The invention relates to the technical field of
lithium ion battery negative
electrode materials, in particular to a preparation process of a
silicon-
carbon coated negative
electrode material which takes bamboo wood as a
biomass carbon source and is combined with
nano silicon and a dual
carbon coating technology, and the preparation process comprises the following steps: step a,
sol loading, step b, vacuum impregnation, step c,
interface bonding, step d, inner layer
coating and step e, outer layer
coating. A
silicon-carbon interface in-situ bonding technology and a double-layer
carbon coating technology are utilized, a
sol-
gel method is adopted to construct a Si-O-C
chemical bond on the surface of bamboo-based carbon, molecular-level anchoring of
silicon particles (20-50 nm) on the surface of a
carbon skeleton is achieved, the interface
separation problem of traditional mechanical mixing is solved, meanwhile, inner-layer
amorphous carbon (2-3 nm) is generated in cooperation with bamboo wood
pyrolysis gas, and the surface of the bamboo-based carbon is separated. Then bamboo vinegar is carbonized to form an outer graphitized carbon shell (5-8nm), and the double carbon
layers cooperate to inhibit
volume expansion of silicon, so that the problem of
volume expansion of silicon is solved, and the first charge-
discharge efficiency of the battery and the capacity
retention rate after circulation are effectively improved.