The invention discloses a photovoltaic and thermochemical coupled full-spectrum
solar hydrogen production
system. The
system comprises a concentrating and frequency dividing subsystem, a photovoltaic
electrolysis subsystem and a photo-thermal
methanol reforming subsystem, the light condensation and frequency division subsystem is used for carrying out focusing and frequency division on the incident full-spectrum
sunlight, and then the full-spectrum
sunlight enters the photovoltaic
electrolysis subsystem and the photo-thermal
methanol reforming subsystem; the waveband
sunlight matched with the photovoltaic
band gap is focused and incident into the photovoltaic
electrolysis subsystem to be converted into
electric energy, and then water electrolysis for
hydrogen production is driven; and the sunlight of the rest
wave band is focused and incident to the photo-thermal
methanol cracking subsystem to be converted into
heat energy, so that the methanol / water reaction solution is driven to perform methanol reforming thermal
chemical reaction for
hydrogen production. And the photovoltaic electrolysis subsystem is connected with the photo-thermal methanol reforming subsystem, and is used for recycling
waste heat generated in the
photovoltaic power generation process for preheating a reaction solution and cooling a photovoltaic device at the same time. According to the invention, efficient conversion from full-spectrum
solar energy to
hydrogen energy is realized.