14551 results about "Polyurethane" patented technology

The invention belongs to the technical field of aerogel materials, and particularly relates to antistatic aerogel for 3D printing as well as a preparation method and application of the antistatic aerogel. The preparation method comprises the following steps: (1) dispersing inorganic nanoparticles modified by a silane coupling agent containing epoxy groups and an aniline monomer in an acidic solvent to obtain a monomer mixed solution; (2) stirring and dissolving polyamide in the monomer mixed solution; (3) initiating a reaction to obtain a polyaniline modified polyamide solution; and (4) freeze-drying to obtain the antistatic aerogel for 3D printing. By controlling synthesis conditions, a core-shell structure of acid-doped polyaniline coated inorganic nanoparticles is formed, and a good conductive path is formed in polyamide with a small addition amount of polyaniline. The antistatic aerogel for 3D printing can be applied to technologies such as photocuring molding and fused deposition of polyurethane resin in a 3D printing technology, and the antistatic property and the mechanical property of a 3D printed product are improved.

The invention belongs to the technical field of polymer preparation, and particularly relates to a curved-surface polyaniline modified 3D printing polyurethane material and application thereof. According to the preparation method, an ice crystal hard template method and a polyether glycol soft template method are combined, so that the microstructure of polyaniline is adjusted, and the curved polyaniline with regular morphology is prepared. The curved-surface arc-shaped structure has a large specific surface area, can form more contact sites with resin when being directly melt-blended with the resin, is beneficial to construction of a conductive path, and is not easy to agglomerate due to the curved-surface structure. The polyaniline with the arc-shaped structure is of a three-dimensional space structure and is directly blended with the resin to form a randomly arranged conductive network structure, so that the composite material is not easy to break when being impacted, and can be better embedded between the resin to form a stress transfer channel, and a complex three-dimensional network structure is constructed; the mechanical property and the antistatic capability of the product are improved.

The invention discloses high-toughness ultra-high performance concrete and a preparation method thereof, and relates to the technical field of polymer modified materials thereof. The concrete is composed of a cementitious material composite system, a fiber-reinforced system and a polymer modifier, the cementitious material comprises Portland cement, nano-silica, a rice hull ash-based auxiliary cementitious material and gradient grading quartz powder, and the fiber system adopts steel fiber / basalt fiber / polypropylene fiber multi-scale composite reinforcement. And a polyurethane emulsion interface modifier is matched. During preparation, a dry mixing-fiber dispersion-wet mixing three-stage process is combined with a microfluidization emulsification and segmented polymerization technology, so that uniform dispersion of fibers and matrix-fiber interface reinforcement are realized. The scheme has high strength, high toughness and industrial feasibility, and is suitable for harsh engineering scenes such as bridge joints and explosion-proof structures.

The invention relates to a photo-thermal super-hydrophobic multifunctional anti-icing coating as well as a preparation method and application thereof. The photo-thermal super-hydrophobic multifunctional anti-icing coating comprises primer and finish paint, the primer comprises the following raw materials in parts by weight: 20-25 parts of bisphenol A type epoxy resin and / or fluorine modified epoxy resin, 10-20 parts of fluorine modified polyacrylic resin and / or polyurethane resin, 5-10 parts of a curing agent and 40-55 parts of a solvent; the finish paint comprises the following components in parts by weight: 2-5 parts of polytetrafluoroethylene, 1-3 parts of soluble polytetrafluoroethylene, 1-5 parts of polydimethylsiloxane and 85-90 parts of fluorinated MOF dispersion liquid. Compared with the prior art, the photo-thermal super-hydrophobic multifunctional anti-icing coating provided by the invention has the characteristics of super-hydrophobicity, rapid ice melting, wear resistance, reduction of ice adhesion strength and reduction of icing amount, can effectively solve the problem of icing of an aluminum conductor of a power transmission line of a power system, and can be applied to power equipment such as the aluminum conductor of the power transmission line.

The invention relates to the technical field of high polymer materials, and particularly provides a self-repairing type UV curing alumite color layer coating and a preparation method thereof. The water-based ink is prepared from, by weight, 30-50 parts of polyurethane acrylic resin, 10-25 parts of modified acrylic oligomer containing dynamic covalent bonds, 2-5 parts of photoinitiator, 3-8 parts of hydrophobic modified nano filler and 1-3 parts of cross-linking agent, and the dynamic covalent bonds are selected from at least one of hydrazide bonds, boric acid ester bonds and Diels-Alder bonds. By introducing a gradient energy collaborative network of dynamic covalent bonds and quadruple hydrogen bonds, rapid self-repairing of the coating at normal temperature and thermal triggering recombination of deep damage are achieved, and meanwhile through the micro-phase separation design of the hydrophobic core-shell filler and the graft modified silicon carbide nanowires, the hydrolysis resistance is improved.

The invention relates to the technical field of cold storage spraying, and discloses a cold storage spraying polyurethane real-time monitoring system based on temperature and humidity feedback, and the system comprises an environment collection module, a state analysis module, a parameter regulation and control module, a dynamic fusion module, a mode matching module and a feedback execution module. The environment acquisition module acquires temperature and humidity data and sets a monitoring interval; the state analysis module divides coating detection nodes and generates feature vectors; the parameter regulation and control module is used for separating influence factors, establishing control rules and acquiring process parameters; the dynamic fusion module identifies the equipment state, performs dynamic compensation and calculates the parameter difference degree; the mode matching module deduces an optimal curing threshold value and generates a deviation sequence; and the feedback execution module analyzes the deviation sequence and generates an adjustment instruction. The system realizes real-time monitoring and accurate regulation and control of the process of spraying polyurethane on the refrigeration house, improves the quality stability of the coating and the construction efficiency, is suitable for refrigeration house construction and maintenance scenes, and has the advantages of high environmental adaptability, accurate parameter regulation and control and the like.

The invention relates to the technical field of silica gel cables, and discloses a silica gel cable with high reliability and high flexibility and a process thereof, and the silica gel cable comprises a conductor layer which is formed by hierarchically twisting a plurality of tinned copper wires with the diameter of 0.05-0.10 mm, and the twisting helical angle gradually changes from 25 degrees in the inner layer to 55 degrees in the outer layer; the insulating layer coats the conductor layer and comprises a silica gel material, a hydrogen-containing silicone oil cross-linking agent and a plasticizer, microcapsules with the particle size of 20-50 microns are dispersed in the silica gel material, a shell layer of each microcapsule is polyurethane, and a core layer of each microcapsule is a siloxane repairing agent containing a platinum catalyst; and a sheath layer. A hydrogen-containing silicone oil cross-linking agent in the insulating layer enables molecular chains to be cross-linked to form a net structure, the physical and chemical stability is enhanced, microcapsules are matched to endow a self-repairing function, a repairing agent is released when the cable is damaged, the self-repairing performance of the insulating layer is further guaranteed, damage is filled through a cross-linking reaction, insulation is recovered, the reliability of the cable is remarkably improved, and the service life of the cable is remarkably prolonged.

The invention relates to the field of adhesives, and particularly discloses an OCA optical adhesive for a folding screen and a preparation method of the OCA optical adhesive. The OCA optical adhesive for the folding screen is prepared from the following raw materials in parts by weight: 60 to 80 parts of urethane acrylate, 15 to 25 parts of organic silicon grafted glycidyl ether, 20 to 30 parts of a diluent, 5 to 10 parts of a photoinitiator and 1 to 2 parts of an antioxidant, the organic silicon grafted glycidyl ether is prepared by reacting vinyl siloxane, pentaerythritol triallyl ether, allyl glycidyl ether and a catalyst. The OCA optical cement for the folding screen prepared by the invention is applied to the folding screen, and can keep relatively good elasticity, bending resistance and bonding strength in the long-term repeated folding use process, and wrinkles and bubbles are not easy to appear.

The invention relates to a polyurethane foam technology in the technical field of medical dressings, in particular to medical silver-containing porous polyurethane foam. The composite material comprises a foam matrix, the foam matrix adopts gradient layering design and comprises a matrix inner layer, a matrix middle layer and a matrix outer layer, the aperture of each layer is sequentially increased, the porosity is gradually increased layer by layer, the matrix inner layer is provided with randomly dispersed inner-layer hollow silver-loaded fibers capable of slowly releasing silver ions for bacteriostasis, the matrix middle layer is fixedly provided with pH response microcapsules, and the pH response microcapsules are fixed on the matrix outer layer. In an alkaline environment, antibacterial peptides are released for synergic antibiosis, and silver-loaded fibers in the outer layer of the matrix outer layer are arranged in the radial direction to form a flow guide channel and release silver ions. Through gradient layered design, different sterilization structures are added, the temperature-sensitive hydrogel layer covering the surface of the outer layer of the base body is matched, sterilization and seepage are managed through environmental changes, and the advantages of being excellent in antibacterial performance, high in seepage management capacity, intelligent in adjustment and the like are achieved.

The invention discloses a flexible circuit board made of weldable low-temperature silver paste and a preparation process of the flexible circuit board, and relates to the technical field of flexible electronic device manufacturing, and the flexible circuit board comprises a base material layer, a low-temperature weldable silver paste conductive layer and a protective layer. According to the invention, the collaborative design of the weldable low-temperature silver paste and the self-repairing protection layer is integrated, the efficient preparation of the flexible circuit board is realized through the printing technology, the weldable low-temperature silver paste breaks through the traditional high-temperature limitation, supports a wide range of substrates and can be directly welded without surface treatment, and in addition, the polyurethane protection layer containing the dynamic disulfide bond has a self-repairing function. Compared with a traditional FPC, only two core processes of printing and baking are needed, the process is greatly simplified, the equipment investment is reduced, and double reduction of the manufacturing cost and the material cost is achieved.

The invention relates to the technical field of data analysis, in particular to a dynamic mold pressure data analysis system for polyurethane pultrusion production, which comprises a mold pressure data capture module, a pressure gradient trend calculation module, a mold abnormal pressure identification module, a mold pressure adjustment data module and a multi-dimensional pressure state monitoring module. According to the invention, through data capture of the multi-node pressure sensor, high-precision real-time monitoring of internal pressure of the mold is realized, data integrity is enhanced, limitation of single data is avoided, pressure feature identification of different areas of the mold is realized, abnormality judgment accuracy is improved, normal fluctuation and abnormal accumulation are distinguished, and abnormal areas are accurately locked; temperature and ultrasonic signal analysis is introduced, curing abnormity and bubble aggregation are identified, the monitoring range is expanded, the data acquisition precision, the analysis depth and the regulation and control capability are improved, abnormity detection is more scientific, regulation and control are more intelligent, resin flowing is optimized, and the quality fluctuation risk is reduced.

The invention provides a treatment method of ammonia-nitrogen-containing wastewater, and belongs to the technical field of wastewater treatment. The preparation process comprises the following steps: preparing the wastewater treatment agent; preparing an immobilized microbial compound; and treating the ammonia-nitrogen-containing wastewater. According to the immobilized microbial carrier prepared by the invention, a stable dual-network structure and proper pore channels are formed through the synergistic effect of the polyvinyl alcohol, the carboxymethyl chitosan and the polyurethane; secondary cross-linking significantly enhances the stability of the carrier, optimizes internal pore channels, and is beneficial to attachment and proliferation of microorganisms; after the corn straw biochar is modified by Ca / Al, the specific surface area and functional groups are increased, and the physicochemical adsorption of ammonia nitrogen is enhanced. The three are combined, and ammonia nitrogen in wastewater is efficiently removed through synergism of carrier adsorption and microbial metabolism.

The invention discloses a preparation method and application of a pH-responsive controllable oil-water separation material, polyurethane sponge is used as a substrate, polypyrrole is attached to the sponge substrate through an in-situ polymerization method, a pH-responsive polymer is introduced into the sponge substrate through a soaking method, and finally the pH-responsive controllable oil-water separation material is obtained. The controllability of the material in the oil-water separation process is reflected as follows: due to the introduction of the pH responsive polymer, the surface of the material has pH responsiveness, the surface of the material has different wettability by adjusting the pH value, different types of oil-water mixtures can be controllably separated in a targeted manner, and the adsorption and desorption of oil products can be realized. Due to the introduction of polypyrrole, the material has good photo-thermal conversion capacity, the viscosity of crude oil can be effectively reduced, and the absorption rate of the crude oil can be improved. The material with pH responsiveness has wide application prospects in the fields of oil-water separation, oil product adsorption and desorption and crude oil absorption.

The invention discloses an anti-corrosion coating method for a steel structure, belongs to the technical field of metal anti-corrosion coating, and solves the problems of reduced anti-corrosion effect and short maintenance period caused by incomplete pretreatment, insufficient coating adhesive force and poor complex environment adaptability in the existing anti-corrosion coating process for the steel structure. According to the technical scheme, the method is characterized by comprising the steps that the surface of the steel structure is pretreated through chemical oil removal, sand blasting and acid pickling and phosphating; epoxy zinc-rich primer, epoxy micaceous iron oxide intermediate paint and polyurethane finish paint are sequentially sprayed, and plasma treatment is introduced in the coating of each layer so as to enhance the interface bonding force of the coating; the uniformity and the corrosion resistance of the coating are optimized by regulating and controlling spraying parameters, plasma processing power and a gas ratio; and finally, a gradient heating curing process is adopted, so that the compactness and durability of the coating are ensured. The method is mainly used for long-term anti-corrosion protection of steel structures such as bridges and buildings, and the anti-corrosion performance and the service life in a complex environment can be remarkably improved.

The invention discloses a porphyrin-based covalent organic framework nano material, a preparation method and application of the porphyrin-based covalent organic framework nano material in polyurethane, and belongs to the field of functional nano materials and antibacterial materials. The porphyrinyl covalent organic framework nano material is prepared from 5, 10, 15, 20-tetra (4-aminophenyl) porphyrin and bis-(5-formyl furfuryl) ether through a Schiff base reaction, and the structural formula of the porphyrinyl covalent organic framework nano material is # imgabs0. The porphyrinyl covalent organic framework nano material prepared by the invention has relatively high photothermal conversion efficiency when being used as a photothermal agent, and has a relatively good sterilization effect under the condition of relatively low concentration. Besides, based on the porphyrin-based covalent organic framework nano material, a WPUS / Por-COF composite film is prepared, the composite film has excellent mechanical properties and excellent photothermal conversion efficiency, and has a good sterilization effect under the condition of relatively low concentration, bacteria can be inactivated within a short time, and the sterilization rate can reach 99% or above.

The invention discloses a composite optical film with a polarization function, a preparation method and application thereof. The composite optical film comprises a transparent substrate layer, and a buffer layer, an oriented calcite crystal layer and an anti-reflection layer which are laminated on one side of the transparent substrate layer. Wherein the oriented calcite crystal layer is obtained by coating a superparamagnetic modified calcite crystal composite material suspension on the surface of the buffer layer, inducing optical axis oriented arrangement through a magnetic field and performing UV curing; the buffer layer is obtained by co-extruding a cycloolefin polymer and a polyurethane acrylate mixture, and a thermal expansion coefficient transition system is formed; the anti-reflection layer is composed of nano-porous titanium dioxide with the refractive index changing from 1.8 to 2.3 in a gradient mode, and a refractive index gradient structure is formed. According to the composite optical film, the polarization efficiency and the light transmittance of the composite optical film are improved and the industrial stability is improved through the design of the polarization functional layer in which the calcite nanocrystals are directionally arranged under the induction of a magnetic field and in combination with the gradient refractive index scattering layer.

The invention discloses low-migration UV ink-jet ink and a preparation method thereof, and belongs to the technical field of novel ink. Comprising the following components in parts by mass: 10-15 parts of a dynamic cross-linked polyurethane acrylate oligomer, 5-8 parts of an epoxy silicone resin oligomer, 2-3 parts of modified silicon dioxide, 4-5 parts of a photoinitiator, 15-20 parts of sorbic acid modified color paste, 1-2 parts of nano cerium oxide and 0.5-1 part of an antioxidant. The molecular chain of the dynamic cross-linked polyurethane acrylate oligomer prepared by the invention contains an active group capable of forming a cross-linked structure and a dynamic covalent bond. The groups and bonds promote molecular chain crosslinking when the ink is cured, a three-dimensional network is formed, and the molecular crosslinking density is improved. Through interaction of palmitic acid modified silicon dioxide and oligomer, the palmitic acid modified silicon dioxide is uniformly dispersed in a matrix and interferes molecular chain movement during curing, so that the crosslinking density is further improved, an ink film layer is more compact and firmer, the wear resistance and the scratch resistance are improved, and the tinting strength and the stability are indirectly enhanced.

The invention discloses a hydrogel wound dressing for promoting healing of infectious wounds. The hydrogel wound dressing is prepared from the following raw materials: oxidized methacrylic acid hyaluronic acid, waterborne polyurethane, polylysine, cannabidiol, neomycin sulfate and 2-roots alcohol. The invention also provides a preparation method of the hydrogel wound dressing and application of the hydrogel wound dressing in preparation of products for repairing infectious wounds. The wound dressing provided by the invention has a microporous structure, good biocompatibility and biodegradability, and can be used for stopping bleeding, reducing wound infection and promoting cell proliferation and wound healing.

The invention relates to the technical field of optical lens clamp spectacle frames, in particular to a three-jaw clamp spectacle frame capable of adjusting load of optical lenses. According to the technical scheme, the miniature three-jaw clamp comprises a miniature three-jaw clamp chuck, the miniature three-jaw clamp chuck comprises a chuck body with a round hole in the middle, three annular and uniform claws are slidably mounted on the end face of the chuck body, and polyurethane gaskets are mounted on the inner sides of the claws. A driving mechanism for driving the three claws to synchronously and radially move is arranged on the chuck body; the lens angle-adjustable lens bracket is used for mounting and supporting the micro three-jaw clamp chuck, the lens bracket comprises a three-jaw clamp fixing plate, and a chuck positioning groove and a chuck positioning hole communicated with the chuck positioning groove are formed in the three-jaw clamp fixing plate. According to the invention, through deep fusion of the self-centering symmetric clamping structure and optical adjustment requirements, a lens fixing solution which is more efficient, more reliable and higher in universality is provided for the field of precision optics.

The invention discloses a lithium ion battery composite diaphragm, a preparation method and a lithium ion battery, and relates to the technical field of lithium ion batteries. The lithium ion battery composite diaphragm comprises a base membrane and a functional coating arranged on the negative electrode side of the base membrane, the functional coating sequentially comprises an ion conducting layer, a thermal barrier layer and a self-repairing layer from the position close to the base film to the position far away from the base film; wherein the base membrane is a polyimide and aramid nanofiber blended electrostatic spinning membrane; the ion conducting layer comprises a compound of a modified fast ion conductor and polyvinylidene fluoride-hexafluoropropylene; the thermal barrier layer comprises a cross-linked network of boron nitride nanosheets and polybenzimidazole; the self-repairing layer comprises polyurethane microspheres loaded with dynamic disulfide bonds. The composite diaphragm provided by the invention can remarkably inhibit a purple area on the surface of a negative electrode, and enhance high-temperature self-protection and interface self-repairing of the lithium ion battery, so that the cycle and safety performance of the lithium ion battery are remarkably improved.

The invention discloses a preparation method of a salt-resistant polyurethane sponge evaporator for a photo-thermal interface, which comprises the following steps: taking polyurethane sponge as a support framework, taking polyvinyl alcohol as a precursor solution, adding carbon black and PEDOT: PSS (poly (3, 4-ethylenedioxythiophene): poly (styrenesulfonate)) into the precursor solution as photo-thermal materials, and synthesizing the salt-resistant polyurethane sponge evaporator by an extrusion thermal crosslinking freeze-drying method. According to the obtained evaporator, the excellent photothermal conversion performance of carbon black / PEDOT: PSS and a porous framework structure mainly comprising polyurethane / polyvinyl alcohol are fully utilized, the water absorption, the mechanical performance and the photothermal conversion efficiency of the evaporator are effectively improved, the heat conductivity is reduced, it is guaranteed that salt crystals do not appear inside and on the surface of the evaporator while efficient interface evaporation is achieved, and the service life of the evaporator is prolonged. The device can be widely applied to solar interface evaporation in saline water, actual seawater or high-salinity wastewater so as to obtain clean water resources.

The invention discloses a low-temperature-resistant, acid-resistant and alkali-resistant roof waterproof coating and a preparation method thereof. The coating is prepared from various raw materials such as acrylate-organosilicone copolymer emulsion and polyurethane modified acrylate resin, and a key raw material is prepared through free radical polymerization and addition polymerization reaction. The preparation method comprises the steps of pre-dispersion, auxiliary agent dispersion, pigment and filler dispersion, emulsion and functional auxiliary agent compounding, performance regulation and control and the like. The acrylate-organic silicon copolymer emulsion and the polyurethane modified acrylate resin form an interpenetrating network through physical blending and chemical crosslinking, and the low-temperature toughness of a flexible phase and the chemical resistance of a rigid phase are both achieved. In a low-temperature environment, the rigidity embrittlement of the polyurethane resin is counteracted by the flexibility of the organosilicone chain segment, so that the cracking of the coating is avoided; in an acid-base environment, a urethane bond of polyurethane and a silicon-oxygen bond of organic silicon cooperate to resist chemical erosion, molecular chain breakage is reduced, and the problem that an existing waterproof coating is insufficient in performance in the low-temperature and acid-base environment is effectively solved.

The invention discloses a preparation method of a cellulose acetate / thermoplastic polyurethane / polypyrrole composite conductive nanofiber aerogel composite pressure sensing material. The preparation method comprises the following steps: (1) preparing a cellulose acetate and thermoplastic polyurethane spinning solution; (2) preparing a cellulose acetate / thermoplastic polyurethane composite nanofiber membrane; (3) preparing cellulose acetate / thermoplastic polyurethane short nano dispersion liquid; (4) preparing a cellulose acetate / thermoplastic polyurethane / polypyrrole polymerization solution; and (5) preparing the cellulose acetate / thermoplastic polyurethane / polypyrrole composite conductive nanofiber aerogel. According to the preparation method, a high-temperature thermal annealing process is not needed, and the prepared nanofiber composite aerogel has high conductivity, ultralow volume density, high compression deformation performance and high pressure resistance sensing sensitivity.

The invention discloses water-based wear-resistant ink and a preparation method thereof, and belongs to the technical field of ink. The ink is prepared from the following components in parts by weight: 20 to 35 parts of waterborne polyurethane resin, 15 to 25 parts of waterborne acrylic resin with an acid value of 40 to 80 mg KOH / g, 5 to 15 parts of KH570 silane coupling agent modified nano aluminum oxide, 3 to 8 parts of polyethylene wax emulsion, 10 to 20 parts of pigment and auxiliaries. The preparation method comprises the following steps: firstly, carrying out surface modification on the nano aluminum oxide by using KH570, and then mixing, dispersing and grinding all the components. Through the synergistic effect of the acrylic resin with a specific acid value and the modified nano aluminum oxide, the problem that nano particles are easy to agglomerate in a system is solved, the nano particles can be stably dispersed, and the interface bonding with the resin is enhanced, so that the ink is endowed with excellent adhesive force, wear resistance and storage stability while the process is simplified and the cost is reduced; the BOPP film packaging material is especially suitable for BOPP film packaging materials.

The invention discloses a composite current collector, a preparation method thereof, an electrode plate containing the composite current collector, and a secondary battery. The composite current collector sequentially comprises a first conducting layer, a first bonding layer, an insulating layer, a second bonding layer and a second conducting layer, and the first conducting layer and the second conducting layer are both copper layers; binders of the first bonding layer and the second bonding layer are respectively and independently selected from any one of epoxy resin, polyolefin, polyester and polyurethane. The composite current collector prepared by the invention has good structural stability, has low requirements on an insulating layer, is high in safety when being applied to a battery, and is beneficial to improving the energy density of the battery.

The invention discloses a sunlight response high-strength self-repairing polyurethane material and a preparation method thereof, and belongs to the technical field of self-repairing materials, the sunlight response high-strength self-repairing polyurethane material is obtained by coordinating polyurethane containing an azothiazole structure and metal ions according to a certain proportion, the polyurethane containing the azothiazole structure is prepared by stirring diisocyanate, diol containing the azothiazole structure, long-chain diol and aminophenylboronic acid according to a certain proportion in N, N-dimethylformamide at room temperature to react for 5 hours. According to the invention, a photoactive azothiazole structure is introduced into polyurethane, and reversible metal coordination bonds are formed by the azothiazole structure and metal ions, so that rapid sunlight response self-repairing of the polyurethane material is realized. The self-repairing efficiency of the prepared photoresponse self-repairing polyurethane material is 95.1% after the photoresponse self-repairing polyurethane material is irradiated by sunlight for 2 h, and the photoresponse self-repairing polyurethane material has rapid photoresponse self-repairing performance and has wide application prospects in the fields of self-repairing coatings, intelligent coatings and anti-corrosion coatings.

The invention discloses a high-refractive-index nano-composite optical adhesive and a preparation method thereof, and belongs to the technical field of optical transparent adhesives. The optical adhesive is prepared by taking a polyurethane acrylate oligomer with a specific structure as matrix resin, introducing surface-modified barium titanate and zirconium oxide core-shell nanoparticles as a functional filler, and matching with an active diluent, a photoinitiator and a silane coupling agent in a specific proportion. Through the design of the core-shell structure, the core problems that the high-refractive-index nanoparticles are easy to agglomerate in an organic resin matrix, the dispersion stability is poor and the bonding force with a matrix interface is weak are effectively solved. The prepared optical adhesive has a refractive index of more than 1.65, a light transmittance of more than 99% and a haze of less than 0.3% after being cured, has excellent bonding strength, weather resistance and long-term use stability, and is especially suitable for precise lamination of high-end display devices (such as OLEDs (Organic Light Emitting Diodes) and micro-lens arrays).

The invention relates to a polyurethane carrier roller press-fitting device and a working method thereof.The polyurethane carrier roller press-fitting device comprises a base, a supporting mechanism and press-fitting mechanisms, the supporting mechanism is installed in the middle of the top side of the base, the press-fitting mechanisms are slidably installed at the two ends of the top side of the base, the supporting mechanism comprises a supporting frame, and two supporting roller seats are slidably installed on the top side of the supporting frame; first pneumatic cylinders are installed at the two ends of the supporting frame, and supporting shaft seats provided with V-shaped grooves are installed at the telescopic ends of the first pneumatic cylinders. Through three core technologies of modular adjustment, automatic press fitting and dynamic lubrication cleaning, the problems of low efficiency, poor precision, uneven lubrication and the like in traditional carrier roller assembly are solved, the device is particularly suitable for production scenes of high-precision and large-batch polyurethane carrier rollers, and the comprehensive performance reaches the industry leading level.

The invention belongs to the technical field of sole materials, and particularly discloses an anti-skid sole material and a preparation method thereof. The anti-skid sole material comprises a sole body, the sole body comprises an anti-skid layer and a rubber layer, and the anti-skid layer comprises the following raw material components in parts by weight; comprising 50-55 parts of polyurethane, 16-20 parts of a silicon carbide composite material, 10-14 parts of polyethylene composite fibers, 4-8 parts of a maleic anhydride grafted polyethylene octylene co-elastomer, 3-5 parts of a silane coupling agent, 1-2 parts of an antioxidant and 0.5-0.8 part of a lubricant. The anti-skid sole material prepared in the invention has excellent mechanical strength, skid resistance and wear resistance, and can provide protection for feet and prolong the service life of soles.

The invention belongs to the technical field of personal protection equipment, and particularly relates to a lightweight cut-resistant four-dimensional structure fabric based on high-performance composite fibers and a preparation method of the lightweight cut-resistant four-dimensional structure fabric. The structure is based on a high-performance composite fiber material and a nano silicon carbide embedding technology of high-performance polyethylene fibers, the hardness bottleneck of a single material is broken through, and multi-fiber compatibility is improved through cooperation of polyurethane fiber surface activation and polyurethane fiber anti-melting modification. The gradient twist core sheath yarn is a high-performance composite yarn, and the strength and the flexibility are balanced. In the aspect of the oversleeve fabric structure, a three-dimensional protection system comprising a honeycomb structure, a silica gel liner and a skin-friendly inner layer is adopted, so that the integration of multiple functions of hydrophobicity, fusion resistance and buffering of a light-weight cut-resistant material is realized. Under the EN 388 standard, 5-level cutting prevention can be achieved, a single high-performance polyethylene fiber cutting prevention oversleeve can only reach 3-4 levels, the weight of the composite fiber material is reduced by 40% compared with that of a full aramid fiber oversleeve, the thickness is reduced by 25%, and the composite fiber material can be suitable for complex scenes such as petroleum and electric power.