1912 results about "Mesoporous silica" patented technology

The invention discloses a low-trigger-potential electrochemical luminescence enzyme biosensor for detecting glucose and a construction method and application thereof, the sensor comprises a three-electrode system formed by a working electrode, a reference electrode and a counter electrode, and a liquid to be detected contains luminol; the working electrode is a VMSF modified electrode of confined gold-palladium nanoparticles and is obtained by covalently immobilizing glucose oxidase. Luminol and glucose oxidase are respectively used as an electrochemical luminescence signal molecule and a specific recognition element; by combining the efficient and specific catalytic activity of natural enzyme, the efficient catalytic activity of gold-palladium nanoparticles on luminol electrochemical luminescence and the anti-pollution capacity of a vertical ordered mesoporous silica film, the low-trigger-potential electrochemical luminescence enzyme biosensor without an exogenous co-reactant is constructed; the method has the characteristics of high sensitivity, wide detection linear range and low detection limit, and has great application potential in constructing a portable glucose sensor for diagnosing and monitoring diabetes mellitus.

The invention relates to the technical field, and particularly discloses a nano-modified epoxy building thermal insulation material and a preparation method thereof. The nano modified epoxy building thermal insulation material is prepared from the following raw materials in parts by mass: 80 to 120 parts of Portland cement, 20 to 40 parts of slag powder, 5 to 10 parts of hollow mesoporous silicon dioxide, 0.1 to 1 part of pyrrole, 0.1 to 0.2 part of ammonium persulfate, 5 to 10 parts of nano silicon dioxide, 10 to 15 parts of bisphenol S epoxy resin, 1 to 5 parts of acrylic acid, 1 to 2 parts of polylysine, 0.01 to 0.1 part of catalyst and 1 to 2 parts of curing agent. The concrete is prepared from the following raw materials in parts by weight: 20-30 parts of epoxy resin, 4-8 parts of loaded aerogel, 0.1-1 part of polycarboxylate superplasticizer, 1-4 parts of composite fiber and 0.2-1.25 parts of hydrogen peroxide. The fireproof building material has excellent toughness, can better resist cracking and absorb energy, effectively avoids cracking and damage under the action of thermal stress, and ensures that the building material has a fireproof effect.

The invention belongs to the technical field of composite coatings, and particularly relates to a corrosion-resistant and ultraviolet-resistant protective coating for wind power generation equipment and a preparation method thereof.The corrosion-resistant and ultraviolet-resistant protective coating for the wind power generation equipment is prepared from, by mass, 40-60 parts of gradient fluorosilicone modified polyurethane resin, 5-12 parts of core-shell type ZnO-coated MOFs composite particles, 1-3 parts of a curing agent, 1-3 parts of a curing agent and 1-3 parts of a curing agent. According to the invention, the problems of poor ultraviolet resistance, poor weather resistance, poor corrosion resistance, poor corrosion resistance, poor corrosion resistance, poor corrosion resistance, poor corrosion resistance and the like in the existing coating and the preparation process thereof are well solved; the shielding layer is single and incapable and has a poor self-repairing effect; and the coating toughness of an epoxy resin system is insufficient and cannot adapt to fatigue deformation of equipment under a vibration working condition.

The invention belongs to the technical field of pesticides, and particularly relates to a preparation method of an asymmetric wettability nano-carrier and pesticide delivery application of the asymmetric wettability nano-carrier. In order to improve the deposition efficiency of the mesoporous silicon nano-carrier on the leaf surface of a plant, the invention constructs a Janus mesoporous silicon dioxide nano-carrier (AWJ-MSN) which is obtained by modifying a hydrophilic monomer and a hydrophobic monomer and has asymmetric wettability, and the Janus mesoporous silicon dioxide nano-carrier (AWJ-MSN) is used for loading a hydrophobic pesticide; the obtained AWJ-MSN can obtain improved wettability and leaf surface deposition capability on plant leaves with different wettability; compared with a free hydrophobic pesticide, a delivery system formed after the asymmetric wettability nano-carrier is loaded with the pesticide can enhance leaf surface deposition and provide continuous release of active ingredients, so that the utilization rate of the pesticide is increased, and the environmental risk is reduced.

The invention provides a high-temperature-resistant and high-salt-resistant nano imbibition agent as well as a preparation method and application thereof. The high-temperature-resistant and high-salt-resistant nano imbibition agent is prepared from amination modified mesoporous silica nanoparticles, nano cellulose, rhamnolipid, an anionic surfactant, citrate modified sodium zirconium phosphate, polyethylene glycol-b-polycaprolactone and a sulfydryl-carboxyl imidazoline derivative, therefore, the composite carrier formed by the aminated mesoporous silica nanoparticles and the nanocellulose has high mechanical strength and uniform dispersity, the oil-water interfacial tension is reduced through the synergistic effect of the rhamnolipid and the anionic surfactant, and the crude oil stripping efficiency is remarkably improved; the citrate modified sodium zirconium phosphate enables the salt resistance of the system to be greatly improved, and in a high-temperature and high-salt oil reservoir environment, the nano imbibition agent can remarkably improve the crude oil recovery rate and reduce the injection pressure and dosage; meanwhile, good adsorption resistance is achieved, and reservoir blockage is prevented; in addition, low-toxicity corrosion inhibition components protect equipment, and the service life of an oil well is prolonged.

The invention relates to the field of traditional Chinese medicine effective component new dosage form pharmaceutical preparations, and discloses an M2 type macrophage membrane coated ROS responsive bionic nano drug delivery system, preparation and application. Mesoporous silica is used as a core to load a traditional Chinese medicine effective component, namely tripterine, and lipid components, namely PEGylated distearoyl phosphatidyl ethanolamine (DSPE-PEG), dioleoyl lecithin (DOPC), cholesterol and the like, are used as raw materials to prepare a ROS-responsive lipid coating, so that ROS-responsive tripterine mesoporous silica is formed. And then realizing bionic fusion with the M2 type macrophage membrane on the outer layer through an ultrasonic coating technology to prepare the M2 type macrophage membrane coated ROS responsive bionic mesoporous silica nano drug delivery system. The invention can realize targeted therapy of rheumatoid arthritis, and has the advantages of biological safety and the like.

The invention relates to the technical field of metal surface protection, and discloses a corrosion-resistant self-repairing metal fastener and a preparation method thereof.The corrosion-resistant self-repairing metal fastener comprises a zinc alloy matrix, a nanometer passivation layer, a slow-release corrosion-resistant layer and a self-repairing functional layer, and the nanometer passivation layer, the slow-release corrosion-resistant layer and the self-repairing functional layer sequentially wrap the zinc alloy matrix; the zinc alloy matrix consists of Al, Cu, Mg, Ce and Zn; the nano passivation layer adopts zinc phosphate / silane composite sol to construct a Si-O-P covalent bond network, and plasma is combined to graft epoxy groups to enhance the interface bonding strength; the slow-release anti-corrosion layer is used for loading a pH response type benzotriazole derivative through gradient aperture mesoporous silica, so that the dynamic controlled release of a corrosion inhibitor is realized; the self-repairing functional layer adopts a synergistic effect of a mechanical triggering type sulfydryl siloxane microcapsule and a pH triggering type EDTA chelating agent microcapsule to form a physical plugging-chemical passivation dual-mode repairing mechanism. Through four-stage cooperation of matrix modification, interface strengthening, slow-release regulation and control and intelligent repair, the corrosion resistance of the corrosion-resistant self-repairing metal fastener in a complex environment is remarkably enhanced.

Manganese-doped hollow mesoporous silica nanoparticles loaded with curcumin and an application in periodontal bone tissue repair are provided in the present disclosure, belonging to the technical field of targeted delivery of nanoparticles and bone tissue regeneration. In the present disclosure, alendronate is grafted on the surface of silica nanoparticles to achieve bone targeting, manganese is doped on the nanoparticles by a chemical method, and curcumin is wrapped in the nanoparticles.

The invention relates to the field of essential oil slow release, and discloses a mildew-proof tablet containing plant essential oil and a preparation method and application thereof.The mildew-proof tablet containing the plant essential oil comprises two epidermal layers and an essential oil slow-release layer arranged between the two epidermal layers, the preparation method comprises the following steps: grafting sodium abietate and aminated mesoporous silica to prepare functionalized mesoporous silica, loading plant essential oil on the functionalized mesoporous silica to obtain a core material, introducing dihydroxyl polyhedral oligomeric silsesquioxane into a polyurethane main chain, wrapping the core material to prepare an essential oil slow-release agent, taking lignin as a base material, taking the essential oil slow-release agent as an effective component, and preparing the essential oil slow-release agent. And preparing to obtain the essential oil slow-release layer. The prepared essential oil slow-release layer can achieve the effects of essential oil slow release and antibiosis and mildew prevention, the slow-release effect is remarkable under the normal-temperature and high-temperature conditions, the good slow-release effect is still kept in the humid environment, and the efficacy period of the material is greatly prolonged.

The invention discloses a multifunctional coating with flame retardance, bacteriostasis and electromagnetic shielding as well as preparation and application of the multifunctional coating, and belongs to the technical field of textiles. The preparation method comprises the following steps: firstly, preparing a flame-retardant solution by combining phosphorylated sodium alginate and MXene, and padding a fabric into the solution to obtain a fabric with a flame-retardant function; the preparation method comprises the following steps: preparing a flame-retardant solution, adsorbing zanthoxylum bungeanum essential oil by adopting mesoporous silica to prepare a bacteriostatic agent solution, mixing the flame-retardant solution, the bacteriostatic agent solution and polyvinylpyrrolidone to obtain a flame-retardant and bacteriostatic composite solution, and padding a fabric into the flame-retardant and bacteriostatic composite solution to obtain a fabric with flame-retardant and bacteriostatic functions; mXene solution is sprayed on the fabric with the flame-retardant and antibacterial functions to serve as an enhanced electromagnetic shielding layer, and the multifunctional fabric with the flame-retardant, antibacterial and electromagnetic shielding functions is prepared. The flame-retardant solution and the bacteriostatic agent solution are both made of bio-based materials, have the advantages of being low in price, environmentally friendly and degradable, and can also be used as coatings to be applied to multiple fields.

The invention belongs to the technical field of grease modification and lipid deep processing, and particularly relates to a method for enriching n-3 polyunsaturated fatty glyceride by an enzymic method. According to the method, alkyl-modified hollow mesoporous silica spheres are used as an immobilized enzyme carrier and an emulsifier, grease rich in n-3 polyunsaturated fatty acid is used as a raw material in a stable Pickering emulsion system, saturated fatty acid and monounsaturated fatty acid are selectively hydrolyzed by lipase, and polyunsaturated fatty glyceride is enriched. The method has the characteristics of fast reaction, high yield, wide substrate application range and reusability of the immobilized enzyme, and the content of polyunsaturated fatty acid in the polyunsaturated fatty glyceride reaches 58.05-90.53%.

The invention relates to the field of coatings, in particular to an industrial anticorrosive coating and a preparation method thereof. The coating comprises film-forming resin, a curing agent, a solvent and an anti-corrosion composite nanofiller. The anti-corrosion composite nanofiller has a three-layer structure, wherein an inner core is mesoporous silica loaded with an organic corrosion inhibitor; the middle shell layer is an amino-functionalized metal organic framework material grown in situ; and the outer layer is a low-surface-energy layer formed by modification of a hydrophobic modifier.

The invention provides a quick-charge and quick-discharge type lithium battery and a preparation method thereof, and belongs to the technical field of lithium battery preparation. The preparation process comprises the following steps: preparing a fluorinated carbon nanotube based on biomass carbon; preparing a positive electrode plate; preparing the dendritic mesoporous silicon dioxide nano particles; preparing a cerium oxide-loaded two-dimensional hierarchical porous composite material; preparing a negative electrode plate; and assembling the lithium battery. According to the preparation method, the eutectic and the carbon fluoride nanotubes are added in the preparation of the positive electrode plate, and the cerium oxide-loaded two-dimensional hierarchical porous composite material and the carbon fluoride nanotubes are added in the preparation of the negative electrode plate, so that the prepared positive electrode plate and the prepared negative electrode plate have relatively high conductivity; and moreover, the ion transmission efficiency is improved, the rapid ion transmission is beneficial to reducing the polarization phenomenon of the battery, improving the charging and discharging rate and the power performance of the battery, enhancing the structural stability of the electrode, improving the performance and the safety of the battery, and being more beneficial to rapid charging and rapid discharging.

The invention relates to a concrete anti-cracking self-repairing agent in the technical field of building materials, and aims to solve the problem that concrete cracks are difficult to self-repair. According to the technical scheme, the self-repairing agent is characterized by comprising a microbial repairing unit formed by ZSM-5 type zeolite molecular sieve loaded bacillus pasteurii spores, mesoporous silica particles loaded with L-calcium aspartate and Fe3O4 (at) SiO2 core-shell nanoparticles which are fixed through an in-situ polymerization coating layer to form a magnetic thermal response capsule layer coating the surface of the microbial repairing unit, pLGA microspheres containing yeast extract are positioned on an interface of zeolite and hydrogel, and a trehalose-anhydrous calcium chloride eutectic compound is used as a directional mineralization accelerant. The concrete anti-cracking self-repairing agent provided by the invention is mainly used for intelligent identification and self-repairing of concrete cracks, and efficient repairing is realized through a microbial mineralization, calcium ion slow release and magnetic thermal response synergistic mechanism.

The invention discloses an antibacterial corrosion-resistant coating and a preparation method thereof, and relates to the field of coating materials. The coating is prepared from the following components in percentage by mass: 2 to 5 percent of nano silver ion loaded mesoporous silicon dioxide nano particle antibacterial aid, 5 to 10 percent of zinc powder-containing corrosion inhibitor, 3 to 8 percent of nano montmorillonite, 30 to 40 percent of modified epoxy resin, 20 to 30 percent of polyurethane prepolymer and other aids. The nano silver ion antibacterial auxiliary agent is loaded in mesoporous silica nanoparticles through an ion exchange method, the zinc powder corrosion inhibitor is prepared through stirring and ball milling dispersion, and the modified epoxy resin is modified by adopting a silane coupling agent. The preparation process of the coating comprises the stages of premixing, grinding and refining, initiating polymerization and post-treatment, wherein a grinding medium is zirconium oxide beads with the diameter of 0.5-2 mm. The coating has excellent antibacterial and corrosion-resistant performance, is suitable for metal surface protection, and can effectively solve the problems that an existing coating is not lasting in antibacterial effect, insufficient in corrosion-resistant performance and not ideal in comprehensive performance.

The invention relates to the field of anticorrosive paint, in particular to anticorrosive paint containing lanthanum cerium oxide and a preparation method of the anticorrosive paint. The invention relates to an anticorrosive coating containing lanthanum cerium oxide. The anticorrosive coating is prepared from the following raw materials: 28 to 45 parts of ultraviolet stable composite film forming matter, 5 to 10 parts of composite rare earth filler, 6 to 12 parts of supported synergistic antirust agent, 18 to 30 parts of mixed solvent, 0.8 to 2.5 parts of dispersing agent, 2.7 to 5.3 parts of functional additive and 0.5 to 1.2 parts of nano montmorillonite, the composite rare earth filler is lanthanum cerium oxide-hydroxyapatite composite powder with a core-shell structure, wherein lanthanum cerium oxide is used as a core, hydroxyapatite is used as a shell, and the thickness of the shell layer is 10-20 nm; the ultraviolet stable composite film forming substance comprises epoxy resin and ultraviolet grafting modified polyurethane in a weight ratio of 1: (0.6-2.2); the supported synergistic antirust agent is a mixture of mesoporous silica supported benzotriazole and zinc molybdate. And the obtained coating is high in adhesive force and long in service life.

The invention relates to the technical field of medical dressings, in particular to a perianal drug dressing of a multi-layer flow guide composite fabric and a preparation method and application of the perianal drug dressing of the multi-layer flow guide composite fabric. The perianal drug dressing is of a four-layer structure, a wet tissue adhesion layer is made of polydopamine modified chitosan / oxidized hyaluronic acid hydrogel, and wet-state adhesion is achieved; the drug sustained-release layer is used for dispersing mesoporous silica loaded with ciprofloxacin hydrochloride / defensin and chitosan microspheres loaded with epidermal growth factors / lonicera japonica into a polycaprolactone fiber membrane to achieve synergistic antibacterial and healing promotion; the directional flow guide layer is of a gradient wettability sandwich structure with a bionic micro-channel, and one-way rapid drainage can be achieved; the high-absorption outer layer is carboxymethyl cellulose / sodium polyacrylate composite sponge, liquid is locked efficiently, the wound surface is kept dry and comfortable, the clinical problem in perianal infection wound treatment can be effectively solved, and the treatment effect and the patient comfort are remarkably improved.

The invention discloses a household nano self-cleaning material containing rare earth elements and a preparation method of the household nano self-cleaning material, and aims at solving the problems that a traditional self-cleaning material is narrow in light response range, single in function, poor in durability, non-environment-friendly in preparation process and the like. The material comprises 5-15 parts of rare earth oxide, 50-70 parts of nano titanium dioxide, 10-20 parts of mesoporous silica, 3-8 parts of a fluorinated modifier and 2-5 parts of a bio-based adhesive. Wherein the rare earth elements are doped in titanium dioxide crystal lattices, so that the forbidden band width is reduced, the photocatalytic response range is widened to visible light, and the photocatalytic efficiency is remarkably improved. The preparation method of the material comprises the steps of precursor preparation, hydrothermal reaction, fluorination modification and coating forming, a low-temperature hydrothermal method, supercritical CO2 modification and a photocuring technology are adopted, and the material has the functions of self-cleaning, antibiosis and VOCs degradation, is suitable for various base materials such as household building materials, textiles and electric appliance surfaces, meets the composite requirements of modern home for health and environmental protection, and has wide application prospects. And the preparation process is green and pollution-free, and conforms to the sustainable development concept.

The invention relates to blue high borosilicate glass and a preparation method thereof, and belongs to the technical field of glass manufacturing, and the blue high borosilicate glass comprises the following raw materials in parts by weight: 50-60 parts of silicon dioxide, 10-15 parts of boron oxide, 2-3 parts of aluminum oxide, 6-8 parts of alkali metal oxide, 3-4 parts of a compound clarifying agent and 1-3 parts of a modified coloring agent. According to the technical scheme, the cobalt blue pigment is coated with mesoporous silica, and the composite material is obtained; combining the composite material with a silane coupling agent to obtain a silanized composite material; combining the silanized composite material with boric acid ester to obtain a modified coloring agent; the prepared modified coloring agent enables the high borosilicate glass to have remarkable blue color and to be stable in color and not prone to volatilization under high-temperature and high-pressure conditions, the added composite clarifying agent is formed by mixing cerium dioxide, sodium sulfate and tin oxide, the clarity of the glass is improved, volatilization of boron is effectively reduced, and the service life of the glass is prolonged. The mechanical property and the stability of the high borosilicate glass are generally improved, and the quality of the glass is improved.

The invention belongs to the field of catalyst preparation, and relates to a preparation method and application of a novel hydrocarbon isomerization catalyst. The preparation method comprises the following steps: firstly, preparing a metal precursor, wherein the metal precursor can be prepared by loading a metal species in a mesoporous silica channel or interacting the metal species with an anionic polymer; then adding the precursor into an SAPO-11 synthesis system containing a phosphorus source, an aluminum source, a silicon source and a structure-directing agent, and carrying out hydrothermal or dry glue water vapor assisted crystallization; and finally, washing, drying and roasting the crystallized product to obtain the hierarchical porous SAPO-11-based metal catalyst with highly dispersed metal species. The method provided by the invention successfully realizes simultaneous modulation of the dispersity of metal species and the pore structure property of SAPO-11, and effectively improves the activity and isomer selectivity of the catalyst in a hydrocarbon skeletal isomerization reaction; the catalyst can be used for improving the octane number of gasoline, the condensation point of diesel oil, the viscosity-temperature performance of lubricant base oil, the freezing point of biological aviation kerosene and the like.

The invention relates to the technical field of defoaming agents, and discloses a polyether modified organic silicon defoaming agent and a preparation method thereof. The polyether modified organic silicon defoaming agent is prepared from the following raw materials in parts by mass: 10 to 30 parts of polyether modified organic silicon, 20 to 40 parts of simethicone, 2 to 5 parts of modified mesoporous silicon dioxide, 2 to 4 parts of a thickening agent, 6 to 10 parts of an emulsifying agent and 35 to 55 parts of deionized water. The preparation method comprises the following steps: firstly, synthesizing hydrogen-terminated organic silicon with a hyperbranched structure, then synthesizing polyether containing a double-bond structure, and connecting the hydrogen-terminated organic silicon and the polyether with a hydrosilylation method to synthesize polyether modified organic silicon; secondly, synthesizing mesoporous silica with an amino group on the surface, and grafting the fluorine-containing chain segment on the mesoporous silica to synthesize modified mesoporous silica; by adopting the synergistic effect of the two components, the defoaming and foam inhibiting properties of a matrix in the foaming liquid are improved, and meanwhile, the foaming liquid has very good wettability and stability.

The invention relates to the technical field of catalyst materials, and particularly discloses a high-stability hydrogenation catalyst and a preparation method thereof. The invention relates to a preparation method of a high-stability hydrogenation catalyst, which comprises the following steps: preparing a hollow porous microsphere as an inner core from amino-terminated hyperbranched polyaryletherketone and polyvinyl alcohol, and then coating the porous microsphere with a mesoporous silicon dioxide intermediate layer by a sol-gel method; and finally, forming an Mg-Al hydrotalcite layer on the outermost side through a coprecipitation method, dipping and modifying with La (NO3) 3 and Ce (NO3) 3 solutions to obtain a catalyst carrier, dipping the catalyst carrier in an active metal dipping solution, and drying to obtain the catalyst. The high-stability hydrogenation catalyst provided by the invention has excellent mechanical properties and more reaction active sites, has high catalytic activity and catalytic efficiency, and is relatively long in catalytic life.

The invention relates to the field of rubber materials, and particularly discloses a lightweight wear-resistant rubber sole and a preparation method thereof. The lightweight wear-resistant rubber sole comprises the following raw materials in parts by weight: 100 parts of main rubber, 30-40 parts of a reinforcing agent, 25-30 parts of a foaming agent, 20-25 parts of a foaming aid, 4.8-5.2 parts of a cross-linking agent, 1-3 parts of an accelerant, 2-3 parts of stearic acid, 4-5 parts of zinc stearate, 9-12 parts of a dispersing agent and 1-2.5 parts of an anti-aging agent, the reinforcing agent comprises coupling modified hollow mesoporous silica spheres; the main rubber is prepared from cis-1, 4-polybutadiene rubber, polystyrene-butadiene rubber and isoprene according to the mass ratio of 1 to (2.3 to 2.5) to (2 to 2.3). The rubber sole is small in density, high in rebound rate, lighter and more comfortable to wear, high in wear resistance and tear resistance, small in compression rebound rate and long in service life.

The invention discloses a production process of a modified p-phenylenediamine rubber anti-aging agent, which comprises the following steps: S1, catalyzing a ring-closure reaction through lipase, and accurately controlling pH by combining a phosphate buffer solution, so that the bonding efficiency of 6PPD and tea polyphenol is remarkably improved, and the release amount of aniline is effectively reduced; s2, carrying out spray drying to obtain EP-TP powder to control the particle morphology; s3, increasing the load rate of the anti-aging agent and effectively inhibiting the migration rate of the anti-aging agent through the pore diameter physical confinement of mesoporous silica and an amination gas phase modification technology, and ensuring uniform dispersion of anti-aging agent particles through the synergistic effect of staged load reaction and a polyethylene glycol dispersant; and S4, the particle morphology is cooperatively controlled through vacuum microwave drying, the dispersion requirement of the rubber mixing technology is met, and the interface bonding strength is improved by combining the staged loading reaction with a polyethylene glycol dispersing agent.

The invention relates to the field of caprolactam production, and discloses a green and efficient production process and device. The process comprises the following steps: continuously oximating cyclohexanone and hydroxylamine in a microreactor under the catalysis of mesoporous silica solid acid; carrying out gas phase rearrangement on cyclohexanone-oxime in the presence of a ZSM-5 molecular sieve under the assistance of microwaves; coupling, rectifying and purifying the crude product through a four-stage molecular sieve membrane; and performing catalytic cracking on the by-product to obtain N2 / H2O and recycling. The device comprises a micro-reaction unit, a microwave-radial reactor, a membrane coupling rectifying tower group and a tail gas cracking unit. Zero emission of ammonium sulfate is achieved, the product purity is larger than or equal to 99.95%, and energy consumption is reduced by 45%.

This invention belongs to the field of polymer material reinforcement and toughening, specifically relating to a spiked-mesoporous silica nanosphere, its preparation method, and its application in polymer material reinforcement and toughening. The basic steps for synthesizing this spiked-mesoporous silica nanosphere include: firstly, synthesizing low-crosslinked, smooth-surfaced mesoporous silica nanospheres through an oil-water two-phase reaction system; subsequently, inducing normal shrinkage of the pore walls through secondary deep crosslinking to form a rigid nanospike surface structure while maintaining the original mesoporous structure. This spiked-mesoporous silica nanosphere exhibits good monodispersity, high particle size uniformity (50-100 nm adjustable), centrally divergent mesopores with high pore size uniformity (6-8 nm adjustable), highly open pores on the sphere surface, and spike height adjustable from 3-5 nm. This material is suitable for reinforcing and toughening various elastomers, resins, and other polymer materials, effectively overcoming the "strength-toughness mutual exclusion" problem and synergistically enhancing existing mechanical property reinforcement systems.

The invention discloses an M2M-SeMSN-coated C176 nano-particle, a preparation method and application thereof, the nano-particle comprises an STING inhibitor C176 and a carrier, and the carrier is based on an M2 macrophage membrane and a selenium-bridged mesoporous silica nano-particle. Specifically, the M2M-SeMSN-coated C176 nano-particles are obtained by loading an STING inhibitor C176 by using a selenium-bridged mesoporous silica nano-particle SeMSN and M2 macrophage cell membrane. The invention further discloses a preparation method of the M2M-SeMSN-coated C176 nano-particles. The M2M-SeMSN-coated C176 nanoparticles can be used for preparing a medicine for treating acute kidney injury.

The invention discloses a method for preparing 12-mercaptan through solid organic acid catalysis, belongs to the technical field of 12-mercaptan preparation, and aims to solve the problems of low catalyst activity, harsh reaction conditions, serious pollution, high cost and dependence on import in the prior art. N-dodecanol and hydrogen sulfide are used as raw materials and are mixed according to the molar ratio of 1: 1.2-1: 1.3; the method comprises the following steps: gasifying n-dodecanol, mixing with purified hydrogen sulfide, preheating to 210-240 DEG C, introducing into a fixed bed reactor filled with a solid organic acid catalyst, and reacting at-0.08-3.0 MPa for 3.5-4 hours; and cooling and condensing the reaction product, carrying out gas-liquid separation, rectifying and purifying the liquid product to obtain 12-mercaptan with the purity of more than or equal to 99.5%, and recycling unreacted hydrogen sulfide. The solid organic acid can be a catalyst of p-toluenesulfonic acid and the like or mesoporous silica loaded nickel, cobalt and molybdenum metal oxides. The method has the advantages of high catalytic activity, mild reaction conditions, high product yield (the conversion rate of n-dodecanol is greater than or equal to 94.5%), environmental protection and low cost, can realize the domestic mass production of 12-mercaptan, and meets the market demand.

The invention discloses a preparation method and application of washable tin-based perovskite quantum dots, and the preparation method comprises the following steps: mixing cesium iodide powder, tin iodide powder and mesoporous silica powder, and then placing the mixture in a plasma ball mill for ball-milling diffusion, cesium iodide and tin iodide react in a confinement space of mesoporous silica to generate a CsSn I < 3 >-coated SiO2 composite structure, CsSn I < 3 > quantum dots are dispersed and coated in the mesoporous silica, and the application of the tin-based perovskite quantum dots in the anti-ultraviolet textile fabric is provided. The method has the following beneficial effects that the purpose of remarkably improving the stability of the tin-based perovskite quantum dots and the washing resistance of the textile is achieved.

The invention discloses a high-strength modified polyethylene composite fiber and a preparation method thereof, and belongs to the technical field of fiber materials, carboxylated mesoporous silica microspheres are used as a matrix, the surface of the matrix is coated with a graphene sheet layer, then hydroxyethyl methylacrylate is grafted, functionalized graphene / mesoporous silica microspheres are obtained, the functionalized graphene / mesoporous silica microspheres are used as a filler, and the high-strength modified polyethylene composite fiber is prepared. When the polyethylene composite fiber is applied to a ship cable, the overall weight of the ship cable can be reduced, and relative slippage can be generated between graphene lamellas and mesoporous silica microspheres, so that stress is dispersed, and the strength of the polyethylene composite fiber is improved; a hydrophobic alkane long chain is introduced through esterification of the graphene / mesoporous silica microspheres and hydroxyethyl methylacrylate and graft modification of hydroxyethyl methylacrylate, so that the hydrophobic alkane long chain has good compatibility with white oil, and the microspheres are prevented from approaching and gathering by a steric hindrance effect, so that the hydrophobic alkane long chain is more uniformly and stably dispersed in the white oil.