The invention relates to a method for preparing
new energy hydrogen from waste wood, which comprises the following steps of: (1) pretreating the waste wood, baking and carbonizing, and activating and coordinating by using
water vapor containing CO2 to prepare string-hole carbon; (2) reacting the string-hole carbon with
superheated steam, and controlling the temperature to obtain a large amount of H2 and a small amount of CO; (3) introducing the gas product into a reactor filled with an innovative composite catalyst consisting of Fe, Au elementary substances and four
metal oxides, and carrying out catalytic reaction on the gas product and overheated
water vapor to convert CO into CO2 and synchronously produce H2; (4) mixing the obtained CO2 and H2, introducing the mixture into a reactor containing a cheap CO2 targeted selective absorption reactant, and removing CO2 while byproducts of high-value nano
calcium carbonate whiskers and
sodium carbonate nanoparticles are obtained; and (5) treating the
tail gas to obtain pure H2. According to the method, the low-value waste wood is converted into high-value
hydrogen through a combined process, meanwhile, a high-value product is produced as a byproduct, and the method has the advantages of being
environmentally friendly, low in carbon, free of emission, high in
hydrogen production rate, small in catalyst loss, low in cost, zero in CO2 emission and the like.