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10087 results about "Polyurethane" patented technology

Polyurethane (PUR and PU) is a polymer composed of organic units joined by carbamate (urethane) links. While most polyurethanes are thermosetting polymers that do not melt when heated, thermoplastic polyurethanes are also available.

Antistatic aerogel for 3D printing and preparation method and application thereof

The invention belongs to the technical field of aerogel materials, and particularly relates to antistatic aerogel for 3D printing as well as a preparation method and application of the antistatic aerogel. The preparation method comprises the following steps: (1) dispersing inorganic nanoparticles modified by a silane coupling agent containing epoxy groups and an aniline monomer in an acidic solvent to obtain a monomer mixed solution; (2) stirring and dissolving polyamide in the monomer mixed solution; (3) initiating a reaction to obtain a polyaniline modified polyamide solution; and (4) freeze-drying to obtain the antistatic aerogel for 3D printing. By controlling synthesis conditions, a core-shell structure of acid-doped polyaniline coated inorganic nanoparticles is formed, and a good conductive path is formed in polyamide with a small addition amount of polyaniline. The antistatic aerogel for 3D printing can be applied to technologies such as photocuring molding and fused deposition of polyurethane resin in a 3D printing technology, and the antistatic property and the mechanical property of a 3D printed product are improved.
Owner:SUZHOU GANGRUITONG NANO MATERIALS TECH CO LTD

Curved polyaniline modified 3D printing polyurethane material and application thereof

The invention belongs to the technical field of polymer preparation, and particularly relates to a curved-surface polyaniline modified 3D printing polyurethane material and application thereof. According to the preparation method, an ice crystal hard template method and a polyether glycol soft template method are combined, so that the microstructure of polyaniline is adjusted, and the curved polyaniline with regular morphology is prepared. The curved-surface arc-shaped structure has a large specific surface area, can form more contact sites with resin when being directly melt-blended with the resin, is beneficial to construction of a conductive path, and is not easy to agglomerate due to the curved-surface structure. The polyaniline with the arc-shaped structure is of a three-dimensional space structure and is directly blended with the resin to form a randomly arranged conductive network structure, so that the composite material is not easy to break when being impacted, and can be better embedded between the resin to form a stress transfer channel, and a complex three-dimensional network structure is constructed; the mechanical property and the antistatic capability of the product are improved.
Owner:SUZHOU GANGRUITONG NANO MATERIALS TECH CO LTD

Lithium ion battery composite diaphragm, preparation method and lithium ion battery

The invention discloses a lithium ion battery composite diaphragm, a preparation method and a lithium ion battery, and relates to the technical field of lithium ion batteries. The lithium ion battery composite diaphragm comprises a base membrane and a functional coating arranged on the negative electrode side of the base membrane, the functional coating sequentially comprises an ion conducting layer, a thermal barrier layer and a self-repairing layer from the position close to the base film to the position far away from the base film; wherein the base membrane is a polyimide and aramid nanofiber blended electrostatic spinning membrane; the ion conducting layer comprises a compound of a modified fast ion conductor and polyvinylidene fluoride-hexafluoropropylene; the thermal barrier layer comprises a cross-linked network of boron nitride nanosheets and polybenzimidazole; the self-repairing layer comprises polyurethane microspheres loaded with dynamic disulfide bonds. The composite diaphragm provided by the invention can remarkably inhibit a purple area on the surface of a negative electrode, and enhance high-temperature self-protection and interface self-repairing of the lithium ion battery, so that the cycle and safety performance of the lithium ion battery are remarkably improved.
Owner:HUANENG CLEAN ENERGY RES INST

Preparation method of cellulose acetate / thermoplastic polyurethane / polypyrrole conductive nanofiber aerogel composite pressure sensing material

The invention discloses a preparation method of a cellulose acetate / thermoplastic polyurethane / polypyrrole composite conductive nanofiber aerogel composite pressure sensing material. The preparation method comprises the following steps: (1) preparing a cellulose acetate and thermoplastic polyurethane spinning solution; (2) preparing a cellulose acetate / thermoplastic polyurethane composite nanofiber membrane; (3) preparing cellulose acetate / thermoplastic polyurethane short nano dispersion liquid; (4) preparing a cellulose acetate / thermoplastic polyurethane / polypyrrole polymerization solution; and (5) preparing the cellulose acetate / thermoplastic polyurethane / polypyrrole composite conductive nanofiber aerogel. According to the preparation method, a high-temperature thermal annealing process is not needed, and the prepared nanofiber composite aerogel has high conductivity, ultralow volume density, high compression deformation performance and high pressure resistance sensing sensitivity.
Owner:NANJING FORESTRY UNIV

Water-based wear-resistant ink and preparation method thereof

The invention discloses water-based wear-resistant ink and a preparation method thereof, and belongs to the technical field of ink. The ink is prepared from the following components in parts by weight: 20 to 35 parts of waterborne polyurethane resin, 15 to 25 parts of waterborne acrylic resin with an acid value of 40 to 80 mg KOH / g, 5 to 15 parts of KH570 silane coupling agent modified nano aluminum oxide, 3 to 8 parts of polyethylene wax emulsion, 10 to 20 parts of pigment and auxiliaries. The preparation method comprises the following steps: firstly, carrying out surface modification on the nano aluminum oxide by using KH570, and then mixing, dispersing and grinding all the components. Through the synergistic effect of the acrylic resin with a specific acid value and the modified nano aluminum oxide, the problem that nano particles are easy to agglomerate in a system is solved, the nano particles can be stably dispersed, and the interface bonding with the resin is enhanced, so that the ink is endowed with excellent adhesive force, wear resistance and storage stability while the process is simplified and the cost is reduced; the BOPP film packaging material is especially suitable for BOPP film packaging materials.
Owner:ANQING YITU INK TECHNOLOGY CO LTD

Nano-composite optical cement with high refractive index and preparation method of nano-composite optical cement

The invention discloses a high-refractive-index nano-composite optical adhesive and a preparation method thereof, and belongs to the technical field of optical transparent adhesives. The optical adhesive is prepared by taking a polyurethane acrylate oligomer with a specific structure as matrix resin, introducing surface-modified barium titanate and zirconium oxide core-shell nanoparticles as a functional filler, and matching with an active diluent, a photoinitiator and a silane coupling agent in a specific proportion. Through the design of the core-shell structure, the core problems that the high-refractive-index nanoparticles are easy to agglomerate in an organic resin matrix, the dispersion stability is poor and the bonding force with a matrix interface is weak are effectively solved. The prepared optical adhesive has a refractive index of more than 1.65, a light transmittance of more than 99% and a haze of less than 0.3% after being cured, has excellent bonding strength, weather resistance and long-term use stability, and is especially suitable for precise lamination of high-end display devices (such as OLEDs (Organic Light Emitting Diodes) and micro-lens arrays).
Owner:ZHENJIANG RISP NEW MATERIAL TECHNOLOGY CO LTD

Anti-corrosion coating containing lanthanum cerium oxide and preparation method of anti-corrosion coating

The invention relates to the field of anticorrosive paint, in particular to anticorrosive paint containing lanthanum cerium oxide and a preparation method of the anticorrosive paint. The invention relates to an anticorrosive coating containing lanthanum cerium oxide. The anticorrosive coating is prepared from the following raw materials: 28 to 45 parts of ultraviolet stable composite film forming matter, 5 to 10 parts of composite rare earth filler, 6 to 12 parts of supported synergistic antirust agent, 18 to 30 parts of mixed solvent, 0.8 to 2.5 parts of dispersing agent, 2.7 to 5.3 parts of functional additive and 0.5 to 1.2 parts of nano montmorillonite, the composite rare earth filler is lanthanum cerium oxide-hydroxyapatite composite powder with a core-shell structure, wherein lanthanum cerium oxide is used as a core, hydroxyapatite is used as a shell, and the thickness of the shell layer is 10-20 nm; the ultraviolet stable composite film forming substance comprises epoxy resin and ultraviolet grafting modified polyurethane in a weight ratio of 1: (0.6-2.2); the supported synergistic antirust agent is a mixture of mesoporous silica supported benzotriazole and zinc molybdate. And the obtained coating is high in adhesive force and long in service life.
Owner:TIANJIN RONGRUI TECHNOLOGY DEVELOPMENT CO LTD

Preheating control method and system for polyurethane raw material

The invention relates to the technical field of industrial production control, in particular to a polyurethane raw material preheating control method and system. The method comprises the following steps: acquiring tank body temperature, environment temperature, batch temperature rise, tank body structure and raw material liquid data, constructing a thermal resistance-thermal capacitance series-parallel model to represent system thermal inertia characteristics, then identifying an initial value drift resistance section, a main temperature rise section and a disturbance absorption section in a segmented manner, and implementing power back-stepping based on segmented data, so as to obtain the thermal inertia characteristic of the system. Dynamically generating a heating power track; and a heating track is replanned in combination with real-time change data, so that precise modeling and self-adaptive control of a temperature rise process are realized, and the temperature control precision and energy efficiency response capability of the preheating system under different raw material batches and different working conditions are effectively improved.
Owner:QINGDAO RENCHENG SPONGE PROD CO LTD

High-temperature-resistant and aging-resistant polyurethane material and preparation method therefor

A high-temperature-resistant and aging-resistant polyurethane material and a preparation method therefor. The polyurethane material comprises the following components in parts by mass: 21-27 parts of a modified polyurethane resin, 10-15 parts of a phenolic resin, 10-15 parts of an epoxy resin, 16-20 parts of a modified solid filler, 7-13 parts of a curing agent, 1-2 parts of a defoaming agent, 1-3 parts of a wetting agent, 0.7-1 part of a leveling agent, and 5-10 parts of water. The high-temperature-resistant and aging-resistant polyurethane material has excellent temperature resistance and moisture resistance, high aging resistance, and strong adhesion to a glass surface and can be used as a coating with which a glass surface is coated.
Owner:SHANGHAI JIELI NEW MATERIALS TECHNOLOGY CO LTD

Compressed air energy storage power station underground chamber structure, construction method and parameter optimization design method

The invention discloses an underground chamber structure of a compressed air energy storage power station, a construction method and a parameter optimization design method, and belongs to the field of compressed air energy storage and underground space engineering. A hard rock stratum building chamber is determined through systematic site selection investigation, a high-performance concrete lining (containing fiber reinforcement) and a polyurethane buffer layer are adopted to synergistically improve the stability, and a vinyl ester resin-based glass fiber reinforced plastic three-layer composite structure serves as a sealing layer (including a bonding layer, a reinforcement layer and an impermeable layer); the processes of sand blasting pretreatment, stepped joint and the like are combined to guarantee the sealing performance; meanwhile, on the basis of a finite element model, structural parameters are optimized by taking the lowest whole life cycle cost as a target and taking strength, deformation, leakage rate and the like as constraints, and a recommended parameter combination of each structural layer is obtained in combination with an orthogonal experimental design and an improved genetic algorithm. The method is suitable for various geological conditions, the safety, economical efficiency and adaptability of the compressed air energy storage power station are effectively improved, and the method is suitable for large-scale application and popularization.
Owner:GUOHUA ZHUCHENG WIND POWER GENERATION CO LTD

Flexible fireproof cable and preparation method thereof

The invention discloses a flexible fireproof cable and a preparation method thereof, and belongs to the technical field of cables. The cable comprises a conductor, a mica insulation layer, a copper protection layer, a buffer layer and a cable sheath layer. The buffer layer is made of a polyurethane foaming material; the cable sheath layer is prepared from the following components in parts by weight: 80 to 100 parts of methyl vinyl silicone rubber, 18 to 20 parts of modified carbon black, 5 to 8 parts of titanium dioxide, 1 to 2 parts of platinum catalyst, 3 to 6 parts of hydroxyl silicone oil, 0.5 to 1 part of zinc stearate and 0.8 to 1 part of dicumyl peroxide. The modified carbon black is added into the raw materials of the sheath layer, so that the compatibility, the interface bonding force and the flame retardant property of the carbon black and a silicone rubber matrix are effectively improved, and the mechanical property, the wear resistance and the fireproof property of the cable sheath layer are remarkably enhanced.
Owner:SICHUAN XINRONG ELECTRIC CABLE CO LTD

Inorganic modified super-long salt-spray-resistant water-based paint and preparation method thereof

The invention discloses an inorganic modified super-long salt-spray-resistant water-based paint and a preparation method thereof, and relates to the technical field of water-based industrial paints. The inorganic modified super-long salt-spray-resistant water-based paint at least comprises the following raw materials in parts by mass: 60-70 parts of water-based acrylic resin, 0.1-0.5 part of a bactericide, 0.2-0.4 part of a wetting agent, 0.5-1 part of a dispersing agent, 0.1-0.3 part of a defoaming agent, 0.5-1 part of a pH regulator, 8-12 parts of nano silicon dioxide coated polymerized calcium phosphate, 0.5-2 parts of modified zinc phosphate, 8-10 parts of silk mica powder, 2-4 parts of a coalescing agent and 10-20 parts of water. And 0.5 to 1 part of a polyurethane thickening agent. The inorganic modified super-long salt-fog-resistant water-based paint prepared by the invention has super-long salt fog resistance, high base material adhesion and low ion dissolution amount, and the hardness and water resistance of a coating are also improved.
Owner:JUNXIU NEW MATERIAL TECH (SUZHOU) CO LTD

Degradable PHA / PU composite water-based barrier coating and coated paper product

The invention discloses a degradable PHA / PU composite water-based barrier coating and a coated paper product, and belongs to the field of biodegradable polymer coatings. The coating composition comprises a high proportion of polyhydroxyalkanoates as a barrier phase and a bio-based polyurethane as a toughening and heat sealing phase. The key innovation lies in that the cooperation of rigid barrier and flexible functions is realized by accurately regulating and controlling the ratio of two phases and adopting bio-based crosslinking, and the problem that the barrier property, the heat sealability and the flexibility of a traditional single material are difficult to consider at the same time is solved under the condition of low coating amount. The invention provides a full-life-cycle green packaging solution, aims to replace a polyethylene spraying film and a fluorine-containing coating, and has a remarkable application value in the field of food packaging.
Owner:DU BAI CHENG NEW MATERIAL TECH (SHANGHAI) CO LTD +2

Lower supporting film for flexible folding display screen and preparation method of lower supporting film

The invention belongs to the technical field of film materials, and particularly relates to a lower supporting film for a flexible folding display screen and a preparation method of the lower supporting film. The supporting film sequentially comprises a protective film layer, a stainless steel base material layer, an adhesive layer and a release film layer from top to bottom; wherein the adhesive layer is prepared by coating a release film with modified organic silica gel liquid, drying and curing. The ultra-thin stainless steel is used as the base material layer, can resist external force impact and scraping, is low and stable in thermal expansion coefficient, can reduce the influence of environment temperature and humidity on the size of the supporting film, and guarantees the structural consistency of the screen module in long-term use; and through multi-component composite modification of polyurethane-thiazole-organic silicon, the peeling strength of the adhesive layer and stainless steel and the bending frequency of the supporting film are improved, and the service life of the supporting film is prolonged.
Owner:TAICANG ZHANXIN ADHESIVE MATERIAL

Bionic Al / SiC composite material with three-dimensional network multilevel structure and preparation method of bionic Al / SiC composite material

PendingCN121248321ACeramicwareFreeze-dryingFreeze-casting
The invention relates to a bionic Al / SiC composite material with a three-dimensional network multilevel structure and a preparation method of the bionic Al / SiC composite material, and belongs to the technical field of new material preparation. According to the method, through the collaborative process of freeze casting and organic foam impregnation, the problem that in the prior art, the multilevel aperture and the complex network structure are difficult to cooperatively regulate and control is solved. The preparation method comprises the following specific steps: preparing tert-butyl alcohol-based ceramic slurry, impregnating the slurry with polyurethane foam, performing freeze casting molding, removing a solvent through freeze drying, performing high-temperature sintering to form SiC ceramic with a three-dimensional reticular hierarchical pore structure, and finally preparing the Al / SiC composite material through a vacuum pressure infiltration process. Wherein a sintering aid is added into the slurry, so that the sintering temperature is obviously reduced; the specification (40-60 ppi) of polyurethane foam, the solid phase content (20-30 vol.%) of slurry, the freezing speed (0-90 DEG C) and the content (5-20 wt.%) of a sintering aid are regulated and controlled. And the cross-scale collaborative design of micron-scale directional holes and millimeter-scale mesh holes is realized. The Al / SiC composite material prepared by the invention has the advantages that the compressive strength, fracture toughness and other properties are obviously higher than those of the traditional single-aperture porous ceramic, and the Al / SiC composite material is suitable for the fields of manufacturing and energy absorption of precise instruments, electronic packaging and optical devices.
Owner:JILIN JIANZHU UNIVERSITY

Polyurethane modified silicone rubber, sprayable conductive glue and preparation method and application thereof

The invention relates to the technical field of conductive glue, in particular to polyurethane modified silicone rubber, sprayable conductive glue and a preparation method thereof. The polyurethane modified silicone rubber is prepared from the following components in parts by weight: 50 to 150 parts of vinyl silicone oil, 20 to 50 parts of polyurethane powder and 5 to 15 parts of compatilizer, the sprayable conductive glue comprises the following components in parts by weight: 20-40 parts of conductive particles, 5-15 parts of hydrogen-containing silicone oil, 50-150 parts of polyurethane modified silicone rubber, 1-10 parts of a coupling agent, 1-5 parts of a catalyst, 1-2 parts of an inhibitor, 40-90 parts of a diluent and 1-2 parts of a defoaming agent, compared with traditional silicone rubber, the polyurethane modified silicone rubber provided by the invention is high in mechanical strength and not easy to tear, when the polyurethane modified silicone rubber provided by the invention is used for preparing sprayable conductive glue, a conductive layer formed by the conductive glue is excellent in conductivity, and meanwhile, the mechanical property is also remarkably improved.
Owner:陕西华秦科技实业股份有限公司

Directional moisture-conducting, dry, comfortable, breathable and quick-drying fabric and preparation method thereof

The invention belongs to the field of functional textile materials, and provides a directional moisture-conducting, dry, comfortable, breathable and quick-dry fabric and a preparation method thereof. A three-layer composite structure design is adopted, the outer layer is a gradient wetting structure formed by attaching a thermoplastic polyurethane film subjected to single-face thermal orientation treatment and knitted fabric, the middle layer is a hydrophilic non-woven fabric, the inner layer is a knitted fabric subjected to hydrophilic finishing, and the two layers are compounded through a hot melt adhesive dot-shaped net. Hydrophilic blocks of the thermoplastic polyurethane film are directionally enriched through single-face contact heating, gradient distribution with one hydrophilic side and one hydrophobic side is formed, and the hydrophobic surface is coated with a low-surface-energy coating. The fabric has excellent one-way moisture conduction performance, moisture can be rapidly transmitted from the inner layer to the outer layer and rapidly volatilized, dryness and comfort of the close-fitting fabric are kept, meanwhile, the fabric has good air permeability and quick-drying performance, the moisture conduction rate is increased by 30% or above compared with that of traditional fabric, and the fabric is suitable for being popularized and applied. The fabric has wide application value in the fields of sportswear, outdoor equipment, leakage-proof underpants and the like.
Owner:SHANTOU SUPREME TECH CO LTD

Liquid metal enhanced triboelectric material with bionic surface and preparation method of liquid metal enhanced triboelectric material

The invention discloses a liquid metal enhanced triboelectric material with a bionic surface and a preparation method of the liquid metal enhanced triboelectric material, and belongs to the technical field of triboelectric materials. The preparation method comprises the following steps: mixing an interface stabilizer TEMPO oxidized nanocellulose with a liquid metal gallium-indium alloy to obtain TOCNF (at) LM liquid metal-based micro-nano liquid drops; and doping the obtained TOCNF-coated LM liquid metal-based micro-nano liquid drops into a base material waterborne polyurethane, and constructing a bionic rose petal micro-mastoid process structure by adopting a template method, so as to obtain the liquid metal enhanced triboelectric material with a bionic surface. The composite material with the rose petal micro-nano structure is prepared through bionic design, the micro-mastoid structure of rose petals is successfully re-carved, and the triboelectric property of the waterborne polyurethane is remarkably improved by utilizing TOCNF at LM liquid metal-based micro-nano liquid drops, so that the open-circuit voltage of the prepared composite material reaches 250V, the short-circuit current reaches 8.19 mu A, and the triboelectric property of the waterborne polyurethane is remarkably improved. The short-circuit transfer charge quantity reaches 95nC, and theoretical and practical guidance is provided for the design of a high-performance triboelectric material.
Owner:GUANGXI UNIV

Thermal insulation material with enhanced thermal insulation performance and processing method

The invention discloses a thermal insulation material with enhanced thermal insulation performance and a processing method, and relates to the technical field of thermal insulation material processing. Comprising the following components in parts by weight: 100 to 200 parts of a nanopore matrix material, 20 to 120 parts of expanded perlite, 10 to 350 parts of polystyrene, 30 to 300 parts of polyurethane, 100 to 500 parts of nano titanium dioxide, 10 to 60 parts of graphene, 10 to 40 parts of silica sol and 1 to 55 parts of ferric oxide. A multi-stage pore structure is constructed through a nanopore matrix and expanded perlite, closed-cell foam of polystyrene and polyurethane is combined, and nano titanium dioxide and graphene functional filler are matched, so that the heat conductivity coefficient is reduced to 0.018 W / (mK) or below, the heat insulation efficiency is remarkably improved, nanoscale homogenization is ensured through high-shear dispersion in the process, the porosity is reserved through freeze drying, and the heat insulation performance is greatly improved. The microcapsule self-repairing layer can repair more than 85% of cracks, the service life is greatly prolonged, and in the aspect of function integration, the material has A-level fireproof, waterproof and weather-proof characteristics and heat preservation and heat insulation performance.
Owner:GUANGZHOU QI HI-TECH MATERIALS TECHNOLOGY CO LTD

Silicon negative electrode binder as well as preparation method and application thereof

The invention discloses a silicon negative electrode binder as well as a preparation method and application thereof. The silicon negative electrode binder is a graft copolymer with a comb-shaped structure; the grafted copolymer comprises a polyurethane chain segment forming a main chain of the comb-shaped structure, a polyacrylic acid chain segment serving as a branch chain and connected to the main chain through a covalent bond, and a fluorine-containing chain segment. According to the preparation method, a graft copolymerization method is adopted, the preparation method is carried out in a water-based system, the silicon negative electrode binder with hardness and softness is obtained, and the silicon negative electrode binder is applied to a lithium battery through the synergistic effect of mechanical property, interface stability and electrochemical performance. And a solution of a key material is provided for a high-capacity and long-cycle lithium battery which takes an active material with high silicon content as a negative electrode.
Owner:GUANGDONG HAISIDA NEW ENERGY TECHNOLOGY CO LTD

High-toughness conductive and thermal-conductive epoxy glue, preparation method thereof and conductive film

The invention discloses a high-toughness conductive and thermal-conductive epoxy adhesive, a preparation method thereof and a conductive film, and belongs to the technical field of conductive materials. Comprising the following raw material components in parts by weight: 100 parts of epoxy resin, 4-25 parts of a latent curing agent, 0.5-5 parts of an accelerant, 200-600 parts of conductive filler, 5-15 parts of an epoxy-terminated polyurethane flexibilizer, 5-20 parts of a core-shell flexibilizer, 5-10 parts of a nitrile rubber flexibilizer, 2-10 parts of a reactive diluent, 0.5-2 parts of a coupling agent and 20-50 parts of a solvent. Through compounding of the over-end epoxy type polyurethane flexibilizer, the core-shell flexibilizer and the nitrile rubber flexibilizer, the prepared conductive adhesive has excellent toughness and bonding characteristics, and meanwhile, the shrinkage stress and thermal stress in the curing process can be reduced.
Owner:CHINA BLUESTAR CHENGRAND CO LTD +1

Degradable pha / PU composite water-based barrier coating and coated paper product

The application discloses degradable PHA / PU composite water-based barrier coating and coated paper products, and belongs to the field of biodegradable polymer coating. The coating composition contains a high proportion of polyhydroxyalkanoate as a barrier phase and a bio-based polyurethane as a toughening and heat-sealing phase. The key innovation is that by precisely controlling the ratio of the two phases and using bio-based cross-linking, the synergy of rigid barrier and flexible function is achieved, and the problem that the barrier property, heat-sealing property and flexibility of traditional single material are difficult to balance is solved at low coating amount. The application provides a full life cycle green packaging solution, which aims to replace polyethylene shower film and fluorine-containing coating, and has significant application value in the field of food packaging.
Owner:DU BAI CHENG NEW MATERIAL TECH (SHANGHAI) CO LTD +2

Polyurethane foaming material with gradient-density skin-core structure and preparation method of polyurethane foaming material

The invention discloses a polyurethane foaming material with a gradient density skin-core structure and a preparation method thereof, and the preparation method comprises the following steps: step 1, injecting a mixed polyurethane foaming raw material into a preheated foaming mold, and closing the mold; step 2, synchronously starting a mold rapid cooling system and an air pressure balance system for foaming and curing when the reaction raw materials are injected; and step 3, taking out the product after curing, standing at room temperature, and curing to obtain the polyurethane foam material. The surface temperature of the mold is suddenly reduced through quenching temperature control so as to form a compact skin layer, and an in-mold pressure curve is controlled by using an air pressure balance program so as to accurately regulate and control foaming of a core layer. The prepared material has a continuous gradient density structure, the skin layer density is high, the core layer density is low, a transition interface with strong binding force is arranged between the skin layer and the core layer, and the extreme performance combination of'hard outside and soft inside 'is successfully realized.
Owner:NINGBO INST OF MATERIALS TECH & ENG CHINESE ACAD OF SCI

Photo-thermal evaporation material based on black titanium dioxide as well as preparation method and application of photo-thermal evaporation material

The invention provides a photo-thermal evaporation material based on black titanium dioxide as well as a preparation method and application of the photo-thermal evaporation material. The preparation method comprises the following steps: mixing urea, absolute ethyl alcohol and tetrabutyl titanate into a solution A, mixing absolute ethyl alcohol, ultrapure water and hydrochloric acid into a solution B, dropwise adding the solution B into the solution A, mixing to form a white colloid, heating in a water bath, drying, and calcining in a nitrogen atmosphere to obtain black titanium dioxide powder; the preparation method comprises the following steps: fully mixing a certain amount of black titanium dioxide, sodium alginate and ultrapure water to form a uniform dispersion liquid, dipping the pretreated polyurethane sponge in the dispersion liquid, and crosslinking with a calcium chloride solution to prepare the photo-thermal evaporation material of the black titanium dioxide-calcium alginate composite hydrogel. The photo-thermal evaporation material breaks through the photo-thermal application bottleneck of traditional titanium dioxide, has excellent evaporation rate and seawater desalination performance, and can effectively remove various printing and dyeing wastewater to obtain clean water.
Owner:HUAQIAO UNIVERSITY +1

Preparation method of repairable polyurethane damping material based on multiple non-covalent bond action

The invention relates to the field of preparation of polyurethane damping materials, in particular to a preparation method of a repairable polyurethane damping material based on multiple hydrogen bonds and metal coordination. Compared with a traditional damping material, the damping material has a higher damping temperature range and has a good damping effect at the temperature of-20 DEG C to 60 DEG C. Multiple reversible hydrogen bonds are introduced through diamine containing amido bonds, the material is endowed with self-repairing and high mechanical strength, and damping and self-repairing performance is further enhanced through pyridine nitrogen atom metal coordination. Starting from molecular structure design, multiple hydrogen bonds and metal-ligand coordination bonds constructed on a polyurethane molecular main chain play a role in synergistic enhancement, energy can be effectively dissipated through dissociation and recombination of the multiple hydrogen bonds and fracture and association of the metal coordination bonds, and the energy consumption is reduced. The polyurethane material is endowed with excellent damping performance and self-healing capability by the dual dynamic action.
Owner:SHANDONG AOZO NEW MATERIALS CO LTD

A visible light-responsive dynamically covalently crosslinked self-healing polyurethane and its preparation method

This invention discloses a visible-light-responsive dynamically covalently cross-linked self-healing polyurethane and its preparation method, belonging to the field of self-healing materials technology. The material is prepared by reacting diisocyanate, long-chain diol, butanediol, trimethylolpropane, and a monool containing an azophenylboronic acid structure in a certain proportion at 60°C. This invention achieves visible-light-responsive self-healing of the polyurethane material by introducing a visible-light-responsive azophenylboronic acid structure into the polyurethane and utilizing the photoresponsive cis-trans isomerization of the azo structure to regulate the reversible breakage and recombination of the boron-oxygen hexacyclic ring. The visible-light-responsive dynamically covalently cross-linked self-healing polyurethane material prepared by this invention maintains high mechanical strength (16.47 MPa) while exhibiting a strength self-healing efficiency of 95.8% after 8 hours of visible light irradiation, showing broad application prospects in smart materials, anti-corrosion coatings, and other fields.
Owner:SOUTHWEST PETROLEUM UNIV

Polyurethane composite material, preparation method thereof and cable containing polyurethane composite material

The invention belongs to the field of polyurethane materials, and particularly discloses a polyurethane composite material, a preparation method thereof and a cable containing the polyurethane composite material. The titanium dioxide modified by aminated four-arm polyethylene glycol is used as an anti-aging component, the polyurethane matrix is subjected to fluorinated molecular structure modification, and the titanium dioxide and the polyurethane matrix are matched with each other, so that the damp-heat aging resistance and the mechanical property of the polyurethane composite material are improved, and the service life of the polyurethane composite material is prolonged. And the technical problem that the heat conduction, flame retardance and mechanical properties of the polyurethane composite material are reduced in a severe environment is also solved, so that the heat conduction, flame retardance and mechanical properties are kept stable for a long time.
Owner:GUANGZHOU POWER SUPPLY BUREAU GUANGDONG POWER GRID CO LTD

A fast-curing acrylic adhesive and applications thereof

The application provides a kind of fast curing acrylic glue and application, the fast curing acrylic glue is prepared from the following components according to weight parts: butyl nitrile rubber of terminal methacrylate is 13-17 parts;Polyurethane acrylate is 5-8 parts;Monofunctional acrylate monomer is 14-20 parts;Two functionality acrylate monomer is 7-13 parts;Three functionality acrylate monomer is 1-3 parts;Peroxide is 0.5-1.5 parts;Polymerization inhibitor is 0.01-0.04 parts;Coupling agent is 0.5-0.7 parts.The acrylic glue provided by the application has the advantages of fast curing, low volume resistivity after adding silver powder curing, good bonding strength, moderate elastic modulus, and can be used for photovoltaic tile conductive silver glue.
Owner:HANGZHOU ZHIJIANG SILICONE CHEM +1

Multi-stage flow guide double-sided anisotropic sanitary surface layer spunlace material and preparation method thereof

The invention discloses a multi-stage flow guide double-sided anisotropic sanitary surface layer spunlace material and a preparation method thereof, and relates to the technical field of textile manufacturing. The preparation method of the sanitary surface layer spunlace material comprises the following steps: opening, carding and cross lapping a fiber raw material to obtain a front surface fiber web and a back surface fiber web, overlapping the front surface fiber web and the back surface fiber web in a manner that the front surface is on the upper side and the back surface is on the lower side, performing spunlace reinforcement, finishing after reinforcement, and finally drying and winding to obtain the sanitary surface layer spunlace material. Wherein the front fiber net is made of all-cotton fibers, and the gram weight is 30-50 g / m < 2 >; the reverse side fiber net is made of mixed fibers, and the gram weight is 40-60 g / m < 2 >; the reverse fiber net is obtained by mixing modified regenerated cellulose fibers, polyurethane fibers and bamboo pulp fibers according to the mass ratio of (10-30): (5-10): 100.
Owner:NANTONG TONGZHOU JIANGHUA TEXTILE CO LTD