 part of a lubricant I, 2-5 parts of a compatilizer, 0.1-0.4 part of a nucleating agent and 0.2-0.6 part of an anti-ultraviolet agent. By adding the diethyl aluminum hypophosphite master batch, the flame retardant property of the nylon material is improved, the processability of the nylon material is improved, the ablation resistance of the nylon material is improved, and the problems of insufficient flame retardant property, poor processability and poor ablation resistance of the nylon material can be solved.

The invention provides a nano-carbon composite titanium aluminum lithium phosphate conductive functional material and a preparation process and application thereof, and the process adopts a mode of adding synthetic components step by step, so that the reaction is performed according to preset selectivity; according to the method, the mixing uniformity is improved, the reaction rate is controlled, the utilization rate of raw materials is improved, large-scale production and application can be achieved without complex process control, and the nanocrystallized lithium titanium aluminum phosphate conductive functional material of the in-situ composite carbon layer is synthesized under inert gas, so that the nanocrystallized lithium titanium aluminum phosphate conductive functional material is not limited to the range of being independently used as a solid electrolyte; carbon composite nanocrystallization modification endows electronic insulation titanium aluminum lithium phosphate with high electronic conductivity, the prepared nanocarbon composite titanium aluminum lithium phosphate conductive functional material and slurry thereof can be used as a modified material of a lithium ion battery and a solid or semi-solid battery electrode material, surface activity of the electrode material is passivated, side reaction of a battery material interface is reduced, and the service life of the battery is prolonged. Structural degeneration of the material in circulation is slowed down, and the overall safety of the lithium ion battery is enhanced.

The invention discloses an energy-saving and environment-friendly polyarylate fabric whole-core flame-retardant conveying belt and a manufacturing method thereof. The energy-saving and environment-friendly polyarylate fabric whole-core flame-retardant conveying belt comprises a polyarylate fabric whole belt core, a covering layer and a belt core dipping sizing material, the covering layer comprises the following components: solution polymerized styrene-butadiene rubber, a styrene-butadiene-styrene block copolymer, a thermoplastic polyurethane elastomer, zinc oxide, stearic acid, sulfur, an accelerant, an anti-aging agent, carbon black, a hybrid flame-retardant composite material, a phosphate flame retardant, paraffin oil and an antistatic agent; the covering layer of the energy-saving and environment-friendly polyarylate fabric whole-core flame-retardant conveying belt prepared by the invention is compounded from white carbon black, expanded graphite, diethyl aluminum hypophosphite and dimethyl imidazole zinc, and is subjected to surface treatment through polyacrylamide; and then the styrene-butadiene-styrene block copolymer is used for carrying out macromolecular modification on the hybrid flame-retardant composite material, so that the prepared conveyor belt has excellent flame-retardant and antistatic properties, environment-friendly properties, low rolling resistance and mechanical properties.

The invention discloses a preparation method of a nanoscale lithium aluminum titanium phosphate solid electrolyte, which comprises the following steps: mixing a phosphorus source and a titanium source by using a liquid phase method to react, obtaining a precursor 1 after the reaction is completed under the conditions that the reaction temperature is 25-180 DEG C and the pH value of a reaction system is 0-2, then adding a lithium source and an aluminum source, and preparing a precursor 2 by using a liquid phase reaction, and finally, washing and drying, and carrying out heat treatment to prepare the nano-scale lithium aluminum titanium phosphate solid electrolyte. According to the method, the reaction temperature and the pH value of a reaction system in the process of preparing the precursor 1 are controlled, so that the particle size level of the product is controlled, the introduction of a rear-end crushing process is avoided, the technological process is shortened, and the production period is shortened.

The invention discloses a wear-resistant and mildew-proof ceramic tile which comprises a green body and a glaze layer attached to the green body, and the wear-resistant and mildew-proof ceramic tile is obtained by coating the surface of the green body with a modified interface agent and then glazing, wherein the glaze layer is prepared from the following raw materials in parts by weight: 40 to 50 parts of silicon dioxide, 30 to 35 parts of aluminum oxide, 15 to 20 parts of modified titanium dioxide, 6 to 10 parts of barium carbonate, 6 to 10 parts of mullite, 5 to 8 parts of silver-loaded zirconium phosphate, 4 to 8 parts of potassium carbonate, 4 to 8 parts of sodium carbonate, 3 to 7 parts of limestone, 3 to 5 parts of sodium borate, 2 to 4 parts of zinc oxide and 0.5 to 1 part of sodium tripolyphosphate. According to the ceramic tile, the modified interface agent with specific composition is introduced between the ceramic tile green body and the glaze layer, modified titanium dioxide and inorganic components (such as aluminum phosphate, aluminum acetylacetonate and tetrapropyl zirconate) in the interface agent form oxides in the sintering process, and the interface bonding strength is remarkably enhanced through physical occlusion; and the long-term wear resistance and mildew resistance of the ceramic tile glaze layer are improved.

The invention discloses a flame retardant with a double-layer microcapsule structure, a flame-retardant polyurethane material as well as a preparation method and application of the flame-retardant polyurethane material, and belongs to the technical field of flame retardants. The material is a multifunctional flame retardant with a double-layer core-shell structure, a shell layer is calixarene boric acid resin, a middle shell layer is melamine phthalic anhydride resin, and a core layer is hydroxyapatite modified aluminum hypophosphite. Due to the high cross-linking degree between polymers, the flame retardance of polyurethane is improved, meanwhile, the mechanical property of the polyurethane is improved, and the flame retardance and seawater corrosion resistance of the material are synergistically enhanced through hydroxyapatite dispersed in the core layer. The double-shell layer has excellent hydrophobicity, prevents internal aluminum hypophosphite from being affected with damp and has anti-fouling and self-cleaning effects, and the prepared flame-retardant polyurethane composite material has excellent tensile and flexible characteristics due to a double network of hydrogen bonds and covalent bonds.

The invention discloses a molecular sieve BUCT-10 with a novel topological structure and a unique X-ray powder diffraction characteristic, the molecular sieve BUCT-10 has a one-dimensional ten-membered ring straight pore channel, and can be synthesized in an aluminum phosphate (AlPO), silicoaluminophosphate (SAPO), metal aluminum phosphate (MeAPO) and metal silicoaluminophosphate (MeSAPO) system by taking an alkyl (C1-C5) quaternary ammonium or amine compound as a template agent, and after the template agent is removed through high-temperature calcination, the molecular sieve BUCT-10 can be prepared into the molecular sieve BUCT-10 with the novel topological structure and the unique X-ray powder diffraction characteristic. The structure is stable, and the material can be used as a catalyst, a catalyst carrier or an adsorption separation material.

The flame-retardant ABS composition is prepared from the following components in parts by weight: 70 to 80 parts of ABS resin; 16 to 20 parts of brominated flame retardant; 3-5 parts of an aluminum phosphate flame retardant; and 1-2 parts of a guanidine phosphate flame retardant. Through compounding of the brominated flame retardant, the aluminum phosphate flame retardant and the guanidine phosphate flame retardant, 1.5 mmV-0 flame retardance can be achieved on the premise that antimony trioxide is not added, and the flame retardant has the advantages of being high in melt fluidity, low in density and good in toughness and is suitable for preparing light-weight vehicle-mounted parts.

The invention discloses a titanium lithium aluminum phosphate solid electrolyte polymer interface modification method and a preparation method thereof. The method comprises the following steps: firstly, selecting LITFSI (lithium ion conductor), PVDF-HFP (polyvinylidene fluoride-hexafluoropropylene) and DMSO (dimethyl sulfoxide) liquid, and mixing to form PVDF-HFP-based polymer mixed liquid; then, the PAN film doped with titanium lithium aluminum phosphate powder is uniformly coated with the mixed solution through a press coating method, and the PVDF-HFPPAN film is obtained through drying treatment. And cutting the membrane, placing the cut membrane on two sides of a ceramic chip solid electrolyte, assembling an all-solid-state battery, activating at 40-80 DEG C until the polymer is attached to a metal lithium negative electrode and the surface of the solid electrolyte in a gel state, and cooling to finally obtain the solid electrolyte with a PVDF-HFPPAN coated LATP coated PVDF-HFPPAN sandwich structure. The modified solid-state electrolyte membrane can effectively inhibit the interface reaction of LATP on the lithium negative electrode side and enhance the wettability of the positive and negative electrode interface, thereby meeting the cycle performance requirement of the solid-state battery under the normal temperature condition.

The invention relates to the technical field of fireproof materials, and discloses a flame retardant for fireproof paint and a preparation method of the flame retardant. The flame retardant is prepared from modified aluminum polyphosphate, a borate-phosphate composite acid source, a silica modified carbon forming agent, chitosan modified nano carbon, melamine cyanurate, bicarbonate, graphene oxide, nano titanium dioxide and an interface reinforcing agent. Through the multi-stage catalysis of the composite acid source, the efficient charring of the modified charring agent, the multi-stage gas source release and the synergistic effect of the nano additive, a compact and uniform expansion layer is formed, and the high-temperature stability, the heat insulation performance and the thickness retention rate in a dynamic environment of the expansion layer are remarkably improved. According to the preparation method, by optimizing the steps of mixing, dispersing, drying and curing the components, the high-efficiency exertion of the performance of the flame retardant is ensured. The flame retardant is widely applicable to fireproof coatings for buildings, steel structures, wood and the like, has the characteristics of high expansion efficiency, lasting heat insulation and excellent mechanical properties, and effectively overcomes the defects in the prior art.

The invention discloses a plastic refractory for repairing a furnace lining of an intermediate frequency furnace and a preparation method thereof, and belongs to the technical field of refractory materials for intermediate frequency furnaces. The plastic refractory comprises the following components in percentage: 20%-30% of alumina, 35%-45% of mullite, 5%-15% of kyanite, 5%-10% of a plasticizer, 3%-7% of glucose, 2%-5% of silicon nitride and 10%-15% of modified aluminum polyphosphate. Wherein the modified aluminum polyphosphate is prepared by the following method: reacting aluminum polyphosphate, silica powder, polyvinyl alcohol and water at 180-220 DEG C, and cooling to room temperature to obtain the modified aluminum polyphosphate. The plastic refractory for repairing the furnace lining of the intermediate frequency furnace is low in manufacturing cost, has excellent adhesive property, high temperature resistance and thermal shock resistance, further has the advantages of long service life, long storage time and the like, and solves the problems of poor adhesive property, short service life, short storage time and the like of the plastic refractory in the prior art.

The present invention provides a high temperature resistant inorganic glue, a preparation method, an application and a method for limiting the drift of CVD seed crystals. The high temperature resistant inorganic glue comprises: 100 to 400 parts by weight of aluminum silicate; 50 to 200 parts by weight of aluminum phosphate; 50 to 400 parts by weight of copper oxide-copper-titanium-diamond composite material or copper oxide-titanium-diamond composite material; 50 to 200 parts by weight of phosphoric acid; and 100 to 400 parts by weight of a dispersant. The method for limiting the drift of CVD diamond seed crystals is to apply a high temperature resistant inorganic glue on the bottom of the CVD diamond seed crystal before the chemical vapor deposition growth of the CVD diamond seed crystal, press it flat on a molybdenum sheet and solidify it. The high temperature resistant inorganic glue of the present invention can withstand temperatures above 1200°C and is easy to glue and remove; the CVD diamond seed crystal is bonded to the molybdenum sheet by the high temperature resistant inorganic glue, and the seed crystal drift is limited during chemical vapor deposition growth.

The invention belongs to the field of material protection, and particularly relates to a method for improving spraying efficiency and adhesive force by adding a binder in the plasma spraying process. The binder comprises one or more of bentonite, silicon dioxide, borax, sodium silicate and aluminum phosphate. The device has the function of quickly melting spraying particles at high temperature and adhering the spraying particles to a spraying substrate, so that the powder spraying efficiency is improved, and the production efficiency is improved. The method comprises the following steps: firstly, carrying out sand blasting treatment on a spraying base material, removing dust and impurities on the surface to enable the roughness to reach 8-10 microns, weighing, and measuring the surface area to be sprayed; and then weighing the binder and putting the binder into a drying oven to be dried at 120 DEG C; the method comprises the following steps: uniformly mixing a binder and an analytically pure nano spraying material according to a certain proportion, and pouring into a plasma spraying raw material tank; and spraying is carried out at the position with the voltage of 30-50 V, the current of 300-600 A, the air pressure of 8 Mpa and the distance of 80-120 mm. The spraying time is 3-5 min, and after spraying is completed, the powder spraying amount is calculated by weighing the mass difference of the base material before and after the base material is weighed. And by adding the binder, the powdering rate is increased from 30.79% to 51.24%, the consumption of spraying materials is greatly reduced, and the working efficiency is improved.

The invention relates to the field of solid-liquid waste separation devices, in particular to a solid-liquid waste separation device for aluminum triphosphate production, which comprises a separation component, two support plates arranged on a plate-and-frame filter press, a plurality of filter plates arranged on the support plates, and a pair of extension plates arranged on the filter plates, the first electric sliding rail is arranged on the supporting plate, the switching block is arranged on the first electric sliding rail, and the plate pulling device is arranged on the switching block; the vibration component comprises a lifting assembly arranged on the plate pulling device, a guide assembly arranged on the plate pulling device, a one-way assembly arranged on the guide assembly, an impact assembly arranged on the plate pulling device and a transmission assembly arranged on the guide assembly; according to the multi-directional vibration filter plate, through multi-directional vibration, material cakes are prevented from being adhered to the filter plate, and waste of the material cakes during washing is avoided.

The invention relates to the field of waterproof coatings, and discloses a tunnel macromolecular self-cleaning special waterproof coating which comprises polyurethane resin, epoxy resin, fluorosilicone resin, titanium dioxide nanoparticles, zinc oxide nanoparticles, aluminum triphosphate, silicon dioxide nanoparticles, aluminum oxide microparticles, graphene nanosheets, a flexibilizer, a curing accelerator and a solvent. According to the coating, collaborative optimization of functions of all layers is achieved through a multi-layer composite structure, the bottom layer waterproof layer provides efficient waterproofness and weather resistance, the middle reinforcing layer greatly improves the mechanical strength and wear resistance of the coating, the surface layer self-cleaning layer adopts a fluorosilicone resin matrix and introduces super-hydrophobic nano-particles, the surface is endowed with an excellent self-cleaning function, and the self-cleaning effect is good. Dirt adhesion is prevented; and automatic cleaning is facilitated. The coating effectively solves the common problems of leakage, pollution accumulation, abrasion and peeling in a tunnel environment, the protection performance of a coating is remarkably improved, the service life of the coating is remarkably prolonged, and an efficient and lasting protection solution is provided for building structures such as tunnels and subways.

The invention relates to the field of battery electrode materials, in particular to a doped lithium aluminum titanium phosphate solid electrolyte material, a preparation method and a lithium ion battery containing the doped lithium aluminum titanium phosphate solid electrolyte material. The chemical composition of the doped solid electrolyte material is Li1 + zMyAlxTi2-x-yP3O12-bFa, wherein x is greater than or equal to 0 and less than or equal to 0.4, a is greater than or equal to 0 and less than or equal to 0.8, and b is greater than or equal to 0 and less than or equal to 0.8. Z is less than or equal to 0.8, and M is one or more of Zn, Mg, Ca, Sr, Si and Sn. Raw materials containing doping elements are added in the process of preparing lithium titanium aluminum phosphate (LATP), doping type lithium titanium aluminum phosphate is synthesized through calcination, then crushing and smashing are conducted, and the solid electrolyte material with high conductivity and particle density is obtained. According to the solid electrolyte material, the ionic conductivity and the particle density are improved, and the requirements of the market for high ionic conductivity and high particle density are met; the preparation method and modification steps are simple, the period is short, and the method is suitable for industrial large-scale production.

The invention discloses a modified current collector and a preparation method thereof, a positive plate and a negative-electrode-free sodium ion battery, and relates to the technical field of sodium ion batteries. The aluminum oxide and the solid electrolyte sodium titanium aluminum phosphate grow on the aluminum metal three-dimensional substrate in situ, so that a higher ion conduction rate can be provided, the injection amount of the electrolyte can be reduced, the growth of dendritic crystals can be reduced, and the safety performance of the battery can be improved. The solid electrolyte (sodium aluminum titanium phosphate) and the artificial SEI film (sodium carbonate / sodium fluoride) are formed on the surface of the three-dimensional current collector, so that the deposition of sodium metal in a three-dimensional substrate is facilitated, and sodium dendrites can be prevented from growing on the surface of the current collector so as to prevent the diaphragm from being punctured. The solid electrolyte, the artificial SEI membrane and the cathode-free metal battery are used together, so that the effects of reducing the cost, prolonging the cycle life and improving the battery capacity density and safety are achieved.

The invention discloses a waterborne epoxy coating for heavy corrosion prevention and a preparation method of the waterborne epoxy coating, and relates to the technical field of coatings. The waterborne epoxy resin, the waterborne epoxy curing agent, the titanium dioxide, the barium sulfate, the superfine talcum powder, the mica powder, the zinc phosphate, the aluminum tripolyphosphate, the superfine mica iron oxide, the glass flakes and the like are used as raw materials for preparing the epoxy coating. Meanwhile, the sheet structures of the superfine mica iron oxide and the glass flakes prolong the time for water and a corrosive medium to reach the surface of the base material, and sufficient dissociation time is given to phosphate. The anticorrosive paint disclosed by the invention has good flexibility and corrosion resistance.

The invention provides a trichoderma maple fungicide, a microbial granular fertilizer as well as a preparation method and application of the trichoderma maple fungicide and the microbial granular fertilizer, and relates to the field of microorganisms. The acer rubrum fungicide contains acer rubrum RA with the preservation number of CGMCC No.35889. The acer rubrum fungicide has the capability of decomposing inorganic phosphorus, is wide in phosphorus dissolving range, can decompose tricalcium phosphate, ferric phosphate and aluminum phosphate, and particularly still has the very strong capability of decomposing the inorganic phosphorus under the low-temperature condition; the strain has the capability of producing siderophore and IAA at low temperature; the strain has an inhibition effect on various pathogenic bacteria causing field crop diseases. The microbial granular fertilizer provided by the invention contains various biostimulant substances, can promote crop growth, improve plant stress resistance and improve plant resistance to plant diseases and insect pests, and field tests prove that the microbial granular fertilizer can significantly promote crop growth and improve crop yield.

The invention provides a moniliella malayi and a fungicide and application thereof, and relates to the field of microorganisms. The acer rubrum is specifically acer rubrum RA, and the preservation number of the acer rubrum RA is CGMCC (China General Microbiological Culture Collection Center) No.35889. The acer rubrum RA can be used for preparing the acer rubrum. The strain has the capability of decomposing inorganic phosphorus, is wide in phosphorus-dissolving range, can decompose tricalcium phosphate, iron phosphate and aluminum phosphate, and particularly still has very strong capability of decomposing inorganic phosphorus under a low-temperature condition; the strain has the capability of producing siderophore and IAA at low temperature; the strain has an inhibition effect on various pathogenic bacteria causing field crop diseases, and can inhibit diseases such as corn root rot, sorghum leaf spot or wheat root rot; the strain can be colonized in a soil environment of 5-40 DEG C, a microbial inoculum prepared from the strain can promote crop growth, the crop yield is remarkably improved, and high yield can be achieved even if the usage amount of phosphate fertilizer is reduced.

The present invention relates to the field of the preparation of polyurethane elastic fibers, and relates to a preparation method for a bio-based polyurethane elastic fiber, comprising: preparing polyether polyol from sucrose, glycerol, dimethylamine and propylene oxide; adding a solvent, i.e., N,N-dimethylacetamide, and polyether polyol and polyisocyanate into a reaction tank, and adding p-Toluenesulfonyl semicarbazide and aluminum methylenebis(2,4-di-tert-butylphenoxy) phosphate to prepare a spinning solution; and subjecting the spinning solution to spinning and oil application by means of dry spinning technology to obtain the bio-based polyurethane elastic fiber. The present invention ensures that the properties of polyurethane elastic fibers do not deteriorate or are partially enhanced, while the cost and performance advantages are achieved.

The invention provides a vanadium aluminum phosphate electrode material and a preparation method thereof. In target product components, an aluminum source, a vanadium source and a phosphorus source are respectively aluminum nitrate or other aluminum sources, vanadium pentoxide or ammonium vanadate, ammonium dihydrogen phosphate, phosphoric acid or other phosphorus sources, and a nitrogen source of nitrogen-doped carbon is from polyvinylpyrrolidone or other nitrogen sources of a gel component; the carbon source is selected from polyvinyl alcohol and glycerol. By adopting an exogenous plasticizing physical crosslinking sol-gel method, in the whole reaction system, uniform distribution of reaction ions and intermediates is maintained, and finally, gel is networked, so that the problem of capacity fading caused by an unstable structure of an existing aluminum ion battery positive electrode material in a circulating process is solved, and the service life of the aluminum ion battery positive electrode material is prolonged. And the problems of high reaction system selection requirement, long preparation period and complex process of the existing endogenous covalent polycondensation sol-gel method for preparing the electrode material are solved.

The invention discloses a modified ceramic flame-retardant polyphenyl ether insulated wire and cable material which is prepared from the following raw materials in percentage by mass: 15%-20% of polyphenyl ether resin, 10%-20% of SEBS thermoplastic elastomer, 4%-8% of polypropylene resin, 3%-8% of maleic anhydride grafted material, 5%-20% of melamine cyanurate, 5%-15% of aluminum diethylhypophosphite, 1%-4% of 2, 3-dimethyl-2, 3-diphenyl butane, 10%-30% of compound ceramic powder and 1%-4% of antioxidant. The insulated wire and cable material disclosed by the invention has outstanding electrical insulativity, flowability and water resistance, relatively good wear resistance and electrical performance, good dimensional stability and relatively high heat resistance; the flame-retardant property is good, and the self-extinguishing property is realized; and the ceramic forming property after high-temperature combustion is excellent, and the ceramic still has excellent insulating property after being formed.

The invention belongs to the technical field of high-molecular flame retardants, and relates to a method for preparing spherical aluminum hypophosphite with a rough surface at low temperature and normal pressure, which comprises the following steps: adding aluminum sulfate hexahydrate into deionized water for dissolving according to a certain molar ratio, adding sodium hypophosphite monohydrate into deionized water and ethylene glycol for dissolving, and stirring under the condition of mechanical stirring to obtain spherical aluminum hypophosphite; the preparation method comprises the following steps: dropwise adding an aluminum sulfate hexahydrate aqueous solution into a sodium hypophosphite monohydrate solution at a relatively low temperature to obtain a mixed solution, heating in a water bath to 90 DEG C, reacting with the mixed solution to generate aluminum hypophosphite, washing the prepared aluminum hypophosphite slurry with deionized water and absolute ethyl alcohol in sequence, centrifuging, drying in vacuum, and grinding to obtain the spherical aluminum hypophosphite. Under general double decomposition reaction conditions, the spherical aluminum hypophosphite is synthesized at low temperature and normal pressure by controlling the dropwise adding temperature of the raw materials and adopting water and ethylene glycol as a mixed solvent. The prepared aluminum hypophosphite is excellent in morphology, narrow in particle size distribution and good in dispersity.

The invention discloses a ternary positive electrode material, a preparation method thereof and an electrochemical device, and the preparation method comprises the following steps: mixing a nickel-cobalt-manganese precursor and a lithium source, and carrying out primary sintering to obtain a base material; mixing the base material, lithium aluminum titanium phosphate and water at the temperature of 10-20 DEG C, and carrying out filter pressing to obtain a solid material; the solid material and lithium phosphate are mixed and subjected to secondary sintering, so that a composite coating layer is formed on the surface of the base material, the composite coating layer comprises titanium aluminum lithium phosphate and lithium phosphate, and the ternary positive electrode material is obtained. By means of low-temperature washing and composite coating, the conductivity and cycling stability of the ternary positive electrode material are improved.

The attapulgite (HNTs) is modified by using the diethyl aluminum hypophosphite (ADP), so that the flame retardant property of the HNTs and the compatibility of the HNTs and a polypropylene matrix can be remarkably improved. Through thermal modification, the treated surfaces of the HNTs can effectively adsorb phosphorus elements, and ADP can form phosphate groups on the surfaces of the HNTs to enhance the flame inhibition effect of the HNTs. Due to the adsorption effect, the modified HNTs can form a carbonized layer more quickly at high temperature, flame spreading is prevented, and the flammability of the material in a fire disaster is reduced. The dispersity and compatibility of the modified HNTs in a polypropylene matrix are remarkably improved, the mechanical property and thermal stability of the composite material are enhanced, and the modification cost is effectively reduced by optimizing the modification method. Compared with a traditional high-content inorganic flame retardant, the ADP modified HNTs has the advantages that the flame retardant property is improved, and meanwhile, the requirement for using other expensive flame retardants is reduced, so that the cost of the composite material is effectively reduced.

The invention relates to a preparation method of a lanthanum-doped lithium borate coated LATP solid electrolyte, which comprises the following steps: S1, mixing a lithium source, an aluminum source, a lanthanum source, a titanium source and a phosphorus source, putting the mixed material into a dispersing agent, putting into a constant-temperature water bath stirrer, and heating and stirring until the mixture is completely dried to obtain a mixed raw material; s2, performing high-temperature primary sintering on the mixed raw material in an air atmosphere to obtain a composite oxide; s3, performing crushing treatment on a composite oxide, adding lithium borate, and performing uniform mixing to obtain a mixture; the mass ratio of the lithium-containing compound to the composite oxide is (0.01-0.05): 1; and S4, tabletting the mixture, and carrying out high-temperature secondary sintering in an air atmosphere to obtain the finished product lithium titanium aluminum phosphate material. The problems that in an existing scheme, the final calcination temperature of a solid electrolyte is generally up to 1100 DEG C or above, high energy consumption is likely to be caused, meanwhile, Li loss is caused, non-conductive AlPO4 is introduced, the crystal structure is unstable, the powder sintering performance is poor, and the ionic conductivity is reduced are solved.

The invention provides a resource utilization method of iron-aluminum-chromium waste acid, and belongs to the field of waste acid resource treatment. According to the hydrochloric acid type iron-aluminum-chromium waste acid, firstly, high-valence metal in the waste acid is reduced through iron powder, the acidity of a system is reduced, and the iron content is increased; secondly, high-efficiency separation of iron, aluminum and chromium is realized by accurately controlling the sodium phosphate amount, the pH value, the reaction temperature and the stirring rotating speed; and then, oxidizing an iron solution obtained by solid-liquid separation to prepare ferric chloride, and carrying out hydrothermal crystallization on aluminum phosphate and chromium phosphate precipitates to prepare chromium-containing aluminum phosphate which can be used as a catalyst. The method realizes thorough step-by-step separation of metals in the iron-chromium-aluminum hydrochloric acid type waste acid, realizes resource utilization, is free of waste gas and waste residues in the process, meets the green and environment-friendly requirements, and has remarkable environmental and social benefits.