709 results about "Glycidyl ether" patented technology

A fireproof magnesium oxide board is prepared by mixing the following raw materials, the raw material names and weight parts are as follows: 80-100 parts of magnesium oxide; 20-30 parts of anhydrous magnesium chloride; 10-20 parts of modified expanded vermiculite foaming agent; 20-30 parts of aluminum silicate fiber; 5-10 parts of sawdust; 10-15 parts of fly ash; 8-12 parts of glass magnesium board crushed powder; 1.5-5 parts of non-woven fabric; 10-20 parts of water; wherein the modified expanded vermiculite is prepared by the following steps: (1) Vermiculite is incompletely expanded and calcined; (2) acrylic acid monomer, sodium hydroxide, acrylamide monomer, initiator potassium persulfate, crosslinking aid pentaerythritol polyglycidyl ether, incompletely expanded vermiculite, and water are taken, stirred evenly and ultrasonically dispersed to obtain a first reaction solution, which is placed in a reactor for reaction to obtain a gel material; (3) the gel material is preliminarily crushed and dried, and then further crushed in a ball mill to obtain a fire-resistant expanded vermiculite with water absorption performance.

The invention relates to the technical field of polyurethane acrylate, and particularly discloses dual-curing polyurethane acrylate resin and a preparation method thereof. Wherein the dual-curing polyurethane acrylate resin is prepared from the following raw materials: polyester polyol, polyether polyol, diisocyanate, hydroxyl acrylate, a chain extender, a photoinitiator, cardanol glycidyl ether, a polymerization inhibitor and modified nanoparticles. Wherein the citric acid and the polyethyleneimine are adopted to carry out synergistic modification on the nano particles, the dispersion stability of the nano particles is improved, so that the mechanical property of the resin is improved, the cardanol glycidyl ether and the photoinitiator generate a synergistic effect, and the resin can be quickly shaped through photocuring promoted by the photoinitiator; the cardanol glycidyl ether participates in the subsequent thermocuring reaction, so that the curing effect is improved, and the adhesive force between the film layer and the base material is enhanced.

The invention discloses a quick-curing polyurethane seamless expansion joint material for roads and a preparation method, and belongs to the technical field of road engineering materials. The material is prepared from polyether polyol, polycaprolactone glycol, a bisphenol A epoxy-polyether block isocyanate terminated prepolymer, a methyl phenyl silicon-boron hybrid hydroxyl chain extender, diphenylmethane diisocyanate, calcium carbonate, wollastonite, a hindered amine anti-aging agent and dioctyl phthalate. Wherein the bisphenol A epoxy-polyether block isocyanate terminated prepolymer is prepared by the following steps: reacting bisphenol A with epoxy chloropropane to generate epoxy resin, reacting with polytetramethylene ether glycol, and introducing isophorone diisocyanate; the methyl phenyl silicon-boron hybrid hydroxyl chain extender is prepared by carrying out hydrosilylation and ethylene glycol reaction on methyl trimethoxy silane, 3-glycidyl ether oxypropyl trimethoxy silane and allylboronic acid pinacol ester; and the methyl phenyl silicon-boron hybrid hydroxyl chain extender is prepared by carrying out hydrosilylation on methyl trimethoxy silane, 3-glycidyl ether oxypropyl trimethoxy silane and allylboronic acid pinacol ester. The material has the advantages of quick curing property, weather resistance and high-temperature stability, and is suitable for road seamless expansion joint scenes.

The invention discloses a polyurethane modified epoxy resin adhesive as well as a preparation method and application thereof, and the polyurethane modified epoxy resin adhesive is prepared from the following components in parts by mass: 7-10 parts of E51 type bisphenol A diglycidyl ether, 3.5 parts of a phenolic aldehyde amine T31 curing agent and 1-3 parts of synthetic polyurethane, the synthetic polyurethane is prepared from polyether triol, polyether amine, isophorone diisocyanate and glycerol carbonate, and a blending system of the synthetic polyurethane and bisphenol A diglycidyl ether is adopted to be subjected to covalent crosslinking with phenolic aldehyde amine T31, so that the adhesive has high toughness and strength guarantee; the synthetic polyurethane prepared by the method is obtained through simple, green and efficient solvent-free synthesis, and the synthesized product has certain fluidity at room temperature, so that the subsequent stirring preparation process of an adhesive is facilitated. And a solvent-free synthesis method is adopted, so that the use of a toxic organic solvent in the traditional polyurethane synthesis process is avoided, and the synthesis process is greener.

The invention belongs to the technical field of high polymer materials, and particularly relates to a PET decorative film and a preparation method thereof. The preparation method comprises the following steps: synthesizing hydroxyl-terminated hyperbranched polyester by taking pentaerythritol and 2, 2-dimethylolpropionic acid as raw materials, and reacting with polyol glycidyl ether to prepare an epoxy-terminated organic modifier; silver-loaded nano silicon dioxide subjected to surface treatment by an amino silane coupling agent is used as inorganic functional particles; pET resin, an organic modifier and inorganic functional particles are subjected to melt blending and extrusion granulation, and modified PET is prepared; the modified PET is prepared into the film through a two-way stretching process. Epoxy groups of the organic modifier chemically react with amino groups at the tail end of a PET molecular chain and on the surfaces of inorganic particles respectively, a stable organic-inorganic hybrid network is constructed, synergistic improvement of reinforcement, toughening and long-acting antibiosis is achieved, and the technical problems that functional particles are not uniform in dispersion, interface bonding is weak, and antibacterial components are prone to migration are effectively solved.

The invention discloses a DA bond polymer with antibacterial and self-repairing functions for a wood surface as well as a preparation method and a use method of the DA bond polymer. Chitosan serves as a wall material, cinnamon essential oil serves as a core material, the cinnamon essential oil and chitosan antibacterial microcapsules are prepared through emulsification, crosslinking and spray drying, and essential oil controlled release is achieved. Then bisphenol A diglycidyl ether DGEBA and furfuryl alcohol FA are used as raw materials, furyl functional epoxy resin FER is prepared under the catalysis of triethylamine TEA, bismaleimide BMI is added, and a DA bond self-repairing polymer is prepared through a DA reaction; and adding 4, 4-diaminodiphenylmethane DDM into the system, reacting with redundant DGEBA to generate a cross-linked polymer network, and adding the microcapsules into a DA bond semi-interpenetrating self-repairing network solution to obtain the DA bond polymer. A thin film formed by brushing and curing wood has antibacterial and self-repairing functions, scratches and microcracks on the surface of the wood can be repaired, and microbial erosion is inhibited.

A photoelectric composite cable for an underwater buoy, and a preparation process therefor. A polyurethane, a self-repairing polyurethane prepolymer, and a composite nano zinc oxide are selected as an outer sheath base material. A modified polysiloxane having a B-O six-membered ring dynamic cross-linked network and a long-chain alkane group and an amino is introduced into the self-repairing polyurethane prepolymer; 5,5'-methylenedisalicylaldehyde and isophorone diisocyanate are together subjected to stepwise polymerization with the modified polysiloxane, and the 5,5'-methylenedisalicylaldehyde is cross-linked with diphenylmethane diisocyanate to obtain a self-repairing polyurethane prepolymer; and nano zinc oxide is subjected to a modification treatment, wherein dodecyltrimethoxysilane and 3-glycidoxypropyltrimethoxysilane are used for dual modification, such that super-hydrophobic nano zinc oxide having good thermal stability and high dispersity is prepared in a toluene system.

The invention discloses a single-component high-heat-resistance type epoxy adhesive and a preparation method of the single-component high-heat-resistance type epoxy adhesive. The adhesive is prepared from the following components in parts by weight: 30 to 40 parts of N, N-4, 4 '-diphenylmethane bismaleimide; 50 parts of bisphenol F epoxy resin; 36.47 parts of 4, 4 '-diaminodiphenyl sulfone; 20 to 40 phr of phenyl glycidyl ether; 1 to 2 phr of two terminal type epoxy silicone oil; 4 to 6 phr of hydroxyl-terminated polyether sulfone; 10 to 20 phr of boron nitride, the surface of which is modified by gamma-glycidyl ether oxypropyl trimethoxy silane; and 1 to 3 phr of an adhesion promoter. According to the adhesive disclosed by the invention, the heat resistance, the mechanical property, the dimensional stability, the process adaptability and the like are synergistically improved, the use requirements of an aviation structural part on long-term service at 150-180 DEG C and an electronic packaging device on the condition of short-time reflow soldering at about 200 DEG C can be met, and the reliability of the adhesive in a high-temperature environment is remarkably improved.

The invention relates to an aliphatic copolyester elastomer and a preparation method thereof, and belongs to the field of high polymer materials. The elastomer is prepared through a series ring-opening copolymerization reaction of epoxide and cyclic anhydride, and the method comprises the following steps: under the action of a metal-free catalyst (a phosphazene ligand P1-tert-octyl / triethyl boron system) and an initiator (terephthalyl alcohol), carrying out a series ring-opening copolymerization reaction on epoxide and cyclic anhydride, the preparation method comprises the following steps: reacting epoxide (such as epoxypropane and allyl glycidyl ether) with aliphatic anhydride (such as glutaric anhydride) in a xylene solvent to generate a polyester prepolymer retaining an active end; adding a second group of epoxide (such as cyclohexene oxide) and anhydride (such as tetrahydrophthalic anhydride and norbornene dianhydride), continuously reacting to form a block copolymer, and then crosslinking. The material performance can be regulated by changing the monomer combination, the atom economy is high, and the raw materials can be produced on a large scale. The process is simple and environment-friendly, and a new choice is provided for application of the degradable elastomer in the fields of medical treatment, environmental protection and the like.

The invention discloses a high-build waterborne epoxy heavy anti-corrosion coating and a preparation method thereof. The coating is a water-based, double-component and room-temperature self-drying type product and is prepared from water-based epoxy resin, modified amine emulsion, castor oil polyglycidyl ether, pigment filler, anti-rust pigment, a cosolvent, water and a functional additive. Due to the adoption of a special amine curing system and an auxiliary material compatibility scheme, the obtained coating is high in solid content in volume, quick to dry, capable of realizing thick coating construction, resistant to chemicals, resistant to corrosion and capable of being attached to multiple base materials, and is a thick-paste water paint suitable for heavy-duty anticorrosion fields such as petrifaction, maritime work, energy, bridges and the like.

The invention discloses a two-component epoxy pouring sealant as well as a preparation method and application thereof, and belongs to the technical field of high polymer materials. The bi-component epoxy pouring sealant comprises a component A and a component B. The component A comprises the following raw materials: 60-100 parts of modified epoxy resin; 5-25 parts of a reactive diluent; 1 to 10 parts of nano silicon dioxide; the component B comprises the following raw materials in parts by mass: 50-60 parts of an alicyclic amine curing agent; 20-30 parts of a polyether amine curing agent; 10 to 15 parts of methyl tetrahydrophthalic anhydride; 3-5 parts of a silane modifier; 0.1 to 0.5 part of a defoaming agent; the modified epoxy resin is prepared by carrying out esterification reaction on bisphenol A type epoxy resin and long-chain fatty acid for modification and then carrying out graft modification with polypropylene glycol diglycidyl ether. In addition, the invention also provides a preparation method of the two-component epoxy pouring sealant. The epoxy pouring sealant provided by the invention has excellent bonding performance on non-polar plastics such as PP / PE and the like.

The invention discloses a peracetylated polysaccharide derivative mixing accelerator as well as a preparation method and application thereof, and relates to the technical field of polysaccharide derivatives. Alkyl polyglucoside and glycidyl ether are subjected to etherification reaction to obtain polysaccharide derivatives; and adding acetic anhydride and an organic weak base catalyst into the polysaccharide derivative, and carrying out esterification reaction to obtain the peracetylated polysaccharide derivative. The obtained peracetylated polysaccharide derivative can be used for reducing the minimum miscible pressure of CO2 in an offshore oilfield. The polysaccharide derivative provided by the invention is simple in synthesis process, and the molecular activity of the polysaccharide derivative can be regulated and controlled by changing the number of carbon dioxide-philic groups and the length of oleophylic unsaturated hydrocarbon chains, so that the polysaccharide derivative can be used in the CO2 oil displacement process of oilfield exploitation, and the minimum miscible pressure in the CO2 oil displacement process is effectively reduced.

The invention relates to the technical field of coatings, in particular to a graphene modified epoxy anticorrosive coating and a preparation method thereof. The coating is prepared from epoxy resin, graphene-hyperbranched epoxy resin, a reactive diluent and an auxiliary agent, wherein the graphene-hyperbranched epoxy resin is prepared by a three-step method comprising the following steps: firstly, performing dual modification on graphene oxide by adopting 11-aminoundecyltriethoxysilane and 3-aminopropyltriethoxysilane; then reacting with 2-formyl-5-phenylphenol, and finally carrying out condensation polymerization with trimethylolpropane triglycidyl ether to form a hyperbranched structure. According to the invention, collaborative optimization of mechanical strength and corrosion resistance is realized, and the coating has excellent adhesive force, hardness and long-acting corrosion resistance, and is suitable for severe corrosion environments such as ocean engineering and the like.

The present invention provides an epoxy resin adhesive and a preparation method thereof, and relates to the technical field of building structure adhesives, the epoxy resin adhesive is prepared from a component A and a component B, the component A comprises the following raw materials by weight: 90-110 parts of epoxy resin, 15-25 parts of a toughening agent, 40-50 parts of a filler I and 15-20 parts of benzyl alcohol, and the toughening agent comprises polycarbonate, polyamide and polypropylene glycol diglycidyl ether; the component B is prepared from the following raw materials in parts by weight: 40 to 60 parts of curing agent, 10 to 20 parts of filler II, 1.5 to 3 parts of polyvinylpyrrolidone and 5 to 10 parts of benzyl alcohol. The preparation method comprises the following steps: S1, preparing A glue; s2, preparing B glue; and S3, mixing glue. The toughening agent is added in the component A, polycarbonate, polyamide and polypropylene glycol diglycidyl ether are selected as the toughening agent, the three raw materials are compounded and cooperated, the processability and flowing property of the epoxy resin adhesive can be effectively improved, and the problems that a cured finished product is high in brittleness and poor in impact resistance are solved.

The invention discloses a preparation method of a poly (1, 3-dioxolame)-based composite electrolyte, and belongs to the technical field of sodium ion batteries. The preparation method comprises the following steps: adding a sodium salt and a 1, 3-dioxolame monomer into a solvent, then mixing with an additive to obtain a precursor, and carrying out standing and polymerization curing treatment to obtain the poly (1, 3-dioxolame)-based composite electrolyte. According to the invention, the polymerization curing time of the precursor is greatly shortened by optimizing a solvent system; the additive is introduced into the precursor, the additive comprises a cross-linking agent and / or an inorganic filler, the cross-linking agent is trimethylolpropane triglycidyl ether, and the inorganic filler is NASICON type solid electrolyte powder, so that the ionic conductivity of the poly (1, 3-dioxolame)-based composite electrolyte is effectively improved, and the service life of the poly (1, 3-dioxolame)-based composite electrolyte is prolonged. And the cycling stability and the first-cycle discharge specific capacity of the assembled battery are remarkably improved.

The invention discloses fluorine-containing bio-based epoxy resin as well as a preparation method and application thereof, and relates to the technical field of high polymer materials. The preparation method of the fluorine-containing bio-based epoxy resin comprises the following steps: enabling octafluoropentyloxy glycidyl ether as a fluorine unit to react with dihydric alcohol to obtain fluorine-terminated side chain butanediol, enabling the fluorine-terminated side chain butanediol to react with isocyanate to obtain a polyurethane prepolymer, and performing boric acid end capping on the polyurethane prepolymer by using 3-aminophenylboronic acid to obtain the fluorine-containing bio-based epoxy resin. The fluorine-containing bio-based epoxy resin (FBPU-ER) is prepared by the following steps: adding fluorine-containing polyurethane resin and phenylboronic acid into epoxidized soybean oil to obtain phenylboronic acid modified fluorine-containing polyurethane resin (FBPU), carrying out boric acid treatment on the epoxidized soybean oil by using 3-aminophenylboronic acid to obtain phenylboronic acid modified epoxy resin (BER), and finally, mixing the phenylboronic acid modified fluorine-containing polyurethane resin and the phenylboronic acid modified epoxy resin to obtain the fluorine-containing bio-based epoxy resin (FBPU-ER). The fluorine-containing bio-based epoxy resin prepared through fluorine-containing modification and toughening design has good mechanical properties, stability and self-repairing performance.

The invention discloses composite epoxy resin resistant to damp-heat aging and a preparation method and application thereof, and belongs to the technical field of electrical equipment insulating materials. The composite epoxy resin is prepared by the following steps: preparing an epoxy resin mixture from bisphenol A diglycidyl ether type epoxy resin and N, N, N ', N'-tetraepoxypropyl-4, 4 '-diaminodiphenylmethane according to a mass ratio of (1.5-4): 1, and reacting the epoxy resin mixture with a methylhexahydrophthalic anhydride curing agent with a specific molar ratio and a 2, 4, 6-tri (dimethylaminomethyl) phenol accelerant with a certain amount. Through collaborative optimization of the components and the process, the glass-transition temperature, bending strength and breakdown field strength of the epoxy resin are remarkably improved, and the dielectric loss is effectively reduced, so that the epoxy resin shows excellent thermal stability, mechanical property retention rate and insulation reliability in a high-temperature and high-humidity environment; the method is especially suitable for manufacturing insulation parts of electrical equipment in coastal and other high-humidity areas.

The invention provides a cationic waterborne epoxy hardener without containing free amine and a preparation method thereof, and relates to the technical field of epoxy hardeners, the method comprises the following steps: 1) mixing small molecular aldehyde and hydroxyethyl diethylenetriamine for reaction to obtain oxazolidine and aldimine terminated modified amine; (2) carrying out reaction on the modified amine and polyfunctional epoxy resin to obtain modified oxazolidine and aldimine-terminated modified resin amine; 3) mixing the modified oxazolidine and aldimine terminated modified resin amine, monofunctional glycidyl ether and water for reaction to obtain terminated modified resin amine; and 4) adding small molecular acid to neutralize the terminated modified amine, and transferring water to obtain the cationic waterborne epoxy curing agent without free amine. The paint film can be endowed with excellent boiling water resistance, acid and alkali resistance, neutral salt mist resistance and the like, the preparation process is simple, the production cost is low, and the paint is suitable for large-scale industrial application.

The invention provides a high-barrier nanocellulose-based liquid mulching film and a preparation method thereof. The high-barrier nanocellulose-based liquid mulching film comprises a carboxylated nanocellulose solution, hydrophobic modified starch, a compound emulsifier, glycerol, xanthan gum and potassium humate, the carboxylated nano-cellulose solution is obtained by carboxylating and modifying a nano-cellulose solution through succinic anhydride; the compound emulsifier comprises rosin glyceride, polyethylene glycol 400 and nano silicon dioxide; the hydrophobic modified starch is obtained by sequentially carrying out hydrophobic modification on starch through dodecyl glycidyl ether and crosslinking with glycerol triglycidyl ether. The liquid mulching film provided by the invention has excellent barrier property, mechanical strength and environmental adaptability, the effective covering time in a field is remarkably prolonged, and the repeated application requirement caused by rapid damage of a film layer is reduced.

The invention discloses polymer-based anti-crack concrete and a preparation method thereof, and relates to the technical field of concrete. When the polymer-based anti-crack concrete is prepared, acrylic acid is grafted on the surfaces of pretreated polypropylene particles to prepare modified polypropylene particles; coating sodium metasilicate with sodium alginate to prepare a self-repairing microcapsule; the preparation method comprises the following steps: hydrolyzing 3-glycidyl ether oxypropyl trimethoxy silane, and grafting the hydrolyzed 3-glycidyl ether oxypropyl trimethoxy silane on the surface of silicon dioxide to prepare modified silicon dioxide; mixing the modified polypropylene particles, basalt fibers and polyacrylonitrile fibers to obtain a solid functional component; cement, slag powder, silica fume, an expanding agent, a solid functional component, modified silicon dioxide, a water reducing agent, an air entraining agent, deionized water, river sand, gravel and the pre-wetted self-repairing microcapsule are mixed, and the polymer-based anti-crack concrete is prepared. The polymer-based anti-crack concrete prepared by the invention has excellent anti-crack, freeze-thaw-resistant and self-repairing properties.

The present invention relates to the technical field of polyurethane coatings, and in particular to a polyurethane coating with sufficient tack-free dryness and a preparation method therefor. In the present invention, ethylene glycol, potassium methoxide, and glycidol are used to prepare a branched polyglycidyl ether and silicon dioxide is modified using the branched polyglycidyl ether. The addition of the branched polyglycidyl ether improves the compatibility of the modified silicon dioxide in a modified polyurethane emulsion, thereby enhancing the hydrophobicity and corrosion resistance of the coating. The backbone of the branched polyglycidyl ether has a high molecular weight, providing a large number of crosslinking sites, and by adding the branched polyglycidyl ether-modified silicon dioxide to the polyurethane coating, the water resistance of the polyurethane coating is enhanced. In the present invention, benzotriazole is also loaded on the silicon dioxide as a corrosion inhibitor, thereby imparting a corrosion-resistant effect to the coating.

A conductive epoxy composition is disclosed comprising an epoxy resin, a low-viscosity hydrocarbon diluent, silver, and graphene. The one-part formulation provides enhanced electrical conductivity, mechanical strength, and process stability. The epoxy resin may include resorcinol diglycidyl ether, diglycidyl ether of Bisphenol A, or Bisphenol F. The hydrocarbon diluent may include glycidyl-ether-family resins having defined carbon-chain characteristics and molecular weights. Silver may be present in particulate, flake, nanoparticle, or coated forms at about 55-90 wt. %, while graphene may be present at 0.03-0.3 wt. % with dimensions of 1-10 μm and surface areas of 400-2,000 m2 / g. Optional additives include solvents, ionic liquids, latent curing agents, and strength enhancers to optimize curing and adhesion.

The invention relates to organosilicone modified acrylic resin, a UV-thermal dual-curing adhesive and a preparation method of the organosilicone modified acrylic resin. The organosilicone modified acrylic resin is obtained by reacting a bifunctional acrylate monomer and modified polysiloxane under the action of a polymerization inhibitor 1 and a catalyst 1; the modified polysiloxane is obtained by reacting hydrogen-containing silicone oil, allyl glycidyl ether and 1, 4-cyclohexanedimethanol divinyl ether under the action of a polymerization inhibitor 2 and a catalyst 2. The adhesive prepared by matching the organic silicon modified acrylic resin with auxiliaries such as a monomer and an initiator can be subjected to UV-heat dual curing, the surface is dry and comfortable after curing, the sticky'oxygen inhibition 'phenomenon is avoided, and the adhesive has good hardness; the adhesive force with various base materials including PC, aluminum materials, glass and PET is good; the shear strength retention rate of each base material after double 85 1000 hours of aging is 70% or above; the appearance is not obviously changed in a high-temperature aging test, and better heat resistance is shown.

The invention discloses a temperature-resistant and salt-resistant tackifier and a preparation method thereof, and relates to the technical field of fracturing fluids. The preparation method of the temperature-resistant and salt-resistant tackifier comprises the following steps: taking a first monomer and diethanol amine to carry out epoxy ring-opening reaction, and after the reaction is finished, separating and purifying to obtain an intermediate; taking the intermediate, adding a quaternization reagent for quaternization reaction, and then separating and purifying to obtain an active monomer; the first monomer is one of allyl alcohol glycidyl ether, acrylic acid glycidyl ether and methacrylic acid glycidyl ether, and the quaternization reagent is one of halogenated carboxylate or halogenated sulfonate; the preparation method comprises the following steps: dissolving acrylamide, an active monomer and unsaturated phosphate, and carrying out free radical polymerization under the action of an initiator. The tackifier provided by the invention has good temperature-resistant and salt-resistant effects, and can tolerate salt water with mineralization degree of 120,000 mg / L and high temperature of 150 DEG C.

The invention relates to the technical field of sound insulation materials, in particular to flame-retardant epoxy resin composite diatomite sound insulation cotton and a preparation method thereof. The flame-retardant epoxy resin composite diatomite sound insulation cotton is prepared from epoxy resin, diatomite, a composite flame retardant, a coupling agent, a curing agent, a diluent, a foaming agent and a charring agent. The composite flame retardant at least comprises ammonium polyphosphate and melamine; the coupling agent is a silane coupling agent or a titanate coupling agent; the curing agent is methyl tetrahydrophthalic anhydride; the diluent is n-butyl glycidyl ether; the foaming agent is azodicarbonamide; the charring agent is pentaerythritol. By optimizing the diatomite modification process and combining physical dispersion and chemical modification means, the compatibility of the diatomite and the epoxy resin is greatly improved, the pain point of filler agglomeration in the traditional process is thoroughly solved, the porous sound insulation potential of the diatomite is fully released, and the sound absorption and sound insulation performance of the material is qualitatively improved.

The invention relates to low-viscosity high-strength two-component epoxy winding resin and a preparation method and application thereof, the resin comprises a component A and a component B, and the mass ratio of the component A to the component B is 100: (80-110); the component A consists of the following raw materials in percentage by mass: 70-85% of modified epoxy resin, 14-20% of a functional reactive diluent and 1-10% of an impregnating compound; the modified epoxy resin is formed by compounding bisphenol A epoxy resin and polyether modified epoxy resin, and the functional active diluent is formed by compounding 1, 6-hexanediol diglycidyl ether and phenyl glycidyl ether; the component B is prepared from the following raw materials in percentage by mass: 85-96% of a composite anhydride curing agent, 2.5-10% of a high-efficiency accelerant and 1.5-5% of a defoaming agent; the composite anhydride curing agent is compounded by methyl tetrahydrophthalic anhydride and succinic anhydride, the efficient accelerant is compounded by imidazole and phosphine, and the defoaming agent is an organic silicon defoaming agent.

The invention provides an elastic polyaspartic acid ester polyurea floor coating and a preparation method thereof, the floor coating comprises a main agent and a curing agent, the main agent comprises first polyaspartic acid ester resin, second polyaspartic acid ester resin, a functional auxiliary agent, and a pigment filler; the curing agent comprises first isocyanate and second diisocyanate; the first polyaspartic acid ester resin is selected from PAE0760, and the second polyaspartic acid ester resin is selected from F520; the first isocyanate is selected from a glycidyl ether compound modified HDI (Hexamethylene Diisocyanate) tripolymer; and the second diisocyanate is selected from HDI (hexamethylene diisocyanate) uretdione. The polyaspartic acid ester polyurea floor coating disclosed by the invention can be used for obviously improving the tensile strength and the scratch resistance of the polyaspartic acid ester polyurea floor coating and improving the leveling property of the polyaspartic acid ester polyurea floor coating while keeping good elastic property, and is a solvent-free polyaspartic acid ester polyurea floor coating with excellent comprehensive performance.

The invention provides epoxy resin for halogen-free flame-retardant self-leveling powder coating and a preparation method of the epoxy resin, and belongs to the technical field of powder coating. The flame retardant is mainly prepared from anhydrous piperazine, bisphenol A diglycidyl ether, trihydroxymethyl phosphorus oxide, triethyl phosphite, epoxy chloropropane, sodium hydroxide, N-methyl iminodiacetic acid, ethylene glycol diglycidyl ether and other main raw materials through polymerization. The prepared epoxy resin and 2-phenylimidazoline are subjected to low-temperature curing (135 DEG C / 20 min) on the premise that an additional flatting agent does not need to be used, the flexibility of a coating film is good, the impact resistance grade is high, the impact performance reaches the condition that no cracking phenomenon exists in the front and back 60cm, the leveling grade reaches the grade 7 or above, the gloss is high and reaches 95% or above, the oxygen index reaches 34% or above, and the halogen-free flame retardant performance is excellent.

The invention provides a special fiber material and a preparation method thereof, and belongs to the technical field of polymer composites.The preparation method comprises the following steps that cellulose and an ethanol solution are mixed, polyvinyl alcohol and a 3-glycidoxypropyltrimethoxysilane solution are added, the pH is adjusted to be acidic, heating, suction filtration and drying are conducted, and modified cellulose is obtained; mixing expanded graphite, deionized water, ammonium persulfate and dilute sulphuric acid, heating, cooling, dropwise adding amino polyethylene glycol silane, heating, washing and drying to obtain modified expanded graphite; the preparation method comprises the following steps: mixing modified cellulose, modified expanded graphite, phosphate montmorillonite, 3-(methacryloyloxy) propyltrimethoxysilane, bisphenol A diglycidyl ether and 2-methylimidazole, stirring, heating, defoaming, and carrying out two-stage constant-temperature treatment to obtain the special fiber material. The special fiber material disclosed by the invention has good flame retardance, mechanical strength, water resistance and filtering performance, and can be applied to various organic composite boards, filter membranes and the like with high quality requirements.

The invention relates to the technical field of adhesives, and particularly discloses an adhesive for repairing a glass fiber reinforced plastic pipeline and a preparation process. The invention relates to an adhesive for repairing a glass fiber reinforced plastic pipeline. The adhesive is prepared from the following raw materials: modified bisphenol A epoxy resin, a curing agent, a glass fiber reinforced filler, a silane coupling agent, phenyl glycidyl ether, hydroxyl-terminated nitrile rubber and an antioxidant 1076, the modified bisphenol A type epoxy resin is prepared by grafting and modifying bisphenol A type epoxy resin through amino-terminated polyether; the glass fiber reinforced filler is prepared from hydroxylated glass fibers and a graphene-carbon nanotube compound through covalent grafting. The adhesive can be used for emergency repair of glass fiber reinforced plastic pipelines, has the advantages of high low-temperature curing speed, high bonding strength and good durability, can effectively avoid cracking and leakage of repaired parts, and is adaptive to low-temperature and high-pressure complex repair working conditions. The preparation process is simple and convenient to operate and high in controllability, the adhesive with uniform performance can be stably prepared, and the repair efficiency and repair quality are guaranteed.