The invention belongs to the technical field of functional materials, and discloses a
cobalt-based MOF
crystal material and a preparation method and application thereof. The molecular formula of the
cobalt-based MOF
crystal material is [Co (H3TPPE) x (H3TTPE) y (HCOO)], wherein the value of x and the value of y meet the condition that x + y = 1; the H3TPPE is partially deprotonated 1, 1, 2, 2-
tetra (4-(1H-pyrazol-4-yl) phenyl)
ethylene, and the H3TPPE is partially deprotonated 1, 1, 2, 2-
tetra (4-(1H The H3TTPE is partially deprotonated 1, 1, 2, 2-
tetra (4-(1H-
tetrazole-4-yl) phenyl)
ethylene, and the
structural formula of the H3TTPE is shown in the description. According to the
cobalt-based MOF
crystal material, through the synergistic effect of the two
nitrogen heterocyclic ligands, while a large number of strong adsorption sites are introduced, the problem of pore channel blockage possibly caused by too dense functional sites is avoided, high
porosity and a good gas
diffusion channel are successfully kept, the material shows excellent adsorption capacity to gas (CO2) at normal temperature and normal pressure, and the cobalt-based MOF crystal material has good application prospects. The specific application potential is realized in the field of carbon capture.