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6047results about "Gasification processes details" patented technology

Mild catalytic steam gasification process

InactiveUS20070000177A1Great carbon conversionLittle additional treatmentGasification processes detailsCombined combustion mitigationMaceralAlkali metal
The present invention provides an improved alkali metal catalyzed steam gasification process that utilizes a CO2 trap material and / or a mineral binder material within the gasifier. The process optimally achieves over 90% carbon conversion with over 80% yield of methane. The raw gas product can be used directly as fuel. The catalyst can be recovered from the solid purge and recycled to the gasifier and / or the CO2 trap can be regenerated and recycled to the gasifier.
Owner:SURE CHAMPION INVESTMENT LTD

Catalytic steam gasification of petroleum coke to methane

The present invention provides a catalytic steam gasification process for gasifying petroleum coke. The solids composition within the gasification reactor of the disclosed invention is maintained by controlling the catalyst composition of the feed. The process utilizes sour water from the raw gasification product gases to recover and recycle catalyst. Fine particles generated in the handling of coke are advantageously utilized to increase the efficiency of the process.
Owner:SURE CHAMPION INVESTMENT LTD

Biomass Char Compositions for Catalytic Gasification

InactiveUS20090217575A1Efficient utilization of carbonEfficient comprehensive utilizationProductsReagentsParticulatesHydrogen
Particulate compositions are described comprising an intimate mixture of a biomass char producedfrom the combustion of a biomass, such as switchgrass or hybrid poplar, with at least a second carbonaceous material, such as petroleum coke or coal, and, optionally a gasification catalyst, for gasification in the presence of steam to yield a plurality of gases including methane and at least one or more of hydrogen, carbon monoxide, and other higher hydrocarbons are formed. Processes are also provided for the preparation of the particulate compositions and converting the particulate composition into a plurality of gaseous products.
Owner:SURE CHAMPION INVESTMENT LTD

Hydrogen production from carbonaceous material

Hydrogen is produced from solid or liquid carbon-containing fuels in a two-step process. The fuel is gasified with hydrogen in a hydrogenation reaction to produce a methane-rich gaseous reaction product, which is then reacted with water and calcium oxide in a hydrogen production and carbonation reaction to produce hydrogen and calcium carbonate. The calcium carbonate may be continuously removed from the hydrogen production and carbonation reaction zone and calcined to regenerate calcium oxide, which may be reintroduced into the hydrogen production and carbonation reaction zone. Hydrogen produced in the hydrogen production and carbonation reaction is more than sufficient both to provide the energy necessary for the calcination reaction and also to sustain the hydrogenation of the coal in the gasification reaction. The excess hydrogen is available for energy production or other purposes. Substantially all of the carbon introduced as fuel ultimately emerges from the invention process in a stream of substantially pure carbon dioxide. The water necessary for the hydrogen production and carbonation reaction may be introduced into both the gasification and hydrogen production and carbonation reactions, and allocated so as transfer the exothermic heat of reaction of the gasification reaction to the endothermic hydrogen production and carbonation reaction.
Owner:BOARD OF SUPERVISORS OF LOUISIANA STATE UNIV & AGRI & MECHANICAL COLLEGE +1

Combustion looping using composite oxygen carriers

A method for producing hydrogen gas is provided and comprises reducing a metal oxide in a reduction reaction between a carbon-based fuel and a metal oxide to provide a reduced metal or metal oxide having a lower oxidation state, and oxidizing the reduced metal or metal oxide to produce hydrogen and a metal oxide having a higher oxidation state. The metal or metal oxide is provided in the form of a porous composite of a ceramic material containing the metal or metal oxide. The porous composite may comprise either a monolith, pellets, or particles.
Owner:OHIO STATE INNOVATION FOUND

Catalyst-Loaded Coal Compositions, Methods of Making and Use

ActiveUS20090048476A1Efficient and high-yielding gasificationHigh yield productionCatalyst regeneration/reactivationSolid fuelsPtru catalystCoal matrix
The present invention relates to catalyst-loaded coal compositions having a moisture content of less than about 6 wt %, a process for the preparation of catalyst-loaded coal compositions, and an integrated process for the gasification of the catalyst-loaded coal compositions. The catalyst-loaded coal compositions can be prepared by a diffusive catalyst loading process that provides for a highly dispersed catalyst that is predominantly associated with the coal matrix, such as by ion-exchange.
Owner:SURE CHAMPION INVESTMENT LTD

Apparatus for converting coal to hydrocarbons

An apparatus for forming liquid hydrocarbons from solid coal. The coal is pulverized to provide a particulate coal feed, which is then extruded to provide a hollow tube of compressed coal supported inside of a support tube. A clay feed is extruded to provide a hollow tube of compressed clay supported inside of the coal tube and a combustible fuel is burned inside of the clay tube. The temperature of combustion is sufficient to fire the extruded clay and pyrolyze the extruded coal to produce hydrocarbon gases and coal char. The support tube has holes for releasing the hydrocarbon gases, which contain suspended particles formed during combustion. The suspended particles are removed from the hydrocarbon gases to provide clean gases, which are passed through an ionizing chamber to ionize at least a portion thereof. The ionized gases are then passed through a magnetic field to separate them from each other according to their molecular weight. Selected portions of at least some of the separated gases are mixed, and the mixed gases are cooled to provide at least one liquid hydrocarbon product of predetermined composition. Portions of the separated gases may also be mixed with the coal char and other input streams, such as waste plastics, and further treated to provide other hydrocarbon products.
Owner:WOOTTEN WILLIAM A

Compositions for Catalytic Gasification of a Petroleum Coke

InactiveUS20090090056A1Cost-effective and high-yielding productionPromote gasificationHydrogenGaseous fuelsParticle compositionMethane gas
The present invention relates to particulate compositions of a lower ash type petroleum coke containing at least two preselected components (alkali metal and calcium) that exhibit an efficient, enhanced-yielding gasification to value added gaseous products, particularly when used in a steady-state integrated gasification process. The compositions of the present invention are particularly useful for catalytic gasification of petroleum coke at moderate temperatures ranging from about 450° C. to about 900° C. Advantageously, the compositions can be readily incorporated into fluidized bed gasification units, and can result in a cost-effective, high-yielding production of methane gas from petroleum coke.
Owner:SURE CHAMPION INVESTMENT LTD

Method and apparatus for producing synthesis gas from carbonaceous materials

A method of producing syn gas from biomass or other carbonaceous material utilizes a controlled devolatilization reaction in which the temperature of the feed material is maintained at less than 450° F. until most available oxygen is consumed. This minimizes pyrolysis of the feed material. The method and apparatus utilizes the formed synthesis gas to provide the energy for the necessary gasification. This provides for a high purity syn gas and avoids production of slag.
Owner:JBK EXTRACTIONS

System and method for converting biomass to ethanol via syngas

A method and apparatus for synthesizing ethanol using synthetic routes via synthesis gas are disclosed. A method and apparatus for gasifying biomass, such as biomass, in a steam gasifier that employs a fluidized bed and heating using hot flue gases from the combustion of synthesis gas is described. Methods and apparatus for converting synthesis gas into ethanol are also disclosed, using stepwise catalytic reactions to convert the carbon monoxide and hydrogen into ethanol using catalysts including iridium acetate.
Owner:WOODLAND BIOFUELS

Catalytic steam gasification process with recovery and recycle of alkali metal compounds

A high efficiency gasification process for converting carbonaceous solids to methane and apparatus for its practice are described. The process includes reacting steam and carbonaceous solids comprising ash in the presence of alkali metal catalyst in a gasification reactor to produce combustible gases and char particles comprising ash and alkali metal catalyst constituents, treating a stream of such char particles in an alkali metal catalyst recovery system to recover the catalyst constituents as alkali metal compounds, and recycling such recovered compounds. Within the alkali metal catalyst recovery system the process includes quenching the stream of char particles with water whereby such particles are cooled and fractured, dissolving soluble alkali metal catalyst constituents from the fractured solids to form a first alkali metal catalyst solution and washed solids, optionally reacting the washed solids in alkaline solution to form a second alkali metal catalyst solution, upgrading said first and optional second alkali solution to recover the alkali metal catalyst constituents as said alkali metal compounds.
Owner:SURE CHAMPION INVESTMENT LTD

Petroleum Coke Compositions for Catalytic Gasification

Particulate compositions are described comprising an intimate mixture of a petroleum coke and an alkali metal gasification catalyst, where the alkali metal gasification catalyst comprises a combination of an alkali metal hydroxide and one or more other alkali metal compounds are loaded onto coke for gasification in the presence of steam to yield a plurality of gases including methane and at least one or more of hydrogen, carbon monoxide, and other higher hydrocarbons are formed. Processes are also provided for the preparation of the particulate compositions and converting the particulate composition into a plurality of gaseous products.
Owner:SURE CHAMPION INVESTMENT LTD

Processes for Gasification of a Carbonaceous Feedstock

The present invention relates to processes and continuous processes for preparing gaseous products, and in particular, methane via the catalytic gasification of carbonaceous feedstocks in the presence of steam. In one aspect of the invention, the processes comprise at least partially combusting a first carbonaceous feedstock with an oxygen-rich gas stream in an oxygen-blown gasifier, under suitable temperature and pressure, to generate a first gas stream comprising hydrogen, carbon monoxide and superheated steam; and reacting a second carbonaceous feedstock and the first gas stream in a catalytic gasifier in the presence of a gasification catalyst under suitable temperature and pressure to form a second gas stream comprising a plurality of gaseous products comprising methane, carbon dioxide, hydrogen, carbon monoxide and hydrogen sulfide. The processes can comprise using at least one catalytic methanator to convert carbon monoxide and hydrogen in the gaseous products to methane and in certain embodiments do not recycle carbon monoxide or hydrogen to the gasifier.
Owner:SURE CHAMPION INVESTMENT LTD

Steam Generating Slurry Gasifier for the Catalytic Gasification of a Carbonaceous Feedstock

Steam generating gasification reactors for providing high-pressure and high-temperature steam for catalytic gasification of a carbonaceous feedstock can be based on oxygen blown gasification reactors adapted for processing a slurry feedstock comprising at least 40% water. The exhaust from the slurry gasifier comprises at least steam, carbon monoxide and hydrogen. The slurry composition and the oxygen to fuel ratio can be varied to control the ratio of carbonaceous gases in the generator exhaust. By directing substantially all of exhaust gases produced from the slurry gasification reactor through the catalytic gasifier and subsequent gas separation and sequestration processes, a greatly higher energy efficiency and decreased carbon footprint can be realized.
Owner:SURE CHAMPION INVESTMENT LTD

Carbonaceous Fuels and Processes for Making and Using Them

The present invention provides carbonaceous fuels and processes for making them. Moreover, the invention also relates to processes using the carbonaceous fuels in the production of cement products. One embodiment of the invention is a carbonaceous fuel comprising (a) unconverted fines of a carbonaceous feedstock, the carbonaceous feedstock having an ash content of greater than 1%, the fines having an average particle size less than about 45 μm; and (b) a char residue formed by catalytic gasification of the carbonaceous feedstock, the char residue having an ash content of greater than about 30%, wherein the ash includes at least one aluminum-containing compound or silicon-containing compound; and having a weight ratio of fines to char residue in the range of about 4:1 to about 1:4, and a total dry basis wt % of carbon of least about 40%. Another embodiment of the invention is a process of making a cement product comprising: (a) providing a carbonaceous fuel as described above; (b) passing the carbonaceous fuel into a cement-making zone; and (c) at least partially combusting the carbonaceous fuel to provide heat for a cement producing reaction within the cement-making zone.
Owner:SURE CHAMPION INVESTMENT LTD

Processes for Gasification of a Carbonaceous Feedstock

The present invention relates to processes for preparing gaseous products, and in particular, methane via the catalytic gasification of carbonaceous feedstocks in the presence of steam and an oxygen-rich gas stream. The processes comprise using at least one catalytic methanator to convert carbon monoxide and hydrogen in the gaseous products to methane and do not recycle carbon monoxide or hydrogen to the catalytic gasifier.
Owner:SURE CHAMPION INVESTMENT LTD

Steam Generation Processes Utilizing Biomass Feedstocks

Integrated catalytic gasification processes are provided involving generating steam for converting carbonaceous materials to combustible gases, such as methane. Generally, steam generated from the combustion of a biomass is provided to a catalytic gasifier, wherein under appropriate temperature and pressure conditions, a carbonaceous feedstock is converted into a plurality of product gases, including, but not limited to, methane, carbon monoxide, hydrogen, and carbon dioxide.
Owner:SURE CHAMPION INVESTMENT LTD

Processes for Making Synthesis Gas and Syngas-Derived Products

The present invention provides processes for making synthesis gas and processes for making syngas-derived products. For example, one aspect of the present invention provides a process for making a synthesis gas stream comprising hydrogen and carbon monoxide, the process comprising (a) providing a carbonaceous feedstock; (b) reacting the carbonaceous feedstock in a gasification reactor in the presence of steam and a gasification catalyst under suitable temperature and pressure to form a raw product gas stream comprising a plurality of gases comprising methane, hydrogen and carbon monoxide; (c) removing steam from and sweetening the raw product gas stream to form a sweetened gas stream; (d) separating and adding steam to the sweetened gas stream to form a first reformer input gas stream having a first steam / methane ratio; and a second reformer input stream having a second steam / methane ratio, in which the first steam / methane ratio is smaller than the second steam / methane ratio; (e) reforming the second reformer input stream to form a recycle gas stream comprising steam, carbon monoxide and hydrogen; (f) introducing the recycle gas stream to the gasification reactor; and (g) reforming the first reformer input stream to form the synthesis gas stream.
Owner:SURE CHAMPION INVESTMENT LTD

Production of Blended Fuel from Renewable Feedstocks

A process for producing a blended fuel from a paraffin rich component and a cyclic rich component, where each of the components are generated from a renewable feedstock, is presented. The paraffin rich component is generated from a first renewable feedstock comprising at least one component selected from the group consisting of glycerides, free fatty acids, biomass, lignocellulose, free sugars, and combinations thereof. The cyclic rich component is generated from a second renewable feedstock comprising at least one component selected from the group consisting of glycerides, free fatty acids, free fatty alkyl esters, biomass, lignocellulose, free sugars, and combinations thereof. The blended fuel may a gasoline boiling point range blended fuel, a diesel boiling point range blended fuel, an aviation boiling point range blended fuel, any combination thereof, or any mixture thereof.
Owner:UOP LLC

Method and apparatus for producing methane from carbonaceous material

A method for producing methane (69) from a carbonaceous (22) material includes conveying pulverized carbonaceous material (28) entrained in an inert carrier fluid, such as carbon dioxide (36), into a reactor (34). The reactor (34) includes a vortex region (72) for receiving hydrogen gas (38) and imparting a swirling motion to the hydrogen gas (38). The pulverized carbonaceous material (28) is exposed to the swirling stream of hydrogen gas (38) in a first reaction zone (114) within the reactor (34) to form an exit gas (40) that includes methane (69). Remaining unreacted carbonaceous material (28) is further exposed to the hydrogen gas (38) in a second, low velocity, reaction zone (120). The methane rich exit gas (40) is subsequently extracted from the reactor (34) for further processing.
Owner:ARIZONA PUBLIC SERVICE

Coal Compositions for Catalytic Gasification

Particulate compositions are described comprising an intimate mixture of a coal and a gasification catalyst in the presence of steam to yield a plurality of gases including methane and at least one or more of hydrogen, carbon monoxide, carbon dioxide, hydrogen sulfide, ammonia and other higher hydrocarbons are formed. Processes are also provided for the preparation of the particulate compositions and converting the particulate composition into a plurality of gaseous products.
Owner:SURE CHAMPION INVESTMENT LTD

Petroleum Coke Compositions for Catalytic Gasification

Particulate compositions are described comprising an intimate mixture of a petroleum coke, coal and a gasification catalyst, where the gasification catalyst is loaded onto at least the coal for gasification in the presence of steam to yield a plurality of gases including methane and at least one or more of hydrogen, carbon monoxide, and other higher hydrocarbons are formed. Processes are also provided for the preparation of the particulate compositions and converting the particulate composition into a plurality of gaseous products.
Owner:SURE CHAMPION INVESTMENT LTD

Process and system for converting carbonaceous feedstocks into energy without greenhouse gas emissions

The process of the invention converts carbonaceous feedstock such as coal, hydrocarbon oil, natural gas, petroleum coke, oil shale, carbonaceous-containing waste oil, carbonaceous-containing medical waste, carbonaceous-containing military waste, carbonaceous-containing industrial waste, carbonaceous-containing medical waste, carbonaceous-containing sewage sludge and municipal solid waste, carbonaceous-containing agricultural waste, carbonaceous-containing biomass, biological and biochemical waste, and mixtures thereof into electrical energy without the production of unwanted greenhouse emissions. The process uses a steam / CO2 reformer operating in the exit range of at least 700° to about 1600° C. (1300-2900°0 F.) to convert the carbonaceous feedstock and a greenhouse gas stream into a synthesis gas comprising mostly carbon monoxide and hydrogen that contains poisons and the compounds that poison fuel cells. The syngas is sent to an interface zone to remove these poisons and other fouling compounds that are electrochemically oxidized in an electricity-producing fuel cell into an exit gas comprising carbon dioxide and water.
Owner:RAVEN SR INC

Catalytic Gasification Process with Recovery of Alkali Metal from Char

Processes are described for the extraction and recovery of alkali metal from the char that results from catalytic gasification of a carbonaceous material. Among other steps, the processes of the invention include a hydrothermal leaching step in which a slurry of insoluble particulate comprising insoluble alkali metal compounds is treated with carbon dioxide and steam at elevated temperatures and pressures to effect the conversion of insoluble alkali metal compounds to soluble alkali metal compounds. Further, processes are described for the catalytic gasification of a carbonaceous material where a substantial portion of alkali metal is extracted and recovered from the char that results from the catalytic gasification process.
Owner:SURE CHAMPION INVESTMENT LTD

Catalytic Gasification Process with Recovery of Alkali Metal from Char

Processes are described for the extraction and recovery of alkali metal from the char that results from catalytic gasification of a carbonaceous material. Among other steps, the processes of the invention include a hydrothermal leaching step in which a slurry of insoluble particulate comprising insoluble alkali metal compounds is treated with carbon dioxide and steam at elevated temperatures and pressures to effect the conversion of insoluble alkali metal compounds to soluble alkali metal compounds. Further, processes are described for the catalytic gasification of a carbonaceous material where a substantial portion of alkali metal is extracted and recovered from the char that results from the catalytic gasification process.
Owner:SURE CHAMPION INVESTMENT LTD

Catalytic Gasification Process with Recovery of Alkali Metal from Char

Processes for extracting and recycling alkali metal compounds present in the char produced from the catalytic gasification of carbonaceous materials are provided involving at least contacting the char with and alkali metal hydroxide followed by carbon dioxide. Both the alkali metal hydroxide and carbon dioxide treatments serve to convert at least a portion of the insoluble alkali metal compounds in the char into soluble species which can be recovered and recycled.
Owner:SURE CHAMPION INVESTMENT LTD

Catalytic Gasification Process with Recovery of Alkali Metal from Char

Processes are described for the extraction and recovery of alkali metal from the char that results from catalytic gasification of a carbonaceous material. Among other steps, the processes of the invention include a hydrothermal leaching step in which a slurry of insoluble particulate comprising insoluble alkali metal compounds is treated with carbon dioxide and steam at elevated temperatures and pressures to effect the conversion of insoluble alkali metal compounds to soluble alkali metal compounds. Further, processes are described for the catalytic gasification of a carbonaceous material where a substantial portion of alkali metal is extracted and recovered from the char that results from the catalytic gasification process.
Owner:SURE CHAMPION INVESTMENT LTD

Biomass fast pyrolysis system utilizing non-circulating riser reactor

A biomass fast pyrolysis system for conversion of biomass vegetation to synthetic gas and liquid fuels includes: a) a non-circulating riser reactor for pyrolysis of biomass vegetation feedstock utilizing a heat carrier, the non-circulating riser reactor being physically structured and adapted to have a rate of reaction of at least 8,000 biomass vegetation feedstock lbs / hr / ft2, utilizing a ratio of heat carrier to biomass vegetation feedstock of about 7:1 to about 11.5:1, the riser reactor having a base input region at its bottom, a central reaction region and an output region at its top, the riser reactor including a cyclone disengager at its output region for separation of pyrolysis resulting char and heat carrier from the pyrolysis product gases, the cyclone disengager having an output downcomer and an output upcomer, the cyclone disengager output downcomer being connected to and feeding into a side combustor unit, the riser reactor being a non-circulating riser reactor in that the heat carrier is not returned directly to the riser reactor from the cyclone disengager and travels first down the cyclone disengager output downcomer to the side combustor unit; and, b) the side combustor unit for combusting pyrolysis resultant char and reheating the heat carrier the side combustor having a heat carrier downcomer connected to the base input region of the riser reactor.
Owner:INNOVATIVE ENERGY GLOBAL

Coal Compositions for Catalytic Gasification

Particulate compositions are described comprising an intimate mixture of a coal and a gasification catalyst. The particulate compositions are gasified in the presence of steam to yield a plurality of gases including methane and at least one or more of hydrogen, carbon monoxide, carbon dioxide, hydrogen sulfide, ammonia and other higher hydrocarbons. Processes are also provided for the preparation of the particulate compositions and converting the particulate composition into a plurality of gaseous products.
Owner:SURE CHAMPION INVESTMENT LTD
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