Preparation method of low-cost high-alumina ceramic thin plate

A high-aluminum ceramics, low-cost technology, applied in the field of architectural ceramics, can solve the problems of high cost and limit the application of ceramic sheets, and achieve the effects of improving strength, extending crack propagation paths, and dispersing stress in the body

Active Publication Date: 2018-02-23
WUHAN UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, industrial alumina is generally added to the formula of high-alumina ceramic sheet blanks, resulting in high costs and limiting the application of ceramic sheets
[0003] Chinese invention patent "A Method for Manufacturing Large Silicon Oxide Ceramic Sheets" (CN201110039459.9) prepared high-silicon ceramic sheets with a fracture strength of only 45-50 MPa; "(Zhou Jianer et al. Journal of Ceramics, 2006, 27(3): 243-249.) A high-alumina ceramic sheet was prepared at 1240°C by adding 30% industrial alumina micropowder, with a strength of 143MPa and a high cost; Chinese invention patent "A method of using coal gangue and potassium feldspar to prepare ceramic thin plates and ceramic thin plates prepared by this method" (CN201610214106.0) Prepare ceramic thin plates by adding coal gangue, the strength reaches 70.29MPa, and the firing temperature is 1270 ℃; "Processing and properties of large-sized ceramic slabs" (Raimondo, Dondi, et al. Boletín De La Sociedad De Cerámica Y Vidrio, 2010,49(4):289-295.) prepared a large-scale ceramic sheet with a flexural strength of 78MPa and a firing temperature of 1220°C; Chinese invention patent "A Quartz Placer Tailings or Silica Placer Tailings-based high-strength ceramic plate and its preparation method” (CN104496438A) uses quartz sand tailings and other raw materials to prepare ceramic thin plates. Although the firing temperature is 900 ° C, the flexural strength is only 32-37 MPa

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  • Preparation method of low-cost high-alumina ceramic thin plate
  • Preparation method of low-cost high-alumina ceramic thin plate
  • Preparation method of low-cost high-alumina ceramic thin plate

Examples

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Embodiment 1

[0029] A method for preparing a low-cost high-alumina ceramic thin plate, which comprises the following steps:

[0030] 1) Raw material processing: Coal-based kaolin, calcined bauxite, ordinary kaolin, feldspar (feldspar is potassium feldspar and albite), talc, and quartz are ball-milled for 16 hours respectively, and sieved to prepare powder for later use. Calcined bauxite requires a 325-mesh sieve, and coal-series kaolin, ordinary kaolin, feldspar, talc, and quartz all pass through a 250-mesh sieve. The coal series kaolin is the coal series kaolin raw ore provided by Shanxi Gold Ocean Energy Co., Ltd. The calcined bauxite is Henan Xinmi calcined bauxite with a particle size of 325 meshes. The ordinary kaolin, feldspar, talc and quartz are from Xiangyang Gaoming Mining Co., Ltd., the green body strengthening agent is TY-2 green body strengthening agent of Jingdezhen Ceramic University;

[0031] 2) Proportion and mixing of raw materials: according to the mass percentage of ea...

Embodiment 2

[0043] A method for preparing a low-cost high-alumina ceramic thin plate, which comprises the following steps:

[0044] 1) Raw material processing: Coal-based kaolin, calcined bauxite, ordinary kaolin, feldspar (feldspar is potassium feldspar and albite), talc, and quartz are ball-milled for 18 hours with a ball mill, and sieved to prepare powder for later use. Calcined bauxite requires a 325-mesh sieve, and coal-series kaolin, ordinary kaolin, feldspar, talc, and quartz all pass through a 250-mesh sieve. The coal series kaolin is the coal series kaolin raw ore provided by Shanxi Gold Ocean Energy Co., Ltd. The calcined bauxite is Henan Xinmi calcined bauxite with a particle size of 325 meshes. The ordinary kaolin, feldspar, talc and quartz are from Xiangyang Gaoming Mining Co., Ltd., the green body strengthening agent is TY-2 green body strengthening agent of Jingdezhen Ceramic University;

[0045] 2) Proportion and mixing of raw materials: according to the mass percentage o...

Embodiment 3

[0053] A method for preparing a low-cost high-alumina ceramic thin plate, which comprises the following steps:

[0054] 1) Raw material processing: Coal-based kaolin, calcined bauxite, ordinary kaolin, feldspar (feldspar is potassium feldspar and albite), talc, and quartz are ball-milled for 20 hours respectively with a ball mill, and sieved to prepare powder for later use. Calcined bauxite requires a 325-mesh sieve, and coal-series kaolin, ordinary kaolin, feldspar, and talc all pass through a 250-mesh sieve. The coal series kaolin is the coal series kaolin raw ore provided by Shanxi Gold Ocean Energy Co., Ltd. The calcined bauxite is Henan Xinmi calcined bauxite with a particle size of 325 meshes. The ordinary kaolin, feldspar, talc and quartz are from Xiangyang Gaoming Mining Co., Ltd., the green body strengthening agent is TY-2 green body strengthening agent of Jingdezhen Ceramic University;

[0055] 2) Proportioning and mixing of raw materials: according to the mass perc...

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Abstract

The invention relates to a preparation method of a low-cost high-alumina ceramic thin plate. The preparation method of the low-cost high-alumina ceramic thin plate is characterized by including the steps: 1) raw material treatment; 2) raw material proportioning and mixing: weighing raw materials including, in weight percent, 10%-25% of coal series kaolinite, 10%-25% of calcined bauxite, 20%-30% ofcommon kaolinite, 15%-25% of feldspar, 0-5% of talcum and 18%-25% of quartz to obtain a blank; adding reinforcing agents equivalently accounting for 0.1%-0.25% of the total weight of the blank, performing ball milling for 12-18 hours and uniformly mixing the raw materials to obtain mixed materials; 3) pelleting and aging; 4) semi-dry pressing; 5) drying; 6) glazing; 7) sintering to obtain the low-cost high-alumina ceramic thin plate. The feldspar is formed by mixing potassium feldspar with soda feldspar, and the weight ratio of K2O to Na2O of the mixed feldspar chemical composition is 2:1. The sintering temperature of the high-alumina ceramic thin plate prepared by the method is only 1180 DEG C, so that the ceramic thin plate is low in cost and high in strength.

Description

technical field [0001] The invention relates to a preparation method of a low-cost high-alumina ceramic thin plate, which is mainly used as a building interior wall, an exterior wall decoration plate, etc., and belongs to the field of building ceramics. Background technique [0002] Ceramic thin plate is a new type of green, energy-saving and environmentally friendly architectural ceramics, which can be 2 o 3 The content is divided into high aluminum (Al 2 o 3 ≥28%) and high silicon (SiO 2 ≥60%, Al 2 o 3 <28%) two categories. Compared with high-silicon ceramic sheets, high-alumina ceramic sheets have the advantages of high strength, good corrosion resistance, and not easy to crack. However, industrial alumina is generally added to the formula of high-alumina ceramic sheet blanks, which leads to high costs and limits the application of ceramic sheets. [0003] Chinese invention patent "A Method for Manufacturing Large Silicon Oxide Ceramic Sheets" (CN201110039459.9...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B33/13C04B33/16C04B33/24C04B33/36C04B41/86
CPCC04B33/131C04B33/16C04B33/24C04B33/36C04B41/009C04B41/5022C04B41/86C04B2235/3217C04B2235/3463C04B2235/3472C04B2235/52C04B2235/96C04B41/0072
Inventor 徐晓虹张晨吴建锋张亚祥
Owner WUHAN UNIV OF TECH
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