28results about "Multiple metal hydrides" patented technology

This invention belongs to the field of compound synthesis technology and provides a method for preparing lithium aluminum hydride. The method includes the following steps: mixing an organic solution of aluminum trichloride and an organic solution of lithium hydride to perform a displacement reaction, obtaining a mixture of lithium aluminum hydride; mixing the lithium aluminum hydride mixture with a hydrocarbon solvent and performing solid-liquid separation to obtain lithium aluminum hydride. Lithium aluminum hydride is insoluble in hydrocarbon solvents and precipitates out, further improving the yield of lithium aluminum hydride; simultaneously, unreacted aluminum trichloride dissolves in the hydrocarbon solvent, thereby increasing the main content of lithium aluminum hydride. The preparation process of this invention has high yield, stable product content, and is easy to implement and industrialize.

Metal-based hydrogen storage fibers capable of selectively absorbing and desorbing / releasing hydrogen gas, and hydrogen storage vessels comprising the fibers, wherein the fibers are preferably arranged in a fabric. The fabric is a porous structure with a large surface area, which is well suited for hydrogen storage and transport. A hydrogen storage system is provided with attractive properties. Hydrogen storage in metal hydride fibers provides a compact and safe method of hydrogen storage, wherein hydrogen molecules in the gas phase can be adsorbed on the surface of the fibers, thereby forming metal hydrides, or dissociated into individual hydrogen atoms, which can further diffuse into the bulk of the metal hydride fiber and occupy sites in the metal hydride fiber matrix.

The invention discloses a preparation method of lithium aluminum deuteride and application of the lithium aluminum deuteride in drug synthesis, and belongs to the technical field of inorganic chemistry. The method comprises the following steps: suspending lithium aluminum hydride in an anhydrous organic solvent under the protection of inert gas, slowly dropwise adding a deuterated methanol solution at the low temperature of-10 DEG C to 0 DEG C, and reacting for 1-2 hours; and carrying out heating reaction, filtration, concentration, seed crystal induced low-temperature crystallization, precooling washing and drying to obtain the high-purity lithium aluminum deuteride. The method is mild in reaction condition, safe to operate and high in deuteration efficiency, the purity of the obtained product is greater than or equal to 98%, and the abundance of deuterium atoms is greater than or equal to 99.8%; the invention also discloses application of the lithium aluminum deuteride in synthesis of a key intermediate of a deuterated drug, and provides a high-quality deuterium source reducing agent and an effective synthesis path for research and development of the deuterated drug.

The invention discloses a hydrogen-based superconducting material Na2GaCuH6 with a double perovskite structure under normal pressure and a preparation method of the hydrogen-based superconducting material Na2GaCuH6. The material has an Fm-3m space group, the lattice constant is calculated and predicted through the first principle, and the material has the superconducting transition temperature of 42.04 K under the normal pressure condition. The material is composed of four common elements of Na, Ga, Cu and H, and the cost is low; the double perovskite structure is stable in thermodynamics and dynamics under normal pressure; the electro-acoustic coupling constant lambda is approximately equal to 0.98, and medium-intensity electro-acoustic coupling is achieved. Compared with an existing high-voltage hydride superconductor, the material can work without high-voltage equipment, and the preparation and application cost is greatly reduced; compared with a traditional normal-pressure superconductor, the superconductor has a higher Tc value. The material can be applied to the fields of low-temperature superconducting devices, superconducting magnets, quantum computing and the like, and has important scientific research value and application prospect.

A method of forming an actinide-yttrium hydride includes introducing an yttrium feedstock and an actinide feedstock to a milling / mixing unit. The yttrium and actinide feedstocks are milled and mixed to form a milled mixture. The milled mixture is consolidated in a consolidation unit at a consolidation temperature to form a high-density bulk solid material. The high-density bulk solid material is exposed to hydrogen at a hydriding temperature and a hydriding pressure to form the actinide-yttrium hydride. A composition and system is also disclosed.

To provide a hydrogen storage material with reduced cost for absorbing or releasing hydrogen.SOLUTION: A hydrogen storage material according to one aspect of the present invention contains a hydride represented by a composition formula AlxMn1-xHy where x is 0.1 or more and 0.5 or less.SELECTED DRAWING: None

Disclosed is a preparation method for a nano magnesium hydride-loaded composite material, comprising the following steps: adding a cationic surfactant into an aqueous dispersion of a two-dimensional transition metal carbide, such that two-dimensional transition metal carbide nanosheets wrinkle, avoiding re-stacking, and then washing and drying same; packing the dried product into a sealed container, vacuumizing same and then raising the temperature to a high temperature, maintaining the temperature for a period of time, then filling the sealed container with high-pressure hydrogen, and maintaining the temperature for a period of time; and finally, adding the product that is subjected to heat treatment and dibutyl magnesium into an organic solvent to obtain a mixture and carrying out ultrasonic dispersion on same, stirring and heating for 12-48 hours under conditions that the hydrogen pressure is 3-6 MPa and the temperature is 180-220°C, and carrying out centrifugal drying to then obtain a nano magnesium hydride-loaded composite material. The two-dimensional transition metal carbide nano magnesium hydride-loaded composite material prepared in the present invention has advantages such as high hydrogen storage density, rapid hydrogen absorption and desorption dynamic performance and excellent cycle stability.

The application discloses a preparation method of a superhigh-nickel high-cycle cobalt-free positive electrode material, and comprises the following steps: S1, a nickel source, a manganese source, a complexing agent and a precipitant are prepared into a reaction solution to perform a coprecipitation reaction, so that slurry is obtained; and centrifugation, washing and drying are performed to obtain nickel-manganese hydroxide; S2, the nickel-manganese hydroxide is uniformly mixed with a lithium source and a dopant to obtain a mixture, and first sintering is performed; the oxygen concentration in a sintering atmosphere is 86%-88%, and the sintering temperature is 650 DEG C-800 DEG C; S3, the sintered material is crushed, pickled and dried; and S4, the dried material is uniformly mixed with a coating agent, and second sintering is performed. The application adjusts the cationic disordering of the material and controls the cationic disordering degree within a certain range; the internal and external lattice distortions are relatively uniform; the cycle performance is good; the capacity attenuation is more uniform; and therefore, the cycle performance of the positive electrode material is optimal.

The invention discloses a monatomic catalyst for catalytic synthesis of sodium aluminum hydride, a composite hydrogen storage system containing the monatomic catalyst and a preparation method, two-dimensional layered Ti3CN is used as a carrier, an active component monatomic zirconium is loaded, the catalyst Zr (SA) / Ti3CN is prepared, Zr stably exists on the surface of the Ti3CN carrier in an atomic-scale dispersion form, and the composite hydrogen storage system is used for catalytic synthesis of sodium aluminum hydride. According to the present invention, by using the single atom catalyst, the near 100% utilization rate of Zr atoms is achieved, the rich N atoms in the Ti3CN carrier and Zr form the strong coordination bond (Zr-N), the single atoms are effectively anchored, the migration and agglomeration of the single atoms are prevented, the initial hydrogen desorption temperature of the composite hydrogen storage system (containing 7 wt% (1 wt% Zr (SA)) / Ti3CN) prepared by using the single atom catalyst is significantly reduced to about 86 DEG C, and the hydrogen desorption amount at 300 DEG C is as high as 5.1 wt%.

The invention belongs to the field of hydrogen storage materials, and provides a planetary shear mixing method of metal hydride powder. According to the invention, a planetary shear mixer is adopted to carry out pulse-type shear mixing on a metal hydride main phase, Ti-MgH2 core-shell intermediate powder, a catalytic doping agent, a heat-conducting and anti-agglomeration auxiliary agent, lithium hydride and a lubricating and coating auxiliary agent in the same direction of revolution and rotation in an inert atmosphere; by accurately controlling revolution speed, autorotation speed ratio and unit mass specific energy input, highly uniform dispersion and interface modification of the powder are realized, and particle size distribution uniformity, specific surface area, compact density and effective hydrogen storage capacity retention rate of the mixed powder are remarkably improved. The technical problems of high compaction density and hydrogen absorption and desorption dynamic coupling, strong shear dispersion and core-shell structure stability balance, contradiction between carbon-based network construction and effective hydrogen storage density and the like of an existing hydrogen storage system are solved, and wide hydrogen storage application value is achieved.

To provide a hydride ion conductor that has high conduction properties at room temperature and a method for producing the same, and an all-solid-state battery that includes the hydride ion conductor and can operate at room temperature.SOLUTION: A hydride ion conductor has a composition represented by the general formula M1xM2yM3zHαOβ (where M1 represents a trivalent rare earth element, M2 represents at least one Group 2 element selected from the group consisting of Mg, Ca, Sr and Ba, and M3 represents at least one Group 1 element selected from alkali metals, with 0.4≤x<1, 0≤y≤0.6, 0≤z≤0.5, 0.7<x+y+z≤1, 0<y+z≤0.6, 2<α<3, 0≤β<0.3, 3x+2y+z=α+2β).SELECTED DRAWING: Figure 1

The invention relates to a process for producing lithium aluminum hydride, LiAlH4, by splitting lithium aluminum hexahydride, Li3AlH6, in an aprotic solvent or an aprotic solvent mixture, wherein the solvent or solvent mixture contains at least one cyclic ether and / or at least one polyfunctional ether.

The hydride ion conductor has the general formula represented by formula (1): Ba2-x-mAxMg1-y-nByH6-x-y-2m-2n where A and B are each selected from at least one or more species in the group consisting of Li, Na, K, Rb, and Cs, and 0 ≤ x ≤ 1, 0 ≤ y ≤ 1, 0 ≤ m ≤ 0.2, and 0 ≤ n ≤ 0.2, with the proviso that x = y = m = n = 0 is excluded.

This invention provides a method for preparing a modified magnesium-based hydrogen storage material, comprising the following steps: mixing a certain amount of magnesium-based hydrogen storage material precursor with a certain amount of dispersion at room temperature and stirring until homogeneous; adding a certain amount of acid etchant dropwise under continuous stirring; reacting for 1-3 hours; then separating the solid phase material and drying it under vacuum to obtain the modified magnesium-based hydrogen storage material. The modified magnesium-based hydrogen storage material of this invention is obtained through a simple acid etching process, which can effectively improve the catalytic activity of the material in the hydrogenation reaction of organic liquids, thereby solving the problem of low hydrogenation activity and high energy consumption caused by long reaction times of existing catalysts.

The invention discloses a lithium aluminum hydride diethyl ether solution filtering and impurity removing method and device. The method comprises the following steps: enabling a lithium aluminum hydride diethyl ether solution needing to be filtered for impurity removal to flow through a plate-and-frame filter; the plate-and-frame filter is used for filtering lithium chloride particles in the lithium aluminum hydride diethyl ether solution based on the pore size and the material of the plate-and-frame filter; enabling the lithium aluminum hydride diethyl ether solution passing through the plate frame filter to flow through a precision filter; the precision filter is used for filtering insoluble substance lithium chloride small particles in the lithium aluminum hydride diethyl ether solution; and collecting the lithium aluminum hydride diethyl ether solution passing through the precision filter to obtain filtered and impurity-removed clear liquid. The method provided by the invention is used for filtering and impurity removal of lithium chloride in the lithium aluminum hydride diethyl ether solution produced on a large scale, and the method is simple to operate, low in cost and suitable for large-scale production.

The invention discloses a preparation method of a metal hydride block, the block obtained through the preparation method and hydrogen storage equipment, and relates to the field of hydrogen storage and transportation and medium preparation. The preparation method of the metal hydride block comprises the following steps: uniformly mixing powder or filaments of crushed hydrogen storage metal / metal alloy and heat-conducting metal and / or nonmetal, and carrying out cold pressing in a preset mold to obtain a block; and carrying out high-temperature hydrogenation on the pressed and molded block in a hydrogenation reactor to obtain the metal hydride block. According to the method, hydrogenation is conducted after pressing, the problems that in an existing magnesium powder hydrogenation process, powder particles are prone to agglomeration and sintering, the safety risk is large, and heat and mass transfer is slow are solved, the method has better heat conductivity and higher porosity, and safe and efficient large-scale metal hydride preparation is better achieved.

A hydride ion conductor, the general formula of which is represented by formula (1), MAMBH 4－x F x (1), wherein MA is selected from Ca, Sr and Ba, MB is selected from Mg and Ca and is different from MA, and 0 < x < 4.

The invention provides an electrochemical preparation method of a coordination hydride, which comprises the following steps: mixing a simple hydride AaHb of a metal A with a metal B or an alloy containing the metal B to obtain a mixture; using the mixture as a working electrode, using an A < + >-containing ion conductor as an electrolyte, and using a material capable of reversibly storing A ions as a counter electrode to assemble an electrochemical battery; voltage or current is applied, so that external circuit electrons flow from the counter electrode to the working electrode, meanwhile, A < + > flows from the working electrode to the counter electrode through the electrolyte, and the coordination hydride AXBYHZ is generated through in-situ electrochemical oxidation. The method is simple in process, mild in condition and low in cost, the ion / electron conductivity, the reaction kinetics and the cycling stability of the material can be effectively improved, the electrochemical performance and the hydrogen storage performance of the material can be effectively improved, and a new material system is expanded.

The application discloses a process method for preparing a nano-limited NaAlH4 hydrogen storage material capable of low-pressure circulation with low energy consumption, and comprises the following preparation steps: (1) pretreating selected two-dimensional carrier materials; (2) placing aluminum powder, sodium, triethylaluminum and an organic solvent into a high-pressure reaction kettle in an argon-filled glove box; (3) dispersing the pretreated two-dimensional carrier materials in the organic solvent, and sealing the reaction kettle; (4) placing the reaction kettle in an ultrasonic machine for ultrasonic mixing and dispersion; (5) vacuumizing the reaction kettle, filling hydrogen into the reaction kettle, heating the reaction kettle at a certain heating rate, and keeping for a period of time; (6) after the reaction is completed, cooling the reaction kettle to room temperature, and discharging the remaining hydrogen pressure; (7) placing the mixture under dynamic vacuum for solvent removal and drying, and obtaining the nano-limited NaAlH4. Through the above method, the pressure and temperature of the loading process are effectively reduced, and the synthesis of NaAlH4 and nano-loading are combined.

A method of treating an at least partially unconsumed hydrogen generator cartridge including water and a metal hydride includes treating the at least partially unconsumed hydrogen generator cartridge to form a treated hydrogen generator cartridge. When subjected to testing conditions the treated hydrogen generator cartridge produces no hydrogen gas or produces hydrogen gas at a lower rate than the at least partially unconsumed hydrogen generator cartridge subjected to the testing conditions. The testing conditions include heating at less than or equal to 300° C., agitation, exposing the metal hydride to a protic solvent, or a combination thereof.

A method (100) for producing a particulate titanium alloy product can include preparing (110) a composite particulate oxide mixture with TiO2 powder and at least one alloying element powder. The composite particulate oxide mixture can be co-reduced (120) using a metallic reducing agent under a hydrogen atmosphere at a reduction temperature for a reduction time sufficient to produce a hydrogenated titanium alloy product. The hydrogenated titanium alloy product can then be heat treated (130) under a hydrogen atmosphere and a heat treating temperature to reduce pore size and specific surface area to form a heat treated hydrogenated titanium product. The heat treated hydrogenated titanium product can be deoxygenated (140) to reduce residual oxygen to less than 0.2 wt% to form a deoxygenated hydrogenated titanium product as a particulate. The deoxygenated hydrogenated titanium product can optionally be dehydrogenated (150) to form the titanium alloy product as a particulate.

The invention discloses a g-C3N4 loaded LiAlH4 composite material based on an anti-solvent method as well as a preparation method and application of the g-C3N4 loaded LiAlH4 composite material. The composite material is named g-C3N4 / LiAlH4, the ratio of the g-C3N4 to the LiAlH4 is (1-5): (5-10), the macroscopic form of the composite material is a solid nano particle, and the particle size is 10-20 nm. The preparation method comprises the following steps: weighing LiAlH4 and anhydrous LiI, dissolving the LiAlH4 and the anhydrous LiI in diethyl ether, and filtering out insoluble substances to form a solution A; weighing g-C3N4, dissolving g-C3N4 in diethyl ether, and performing ultrasonic treatment to form a solution B; mixing the solution A with the solution B to form a solution C; cooling the n-pentane to-10 DEG C to 0 DEG C by using a semiconductor cooler; ultrasonic shearing dispersion is started, so that the n-pentane liquid level does not fluctuate; absorbing the solution C, and dropwise adding the solution C into n-pentane during the ultrasonic starting period to form a turbid liquid D; centrifuging or performing suction filtration on the turbid liquid D to obtain a precipitate; and carrying out vacuum drying on the precipitate to obtain the g-C3N4 / LiAlH4. According to the preparation method, LiAlH4 is loaded on g-C3N4 in a nanocrystallization manner by utilizing an anti-solvent method, the hydrogen storage performance of the composite material is remarkably improved, the process is simple, the thermodynamic and dynamic performance of LiAlH4 is optimized, and the preparation method has potential application value in the field of solid hydrogen storage.

Disclosed is a device for preparing multi-component metal hydroxide including a raw material feeder configured to feed raw materials including a metal raw material, a pH adjuster and a complexing agent, a reactor configured to react the raw materials fed from the raw material feeder to prepare a reaction solution and grow particles of multi-component metal hydroxide contained in the reaction solution, a storage tank configured to store the reaction solution transferred from the reactor, a first duct configured to transfer the raw materials from the raw material feeder to the reactor, a second duct configured to transfer the reaction solution from the reactor to the storage tank, a third duct configured to transfer the reaction solution from the storage tank to the reactor, and an operation controller configured to control operations of the reactor and the storage tank to circulate the reaction solution between the reactor and the storage tank until the particles of multi-component metal hydroxide grow to a target particle size.

The invention relates to a process for the preparation of lithium aluminum hydride, LiAlH4, by decomposition of lithium aluminum hexahydride, Li3AlH6, in an aprotic solvent or an aprotic solvent mixture, wherein the solvent or solvent mixture contains at least one cyclic ether and / or at least one polyfunctional ether.

The invention discloses a lithium aluminum hydride crystallization drying method and system. The method comprises the following steps: concentrating and distilling a lithium aluminum hydride diethyl ether solution to separate out diethyl ether to obtain a lithium aluminum hydride concentrated solution; introducing the lithium aluminum hydride concentrated solution into a dynamic crystallizer, continuously stirring at a first stirring speed within a first stage time, and controlling the temperature of the lithium aluminum hydride concentrated solution to be kept at a first temperature for vacuum crystallization and drying; in the second stage time, continuously stirring according to a second stirring speed, controlling the temperature of the lithium aluminum hydride concentrated solution to be kept at a second temperature, and performing vacuum crystallization and drying to obtain dried lithium aluminum hydride; the first temperature is higher than the second temperature, and the first stirring speed is lower than the second stirring speed. Through the method, dynamic crystallization and drying of lithium aluminum hydride are realized, and the production efficiency and the product quality can be improved.

The present disclosure relates to a method of preparing a nano-porous powder material. The method includes: firstly removing A in the alloy AxTy by using an ultrasonically-assisted de-alloying method to prepare a nano-porous T coarse powder, and then, allowing the nano-porous T coarse powder to perform M-ization reaction with a gas reactant containing M to obtain a nano-porous T-M coarse powder, and finally, further crushing the nano-porous T-M coarse powder using a jet mill to obtain a nano-porous T-M fine powder. The method can achieve low-cost mass production of the nano-porous T-M fine powder, bringing broad application prospects.

The invention discloses a high-entropy alloy hydride material which is a metal hydride and comprises the following metal elements in percentage by mass: 15-25% of Ti, 15-25% of Nb, 15-25% of V, 15-25% of Hf, 15-25% of Zr and the balance of H. The preparation method of the high-entropy alloy hydride material comprises the following steps: (1) in an argon atmosphere, mixing niobium pentachloride, zirconium tetrachloride, hafnium tetrachloride, titanium tetrachloride and vanadium trichloride in proportion, adding anhydrous lithium chloride, and carrying out ball milling; (2) adding lithium hydride, and carrying out ball milling and sample tamping; (3) carrying out repeated ultrasonic cleaning and centrifugation on the obtained substance, and collecting a solid precipitate; and (4) the obtained solid precipitate is subjected to vacuum drying and grinding, and the high-entropy alloy hydride material is obtained. The prepared material has excellent thermocatalytic performance, the preparation method is simple and efficient, and the hydrogen absorption and desorption performance and reversibility of MgH2 can be effectively improved.