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9255 results about "Polyurethane" patented technology

Polyurethane (PUR and PU) is a polymer composed of organic units joined by carbamate (urethane) links. While most polyurethanes are thermosetting polymers that do not melt when heated, thermoplastic polyurethanes are also available.

Curved polyaniline modified 3D printing polyurethane material and application thereof

The invention belongs to the technical field of polymer preparation, and particularly relates to a curved-surface polyaniline modified 3D printing polyurethane material and application thereof. According to the preparation method, an ice crystal hard template method and a polyether glycol soft template method are combined, so that the microstructure of polyaniline is adjusted, and the curved polyaniline with regular morphology is prepared. The curved-surface arc-shaped structure has a large specific surface area, can form more contact sites with resin when being directly melt-blended with the resin, is beneficial to construction of a conductive path, and is not easy to agglomerate due to the curved-surface structure. The polyaniline with the arc-shaped structure is of a three-dimensional space structure and is directly blended with the resin to form a randomly arranged conductive network structure, so that the composite material is not easy to break when being impacted, and can be better embedded between the resin to form a stress transfer channel, and a complex three-dimensional network structure is constructed; the mechanical property and the antistatic capability of the product are improved.
Owner:SUZHOU GANGRUITONG NANO MATERIALS TECH CO LTD

Lithium ion battery composite diaphragm, preparation method and lithium ion battery

The invention discloses a lithium ion battery composite diaphragm, a preparation method and a lithium ion battery, and relates to the technical field of lithium ion batteries. The lithium ion battery composite diaphragm comprises a base membrane and a functional coating arranged on the negative electrode side of the base membrane, the functional coating sequentially comprises an ion conducting layer, a thermal barrier layer and a self-repairing layer from the position close to the base film to the position far away from the base film; wherein the base membrane is a polyimide and aramid nanofiber blended electrostatic spinning membrane; the ion conducting layer comprises a compound of a modified fast ion conductor and polyvinylidene fluoride-hexafluoropropylene; the thermal barrier layer comprises a cross-linked network of boron nitride nanosheets and polybenzimidazole; the self-repairing layer comprises polyurethane microspheres loaded with dynamic disulfide bonds. The composite diaphragm provided by the invention can remarkably inhibit a purple area on the surface of a negative electrode, and enhance high-temperature self-protection and interface self-repairing of the lithium ion battery, so that the cycle and safety performance of the lithium ion battery are remarkably improved.
Owner:HUANENG CLEAN ENERGY RES INST

Preparation method of cellulose acetate / thermoplastic polyurethane / polypyrrole conductive nanofiber aerogel composite pressure sensing material

The invention discloses a preparation method of a cellulose acetate / thermoplastic polyurethane / polypyrrole composite conductive nanofiber aerogel composite pressure sensing material. The preparation method comprises the following steps: (1) preparing a cellulose acetate and thermoplastic polyurethane spinning solution; (2) preparing a cellulose acetate / thermoplastic polyurethane composite nanofiber membrane; (3) preparing cellulose acetate / thermoplastic polyurethane short nano dispersion liquid; (4) preparing a cellulose acetate / thermoplastic polyurethane / polypyrrole polymerization solution; and (5) preparing the cellulose acetate / thermoplastic polyurethane / polypyrrole composite conductive nanofiber aerogel. According to the preparation method, a high-temperature thermal annealing process is not needed, and the prepared nanofiber composite aerogel has high conductivity, ultralow volume density, high compression deformation performance and high pressure resistance sensing sensitivity.
Owner:NANJING FORESTRY UNIV

Water-based wear-resistant ink and preparation method thereof

The invention discloses water-based wear-resistant ink and a preparation method thereof, and belongs to the technical field of ink. The ink is prepared from the following components in parts by weight: 20 to 35 parts of waterborne polyurethane resin, 15 to 25 parts of waterborne acrylic resin with an acid value of 40 to 80 mg KOH / g, 5 to 15 parts of KH570 silane coupling agent modified nano aluminum oxide, 3 to 8 parts of polyethylene wax emulsion, 10 to 20 parts of pigment and auxiliaries. The preparation method comprises the following steps: firstly, carrying out surface modification on the nano aluminum oxide by using KH570, and then mixing, dispersing and grinding all the components. Through the synergistic effect of the acrylic resin with a specific acid value and the modified nano aluminum oxide, the problem that nano particles are easy to agglomerate in a system is solved, the nano particles can be stably dispersed, and the interface bonding with the resin is enhanced, so that the ink is endowed with excellent adhesive force, wear resistance and storage stability while the process is simplified and the cost is reduced; the BOPP film packaging material is especially suitable for BOPP film packaging materials.
Owner:ANQING YITU INK TECHNOLOGY CO LTD

Nano-composite optical cement with high refractive index and preparation method of nano-composite optical cement

The invention discloses a high-refractive-index nano-composite optical adhesive and a preparation method thereof, and belongs to the technical field of optical transparent adhesives. The optical adhesive is prepared by taking a polyurethane acrylate oligomer with a specific structure as matrix resin, introducing surface-modified barium titanate and zirconium oxide core-shell nanoparticles as a functional filler, and matching with an active diluent, a photoinitiator and a silane coupling agent in a specific proportion. Through the design of the core-shell structure, the core problems that the high-refractive-index nanoparticles are easy to agglomerate in an organic resin matrix, the dispersion stability is poor and the bonding force with a matrix interface is weak are effectively solved. The prepared optical adhesive has a refractive index of more than 1.65, a light transmittance of more than 99% and a haze of less than 0.3% after being cured, has excellent bonding strength, weather resistance and long-term use stability, and is especially suitable for precise lamination of high-end display devices (such as OLEDs (Organic Light Emitting Diodes) and micro-lens arrays).
Owner:ZHENJIANG RISP NEW MATERIAL TECHNOLOGY CO LTD

Anti-corrosion coating containing lanthanum cerium oxide and preparation method of anti-corrosion coating

The invention relates to the field of anticorrosive paint, in particular to anticorrosive paint containing lanthanum cerium oxide and a preparation method of the anticorrosive paint. The invention relates to an anticorrosive coating containing lanthanum cerium oxide. The anticorrosive coating is prepared from the following raw materials: 28 to 45 parts of ultraviolet stable composite film forming matter, 5 to 10 parts of composite rare earth filler, 6 to 12 parts of supported synergistic antirust agent, 18 to 30 parts of mixed solvent, 0.8 to 2.5 parts of dispersing agent, 2.7 to 5.3 parts of functional additive and 0.5 to 1.2 parts of nano montmorillonite, the composite rare earth filler is lanthanum cerium oxide-hydroxyapatite composite powder with a core-shell structure, wherein lanthanum cerium oxide is used as a core, hydroxyapatite is used as a shell, and the thickness of the shell layer is 10-20 nm; the ultraviolet stable composite film forming substance comprises epoxy resin and ultraviolet grafting modified polyurethane in a weight ratio of 1: (0.6-2.2); the supported synergistic antirust agent is a mixture of mesoporous silica supported benzotriazole and zinc molybdate. And the obtained coating is high in adhesive force and long in service life.
Owner:TIANJIN RONGRUI TECHNOLOGY DEVELOPMENT CO LTD

Preheating control method and system for polyurethane raw material

The invention relates to the technical field of industrial production control, in particular to a polyurethane raw material preheating control method and system. The method comprises the following steps: acquiring tank body temperature, environment temperature, batch temperature rise, tank body structure and raw material liquid data, constructing a thermal resistance-thermal capacitance series-parallel model to represent system thermal inertia characteristics, then identifying an initial value drift resistance section, a main temperature rise section and a disturbance absorption section in a segmented manner, and implementing power back-stepping based on segmented data, so as to obtain the thermal inertia characteristic of the system. Dynamically generating a heating power track; and a heating track is replanned in combination with real-time change data, so that precise modeling and self-adaptive control of a temperature rise process are realized, and the temperature control precision and energy efficiency response capability of the preheating system under different raw material batches and different working conditions are effectively improved.
Owner:QINGDAO RENCHENG SPONGE PROD CO LTD

Compressed air energy storage power station underground chamber structure, construction method and parameter optimization design method

The invention discloses an underground chamber structure of a compressed air energy storage power station, a construction method and a parameter optimization design method, and belongs to the field of compressed air energy storage and underground space engineering. A hard rock stratum building chamber is determined through systematic site selection investigation, a high-performance concrete lining (containing fiber reinforcement) and a polyurethane buffer layer are adopted to synergistically improve the stability, and a vinyl ester resin-based glass fiber reinforced plastic three-layer composite structure serves as a sealing layer (including a bonding layer, a reinforcement layer and an impermeable layer); the processes of sand blasting pretreatment, stepped joint and the like are combined to guarantee the sealing performance; meanwhile, on the basis of a finite element model, structural parameters are optimized by taking the lowest whole life cycle cost as a target and taking strength, deformation, leakage rate and the like as constraints, and a recommended parameter combination of each structural layer is obtained in combination with an orthogonal experimental design and an improved genetic algorithm. The method is suitable for various geological conditions, the safety, economical efficiency and adaptability of the compressed air energy storage power station are effectively improved, and the method is suitable for large-scale application and popularization.
Owner:GUOHUA ZHUCHENG WIND POWER GENERATION CO LTD

Flexible fireproof cable and preparation method thereof

The invention discloses a flexible fireproof cable and a preparation method thereof, and belongs to the technical field of cables. The cable comprises a conductor, a mica insulation layer, a copper protection layer, a buffer layer and a cable sheath layer. The buffer layer is made of a polyurethane foaming material; the cable sheath layer is prepared from the following components in parts by weight: 80 to 100 parts of methyl vinyl silicone rubber, 18 to 20 parts of modified carbon black, 5 to 8 parts of titanium dioxide, 1 to 2 parts of platinum catalyst, 3 to 6 parts of hydroxyl silicone oil, 0.5 to 1 part of zinc stearate and 0.8 to 1 part of dicumyl peroxide. The modified carbon black is added into the raw materials of the sheath layer, so that the compatibility, the interface bonding force and the flame retardant property of the carbon black and a silicone rubber matrix are effectively improved, and the mechanical property, the wear resistance and the fireproof property of the cable sheath layer are remarkably enhanced.
Owner:SICHUAN XINRONG ELECTRIC CABLE CO LTD

Bionic Al / SiC composite material with three-dimensional network multilevel structure and preparation method of bionic Al / SiC composite material

PendingCN121248321ACeramicwareFreeze-dryingFreeze-casting
The invention relates to a bionic Al / SiC composite material with a three-dimensional network multilevel structure and a preparation method of the bionic Al / SiC composite material, and belongs to the technical field of new material preparation. According to the method, through the collaborative process of freeze casting and organic foam impregnation, the problem that in the prior art, the multilevel aperture and the complex network structure are difficult to cooperatively regulate and control is solved. The preparation method comprises the following specific steps: preparing tert-butyl alcohol-based ceramic slurry, impregnating the slurry with polyurethane foam, performing freeze casting molding, removing a solvent through freeze drying, performing high-temperature sintering to form SiC ceramic with a three-dimensional reticular hierarchical pore structure, and finally preparing the Al / SiC composite material through a vacuum pressure infiltration process. Wherein a sintering aid is added into the slurry, so that the sintering temperature is obviously reduced; the specification (40-60 ppi) of polyurethane foam, the solid phase content (20-30 vol.%) of slurry, the freezing speed (0-90 DEG C) and the content (5-20 wt.%) of a sintering aid are regulated and controlled. And the cross-scale collaborative design of micron-scale directional holes and millimeter-scale mesh holes is realized. The Al / SiC composite material prepared by the invention has the advantages that the compressive strength, fracture toughness and other properties are obviously higher than those of the traditional single-aperture porous ceramic, and the Al / SiC composite material is suitable for the fields of manufacturing and energy absorption of precise instruments, electronic packaging and optical devices.
Owner:JILIN JIANZHU UNIVERSITY

Polyurethane modified silicone rubber, sprayable conductive glue and preparation method and application thereof

The invention relates to the technical field of conductive glue, in particular to polyurethane modified silicone rubber, sprayable conductive glue and a preparation method thereof. The polyurethane modified silicone rubber is prepared from the following components in parts by weight: 50 to 150 parts of vinyl silicone oil, 20 to 50 parts of polyurethane powder and 5 to 15 parts of compatilizer, the sprayable conductive glue comprises the following components in parts by weight: 20-40 parts of conductive particles, 5-15 parts of hydrogen-containing silicone oil, 50-150 parts of polyurethane modified silicone rubber, 1-10 parts of a coupling agent, 1-5 parts of a catalyst, 1-2 parts of an inhibitor, 40-90 parts of a diluent and 1-2 parts of a defoaming agent, compared with traditional silicone rubber, the polyurethane modified silicone rubber provided by the invention is high in mechanical strength and not easy to tear, when the polyurethane modified silicone rubber provided by the invention is used for preparing sprayable conductive glue, a conductive layer formed by the conductive glue is excellent in conductivity, and meanwhile, the mechanical property is also remarkably improved.
Owner:陕西华秦科技实业股份有限公司

Liquid metal enhanced triboelectric material with bionic surface and preparation method of liquid metal enhanced triboelectric material

The invention discloses a liquid metal enhanced triboelectric material with a bionic surface and a preparation method of the liquid metal enhanced triboelectric material, and belongs to the technical field of triboelectric materials. The preparation method comprises the following steps: mixing an interface stabilizer TEMPO oxidized nanocellulose with a liquid metal gallium-indium alloy to obtain TOCNF (at) LM liquid metal-based micro-nano liquid drops; and doping the obtained TOCNF-coated LM liquid metal-based micro-nano liquid drops into a base material waterborne polyurethane, and constructing a bionic rose petal micro-mastoid process structure by adopting a template method, so as to obtain the liquid metal enhanced triboelectric material with a bionic surface. The composite material with the rose petal micro-nano structure is prepared through bionic design, the micro-mastoid structure of rose petals is successfully re-carved, and the triboelectric property of the waterborne polyurethane is remarkably improved by utilizing TOCNF at LM liquid metal-based micro-nano liquid drops, so that the open-circuit voltage of the prepared composite material reaches 250V, the short-circuit current reaches 8.19 mu A, and the triboelectric property of the waterborne polyurethane is remarkably improved. The short-circuit transfer charge quantity reaches 95nC, and theoretical and practical guidance is provided for the design of a high-performance triboelectric material.
Owner:GUANGXI UNIV

Silicon negative electrode binder as well as preparation method and application thereof

The invention discloses a silicon negative electrode binder as well as a preparation method and application thereof. The silicon negative electrode binder is a graft copolymer with a comb-shaped structure; the grafted copolymer comprises a polyurethane chain segment forming a main chain of the comb-shaped structure, a polyacrylic acid chain segment serving as a branch chain and connected to the main chain through a covalent bond, and a fluorine-containing chain segment. According to the preparation method, a graft copolymerization method is adopted, the preparation method is carried out in a water-based system, the silicon negative electrode binder with hardness and softness is obtained, and the silicon negative electrode binder is applied to a lithium battery through the synergistic effect of mechanical property, interface stability and electrochemical performance. And a solution of a key material is provided for a high-capacity and long-cycle lithium battery which takes an active material with high silicon content as a negative electrode.
Owner:GUANGDONG HAISIDA NEW ENERGY TECHNOLOGY CO LTD

High-toughness conductive and thermal-conductive epoxy glue, preparation method thereof and conductive film

The invention discloses a high-toughness conductive and thermal-conductive epoxy adhesive, a preparation method thereof and a conductive film, and belongs to the technical field of conductive materials. Comprising the following raw material components in parts by weight: 100 parts of epoxy resin, 4-25 parts of a latent curing agent, 0.5-5 parts of an accelerant, 200-600 parts of conductive filler, 5-15 parts of an epoxy-terminated polyurethane flexibilizer, 5-20 parts of a core-shell flexibilizer, 5-10 parts of a nitrile rubber flexibilizer, 2-10 parts of a reactive diluent, 0.5-2 parts of a coupling agent and 20-50 parts of a solvent. Through compounding of the over-end epoxy type polyurethane flexibilizer, the core-shell flexibilizer and the nitrile rubber flexibilizer, the prepared conductive adhesive has excellent toughness and bonding characteristics, and meanwhile, the shrinkage stress and thermal stress in the curing process can be reduced.
Owner:CHINA BLUESTAR CHENGRAND CO LTD +1

Degradable pha / PU composite water-based barrier coating and coated paper product

The application discloses degradable PHA / PU composite water-based barrier coating and coated paper products, and belongs to the field of biodegradable polymer coating. The coating composition contains a high proportion of polyhydroxyalkanoate as a barrier phase and a bio-based polyurethane as a toughening and heat-sealing phase. The key innovation is that by precisely controlling the ratio of the two phases and using bio-based cross-linking, the synergy of rigid barrier and flexible function is achieved, and the problem that the barrier property, heat-sealing property and flexibility of traditional single material are difficult to balance is solved at low coating amount. The application provides a full life cycle green packaging solution, which aims to replace polyethylene shower film and fluorine-containing coating, and has significant application value in the field of food packaging.
Owner:DU BAI CHENG NEW MATERIAL TECH (SHANGHAI) CO LTD +2

Polyurethane foaming material with gradient-density skin-core structure and preparation method of polyurethane foaming material

The invention discloses a polyurethane foaming material with a gradient density skin-core structure and a preparation method thereof, and the preparation method comprises the following steps: step 1, injecting a mixed polyurethane foaming raw material into a preheated foaming mold, and closing the mold; step 2, synchronously starting a mold rapid cooling system and an air pressure balance system for foaming and curing when the reaction raw materials are injected; and step 3, taking out the product after curing, standing at room temperature, and curing to obtain the polyurethane foam material. The surface temperature of the mold is suddenly reduced through quenching temperature control so as to form a compact skin layer, and an in-mold pressure curve is controlled by using an air pressure balance program so as to accurately regulate and control foaming of a core layer. The prepared material has a continuous gradient density structure, the skin layer density is high, the core layer density is low, a transition interface with strong binding force is arranged between the skin layer and the core layer, and the extreme performance combination of'hard outside and soft inside 'is successfully realized.
Owner:NINGBO INST OF MATERIALS TECH & ENG CHINESE ACAD OF SCI

Photo-thermal evaporation material based on black titanium dioxide as well as preparation method and application of photo-thermal evaporation material

The invention provides a photo-thermal evaporation material based on black titanium dioxide as well as a preparation method and application of the photo-thermal evaporation material. The preparation method comprises the following steps: mixing urea, absolute ethyl alcohol and tetrabutyl titanate into a solution A, mixing absolute ethyl alcohol, ultrapure water and hydrochloric acid into a solution B, dropwise adding the solution B into the solution A, mixing to form a white colloid, heating in a water bath, drying, and calcining in a nitrogen atmosphere to obtain black titanium dioxide powder; the preparation method comprises the following steps: fully mixing a certain amount of black titanium dioxide, sodium alginate and ultrapure water to form a uniform dispersion liquid, dipping the pretreated polyurethane sponge in the dispersion liquid, and crosslinking with a calcium chloride solution to prepare the photo-thermal evaporation material of the black titanium dioxide-calcium alginate composite hydrogel. The photo-thermal evaporation material breaks through the photo-thermal application bottleneck of traditional titanium dioxide, has excellent evaporation rate and seawater desalination performance, and can effectively remove various printing and dyeing wastewater to obtain clean water.
Owner:HUAQIAO UNIVERSITY +1

Preparation method of repairable polyurethane damping material based on multiple non-covalent bond action

The invention relates to the field of preparation of polyurethane damping materials, in particular to a preparation method of a repairable polyurethane damping material based on multiple hydrogen bonds and metal coordination. Compared with a traditional damping material, the damping material has a higher damping temperature range and has a good damping effect at the temperature of-20 DEG C to 60 DEG C. Multiple reversible hydrogen bonds are introduced through diamine containing amido bonds, the material is endowed with self-repairing and high mechanical strength, and damping and self-repairing performance is further enhanced through pyridine nitrogen atom metal coordination. Starting from molecular structure design, multiple hydrogen bonds and metal-ligand coordination bonds constructed on a polyurethane molecular main chain play a role in synergistic enhancement, energy can be effectively dissipated through dissociation and recombination of the multiple hydrogen bonds and fracture and association of the metal coordination bonds, and the energy consumption is reduced. The polyurethane material is endowed with excellent damping performance and self-healing capability by the dual dynamic action.
Owner:SHANDONG AOZO NEW MATERIALS CO LTD

A visible light-responsive dynamically covalently crosslinked self-healing polyurethane and its preparation method

This invention discloses a visible-light-responsive dynamically covalently cross-linked self-healing polyurethane and its preparation method, belonging to the field of self-healing materials technology. The material is prepared by reacting diisocyanate, long-chain diol, butanediol, trimethylolpropane, and a monool containing an azophenylboronic acid structure in a certain proportion at 60°C. This invention achieves visible-light-responsive self-healing of the polyurethane material by introducing a visible-light-responsive azophenylboronic acid structure into the polyurethane and utilizing the photoresponsive cis-trans isomerization of the azo structure to regulate the reversible breakage and recombination of the boron-oxygen hexacyclic ring. The visible-light-responsive dynamically covalently cross-linked self-healing polyurethane material prepared by this invention maintains high mechanical strength (16.47 MPa) while exhibiting a strength self-healing efficiency of 95.8% after 8 hours of visible light irradiation, showing broad application prospects in smart materials, anti-corrosion coatings, and other fields.
Owner:SOUTHWEST PETROLEUM UNIV

Polyurethane composite material, preparation method thereof and cable containing polyurethane composite material

The invention belongs to the field of polyurethane materials, and particularly discloses a polyurethane composite material, a preparation method thereof and a cable containing the polyurethane composite material. The titanium dioxide modified by aminated four-arm polyethylene glycol is used as an anti-aging component, the polyurethane matrix is subjected to fluorinated molecular structure modification, and the titanium dioxide and the polyurethane matrix are matched with each other, so that the damp-heat aging resistance and the mechanical property of the polyurethane composite material are improved, and the service life of the polyurethane composite material is prolonged. And the technical problem that the heat conduction, flame retardance and mechanical properties of the polyurethane composite material are reduced in a severe environment is also solved, so that the heat conduction, flame retardance and mechanical properties are kept stable for a long time.
Owner:GUANGZHOU POWER SUPPLY BUREAU GUANGDONG POWER GRID CO LTD

A fast-curing acrylic adhesive and applications thereof

The application provides a kind of fast curing acrylic glue and application, the fast curing acrylic glue is prepared from the following components according to weight parts: butyl nitrile rubber of terminal methacrylate is 13-17 parts;Polyurethane acrylate is 5-8 parts;Monofunctional acrylate monomer is 14-20 parts;Two functionality acrylate monomer is 7-13 parts;Three functionality acrylate monomer is 1-3 parts;Peroxide is 0.5-1.5 parts;Polymerization inhibitor is 0.01-0.04 parts;Coupling agent is 0.5-0.7 parts.The acrylic glue provided by the application has the advantages of fast curing, low volume resistivity after adding silver powder curing, good bonding strength, moderate elastic modulus, and can be used for photovoltaic tile conductive silver glue.
Owner:HANGZHOU ZHIJIANG SILICONE CHEM +1

Aromatic polyurethane composition, preparation method and aromatic thin-layer fabric

The invention relates to the technical field of high polymer materials, and discloses an aromatic polyurethane composition, a preparation method and an aromatic thin-layer fabric. Eugenol is used as a functional chain extender to be introduced into a polyurethane molecular chain, aromatic microcapsules are compounded to prepare the aromatic polyurethane composition, the aromatic polyurethane composition is applied to fabric finishing, and the antibacterial property, the aroma, the wrinkle resistance and the washing fastness of the fabric are synergistically improved.
Owner:JIAXING HAOYI TEXTILE CO LTD

Anti-burst electroplating primer and preparation method thereof

The invention relates to the technical field of electroplating primers, and particularly discloses an anti-burst electroplating primer and a preparation method thereof. The invention relates to an anti-burst electroplating primer which comprises the following components in parts by weight: 8-12 parts of bifunctional polyurethane acrylate; 20 to 25 parts of trifunctional polyester acrylate; 10 to 15 parts of modified epoxy acrylic resin; 13 to 20 parts of a UV monomer; 4-6 parts of a photoinitiator; 0.1 to 0.2 part of a leveling agent; and 33-45 parts of a solvent. The anti-burst electroplating primer disclosed by the invention can be used for the surface of a plastic base material such as a PET material, has the advantages of no burst in a free falling body with the height of 80cm and adhesive force of more than level 1, endows a subsequent electroplated layer with good adhesive force and reduces the burst problem of a product under pressure.
Owner:SHANGHAI LANBAO PAINT CO LTD

Surgical membrane and preparation process

The invention relates to the technical field of preparation of medical supplies, in particular to a surgical membrane and a preparation process. During specific use, firstly, a polyurethane base membrane is selected and subjected to plasma treatment; spraying a nano SiO2 dispersion liquid containing a photoinitiator on the surface of the treated polyurethane base film, and then performing ultraviolet patterning irradiation to form a micro-bulge structure to obtain a base material layer; projecting the colloidal fluid to a temperature gradient mask through a digital micromirror device, so that the colloidal fluid is subjected to regional thermal polymerization on the substrate layer to form an intelligent adhesive layer with viscosity gradient; by adopting an aerosol jet printing technology, super absorbent fibers and polyvinyl alcohol-borax dynamic crosslinking hydrogel are co-deposited to form a drainage layer, so that the technical problems that a surgical membrane prepared by a surgical membrane preparation mode in the prior art is inflexible in adhesion and poor in surface structure performance, and a preparation process is difficult to accurately control are solved.
Owner:MAIDIKANG MEDICAL ARTICLES JIANGSU

Large-current-carrying-capacity flexible power cable

The invention discloses a large-current-carrying-capacity flexible power cable, which belongs to the technical field of cable preparation, is used for solving the technical problem that the flame retardant property and the mechanical property of the power cable need to be further improved in the prior art, and specifically comprises a cable core, a wrapping layer, an insulating layer and a sheath layer which are sequentially arranged from inside to outside. The preparation method comprises the following steps: preparing alkoxy silane containing a benzocyclobutene group, preparing flame-retardant particles by using a sol-gel method, preparing modified polyurethane by using modified polysiloxane and 2, 5-furandimethanol as soft segments, naphthalene diisocyanate as a hard segment and trimethylolpropane as a chain extender, and preparing the flame-retardant flame-retardant polyurethane. The linear low-density polyethylene, the MAH-g-PE, the modified polyurethane, the flame-retardant particles and the auxiliary additive are melted and extruded outside the wire core to form the insulating layer, so that the power cable is obtained, the flame-retardant property of the power cable is effectively improved, and the mechanical property and the current-carrying stability of the power cable are also improved.
Owner:华远高科电缆有限公司

Hydrogel-based water-energy-resource co-production solar evaporator and application thereof

The invention discloses a hydrogel-based water-energy-resource co-production solar evaporator and application thereof, and belongs to the technical field of chemistry and environment, the hydrogel-based water-energy-resource co-production solar evaporator is prepared by taking sodium alginate hydrogel as a matrix, adding carbon nanotubes and a titanium-based lithium ion sieve or a metal-doped titanium-based lithium ion sieve into a solution of the sodium alginate hydrogel, taking polyurethane sponge as a carrier frame, and preparing the hydrogel-based water-energy-resource co-production solar evaporator. Ca2 + is adopted as a cross-linking agent to construct a solar evaporator with a flexible size (centimeter-level to meter-level components can be prepared according to application scenes), the solar evaporator is used for the solar driven evaporation process of lithium-containing water resources such as salt lake seawater, and Li + selective enrichment, fresh water collection and waste heat power generation are synchronously achieved. Moreover, the evaporator has the characteristics of simple preparation process, low cost and excellent environmental compatibility, also has a good removal effect on salt ions, and keeps stable fresh water collection performance in a long-time operation process.
Owner:SHANDONG UNIV

Preparation method of flexible electromagnetic shielding type force sensor based on coaxial structure

The invention discloses a preparation method of a flexible electromagnetic shielding type force sensor based on a coaxial structure, and belongs to the field of flexible electronics and intelligent sensors. According to the method, a coaxial wet spinning process is adopted, a core-sheath structure conductive fiber is constructed, a core layer is made of a multi-walled carbon nanotube (CNT) and thermoplastic polyurethane (TPU) composite material, and a sheath layer is made of a nickel-coated carbon nanotube (Ni-CNT) and TPU composite material. By regulating and controlling the proportion of the core sheath, the construction of the gradient conductive network is realized, and the sensing sensitivity, the electromagnetic shielding performance and the mechanical flexibility are improved. The obtained Ni-CNT-coated CNT fiber is made into fabric and integrated in a sensing glove, and multi-finger bending detection and wireless man-machine interaction control are achieved. The sensor has the advantages of high sensitivity, wide strain detection range and excellent electromagnetic shielding effectiveness, is suitable for the fields of intelligent wearing, anti-interference man-machine interface and fire-fighting equipment, and can also be expanded to complex application scenes such as aerospace teleoperation.
Owner:邵一前

Graphene-containing far-infrared warm-keeping polyurethane transfer film and preparation method thereof

The invention relates to the technical field of transfer films, in particular to a graphene-containing far-infrared warm-keeping polyurethane transfer film and a preparation method thereof. The far-infrared warm-keeping polyurethane transfer film containing graphene comprises a three-layer structure including a supporting layer, a polyurethane transfer layer and a bonding layer, the polyurethane transfer layer is located on one side of the supporting layer, and the bonding layer is located on the other side of the polyurethane transfer layer; the polyurethane transfer layer is prepared from polyurethane resin, an organic solvent, an organic pigment and a composite modifier, the composite modifier is prepared from alkenyl modified graphene oxide, chloropropenyl modified hindered phenol and 4-allyloxy-2-hydroxybenzophenone, and the composite modifier is added, so that the polyurethane transfer layer is formed. The polyurethane transfer film has far infrared thermal insulation performance and good oxidation resistance and hydrolysis resistance.
Owner:SUZHOU WONDERFUL NEW MATERIAL CO LTD

Polyurethane structural adhesive dispergator as well as preparation method and application thereof

The invention discloses a dispergator of a polyurethane structural adhesive as well as a preparation method and application of the dispergator. The dispergator comprises a polar organic solvent, an alcohol additive, a basic catalyst, an ionic liquid and a surfactant. The dispergator is suitable for removing a bonding interface of a thermosetting polyurethane structural adhesive in a power battery module, the dispergation process is mild and safe, and swelling, fracture and interface release of the structural adhesive can be realized in a range from normal temperature to 55 DEG C. Compared with a traditional high-corrosion and high-energy-consumption dispergation means, the dispergation agent has the advantages of being high in degumming efficiency, little in residual gum, free of base material corrosion and the like, is suitable for the environment-friendly recycling and reusing scene of the retired lithium battery, and has good engineering practicability and popularization value.
Owner:SOUTH CHINA UNIV OF TECH