6results about How to "Long catalyst life" patented technology

The invention discloses a methane reforming catalyst capable of improving hydrothermal resistance as well as a preparation method and application of the methane reforming catalyst, and belongs to the technical field of catalyst preparation. According to the catalyst, a modified HAP-Ce composite carrier is prepared through coprecipitation, hydrothermal treatment and calcination, metal precursor salt serves as a modification component, Ni is impregnated and loaded, calcination is conducted, and then water vapor / nitrogen high-temperature hydrothermal treatment and hydrogen reduction are conducted to obtain the target catalyst. According to the catalyst, a heterogeneous metal oxide composite interface is constructed in situ, stable pinning of Ce species is achieved, and the Ni anchoring effect is enhanced, so that Ce migration and Ni sintering under the hydrothermal condition are inhibited, and high reaction activity, excellent carbon deposition resistance and good hydrothermal stability are shown; the preparation method has the advantages of controllable conditions and simple steps, and is easy for large-scale production and application.

This invention relates to the field of methane catalytic cracking for hydrogen production, and particularly to a glucose-modified activated carbon composite material, its preparation method, and its application. In this invention, activated carbon and glucose are used as the main raw materials, and a glucose-modified activated carbon catalyst is prepared through an impregnation-carbonization process. During carbonization, glucose gradually melts, dehydrates, and cracks to form carbonaceous intermediates. Simultaneously, gases such as H2O, CO, and CO2 are released. These gases activate the pore structure of the activated carbon, promoting the development of micropores and mesopores. Furthermore, the intermediates interact with the activated carbon surface, increasing the content of oxygen-containing functional groups, especially C=O-related functional groups. The resulting fluffy carbon black after glucose carbonization further enhances the initial activity during the methane catalytic cracking reaction and extends the catalytic life.

The invention relates to an activated alumina ball, a preparation method and application of the activated alumina ball in sewage treatment, and relates to the technical field of alumina balls. The activated aluminum oxide ball comprises a ceramic matrix, an activated aluminum oxide layer and a hydrophobic layer which are sequentially arranged from inside to outside, the preparation process comprises the steps of ceramic matrix preparation, intermediate product preparation, vapor deposition of the hydrophobic layer and post-treatment. The silicon dioxide hydrophobic layer is additionally arranged on the outer layer of the prepared activated aluminum oxide ball, direct contact between a water phase and a chemical medium and active components is isolated, the structural protection stability is enhanced, and the prepared activated aluminum oxide ball has a good industrial application prospect in the field of sewage treatment.

The invention provides a synthesis method and application of an H-shaped slice high-silicon mordenite molecular sieve, and belongs to the technical field of molecular sieve synthesis and application. The preparation method comprises the following steps: mixing tetraethylammonium hydroxide and long-chain pyrrolidinium salt as template agents with an alkali source, an aluminum source and a seed crystal to form silicon-aluminum sol, aging the silicon-aluminum sol, carrying out a crystallization synthesis reaction, and carrying out ammonium ion exchange, drying and roasting to obtain the H-type high-silicon slice mordenite molecular sieve (MOR). According to the synthesized H-shaped sheet high-silicon mordenite molecular sieve, the Al element is enriched in an eight-membered ring of an MOR zeolite molecular sieve skeleton structure, acid sites which are subjected to side reactions in HMOR can be effectively shielded, and the H-shaped sheet high-silicon mordenite molecular sieve has good catalytic activity and product selectivity when being applied to a reaction for synthesizing methyl acetate through carbonylation.

The invention provides a diimine catalyst as well as a preparation method and application thereof, and belongs to the technical field of catalyst synthesis. The diimine catalyst has a structural formula as shown in a formula (I), wherein M is Ni or Pd; x is Br or Cl; r is selected from R2 and represents a connection site; r1 is selected from any one of a C6-C30 aryl group and a C1-C8 saturated or unsaturated alkyl group; r2 is selected from any one of a substituted or unsubstituted alkyl group with 1 to 12 carbon atoms, a substituted or unsubstituted naphthenic oxygen group with 2 to 12 carbon atoms, and a substituted or unsubstituted aryl group with 6 to 30 carbon atoms; and when the substituted or unsubstituted groups have substituent groups, the substituent groups are selected from one or more of halogen and C1-C12 alkyl groups. The diimine catalyst provided by the invention has good catalytic activity and stability by inhibiting ligand rotation.

The invention provides a synthesis method and application of an H-type high-silicon-wafer-shaped MOR zeolite molecular sieve, and belongs to the technical field of synthesis and application of molecular sieves. The method comprises the following steps: adding an aluminum source into a mixed solution containing an alkali source, tetraethylammonium hydroxide, long-chain bipiperidine onium salt and water to form slurry, adding a silicon source and a small-grain MOR zeolite molecular sieve seed crystal into the slurry, uniformly mixing to obtain silicon-aluminum sol, aging the silicon-aluminum sol, carrying out a crystallization synthesis reaction, carrying out ammonium ion exchange on the obtained crystallization product, and drying to obtain the small-grain MOR zeolite molecular sieve. And filtering, washing, drying and roasting to obtain the H-type high-silicon-wafer-shaped MOR zeolite molecular sieve. According to the molecular sieve synthesized by the invention, the Al element is enriched in an eight-membered ring of an MOR zeolite molecular sieve skeleton structure, the quantity of B acid in the eight-membered ring is increased, and the molecular sieve has a small-grain morphology feature structure, can effectively shield acid sites in side reaction in HMOR, is applied to a reaction for synthesizing methyl acetate by carbonylation of dimethyl ether, and has a good application prospect. The catalyst has the advantages of high catalytic activity, good product selectivity, simple preparation process and easy industrial amplification.