4760 results about "Alkene" patented technology

The invention discloses an anti-shrinkage light, soft and elastic sole foaming material and a preparation method thereof, and belongs to the technical field of footwear products. The light, soft and elastic sole foaming material is formed by chemically foaming an EVA (Ethylene Vinyl Acetate) composite raw material, the EVA composite raw material is prepared from 50 to 70 parts of EVA, 20 to 40 parts of olefin thermoplastic elastomer, 10 to 20 parts of styrene elastomer, 1.5 to 3 parts of maleic anhydride grafted ethylene-octylene copolymer compatilizer, 0.4 to 0.8 part of peroxide cross-linking agent, 3 to 4 parts of foaming agent, 1 to 1.5 parts of zinc oxide, 1 to 1.5 parts of polyethylene wax substance and 0.5 to 1.5 parts of poly (butylene succinate). 0.3 to 1 part of polyamide 12 microspheres and 2 to 3 parts of nano montmorillonite. The foaming material can resist shrinkage when being used as a shoe sole part, and has good rebound performance and the like, so that the high-quality requirement of sneakers, the mass production stability and the like are met.

The invention discloses a comb-type polyphosphate polymeric dispersant and a preparation method thereof, the dispersant is prepared by preparing a phosphate monomer from acrylate and phosphorus pentoxide, then copolymerizing the phosphate monomer with phenyl alkene or alkyl alkene, and finally adding alkali liquor for neutralization. A phosphate-polyether bifunctional side chain is introduced to a main chain, a phosphate group provides electrostatic repulsion, and a polyether group enhances steric hindrance, so that the dispersing agent can meet the requirements of strong adsorption and long-range stability at the same time, and a more durable and effective stabilizing effect is provided for a dispersion system.

The invention relates to the technical field of PC transparent flame-retardant toughening modification, in particular to phenolic hydroxyl-terminated modified polysiloxane with a side chain containing phenyl and sulfonate groups and a preparation method of copolymerized PC. The modified polysiloxane is prepared by the following steps: performing ring opening polymerization on phenol-containing double end sockets and cyclotetrasiloxane to obtain modified polysiloxane containing double bonds and phenyl functional groups, and grafting sulfonate through a thiol-ene click chemical reaction. Diphenyl carbonate, bisphenol A and the modified polysiloxane are used as raw materials, a polysiloxane-PC block copolymer is formed through copolymerization, efficient flame retardance and high transparency are achieved, and meanwhile extremely high low-temperature impact strength is achieved.

The invention provides a Pt-Sn bimetallic catalyst and a preparation method and application thereof.The preparation method comprises the steps that 1, a Y molecular sieve is placed in a mixed solution of KOH and methyl alcohol, centrifugation and washing are conducted till the Y molecular sieve is neutral after stirring, drying and roasting are conducted, and a non-acid KY molecular sieve is obtained; the silica-alumina ratio of the Y molecular sieve is 3-100; 2) taking the non-acidic KY molecular sieve as a carrier, and loading Sn by adopting an atomic layer deposition technology to obtain a Sn-modified non-acidic KY molecular sieve; and 3) loading Pt by using the Sn-modified non-acidic KY molecular sieve as a carrier and adopting an atomic layer deposition technology to obtain the Pt-Sn bimetallic catalyst. According to the preparation method provided by the invention, spatial distribution of Pt and Sn is accurately regulated and controlled by combining an atomic layer deposition technology, so that the electronic state of Pt species is adjusted, alkane is promoted to be dehydrogenated into an olefin intermediate, and the aromatization catalytic activity and the aromatic hydrocarbon selectivity of alkane are improved.

The application discloses a cross-linked ETFE composite film with gradient ultraviolet shielding function and a preparation method and application thereof, and belongs to the technical field of ETFE film preparation. The cross-linked ETFE composite film is composed of three layers of a surface layer, a middle layer and a bottom layer. The surface layer material comprises ETFE resin and fluorinated carbon quantum dots; the middle layer material comprises ETFE resin, allyl-containing comonomer A and phenyl-containing comonomer B; and the bottom layer material comprises ETFE resin and CeO2 nanowires. The fluorinated carbon quantum dots have a particle size of 3-5 nm and contain a -C4F9 structure. The comonomer A is an allyl-containing fluorine olefin monomer, and the comonomer B is a phenyl-containing organic fluorinated compound. Through the synergistic effect of the surface layer self-migration fluorinated carbon quantum dots, the middle layer copolymerization modification and the bottom layer CeO2 nanowires, high light transmittance, full-waveband ultraviolet shielding and long-term weather resistance are achieved.

This anticorrosive coating composition comprises a main agent (I) and a curing agent (II), wherein: the main agent (I) contains an epoxy resin (a); the epoxy resin (a) contains at least one of a bisphenol A epoxy resin (a-11) and a novolac epoxy resin (a-12) each having a weight average molecular weight of 6,000-12,000; the curing agent (II) contains a polyamine (b) and an alkylphenol (c); the polyamine (b) contains an alicyclic polyamine (b-1) having a cyclic aliphatic hydrocarbon group to which an amino group is bonded and contains a non-alicyclic polyamine (b-2) having no cyclic aliphatic hydrocarbon group to which an amino group is bonded; at least one of the main agent (I) and the curing agent (II) includes a vinyl-based defoaming agent (d) that has a constituent unit derived from at least one monomer selected from the group consisting of alkyl (meth)acrylates, alkyl vinyl ethers, and olefins and that has a number average molecular weight of 30,000-100,000 or 300,000-2,000,000; the content of the alicyclic polyamine (b-1) is 30%-80% by mass of the solid content of the curing agent (II); the content of the non-alicyclic polyamine (b-2) is 2%-45% by mass of the solid content of the curing agent (II); the content of the alkylphenol (c) is 5%-60% by mass of the solid content of the curing agent (II); and the content of the vinyl-based defoaming agent (d) is 0.005-3 parts by mass with respect to 100 parts by mass of the anticorrosive coating composition.

The invention belongs to the field of chemical engineering manufacturing industry, and relates to equipment and a method for producing cyclic ketone compounds by oxidizing cycloolefin by using waste gas produced by adipic acid. Raw material gas A containing nitrous oxide from an adipic acid production process production line can be subjected to oxygen removal, so that the oxygen content is less than 100ppm; the raw material gas A containing nitrous oxide from the adipic acid production line can also be purified into purer gas containing 50-99% of N2O, and the purer gas is used for reacting with the cycloolefin compound; the reaction equation is CnH2n-2 (cycloolefin) + N2O (nitrous oxide)-> CnH2n-2O (a product cyclic ketone compound) + a byproduct + N2 superscript (nitrogen), wherein n is a positive integer from 4 to 24. The device is stable in consumption quota, low in production cost and high in economic benefit compared with the prior art.

The invention relates to a heterogeneous catalysis technology, and aims to provide a method for improving the yield of components of aviation kerosene prepared by ethylene oligomerization through combination of a fixed bed and a slurry bed. Comprising a fixed bed reactor and a slurry bed reactor which are sequentially connected in series, the fixed bed reactor is filled with a metal modified mesoporous zeolite molecular sieve catalyst, and the slurry bed reactor is filled with a mesoporous zeolite molecular sieve catalyst. The method comprises the following steps: firstly, carrying out ethylene oligomerization reaction in a fixed bed reactor to generate a product containing C4-C8 olefin; the reaction product is directly introduced into the fixed bed reactors connected in series for secondary reaction, and the final product comprises C5-C16 + liquid phase olefin as an aviation fuel component. By adopting a fixed bed-slurry bed reactor combined method, the ethylene conversion rate can be greatly improved; secondary oligomerization is carried out by using an acidic mesoporous zeolite molecular sieve catalyst, so that the selectivity of aviation kerosene components is improved; the mesoporous catalyst prepared by an alkali treatment method has a good diffusion effect and keeps high activity for a long time.

A method may include operating a dehydrogenation process whereby a hydrocarbon-containing feed is converted to light olefins, wherein the dehydrogenation process utilizes a fluidized process catalyst that circulates between a reactor and a combustor. The method may comprise withdrawing the process catalyst from the dehydrogenation process, modifying the process catalyst to form a modified catalyst, and adding the modified catalyst back to the dehydrogenation process. The process catalyst may include from 0.1 wt. % to 10 wt. % of one or more metals chosen from gallium, indium, thallium, or combinations thereof, from 1 ppmw to 1000 ppmw of one or more metals chosen from platinum, palladium, rhodium, iridium, ruthenium, osmium, or combinations thereof, and at least 85 wt. % support. Modifying the process catalyst may include adding one or more of manganese, iron, chromium, or vanadium.

The present inventions concerns a copolymer of ethylene and an C3 to C8 alpha-olefin, wherein the copolymer has a density of 870 to 890 kg / m3 measured according to ISO 1183, a MFR2 of 0.5 to 8.0 g / 10 min measured according to ISO 1133, wherein the alpha-olefin is present in the copolymer in an amount of 20 to 35 wt.-%, wherein the copolymer has a first melting temperature Tm1 measured according to ISO 11357-3, characterized in that the first melt point Tm1 is between 90 and 115° C.

The invention discloses flame-retardant hard foam polyether polyol ester as well as a preparation method and application thereof. The preparation method of the polyether polyol ester comprises the following steps: taking hexachlorotripolyphosphazene and hydroxy acid as raw materials, and reacting under the action of a metal chloride catalyst to obtain an intermediate; and carrying out polymerization reaction on the intermediate serving as an initiator and oxyalkylene under the action of a polymerization catalyst to prepare the polyether polyol ester. The polyether polyol ester is prepared by taking a reactant of phosphonitrilic chloride trimer and hydroxy acid as an initiator and carrying out polymerization reaction with oxyalkylene, and the prepared foam has higher flame retardance and foam strength due to the particularity of a molecular structure.

The invention relates to the technical field of energy storage safety, and particularly discloses flame-retardant cooling liquid, a preparation method of the flame-retardant cooling liquid, an immersed energy storage device, a data center and electric equipment. According to the present invention, the base oil is at least one of the liquid halogenated alkane containing 2-6 carbon atoms, the liquid halogenated olefin, the liquid halogenated ketone and the liquid halogenated cycloalkane containing 3-6 carbon atoms, such that the high biodegradability of the base oil is maintained, the system viscosity is effectively reduced, the heat dissipation performance is improved, the insulating property of the base oil is significantly improved, and the service life of the base oil is prolonged. Meanwhile, the flame retardance is further enhanced. Therefore, the heat management efficiency of the cooling liquid is remarkably improved while environmental protection and safety are considered, and the cooling liquid has a good application prospect.

The present invention relates to a process for producing a jet fuel composition (12), the process comprising: a) Processing an oxygenate stream (1) in an Oxygenate-to-Olefin (OtO) unit (2) to produce an olefin stream (3); b) Separating the olefin stream (3) in a fractionation unit (4) into at least a C2-olefin-rich stream (5), a C3-olefin-rich stream (6) and a C4+-olefin-rich stream (7); c) Dimerizing at least a portion of ethylene contained in the C2-olefin-rich stream (5) to C4-olefins in a dimerization unit (20), thereby producing a dimerized product stream (21); d) Processing an oligomerization feed (8) comprising at least a portion of the C4+-olefin-rich stream (7) and at least a portion of the dimerized product stream (21) in an oligomerization unit (9) to produce an oligomerized olefin stream (10); e) Hydrogenating at least a portion of the oligomerized olefin stream (10).

Disclosed in the present invention is a composition for preparing a vinyl block copolymer, the composition comprising: a first monomer ethylene, a second monomer a C3-C20 α-olefin and at least one regulation monomer, the regulation monomer being an olefin or a substituted olefin with the C atom number greater than 3, or styrene / a styrene derivative, and in the same composition, the second monomer being different from the regulation monomer. The composition is catalyzed by a main catalyst and a co-catalyst to obtain the vinyl block copolymer, wherein the main catalyst is a complex L-MR1R2R3 that contains three substituents and that is formed by an IVB-group metal and a monoanionic ligand, and the co-catalyst includes alkyl aluminum, polymerized or oligomerized aluminoxane, a neutral Lewis acid, a non-polymer, a non-coordinated ionic compound, or a mixture of two or more described above. Provided in the present invention is a composition capable of obtaining a lower-olefin block copolymer, the composition can obtain a lower-olefin block copolymer without the need of replenishing monomers or adding a chain transfer reagent for polymerization during polymerization processes, so that a production process is simple and involves low cost.

The invention provides a method for preparing alkane olefin by catalyzing microalgae pyrolysis through an alkali modified molecular sieve, and belongs to the field of biomass energy utilization. According to the method, the ZSM-5 molecular sieve raw powder is modified by adopting the alkaline solution, so that the pore structure of the ZSM-5 molecular sieve can be improved, the distribution of acidic sites can be optimized, the regulation and control of a microalgae pyrolytic reaction path can be realized under relatively mild conditions, the deoxidation reaction can be promoted, the content of oxygen-containing products can be reduced, and the generation of alkane olefin substances can be promoted; the aromatization reaction strength is reduced, and the selectivity of light hydrocarbons is improved, so that the content of alkanes and olefins in the pyrolysis bio-oil reaches 70% or above, and the quality of the pyrolysis bio-oil is remarkably improved. Results of the embodiment show that the pyrolysis bio-oil provided by the invention is subjected to gas chromatography-mass spectrometry detection, and the alkane-olefin peak area content is greater than 70%.

The invention discloses an intelligent catalytic thermal cracking reaction system and method for complex mixed waste plastics, and belongs to the technical field of waste plastic resourceful treatment. The system comprises a feeding device, a high-pressure multi-section cracking reaction kettle, a spraying type heat exchange temperature control system, a heating system, a sensing and analyzing unit, an intelligent control system and a product condensation separation and utilization unit, the method specifically comprises the following steps: (1) pretreating and feeding raw materials; (2) multi-section temperature control cracking reaction; (3) intelligent feedback control; (4) the catalyst has a synergistic effect; and (5) product separation and recovery. According to the invention, a unique spraying type high-pressure multi-section temperature control system is combined with intelligent control of a rate matching algorithm, so that efficient, directional and stable cracking of complex mixed waste plastics is realized, the yield of high-value products such as light olefins, aromatic hydrocarbons and the like is remarkably improved, byproduct residues and energy consumption are reduced, and long-term continuous operation is realized.

The present invention relates to a process for producing a jet fuel composition (12), the process comprising: a) Processing an oxygenate stream (1) in an Oxygenate-to-Olefin (OtO) unit (2) to produce an olefin stream (3); b) Processing an oligomerization feed (8) comprising at least a portion of the olefin stream (3) in an oligomerization unit (9) to produce an oligomerized olefin stream (10); c) Hydrogenating at least a portion of the oligomerized olefin stream (10); wherein a fraction of the oligomerized olefin stream (10) is withdrawn as a recycle stream (40a, 40b) and passed to a steamcracking unit (41) to produce a steamcracking product stream (42), wherein at least a portion of the steamcracking product stream (42) is included in the oligomerization feed (8).

The invention discloses a catalytic method for converting alpha-olefin in an alkane-olefin mixture into internal olefin and application, raw materials and a solid acid catalyst are carried out in a fixed bed or a reaction kettle, the reaction temperature is 50-150 DEG C, the reaction pressure is 15-400 psi, and the reaction environment is an inert gas atmosphere; when the reaction is carried out on the fixed bed, the mass space velocity of the solid acid catalyst is 1h <-1 >-20h <-1 >; when the reaction is carried out in the reaction kettle, the conversion frequency of the raw materials is 5000 mol substrate mol acid site density <-1 > h <-1 > to 50000 mol substrate mol acid site density <-1 > h <-1 >; wherein the raw material is an alkane-alkene mixture; the solid acid catalyst comprises an active component and a carrier, wherein the carrier contains at least one inorganic oxide; the active component has a structure as shown in a formula (1) and / or a formula (2), in the formula (1) and the formula (2), R is alkyl or phenyl, and n is greater than or equal to 1. According to the catalysis method provided by the invention, the conversion rate of alpha-olefin can be increased, and the proportion of skeleton isomerization products and oligomers in internal olefin products can be reduced.

The invention provides dicyclopentadiene phenol resin and a preparation method thereof, dicyclopentadiene phenol epoxy resin and a preparation method and application thereof. Compared with common dicyclopentadiene phenol resin, the dicyclopentadiene phenol resin has unsaturated cycloolefin active functional groups at the tail ends of molecular chains, so that the reactivity of the resin can be improved, and the application field of the dicyclopentadiene phenol resin is expanded.

The invention discloses low-odor thermoplastic vulcanized rubber for an automobile skin as well as a preparation method and application of the low-odor thermoplastic vulcanized rubber. The raw materials comprise 50 to 80 parts of ethylene-propylene-diene copolymer rubber, 20 to 50 parts of polypropylene, 5 to 15 parts of a compatilizer, 0.5 to 2.5 parts of a compound cross-linking agent, 0.5 to 2.0 parts of an odor adsorbent and 0.5 to 1.0 part of an antioxidant. The preparation method comprises the following steps: banburying and blending, dynamically vulcanizing by using a first double-screw extruder, adsorbing and deeply devolatilizing by using a second double-screw extruder, and carrying out vacuum baking at 100 DEG C. By utilizing the synergistic effect of the cross-linking agent and the assistant cross-linking agent, the degradation of polypropylene is inhibited while the cross-linking efficiency is ensured, and a low-boiling-point reaction by-product (tert-butyl alcohol) is thoroughly removed through a multi-stage devolatilization process, so that the problems that the traditional TPV material is strong in odor and easy to atomize are solved. The smell grade of the obtained material is less than or equal to 3.0 grade, and the atomization value is lt; and the coating is suitable for high-end automotive trim skins.

The invention relates to the field of cracking, and discloses a direct electric heating cracking furnace, application and a method for preparing olefin through cracking, the cracking furnace comprises a preheating section, a cracking section and a post-treatment section, and the cracking section adopts a metal furnace tube with resistance gradually reduced in the material flowing direction; the metal furnace tube is directly connected with the electric heating component; the preheating section is used for preheating cracking raw materials and diluting steam; the cracking section is used for cracking the preheated cracking raw material in the presence of the preheated steam; and the post-treatment section is used for cooling and separating the cracking product. According to the direct electric heating cracking furnace disclosed by the invention, heat is directly generated from the heated metal furnace tube instead of being transmitted from the outside through heat radiation, so that the thermal efficiency is high, the heat loss is small, the heating speed is high, the cracking preparation of low-carbon olefin is facilitated, and each product has relatively high yield.

The invention discloses a system and a method for preparing low-carbon olefin through carbon dioxide adsorption and in-situ oxidative dehydrogenation. The invention provides a system and a method for integrating carbon dioxide capture and in-situ oxidation low-carbon alkane (ethane / propane) dehydrogenation, a bifunctional material is composed of an adsorbent and a catalyst, and capture of carbon dioxide and in-situ oxidation low-carbon alkane dehydrogenation can be realized in the same reaction tower, so that the highest one-way carbon dioxide conversion rate can reach 100%, and the conversion rate of carbon dioxide can reach 100%. And meanwhile, the ethylene yield reaches 26%. According to the method, the problems of additional product separation and product gas recycling caused by low carbon dioxide conversion efficiency in the prior art are avoided, and effective heat management is realized, so that the process of integrating carbon dioxide capture and preparing low-carbon olefin by oxidizing low-carbon alkane has more economic advantages.

The invention relates to the technical field of polyolefin materials, in particular to an ethylene and alpha-olefin copolymer and a preparation method thereof. The density of the ethylene and alpha olefin copolymer is 0.860-0.905 g / cm < 3 >, the weight-average molecular weight Mw is greater than 50000 g / mol, the rheological processing parameter STP value of the ethylene and alpha olefin copolymer is in the range of 2.20-3.93, and the STP value is calculated by a specific formula according to the complex viscosity and the weight-average molecular weight of the polymer at different shear rates. According to the copolymer provided by the invention, by combining the structural parameters, the melt strength and the processability of the copolymer are remarkably improved on the premise of not sacrificing the inherent mechanical properties of the material, and the processing window and the application range of the material are effectively widened.

The invention herein comprises systems, devices, and methods for the remediation of per- and polyfluoroalkyl substances, PFAS, including their precursors and degradation compounds such as volatile, semi-volatile, and non-volatile fluorinated alkene and alkane organic chemicals, OFCs, in media through heating the media using electrically powered thermal conduction heaters or other methods, to temperatures between approximately 250°C and 550°C.

The invention discloses a composite material polypropylene film and a preparation method thereof, and belongs to the technical field of polymer modification and polymer films. The preparation method of the composite material polypropylene film comprises the following steps: blending 5-10 wt% of maleic anhydride grafted polypropylene (PP-g-MAH), 5-20 wt% of a cycloolefin copolymer or a cyclic block copolymer and 75-90 wt% of isotactic polypropylene, granulating, carrying out melt extrusion at 240-260 DEG C, and carrying out tape casting at 80-95 DEG C to form a sheet; preheating the sheet at the temperature of 145-170 DEG C, synchronously stretching at the temperature of 150-175 DEG C, carrying out heat setting at the temperature of 160-175 DEG C, and cooling; the composite material polypropylene film is prepared through the steps of extrusion, traction, corona treatment, rolling and the like. The composite material polypropylene film not only has good heat resistance and good dielectric strength at a high temperature, but also has a relatively high dielectric constant and relatively low dielectric loss, and is suitable for a film capacitor.

A process for the continuous production of a polyolefin polymer in a gas-phase polymerization reactor in the presence of a polymerization catalyst and an antistatic agent, including the steps of (a) providing a mixture of polyolefin particles and gas, (b) conveying the mixture through a pipe at a gas velocity of greater than or equal to 2 m / s, and (c) introducing an antistatic agent into the mixture.

The present disclosure provides a drag reducing agent. In an embodiment, the drag reducing agent includes a polymer and a liquid carrier. The polymer is composed of one or more C6-C14 α-olefin monomers. The polymer includes a residual amount of zirconium. The polymer has an absolute weight average molecular weight (Mw(Abs)) greater than 1,300,000 g / mol and a (Mw(Abs) / Mn(Abs) from 1.3 to 3.0.

The invention relates to the technical field of advanced petrochemical and chemical new materials, in particular to a fireproof flame-retardant glass fiber reinforced plastic pipeline material and a preparation method thereof.The fireproof flame-retardant glass fiber reinforced plastic pipeline material is prepared from phenolic resin, alpha-olefin ethylene copolymer, modified nano aluminum hydroxide, glass fiber, a phosphorus-nitrogen flame-retardant synergist, a silane coupling agent, a curing agent and an antioxidant; according to the invention, the formula of the fireproof flame-retardant glass fiber reinforced plastic pipeline material is designed, various fillers are subjected to multi-step modification treatment, and preparation process parameters are optimized, so that the synergistic effect of various components and various process steps is realized, and the material performance is greatly improved from microscopic interface bonding to macroscopic material performance; the technical problems that in the prior art, flame retardance and mechanical performance are difficult to consider, aging resistance is poor, and a formed structure has defects are effectively solved.

The invention provides a preparation method of an alpha-difluoroselenomethyl ketone derivative, which is a method for preparing the alpha-difluoroselenomethyl ketone derivative by using 2, 2-difluoroolefin and dialkyl diselenide in the presence of iodosobenzene diacetate. The preparation method specifically comprises the following steps: dissolving 2, 2-difluoroolefin and a dialkyl diselenide compound in an organic solvent, uniformly mixing, adding iodobenzene diacetate, and stirring and reacting at a certain temperature in an air atmosphere to obtain the product alpha-difluoro (seleno) methyl ketone derivative. The alpha-difluoroselenomethyl ketone derivative can be mildly and efficiently obtained by only adopting iodobenzene diacetate without necessary catalysts, alkali, persulfide and persulfate compounds in the prior art. Wherein R1 and R2 are aliphatic hydrocarbon, substituted and unsubstituted benzene, substituted and unsubstituted naphthalene or other aromatic groups.

The invention provides an olefin polymer composition and application thereof, and relates to the technical field of composite materials. The olefin polymer composition is prepared from the following raw material components in parts by weight: 100 parts of an olefin polymer, 0.5 to 5 parts of an anthraquinone compound and 1 to 5 parts of aspartic ester resin, the structure of the aspartic ester resin contains C8-C24 alkylene and a polyethylene glycol chain segment. The olefin polymer composition has good hydrophilicity, and the treatment effect of the olefin polymer composition on nitrogen-containing sewage can be improved.