273 results about "Silica nanoparticle" patented technology

The invention discloses an antibacterial corrosion-resistant coating and a preparation method thereof, and relates to the field of coating materials. The coating is prepared from the following components in percentage by mass: 2 to 5 percent of nano silver ion loaded mesoporous silicon dioxide nano particle antibacterial aid, 5 to 10 percent of zinc powder-containing corrosion inhibitor, 3 to 8 percent of nano montmorillonite, 30 to 40 percent of modified epoxy resin, 20 to 30 percent of polyurethane prepolymer and other aids. The nano silver ion antibacterial auxiliary agent is loaded in mesoporous silica nanoparticles through an ion exchange method, the zinc powder corrosion inhibitor is prepared through stirring and ball milling dispersion, and the modified epoxy resin is modified by adopting a silane coupling agent. The preparation process of the coating comprises the stages of premixing, grinding and refining, initiating polymerization and post-treatment, wherein a grinding medium is zirconium oxide beads with the diameter of 0.5-2 mm. The coating has excellent antibacterial and corrosion-resistant performance, is suitable for metal surface protection, and can effectively solve the problems that an existing coating is not lasting in antibacterial effect, insufficient in corrosion-resistant performance and not ideal in comprehensive performance.

The invention belongs to the technical field of environmental protection, and provides a preparation method of an imine-modified functionalized mesoporous magnetic silicon dioxide nano material. The method comprises the following steps: synthesizing Fe3O4 magnetic nanoparticles in a Fe < 2 + > / Fe < 3 + > alkaline hydrolysis system through a coprecipitation method; then coating the magnetic nanoparticles with an amorphous silicon dioxide layer by taking TEOS (tetraethoxysilane) as a silicon source by adopting a sol-gel method, so as to prepare magnetic silicon coated nanoparticles; the prepared nano-particles are subjected to secondary silicon coating guided by a cetyl trimethyl ammonium bromide (CTAB) mesoporous template agent, and mesoporous magnetic silicon nano-particles are formed after calcination; and finally, carrying out surface amination modification on the mesoporous magnetic silicon nano-particles by utilizing an amino silane coupling agent, and then carrying out condensation reaction on the mesoporous magnetic silicon nano-particles and various aldehyde derivatives to construct imine bonds, so as to obtain the imine-modified functionalized mesoporous magnetic silicon dioxide nano-material. The imine-modified functionalized mesoporous magnetic silicon dioxide nano-material formed by the invention has the characteristics of efficient adsorption, rapid magnetic recovery and excellent environmental stability, and can effectively remove polystyrene micro-plastics and organic pollutants in a water body.

The invention relates to the technical field of wind power and power grid equipment anti-icing, and discloses a fluorosilicone oil microcapsule anti-icing coating for wind power and power grid equipment. Comprising the following components which are independently subpackaged: a component A, namely a nano ceramic pre-dispersion: 20-30 parts of methyltrimethoxysilane, 5-8 parts of tetraethoxysilane, 40-60 parts of isopropanol and 10-15 parts of silicon dioxide nanoparticles with perfluoroalkyl grafted on the surfaces; the component B is microcapsule dry powder: 25-40 parts of mesoporous alumina microcapsules filled with fluorosilicone oil, 1-4 parts of amino modified carbon nanotubes and 2-5 parts of an oxygen vacancy defect type titanium dioxide photocatalyst, the microcapsules are triggered to release the fluorosilicone oil through the volume expansion rate of a thermal expansion layer and stress sensitive layer composite wall material at low temperature, and meanwhile, when ice pressure exists, the stress sensitive layer can release the fluorosilicone oil, so that the stress sensitive layer can release the fluorosilicone oil. And the polydopamine-coated aluminum oxide layer is elastically deformed to synergistically release the fluorosilicone oil to form a dual-mode anti-icing mechanism.

The application belongs to the technical field of functional coating materials, and particularly relates to a kind of super-hydrophobic solution based on fumed silica and its preparation method and application, comprising: step one, 20-200nm fumed silica nanoparticles are dispersed in ethanol / water mixed system, and sodium dodecyl benzene sulfonate is added to prevent agglomeration;Step two, under the catalysis of ammonia, tetraethyl orthosilicate and 1H, 1H, 2H, 2H-perfluorodecyltriethoxysilane are added dropwise in sequence for fluorination modification;Step three, fluorinated silica nanoparticle suspension is prepared by ultrasonic-assisted reaction;Step four, the solution is sprayed onto the surface of ceramic substrate with micro-nano structure to form a coating;Step five, strong adhesion without adhesive is realized by mechanical anchoring effect.The application realizes super-hydrophobic performance of 153±0.5° high water contact angle and physical adhesion stability under 100-200g load by the synergistic effect of nanoparticle size effect and substrate surface topological structure, low surface energy of fluorinated alkyl chain and Cassie-Baxter air cushion layer effect, and is especially suitable for self-cleaning surface, anti-icing coating and marine corrosion prevention field.

The application discloses a light-controlled nitric oxide releasing hollow single-atom nanoscale enzyme, a preparation method and application, and belongs to the technical field of biomedical materials. In the application, spherical silica nanoparticles are used as a template, and a structure of copper ion-polydopamine coated silica nanoparticles is formed on the surface of the silica nanoparticles through self-polymerization of dopamine and chelation of copper ions, and the spherical structure is maintained with the support of the silica nanoparticles. The copper ion-polydopamine coated silica nanoparticles are pyrolyzed to obtain a copper-based single-atom nanoscale enzyme with a carbon skeleton, and a hollow spherical single-atom nanoscale enzyme is obtained after etching. Nitric oxide donor molecules are loaded into the hollow of the hollow spherical single-atom nanoscale enzyme to obtain the light-controlled nitric oxide releasing hollow single-atom nanoscale enzyme. The application can realize the synergistic treatment effect of photothermal therapy, nitric oxide gas therapy and biological catalytic therapy, is used for efficiently removing bacteria and biofilms at an infected wound site, and effectively promotes the healing of the bacteria-infected wound.

The invention provides low-viscosity high-wear-resistance vehicle engine oil and a preparation method thereof, and belongs to the technical field of engine oil. According to the preparation method, an ionic liquid group is introduced through a reaction, a nano interlayer compound is constructed by combining surface modification of a metal-ionic liquid complex and silicon dioxide nanoparticles, and a microcapsule structure is formed through coating of a urea-formaldehyde prepolymer; the ionic liquid group provides a low friction coefficient and thermal stability, the silicon dioxide nanoparticles provide physical isolation and wear-resistant protection, and the microcapsules realize controlled release and dynamic repair of the lubricating components; a skeleton polymer is prepared through a reaction of polyamidoamine and epoxy chloropropane so as to provide abundant active sites, and oxidation resistance is improved through a synergistic effect of the skeleton polymer, hindered phenol and calixarene; by combining oleic acid modified nanoparticles, the dispersity and the wear resistance are enhanced, and meanwhile, dynamic protection is provided on a friction interface; the synergistic effect prolongs the service life of the engine oil and improves the high-temperature stability of the engine oil.

Methods and compositions including a CO2 foam treatment fluid having a plurality of functionalized silanol group silica nanoparticles the silanol group selected from the group consisting of an isolated silanol group, a vicinal silanol group, a geminaol silanol group, and any combination thereof; and a surfactant. The CO2 foam treatment fluids can be used for stimulation of subterranean formations for hydrocarbon production.

The invention belongs to the technical field of biological medicines, and relates to a protein degradation system based on polyamide-amine dendrimers as well as a preparation method and application of the protein degradation system. The protein degradation system is of a nano-particle structure, and the nano-particle structure comprises silicon dioxide nano-particles and a polyamide-amine type dendritic polymer layer coating the surfaces of the silicon dioxide nano-particles. An MDM2 protein ligand, a GLUT1 protein ligand and an E3 ubiquitin enzyme ligand are connected to the polyamide-amine dendritic polymer layer through chemical bonds. The protein degradation system provided by the invention can be used for synergistically degrading the MDM2 protein and the GLUT1 protein. The synergistic degradation strategy not only can effectively inhibit proliferation and energy metabolism of tumor cells, but also can significantly enhance the stability of the p53 protein. By recovering the normal function of the p53 protein, the growth of tumor cells is further inhibited, and a new strategy is provided for tumor treatment.

The invention relates to the technical field of high polymer materials, in particular to a corrosion-resistant cable sheath material and a preparation method thereof. The sheath material is prepared by taking an ethylene-octylene copolymer as a matrix and compounding functional fillers such as an aminated magnesium ion exchange A type molecular sieve, dopamine shell silicon dioxide nanoparticles and phenylboronic acid / octadecyl double-grafted silicon dioxide nanoparticles. Wherein the aminated Mg-A molecular sieve is used for efficiently capturing and fixing chloride ions through an ion-dipole effect and a hydrogen bond network; the dopamine shell layer silicon dioxide enhances the interface bonding strength through dual active groups of catechol and amido; phenylboronic acid / octadecyl double-grafted silicon dioxide constructs a dynamic boric acid ester cross-linked network and a hydrophobic barrier, and synergistic protection of crack self-healing and moisture barrier is achieved. The sheath material remarkably improves the long-term corrosion resistance and mechanical stability of the cable in a severe environment.

An example of a resin composition includes an epoxy resin matrix and functionalized silica nanoparticles incorporated into the epoxy resin matrix. The functionalized silica nanoparticles have an average particle size up to about 10 nm. The resin composition is imprintable using nanoimprint lithography. The resin composition may be used to manufacture a patterned substrate for a flow cell.

The invention provides a preparation method of morphology-controllable silicon oxide nanoparticles, which comprises the following steps: (1) preparing alkali liquor which contains organic amine or amino acid with buffering capacity and has the pH value of about 8-10.5; (2) preparing hydrolysate which contains deionized water, ethanol and tetraethoxysilane in a certain proportion and has a controllable siloxane hydrolysis state; (3) adding the hydrolysate into the alkali liquor prepared in the step (1) according to a small-amount multi-time method, and reacting for 1-5 hours to obtain a silicon oxide nano-particle solution; and (4) carrying out large particle filtration, solvent replacement and concentration on the silicon oxide nanoparticle solution by an ultrafiltration method to finally obtain the silicon oxide nanoparticle product with controllable morphology. The morphology of the synthesized high-purity silicon oxide nanoparticles can be accurately regulated and controlled according to actual requirements. Due to the characteristic, the silicon oxide nano-particles can fully meet the diversified requirements on abrasive morphology under different chemical mechanical polishing (CMP) scenes.

The application discloses iron oxide coated silica core-shell nanoparticles and a preparation method and application thereof. The iron oxide coated silica core-shell nanoparticles comprise silica nanoparticles as an inner core and iron oxide nanoparticles as an outer shell coated on the inner core surface of the silica nanoparticles; the particle size is 22-112 nm; and the particle uniformity is 0.08-0.3. The preparation method of the iron coated silica nanoparticles provided by the application adopts the measure of adjusting the pH of slurry for multiple times, avoids the agglomeration of nanoparticles in a solution near the isoelectric point, and is thus favorable for finally obtaining core-shell nanoparticles with uniform monodispersity. No surfactant is used in the preparation process, and there is no complicated post-treatment process, thereby reducing the production cost. The uniformly monodispersed nanoparticles prepared by the method have great potential in the field of chemical mechanical polishing.

A method for improving drug solubility and a drug composite material having improved solubility. The method comprises preparing a silica colloidal suspension from silica nanoparticles having a diameter between 2 nm and 100 nm; rapidly evaporating a solvent by means of controlling the temperature and pressure, so as to obtain a porous surface material with ultra-high density silanol groups retained on the surface; and loading drug molecules. By controlling the size of nanoparticles and the density of silanol groups, drug molecules can be effectively adsorbed under anhydrous conditions, and rapidly desorbed and released in an aqueous environment.

The invention provides a preparation method of a TBBPA selective adsorption film. The method comprises the following steps: 1) synthesizing mesoporous silica nanoparticles; the invention discloses a TBBPA selective adsorption membrane and a preparation method thereof, the TBBPA selective adsorption membrane comprises the following steps of 1, TBBPA preparation, 2, base membrane synthesis and 3, blotting membrane synthesis, the TBBPA selective adsorption membrane is suitable for selective adsorption and separation of TBBPA from polluted water, through the design of blotting sites, TBBPA can be selectively adsorbed from analogues, and the TBBPA selective adsorption membrane has good application prospects in the field of selective separation of high-concentration TBBPA pollutants.

We have developed novel shear-thinning biomaterials using silica nanoparticles, gelatin-based polymers and small molecules such as doxorubicin. Shear-thinning biomaterial technology offers enables polymers and drugs loaded inside such polymers to be easily delivered directly through catheters into target area for use, for example, in cancer therapy and immunotherapy. When a force above a certain threshold is applied to inject such materials, they “thin” and behaves as a semi-solid, allowing the material to readily flow through a catheter. When the force is removed, the material instantly becomes a soft solid with significant cohesive properties that prevent it from dislodging or breaking up.

The present invention relates generally to nanoparticle-stabilized fire-fighting foam concentrates, fire-fighting foam solutions, and fire-fighting foams prepared from the concentrates or solutions of the present invention that contain one or more silica nanoparticles (e.g., silica nanoparticles, silica nanoparticles, silica nanoparticles, silica nanoparticles, silica nanoparticles, silica nanoparticles, silica nanoparticles, silica nanoparticles, silica nanoparticles, silica nanoparticles, silica nanoparticles, silica nanoparticles, silica nanoparticles, silica nanoparticles, silica nanoparticles, surface modified silica nanoparticles) and any one or all of one or more components selected from the group consisting of one or more organic solvents, one or more surfactants, one or more biopolymers, and one or more alcohols. The invention also relates to a method for increasing the resistance of fire-fighting foams to polar solvents. The present invention also relates to methods of making fire foam concentrates comprising silica nanoparticles (e.g., surface-modified silica nanoparticles).

A nanoparticle-well treatment additive complex comprising an amine functionalized silica nanoparticle, and a well treatment additive, where the well treatment additive is releasably attached to an amine group of the amine functionalized silica nanoparticle is disclosed. Methods of using the amine functionalized silica nanoparticle is also disclosed.

The invention relates to the technical field of food processing, and provides a method for reducing the use amount of ethanol produced from citrus fibers. Mixing the wet fiber component C with 75%-85% ethanol according to the mass ratio of 1: 1, adding hydrophobic nano silicon dioxide accounting for 1%-3% of the mass of the wet fibers, dispersing and mixing at a high speed by using a colloid mill to gradually flocculate and precipitate the fibers, and discharging an upper-layer mixed solution of ethanol and water; adding 0.5-0.7 time of 95% ethanol into the precipitate, putting the precipitate into an ultrasonic reactor, and treating for a preset time under the conditions that the frequency is 30-50kHz and the power density is not lower than 1W / L to remove the nano silicon dioxide, so as to obtain a precipitate D; and squeezing and dealcoholizing the precipitate D material to obtain the finished product citrus fiber. According to the method, the hydrophobicity is increased by the silicon dioxide nanoparticles so as to reduce the water absorption rate of the fiber, and the ethanol consumption is greatly reduced during the production of the citrus fiber.

This invention discloses a method for preparing a core-shell microneedle patch loaded with dual nanoparticles, comprising: preparing silica nanoparticles loaded with oxyhemoglobin and dihydroporphyrin e6; preparing calcium carbonate nanoparticles loaded with aPD-1 antibody; dispersing the silica nanoparticles loaded with oxyhemoglobin and dihydroporphyrin e6 in a polyvinyl alcohol solution to prepare the shell structure of the microneedles; preparing a polymer hydrogel; dispersing the calcium carbonate nanoparticles loaded with aPD-1 antibody in the polymer hydrogel to prepare the core structure of the microneedles; and casting the polyvinyl alcohol solution onto the backing of the microneedles to finally obtain the core-shell microneedle patch loaded with dual nanoparticles. The core-shell microneedle patch loaded with dual nanoparticles prepared by this invention can deliver nanoparticles to the tumor site, where the nanoparticles respond to the tumor microenvironment and activate the body's own immune system, thereby achieving a therapeutic effect on tumors.

The invention discloses a rare earth element modified nickel-based nano-catalyst and a preparation method and application thereof.The rare earth element modified nickel-based nano-catalyst comprises a carrier and an active component loaded on the carrier, and the carrier is cerium dioxide and yttrium oxide co-doped three-dimensional ordered silicon dioxide nanoparticles; the active component is metal nickel. The application refers to the application of the catalyst in preparation of synthesis gas through carbon dioxide methane reforming. According to the invention, rare earth element doped and modified three-dimensional ordered silicon dioxide nanoparticles are used as a carrier, nickel metal is loaded on the nanoparticles, and the problem of carbon deposition can be effectively reduced by adjusting the interaction of alkaline sites and oxygen vacancies on the surface of the catalyst and the metal carrier. The method provided by the invention is helpful for realizing industrialization of a carbon dioxide methane catalytic reforming reaction, realizing a carbon emission reduction target and solving a green electricity energy storage problem.

The application discloses a carboxyl modified nano oil displacement agent which is composed of a nano silicon dioxide skeleton and a functional group connected to the nano silicon dioxide skeleton, wherein the functional group is -RCOOM, R is CH2 or C2H4, and M is one of Li, K and Na. The application also discloses a preparation method of the carboxyl modified nano oil displacement agent, which comprises the following steps: (1) preparing a hydroxyl silicon dioxide nanoparticle dispersion liquid; (2) preparing an amino modified nano silicon dioxide solution, and obtaining amino modified nano silicon dioxide particles after first post-treatment; and (3) dispersing the amino modified nano silicon dioxide particles in water, adding a halogen acetic acid monovalent salt, and then performing reaction and second post-treatment to obtain the carboxyl modified nano oil displacement agent. The oil displacement system is composed of the carboxyl modified nano oil displacement agent, a polymer, a surfactant and water, wherein the carboxyl modified nano oil displacement agent accounts for 0.05-0.3%, the polymer accounts for 0.1-0.3%, the surfactant accounts for 0.1-1%, and the rest is water.

The invention discloses a porous breathable waterproof automobile tarpaulin material and a preparation method thereof.The preparation method comprises the steps that a polyester fiber membrane is modified through dopamine hydrochloride, the surface tension of a water solvent is regulated and controlled through a surfactant, so that a silicon dioxide precursor is dissolved and dispersed, and silicon dioxide nanoparticles grow on the surface of the modified polyester fiber membrane in situ; then adding a low-surface-energy modifier, namely super-hydrophobic silicon dioxide nanoparticles; and finally, drying the treated polyester fiber film in a heating environment and decomposing the surfactant to obtain the waterproof automobile tarpaulin material with the porous structure. According to the automobile tarpaulin, the porous structure of the polyester fiber film is kept, meanwhile, the waterproof performance is achieved, the automobile tarpaulin has the protection function and the air permeability, the problem that the quality of transported goods is reduced due to the fact that the tarpaulin is shielded is solved, and the application range of the automobile tarpaulin is widened. The waterproof material is synthesized and prepared by using water as a solvent, and the problems of flammable and explosive risks and environmental pollution caused by the use of an organic solvent are avoided.

The present invention provides organic-inorganic hybrid mesoporous silica nanoparticles, their self-template synthesis method and application. Long-chain alkylamino groups are connected to the surface of silica nanoparticles, wherein the long-chain alkylamino groups are dialkyl-substituted alkylamino groups, and the length of the alkyl substituent on the nitrogen atom in the amino group is 1-3, thereby forming a mesoporous structure. The present invention uses the long-chain alkylamino groups as self-templates and synthesizes the mesoporous silica nanoparticle material by a reverse microemulsion method. The organic-inorganic hybrid mesoporous silica nanoparticle material can be used as an adsorbent to remove various organic pollutants in water and has a large adsorption capacity and high adsorption efficiency.

The invention provides a preparation method and application of a ph response type raspberry-shaped nanoparticle emulsifier. Silicon dioxide nano-particles are subjected to surface modification, polystyrene is wrapped to form raspberry-shaped particles, and the surfaces of the silicon dioxide nano-particles are modified with ph response groups. The nano-particles modified by the pH response group can effectively emulsify and stabilize an oil-water system. The method has the advantages of easily available raw materials, low cost, simplicity and convenience in operation, good stability of the obtained emulsion and the like, and has a considerable application prospect in the field of emulsifiers.

The invention relates to a synthesis method and application of a double-layer thermochromic deformation hydrogel, according to the double-layer thermochromic deformation hydrogel, CMC is adopted to perform mechanical enhancement on original PNIPAm, LAP is adopted to perform photo-initiation on a monomer, and the price of CMC and LAP is far lower than that of functionalized silicon dioxide nanoparticles and AIBA in the prior art under the same usage amount. Meanwhile, drugs used in the process are free of volatility and corrosivity, and the safety degree is higher than that of acrylic monomers used in the prior art. Besides, the use temperature of a hydrogel device in the prior art is 60 DEG C and is high, while the double-layer temperature-sensitive hydrogel in the invention can be curled only at 40 DEG C, so that the hydrogel has more advantages in temperature. By adding CMC, the volume change of the hydrogel in the heating process is remarkably reduced, meanwhile, the mechanical property of the hydrogel is greatly improved, the mechanical property of the hydrogel is further improved through impregnation of zirconium ions, and the hydrogel has a wider application scene.

A process to remove H2S from a stream is described and claimed. The process comprises the steps of adding an amine-functionalized silica nanoparticle composition, and optionally a iriazine. The stream is selected from the group consisting of Oil streams, Gas streams, CO2 point source purification streams and Geothermal Energy System streams.

In one embodiment, an article is described comprising: a substrate; a hardcoat layer disposed on the substrate wherein the hardcoat layer comprises the hydrolyzed and condensed reaction product of a composition comprising: i) first silane monomer(s) having the formula R1Si(OR)3 wherein R and R1 is methyl or ethyl; ii) at least one organic polymer comprises one or more functional groups that react with hydrolyzed OR groups of the first silane monomer(s); iii) at least 10 wt.% of silica nanoparticles; and C) a surface layer comprising a hydrophilic silane disposed on the hardcoat layer. Also described is a hardcoat composition and methods of use. One method comprise writing on the hardcoat layer or surface layer; and removing the writing.

PPAB derived near-infrared super-small fluorescent silica nanoparticles and synthesis method and application thereof, the fluorescent silica nanoparticles prepared by the present application exhibit strong near-infrared fluorescence and good water solubility, have a strong fluorescence emission peak near 650 nm-700 nm wavelength, exhibit good fluorescence spectrum performance, and therefore the silicon quantum dots have relatively good cell tissue penetration. Due to the unique optical properties and relatively good cell tissue penetration, the in vivo fluorescence imaging can be effectively carried out. The fluorescent silica nanoparticles prepared by the present application have excellent singlet oxygen generation performance and peroxidase performance in addition to excellent near-infrared optical performance and good biocompatibility, can be used as a photodynamic / chemodynamic synergistic treatment reagent, and are used for antibacterial and antitumor applications, and have no toxic side effects on the organism itself.

This invention relates to a high-temperature resistant industrial coating and its preparation method. The method includes: amylating Fe3O4 nanoparticles; grafting the amylated Fe3O4 nanoparticles with polybenzimidazole to obtain PBI-g-Fe3O4 composite particles; in-situ growing MOF to form polyMOF; and surface modification with a hydrophilic silane coupling agent to obtain a hydrophilic modified polyMOF; simultaneously, co-grafting silica nanoparticles with an aminosilane coupling agent and a long-chain alkylsilane coupling agent to obtain a synergist; finally, dispersing all components in an aqueous polyester resin varnish to prepare a composite coating. This invention achieves stable dispersion and strong interfacial bonding of polyMOF in aqueous polyester through a multi-level chemical bonding structure. The synergist synergistically provides curing and defoaming effects. The resulting coating exhibits grade 0 adhesion, excellent defoaming performance, a pencil hardness of 3H, and a temperature resistance limit of 640℃, showing broad application prospects in the field of high-temperature protection.

The invention discloses a reinforcing and protecting material for paper cultural relics and application of the reinforcing and protecting material. According to super-hydrophobic treatment liquid, silicon dioxide nanoparticles are modified through a silane coupling agent and a perfluoroalkyl trialkoxysilane coupling agent, an extremely low surface energy layer is constructed, and water is effectively prevented; the reinforcing treatment liquid adopts cellulose derivatives to form a hydrogen bond network with paper cellulose, so that the mechanical strength is remarkably improved. The hydrophobic property and the mechanical property are kept stable after dry-heat and damp-heat accelerated aging, and long-term preservation of cultural relics is facilitated. The design of the coating follows the principle of reversibility, the super-hydrophobic layer and the reinforcing layer are microcosmically firm and macroscopically integrally stripped, the super-hydrophobic layer and the reinforcing layer can be removed in a lossless mode through absolute ethyl alcohol and other mild solvents, the surface of the paper is restored to be close to the state before treatment, and a base material is not damaged or the appearance of the base material is not changed.