The invention relates to a nano-material mixed modified superhigh-temperature high-performance well cementing slurry system and a preparation method thereof. The slurry system comprises the followingingredients in parts by weight: 100 parts of oil well cement, 15-25 parts of coarse silica sand, 15-20 parts of fine silica sand, 1-10 parts of nano-silicon dioxide, 1-10 parts of nano-calcium carbonate, 0.2-1 part of a defoaming agent, 4-10 parts of a fluid loss agent, 0-3 parts of a drag reduction agent, 0.5-4 parts of a retarder and 30-100 parts of water. In the slurry system, set cement has excellent compressive strength and toughness under superhigh temperature, and the compressive strength and the elasticity modulus cannot be obviously changed as the maintenance time is prolonged. The slurry system has good rheological property, lower water loss and proper thickening time, and the comprehensive properties of the slurry system can completely meet the related requirements of site wellcementing construction, so that the technical support is provided for well cementing under high temperature. A nano-material obtained by mixing the nano-silicon dioxide and the nano-calcium carbonateis added, and micropores of the set cement can be effectively filled, so that the system becomes denser. Therefore, the volume shrinkage of the set cement is relieved.