382 results about "Pyrolysis oil" patented technology

The invention belongs to the technical field of petroleum processing, and particularly relates to a catalyst and a preparation method and application thereof. The raw materials of the catalyst comprise a metal active component, a carrier and an auxiliary agent, the metal active component is sulfides of Mo and Ni elements, the carrier is spherical gamma-Al2O3 of 0.5-1 mm, and the auxiliary agent is P; the carrier is modified by using the metal active component and the auxiliary agent to serve as the catalyst. The high-activity catalyst is synthesized by adopting the strategy of changing the roasting temperature, adding the additive for doping modification and changing the molar ratio of metal active components, the additive is combined with surface aluminum atoms, the framework strength is enhanced, pore channel collapse caused by acid / water erosion is reduced, the water resistance and acid resistance of the catalyst are improved, and the catalytic reaction activity is further improved. The catalyst disclosed by the invention is accurate and controllable in structure, can be synthesized in batches, and can be applied to the co-catalytic hydrogenation process of biomass pyrolytic oil and / or a model compound thereof and petroleum distillate oil and / or VR.

A pyrolysis method and system are provided that enhances the production of alkanes and minimizes the production of aromatics in the resulting pyrolysis oil. More particularly, the disclosed pyrolysis method and system may be configured to enhance the production of alkanes due to the use of certain pyrolysis catalysts and more intense pyrolysis conditions.

The invention discloses a cyclone separation and moving particle bed coupled pulverized coal pyrolysis oil gas high-temperature dust removal system, and belongs to the technical field of coal clean utilization. The system comprises a cyclone separator, a fine filtration unit, a filter material cyclic regeneration unit and an intelligent control unit, the fine filtration unit comprises a particle bed, a particle bin is arranged at the top end of the particle bed, and a composite filter material layer is arranged on the particle bed; a dust-containing high-temperature oil gas pipeline and a pretreatment high-temperature oil gas pipeline are arranged at the top end of the cyclone separator, dust-containing high-temperature oil gas is introduced into the cyclone separator through the dust-containing high-temperature oil gas pipeline to be pretreated, and the pretreated dust-containing high-temperature oil gas is introduced into the particle bed through the pretreatment high-temperature oil gas pipeline to be finely filtered; and a coke breeze discharge pipe is arranged at the bottom of the cyclone separator. The invention is used for solving the technical problem of low gas-solid separation efficiency at high temperature caused by the adoption of a single filter material in the existing pulverized coal dust removal system.

The invention relates to the technical field of carbon black materials, and discloses special carbon black with high specific surface area and a preparation method thereof, and the special carbon black is prepared by pyrolysis and activation treatment of a precursor mixture, a catalyst and a template agent. The precursor mixture contains a biomass refined product, waste polymer pyrolysis oil and a copolymer template agent, and the performance is optimized through a rotating flow field high-temperature reactor and a microwave-assisted activation process. The carbon black has a hierarchical porous structure, the specific surface area reaches 2000-2500m < 2 > / g, the conductivity is improved by 1-2 orders of magnitude, and the chemical properties can be regulated and controlled through surface functionalization. The low-cost and sustainable production is realized, the mechanical strength, the conductivity and the adsorption performance are remarkably improved, and the requirements of the high-end field are met.

The invention relates to an oil-rich coal in-situ underground combustion and pyrolysis oil and gas recovery cooperative system based on high-temperature heat pipes. The system comprises a vertical shaft, a horizontal drill hole and a high-temperature heat pipe set. A high-temperature heat pipe set is arranged on the coal seam of the vertical shaft. A plurality of vertical wells are arranged with the vertical well as the center. Each vertical well is communicated with two parallel horizontal drill holes with different depths in the coal seam, the horizontal drill holes communicated with the adjacent vertical wells are not at the same depth of the coal seam, and four horizontal drill hole groups with different depths are arranged in the coal seam. Oxygen and carbon dioxide are mixed into oxygen-enriched gas, and combustion of coal in a certain horizontal drill hole is achieved. Flue gas generated by coal combustion is subjected to heat exchange through the high-temperature heat pipe set, and water vapor or carbon dioxide is heated. The high-temperature water vapor or carbon dioxide and the high-temperature flue gas after heat exchange enter the other two horizontal drill holes in the coal seam respectively, coal is pyrolyzed, and pyrolysis gas and tar are generated. According to the system, high-quality tar and high-calorific-value pyrolysis gas can be obtained, and only a small amount of energy needs to be provided from the outside.

The invention belongs to the field of wind power, and relates to a waste wind power blade pyrolysis system and method. The system comprises a pyrolysis device, a combustion device, a carbon removal device and a gas return pipe, wherein the internal space of the pyrolysis device can receive external third gas to pyrolyze the blades, output pyrolysis solids to the carbon removal device and output pyrolysis oil gas to the combustion device; the external space of the pyrolysis device heats the internal space by using the first gas, and outputs a second gas; the combustion device is used for receiving and combusting pyrolysis oil gas and air and outputting first gas to an external space; the carbon removal device is used for receiving the pyrolysis solid and the carbon removal gas, removing residual carbon of the pyrolysis solid and then outputting glass fibers to the outside; the gas return pipe is connected with the internal space, and part of the second gas serves as third gas to be fed into the internal space. The blades are heated in a radiation and convection mode, the amount of smoke fed into the pyrolysis device can be adjusted, the pyrolysis process is stable, fiber strength loss is avoided, and the energy utilization rate is increased.

The invention discloses a device for preparing a molten carbon fertilizer through solid waste microwave pyrolysis and waste heat recovery, and belongs to the field of solid waste treatment and recycling. The device is composed of a pretreatment unit, a microwave pyrolysis unit, a gas-solid separation unit, a gas phase treatment unit, a solid phase treatment unit and a waste heat circulation unit, solid waste enters a microwave rotary kiln after being dried and crushed, a magnetron generates microwave anaerobic pyrolysis under photovoltaic power supply, and a high-temperature gas-solid product is generated; the cyclone separator is used for separating flue gas from solid carbon, the flue gas is condensed to obtain pyrolytic oil and gas, and waste heat of medium-temperature flue gas is recovered through the heat accumulating type heat exchanger for drying; cooling the solid carbon through a heat pipe heat exchanger, recovering waste heat and liquefying urea, and mixing the solid carbon and the urea in a stirring melting pool to prepare a molten carbon fertilizer; and the waste heat backflow fan sends the carbon waste heat back to the drying chamber. The system is driven by green electricity, gas and solid phase waste heat is recovered through double paths, solid waste efficient pyrolysis-product high value-energy self-circulation is achieved, and energy consumption and carbon emission are reduced.

A composition having a recycle content value is obtained by reacting a recycle content feedstock to make a recycle content alpha olefin or by deducting from a recycle inventory a recycle content value applied to an alpha olefin composition. At least a portion of the recycle content value in the feedstock or in an allotment obtained by an alpha olefin manufacturer has its origin in recycled waste and / or pyrolysis of recycled waste and / or in thermal steam cracking of recycle content pyoil.

A composition having a recycle content value is obtained by reacting a recycle content feedstock to make a recycle content oxo alcohol or oxo plasticizer or by deducting from a recycle inventory a recycle content value applied to an oxo alcohol or oxo plasticizer composition. At least a portion of the recycle content value in the feedstock or in an allotment obtained by an oxo alcohol or oxo plasticizer manufacturer has its origin in recycled waste and / or pyrolysis of recycled waste and / or in thermal steam cracking of recycle content pyoil.

The invention discloses an artificial geothermal reservoir construction and development method based on oil shale reverse oxidation, and belongs to the technical field of resource exploitation, the method comprises the following steps: reservoir well construction: arranging an injection well, an exploitation well and a heat recovery well in a target layer section; an initial high-temperature environment is formed through manual heating, so that the oil shale is pyrolyzed to generate fixed carbon; injecting air to form an oxygen-enriched environment, initiating a fixed carbon oxidation self-heating reaction, and continuously pyrolyzing the oil shale; terrestrial heat is exploited through a circulating working medium, the air flow and components are dynamically controlled, and temperature control and safe operation are achieved; and finally reinjecting and sealing the carbon dioxide. The device can convert low-grade oil shale into clean geothermal energy, and has the advantages of energy conservation and environmental protection.

The application discloses a device and method for preparing green hydrogen through biomass pyrolysis and gasification, relates to the technical field of green hydrogen preparation, and solves the problems of blockage and corrosion caused by ash melting and slagging in the pure oxygen gasification process, and the problem of low energy utilization rate. The device for preparing green hydrogen through biomass pyrolysis and gasification comprises a pyrolysis reaction device, and the pyrolysis reaction device comprises a pyrolysis reaction tank connected with a high-temperature heat carrier conveying spiral, a biomass raw material storage bin, a biomass raw material conveying spiral and a pyrolysis solid-phase product conveying spiral. In the application, biomass raw materials are converted into biochar and pyrolysis oil gas through pyrolysis technology, the biomass ash is effectively cut, and problems such as blockage and corrosion caused by ash melting and slagging in the pure oxygen gasification process are effectively avoided; the high-temperature pyrolysis oil gas is directly subjected to pure oxygen gasification reaction through gasification technology, the sensible heat and latent heat in the pyrolysis oil gas are fully utilized, and the energy utilization rate is high.

This invention relates to the field of petroleum refining and chemical engineering, and discloses a method for hydrogenating waste tire pyrolysis oil. The method includes the following steps: (1) in the presence of hydrogen, the waste tire pyrolysis oil raw material undergoes a gas-phase desulfurization reaction in a first gas-phase hydrogenation reactor to obtain a gas-phase desulfurization reaction product; (2) the gas-phase desulfurization reaction product is subjected to gas-liquid separation to obtain a gas-phase component and a liquid-phase component; (3) the liquid-phase component is pressurized and mixed with hydrogen, and then subjected to a liquid-phase dearomatics reaction in a second hydrogenation reactor to obtain a liquid-phase dearomatics reaction product; the nitrogen content in the waste tire pyrolysis oil raw material is 3000-10000 μg / g. This method uses waste tire pyrolysis oil from the middle distillate as raw material, achieving deep desulfurization while reducing the removal of nitrogen oxides and monocyclic aromatic hydrocarbon saturation. It also simplifies the overall process flow, reduces the reaction severity, and lowers energy and hydrogen consumption.

The invention discloses a method for strengthening a co-pyrolysis synergistic effect based on hydrothermal-forming pretreatment. The method comprises the following steps: 1, grinding and screening raw materials, namely oil-rich coal and lignin, and then drying; 2, uniformly mixing with a CaO catalyst, and carrying out hydrothermal pretreatment to obtain a mixture to be formed; 3, mixing the to-be-formed mixture with deionized water, and carrying out double-roller forming treatment to obtain a formed substance; 4, carrying out a co-pyrolysis reaction on the molded product to generate solid semi-coke and a pyrolysis oil gas product; and 5, condensing and separating the pyrolysis oil-gas product to obtain pyrolysis tar and pyrolysis gas, and collecting solid semi-coke. According to the invention, the CaO catalyst, the hydrothermal pretreatment and the double-roller forming are utilized to synergistically improve the yield and the quality of the co-pyrolysis product of the oil-rich coal and the lignin, so that the co-pyrolysis synergistic effect of the oil-rich coal and the lignin can be enhanced to improve the yield of high-value components, and the emission of greenhouse gases and pollutants in the pyrolysis process can be reduced; and high-value utilization of oil-rich coal and waste lignin resources is realized.

The invention discloses an oil-containing solid waste and plastic co-pyrolysis method based on carbon residue in-situ catalysis, and belongs to the technical field of solid waste resource utilization. The method comprises the following steps: pre-treating and mixing oil-containing solid waste and waste plastic, and co-pyrolyzing to prepare primary carbon residue and pyrolysis steam; performing acid dipping or oxidation modification on the primary carbon residue to obtain modified carbon residue, performing in-situ catalytic reforming on the pyrolysis steam and the modified carbon residue under the condition that the temperature is not lower than the final pyrolysis temperature, performing fractional condensation separation on a product to obtain pyrolytic oil and hydrogen-rich gas, and performing high-valued preparation on a functional material from the secondary residue. According to the method, the problems that a catalyst needs to be additionally added and the product quality is low in the existing co-pyrolysis technology are solved. No additional catalyst is needed in the whole process, the process cost is reduced, and related secondary pollution of the catalyst is avoided; product quality improvement is effectively achieved, two kinds of solid waste are treated synchronously, and remarkable environmental protection and economic and social benefits are achieved.

The application discloses a catalytic combustion heater principle prototype, which comprises an air tank, a methane tank, a mixed gas tank and a combustion chamber, the air tank is connected with the mixed gas tank through a connecting pipeline, the gas outlet of the mixed gas tank is connected with the methane tank and the combustion chamber through two connecting pipelines respectively, the top of the combustion chamber is provided with a mixed gas inlet, and a blower is arranged outside the combustion chamber, the application simulates the operation state of the underground catalytic combustion heater, high-temperature tail gas released by catalytic combustion mixed gas is used for heating oil shale layers, so that the oil shale is pyrolyzed to obtain the purpose of exploiting oil and gas, the simulation reference result of the experimental prototype can be understood as the actual operation result, the application not only reduces the exploitation cost of the oil shale in-situ conversion exploitation, but also improves the oil and gas exploitation efficiency, reduces the exploitation cost and reduces the harm of the toxic tail gas generated by incomplete combustion to animals, plants and the environment caused by direct release of the toxic tail gas into the atmosphere.

A recycle content oxo glycol and method of making a recycle content oxo glycol wherein the recycle content is derived directly or indirectly from the cracking of recycle content pyrolysis oil and / or gas. The cracking of the pyrolysis oil can be conducted in a gas furnace or a split furnace.

The invention discloses a method and a system for recycling a carbon fiber composite material through step-by-step thermal cracking based on a nitrogen atmosphere, the nitrogen atmosphere is adopted to replace a high-vacuum system, so that the equipment investment and maintenance cost are greatly reduced, meanwhile, the explosion risk caused by air back-suction is effectively prevented through positive pressure protection, and the method and the system are more suitable for industrial amplification; through a two-step method strategy of taking oil at a low-temperature section and removing residues at a high-temperature section, the cracking process is refined, macromolecular oil products are quickly removed under nitrogen carrying by first-stage low-temperature cracking, secondary cracking is effectively inhibited, and first-stage cracked oil which is simpler in component, higher in quality and easy to refine is obtained; long-time high-temperature exposure of the fibers is avoided through step-by-step cracking, decomposition products can be taken away in time through nitrogen flow, deposition of pyrolytic carbon on the surfaces of the fibers is reduced, the fibers with the clean surfaces can be obtained through follow-up short-time oxidation, and the retention rate of the tensile strength of the fibers can reach 90% or above.

The embodiment relates to a polishing pad that comprises a polishing layer. When pyrolysis oil obtained from the polishing pad is analyzed according to the KS M 2457 standard, the content of chlorine components is 13,000 mg / kg or more. The pyrolysis oil can be used as a high-quality heat source through a refining process. Accordingly, the embodiment can contribute to improving environmental problems while increasing the recycling rate of polishing pads.

This invention relates to a pyrolysis treatment method and system for waste plastics. The waste plastics undergo segmented dehydration and dechlorination in a waste plastic extrusion dehydration and dechlorination unit to obtain dechlorinated waste plastics. The obtained dechlorinated waste plastics then enter a waste plastic impurity removal treatment unit, where they are contacted with pretreatment agents and solvent oil for impurity removal treatment. The resulting effluent undergoes solid-liquid separation to obtain insoluble matter and a depurified plastic-containing solution. This depurified plastic-containing solution enters a pyrolysis unit for pyrolysis to obtain pyrolysis oil. The pyrolysis oil has very low metal, chlorine, and silicon content, effectively reducing the impact of impurities in the waste plastics on subsequent treatment units. This invention has low pollution discharge during production, good environmental performance, reduces carbon emissions, and has good environmental, social, and economic benefits.

The present invention provides a method of preparing a pyrolysis oil from waste plastics, the method comprising the steps of: (S1) supplying a waste plastic raw material to a first reactor to perform primary pyrolysis, and upwardly discharging a gaseous stream generated by the pyrolysis; (S2) supplying the overhead gaseous stream of the first reactor to at least one distillation column and separating the overhead gaseous stream by boiling point to obtain a stream containing a C5-12 light oil (LO), a stream containing a C13-22 middle oil (MO), and a stream containing a C23 or higher heavy oil (HO); and (S3) supplying a portion of the middle oil (MO)-containing stream separated in the distillation column to a second reactor to perform secondary pyrolysis, and supplying a gaseous stream generated by the secondary pyrolysis to the distillation column, wherein the primary pyrolysis and the secondary pyrolysis are each performed under high pressure conditions of 2-40 bar.

According to the multi-construction layered metal oxide and the application thereof in hydro-conversion of the polystyrene waste plastic pyrolytic oil, the prepared multi-construction layered metal oxide serves as a catalyst and is fully mixed with the polystyrene waste plastic pyrolytic oil after being pretreated, and then the mixture is transferred into a reaction kettle; after sealing, filling hydrogen into the reaction kettle, controlling the reaction temperature to be 90-100 DEG C, and stirring to react for 6-12 hours; according to the invention, the multi-constructed NixAl-LDO is combined with the hydrogenation process, and the styrene conversion rate and ethylbenzene selectivity are improved by utilizing the combined action of the structural advantage of the multi-layer catalyst and the hydrogenation reaction.

A system for recovering styrene after depolymerization of styrenic waste plastics includes a depolymerization reactor unit capable of generating a pyrolysis oil stream and a residue stream from a wast

A system can be used to reduce the impurities present in a styrene monomer product distilled from a pyrolysis oil. The system can include a fractionation train downstream from a depolymerization unit. The fractionation train may include four fractionation columns in series and produce a styrene monomer product stream comprises at least 99.0 wt% styrene and 300 ppm or less cumene.

The present invention relates to a process for treating at least one pyrolysis oil PO in a steam cracking unit whereby said at least one pyrolysis oil PO is used as a quench medium in a second quench unit in the downstream section of said steam cracking unit. Thereby, the at least one pyrolysis oil PO is separated into a stream PO1 and a stream PO2, whereby said first cooled effluent CE1 is separated into a stream CE1a and a stream CE1b, whereby said stream PO1 and said stream CE1a form a stream POCE1 in said second quench unit QU2, which stream POCE1 leaves said second quench unit QU2. Said stream PO2 and said stream CE1b form a stream POCE2 in said second quench unit QU2, which stream POCE2 leaves said second quench unit QU2. C2-C4 alkenes and / or C6-C8 aromatic hydrocarbons separated from stream POCE1 and / or stream POCE2, respectively, can optionally be converted into a product PRF1.

A method for producing pyrolysis oil from used plastics is provided, the method comprising (i) supplying used plastic material, (ii) melting the used plastic material to form molten plastic material, (iii) pyrolysis of the molten plastic material in an oxygen-free atmosphere to yield pyrolysis gas and carbonized material, and (iv) condensing the pyrolysis gas to yield pyrolysis oil, the method further comprising dispersing a zeolite material in the used plastic material or molten plastic material, the zeolite material comprising a zeolite having a molar ratio of silica to alumina (SAR) of 10 to 140 and an average crystal diameter of about 200 nm or less, and the zeolite material having a thickness of at least 0.30 cm 3 Mesopore volume of / g and at least 0.10 cm 3 It has a micropore volume of / g.

The invention discloses a skid-mounted carbon fiber composite material fused salt pyrolysis recovery device, which is characterized in that all functional modules are integrated in a standard container skid-mounted base to form an independent unit capable of being integrally transported. The device comprises a fused salt pyrolysis reaction module, a post-treatment module, an oil gas treatment and waste heat recovery module and an integrated control system which are arranged in sequence. The core of the fused salt pyrolytic reaction module is an electric field damping type fused salt storage tank, the electric field damping type fused salt storage tank is of a double-layer structure, shaking of fused salt in the transportation and operation process is actively restrained by applying a controllable electric field, and safety and stability are guaranteed. The vacuum system is a graded vacuum regulation and control system, the vacuum degree can be dynamically regulated according to different pyrolysis stages, the inert reaction environment is efficiently maintained, and the energy consumption is reduced. And the oil gas treatment module realizes pyrolysis oil gas recovery and waste heat utilization. According to the carbon fiber composite material recycling device, movable, intelligent and efficient recycling of the carbon fiber composite material is achieved, and the transportation and treatment cost is reduced.

The present invention relates to a method for treating a feedstock comprising pyrolysis oil from plastics and / or tires and / or solid recovered fuels containing halogenated compounds, said method comprising: a) a hydrotreating step to obtain a partially hydrotreated effluent having a reduced content of halogenated compounds; b) a separation step in which the hydrotreated effluent from step a) and an aqueous solution are fed to obtain a gaseous effluent, an aqueous effluent and a partially hydrotreated hydrocarbon effluent; and c) a step of fluidized bed catalytic cracking or hydrotreating of a petroleum feedstock and / or a feedstock resulting from biomass conversion, in which the partially hydrotreated hydrocarbon effluent is introduced as a co-feed without a prior separate hydrotreatment step at higher temperature and / or pressure, and the mixture of petroleum and / or biomass feedstock and the partially hydrotreated hydrocarbon effluent has a halogenated compound content of 10 ppm or less by weight.

A process for upgrading a pyrolysis oil comprising contacting a pyrolysis oil feed with hydrogen in a first fixed bed reactor in the presence of a mixed metal oxide catalyst wherein: the pyrolysis oil feed comprises a polycyclic aromatic hydrocarbon compound comprising greater than or equal to 16 carbon atoms; and contacting the pyrolytic oil feedstock with hydrogen in the presence of a mixed metal oxide catalyst in a first fixed bed reactor to convert at least a portion of the polycyclic aromatic hydrocarbon compounds in the pyrolytic oil feedstock into bicyclic aromatic hydrocarbon compounds, tricyclic aromatic hydrocarbon compounds, or both, passing the intermediate stream comprising the bicyclic aromatic compound, the tricyclic aromatic compound, or both to a second fixed bed reactor downstream of the first fixed bed reactor; and contacting the intermediate stream with hydrogen in the presence of a mesoporous supported metal catalyst in a second fixed bed reactor.

The invention relates to a method for catalytically pyrolyzing waste tires by utilizing modified sintering ash, which comprises the following steps of: performing high-temperature heat treatment modification on the sintering ash, and performing pyrolytic reaction on the modified sintering ash and the waste tires in a reaction furnace to obtain a pyrolytic oil liquid-phase product rich in monocyclic aromatic hydrocarbon and limonene. According to the invention, the modified sintering ash is used as a catalyst, so that the yield of pyrolytic oil in the pyrolysis process of the waste tire is increased, and the content of monocyclic aromatic hydrocarbon or limonene in the pyrolytic oil is increased. In addition, Fe and Zn metals are recovered through the rotary hearth furnace. The invention provides an efficient treatment and utilization mode of the sintering ash, meanwhile, the composition of the waste tire pyrolytic oil can be effectively improved, metal resources can be recycled, good environmental benefits and economic benefits can be generated, corresponding environmental problems can be solved, and considerable economic benefits can also be brought.

A method for producing a higher alcohol from a waste plastic feedstock is disclosed, comprising: (a) providing a hydrocarbon feed stream comprising a pyrolysis oil feed obtained from pyrolysis of plastic waste, wherein the pyrolysis oil comprises at least 20 wt % higher olefins with a carbon number in the range C5-C20, based on its total hydrocarbon content; (b) contacting the hydrocarbon feed stream with synthesis gas under hydroformylation conditions in the presence of a hydroformylation catalyst and recovering a hydroformylation product; (c) subjecting the hydroformylation product to hydrogenation and / or a distillation to recover a higher alcohol product.