The invention relates to the technical field of catalyst sulfuration in a
coal gasification process, and particularly discloses a method for sulfuration of a shift catalyst by adding
sulfur into low-
sulfur coal, and the method comprises the following steps: fully mixing byproduct
sulfur with
boiler slag by adopting an internal mixing process to prepare a
slag-sulfur mixture; fully and uniformly mixing the
slag-sulfur mixture with low-sulfur
coal, and feeding the mixture into a coal mill for milling to obtain pulverized coal; the method comprises the following steps: in a
coal gasifier, carrying out online
vulcanization on a shift catalyst by using pulverized coal, setting
slag sampling once every half an hour after adding a slag-sulfur mixture, and monitoring the H2S concentration, the ash
water pH value and the
sulfate radical concentration in the synthesis gas in real time. According to the method, the by-product sulfur and the
boiler slag are subjected to banburying compounding to prepare the slag-sulfur mixture, the slag-sulfur mixture and the low-sulfur coal are uniformly mixed in proportion to prepare
powder, and by controlling the outlet temperature of the coal mill, the circulating
air volume and the pressurized conveying temperature, the stable
combustion of the coal
powder and the on-line
vulcanization of the shift catalyst are realized.