697 results about "Diene" patented technology

The present invention relates to an elastomeric laminate comprising at least two adjacent layers, wherein: the rubber composition constituting the first layer is based on 20 phr to 100 phr of at least one copolymer comprising ethylene units and 1,3-diene units of formula CH2=CR-CH=CH2, the ethylene units in the copolymer representing more than 50 mol% of the copolymer monomer units, and the symbol R represents a hydrocarbon chain having 3 to 20 carbon atoms, 0 phr to 80 phr of at least one diene elastomer having a diene unit weight concentration greater than 50%, 10 phr to 100 phr of a plasticizing system comprising at least one plasticizing resin having a glass transition temperature higher than 20°C and / or at least one plasticizer which is liquid at 23°C, and a reinforcing filler, and a crosslinking system; the rubber composition constituting the second layer is based on a diene elastomer having a diene unit weight concentration greater than 50% and a crosslinking system. The present invention also relates to a rubber article, in particular a pneumatic or non-pneumatic tire, comprising such a laminate.

The invention provides a compression-molded light transparent high-heat wear-resistant rubber and plastic outsole and a preparation method thereof, and the compression-molded light transparent high-heat wear-resistant rubber and plastic outsole is prepared from the following materials in parts by mass: 50-60 parts of high-hardness thermoplastic resin; 10 to 20 parts of polydiene rubber; 20 to 30 parts of mixed polyurethane; 3-5 parts of a heat conduction auxiliary agent; 0.5-1 part of an anti-aging agent; 0.1 to 0.3 part of an ultraviolet absorbent; 0.1 to 0.3 part of a lubricant; and 0.3 to 0.5 part of a cross-linking agent. The limited components are internally mixed by an internal mixer and then are subjected to flat-plate mould pressing vulcanization to obtain the light transparent high-heat wear-resistant rubber and plastic outsole which is formed by mould pressing. According to the light transparent high-heat wear-resistant rubber and plastic outsole, nano spherical aluminum oxide is added as a heat-conducting additive, so that light scattering caused by refractive index difference between filler and a matrix and particle aggregation is effectively reduced, and the original transparent texture of the material is maintained to the greatest extent while the material is endowed with a heat-conducting function; the sole is especially suitable for high-strength sports shoes such as basketballs, racing running shoes and the like which have harsh requirements on sole performance.

The invention relates to a transmission belt (10) comprising a body provided with at least one elastomer-based tooth (B), said at least one tooth comprising: - an ethylene-propylene-diene monomer in a proportion of between 85 and 100 parts, per 100 parts of elastomer; - natural rubber in a proportion at most equal to 15 parts; - and regenerated carbon black in a proportion of between 20 and 70 parts.

The invention discloses low-odor thermoplastic vulcanized rubber for an automobile skin as well as a preparation method and application of the low-odor thermoplastic vulcanized rubber. The raw materials comprise 50 to 80 parts of ethylene-propylene-diene copolymer rubber, 20 to 50 parts of polypropylene, 5 to 15 parts of a compatilizer, 0.5 to 2.5 parts of a compound cross-linking agent, 0.5 to 2.0 parts of an odor adsorbent and 0.5 to 1.0 part of an antioxidant. The preparation method comprises the following steps: banburying and blending, dynamically vulcanizing by using a first double-screw extruder, adsorbing and deeply devolatilizing by using a second double-screw extruder, and carrying out vacuum baking at 100 DEG C. By utilizing the synergistic effect of the cross-linking agent and the assistant cross-linking agent, the degradation of polypropylene is inhibited while the cross-linking efficiency is ensured, and a low-boiling-point reaction by-product (tert-butyl alcohol) is thoroughly removed through a multi-stage devolatilization process, so that the problems that the traditional TPV material is strong in odor and easy to atomize are solved. The smell grade of the obtained material is less than or equal to 3.0 grade, and the atomization value is lt; and the coating is suitable for high-end automotive trim skins.

The invention relates to the technical field of lithium ion battery assistants, in particular to an anode slurry dispersing, compacting and anti-cracking assistant for a lithium battery and a preparation method of the anode slurry dispersing, compacting and anti-cracking assistant. The anti-cracking aid is prepared from the following raw materials in parts by mass: 20-80 parts of a special polymer, 10-30 parts of a wetting agent, 10-30 parts of a plasticizer and 10-100 parts of a solvent, wherein the preparation raw materials of the special polymer comprise a vinyl monomer, an acrylic monomer, a diene monomer and an initiator; the wetting agent comprises the following raw materials: an amine compound and a hydrazine compound; and the plasticizer is polyether phosphate. When the additive is used for preparing the lithium battery positive electrode slurry, the slurry is uniformly dispersed and low in viscosity, the use of solvents can be reduced, the production process is shortened, and the actual use effect is excellent.

The invention relates to the technical field of cables, and provides a corrosion-resistant control cable and a preparation method thereof. The corrosion-resistant control cable sequentially comprises a conductor, an insulating layer, a shielding layer and a sheath layer from inside to outside, wherein the sheath layer comprises the following components in parts by weight: 50-70 parts of polyvinyl chloride, 15-25 parts of ethylene propylene diene monomer, 10-20 parts of modified graphene oxide, 0.5-1.5 parts of an antioxidant, 3-5 parts of a plasticizer, 15-20 parts of a flame retardant, 2-4 parts of a compatilizer, 4-5 parts of an active agent, 1-3 parts of an assistant crosslinking agent and 1-3 parts of a crosslinking agent; wherein the modified graphene oxide is obtained by modifying graphene oxide with dimethyl 5-hydroxyisophthalate and N-hydroxymethyl acrylamide. According to the technical scheme, the problem of insufficient corrosion resistance of the control cable in the prior art is solved.

The invention relates to the technical field of automobile sealing strips, and provides an anti-aging rubber sealing strip for an automobile and a preparation method of the anti-aging rubber sealing strip. The anti-aging rubber sealing strip for the automobile comprises the following components in parts by weight: 55-70 parts of ethylene propylene rubber, 30-45 parts of ethylene propylene diene monomer, 4-8 parts of an anti-aging agent, 35-60 parts of a filling agent, 3-7 parts of a softening agent, 8-10 parts of a plasticizer, 1.2-2.5 parts of an accelerant, 4-8 parts of zinc oxide and 1-2 parts of a vulcanizing agent. The anti-aging agent comprises diatomite-loaded tea polyphenol and a diatomite-loaded anti-aging agent. By means of the technical scheme, the problem that in the prior art, an automobile rubber sealing strip is poor in aging resistance is solved.

The invention discloses high-rubber-impact-resistance co-polypropylene and a preparation method thereof. The preparation method comprises the following steps: propylene is subjected to a homopolymerization reaction in a catalytic system; and adding the long-chain substituted diene mixed with the solvent in a copolymerization stage, and introducing mixed gas of propylene and other monoene for reaction to obtain the high-rubber anti-impact co-polypropylene. The long-chain substituted diene mixed with the solvent is added in the copolymerization stage, the crosslinking degree and the product uniformity of the high-rubber-impact-resistance co-polypropylene prepared by the method disclosed by the invention are remarkably improved, the introduction amount of the long-chain substituted diene is reduced, the cost is reduced, and the production efficiency is improved. In addition, the content of a rubber phase is broken through, the particle surface is not sticky, the viscosity index change is small after heating, the distribution and fluidity of the propylene copolymer are effectively controlled, and the low-temperature impact toughness is higher.

The invention discloses a high-strength bamboo-plastic composite material which comprises the following components in parts by mass: 30-55 parts of modified bamboo powder; 20 to 40 parts of high melt index polypropylene; 15 to 30 parts of low melt index polypropylene; 3 to 5 parts of maleic anhydride grafted polypropylene; 5 to 14 parts of maleic anhydride grafted POE (Polyolefin Elastomer); 5-8 parts of ethylene propylene diene monomer; the modified bamboo powder is prepared by carrying out microwave treatment, dilute alkali liquor treatment, composite enzymolysis and grafting modification on bamboo powder. The high-strength bamboo-plastic composite material provided by the invention is high in bamboo powder filling content, environment-friendly and good in mechanical property, the tensile strength can reach 33 MPa or above, the bending strength can reach 55 MPa or above, the normal-temperature toughness and the low-temperature toughness are remarkably improved, the notch impact strength at the temperature of-20 DEG C can reach 8 kJ / m < 2 > or above, and the processing fluidity is good; the method is suitable for industrial processing technologies such as injection molding and extrusion, and has great market value.

The invention discloses a durable corrosion-resistant water-stop belt and a preparation method thereof, and relates to the technical field of compositions containing polyisobutene high-molecular compounds. The durable corrosion-resistant water-stop belt is prepared from the following raw materials in parts by mass: 30 to 60 parts of ethylene propylene diene monomer, 20 to 40 parts of polyisobutene, 20 to 50 parts of filler, 0.5 to 3 parts of antioxidant, 0.5 to 3 parts of anti-aging agent, 1 to 5 parts of peroxide cross-linking agent and 1 to 10 parts of processing aid. Through the synergistic effect of the specific anti-aging agent and the antioxidant, photo-oxidative aging and thermo-oxidative aging of the material are effectively inhibited. The anti-aging agent absorbs ultraviolet rays and converts the ultraviolet rays into heat energy to prevent the ultraviolet rays from damaging polymer chains; and the antioxidant delays oxidative degradation. The two layers form double protective barriers, so that the service life of the waterstop is greatly prolonged, and the performance attenuation trend is slowed down. Through material innovation (anti-aging agent + PBS + EPDM) and process optimization (segmented mixing / cooling), three core advantages of prolonging the service life, strengthening corrosion resistance and improving construction convenience are synchronously realized.

The invention provides a high-toughness bundling grating and a production process of the high-toughness bundling grating. The composite material is prepared from the following raw materials in parts by weight: 32 to 42 parts of epoxy modified unsaturated polyester resin, 26 to 36 parts of alkali-free glass fiber, 7 to 11 parts of metallocene polyolefin, 5 to 9 parts of high-branching-degree polyolefin, 4 to 8 parts of ethylene propylene diene monomer, 2.5 to 5.5 parts of core-shell structure elastomer toughening agent, 1.5 to 4.5 parts of modified nano aluminum nitride-graphene composite filler, 0.7 to 1.1 parts of silane coupling agent and 0.5 to 0.9 part of antioxidant. 0.4 to 0.7 part of ultraviolet stabilizer, 0.4 to 0.8 part of calcium stearate and 0.1 to 0.3 part of conductive additive. According to the invention, the core-shell structure elastomer toughening agent realizes toughening without damaging strength through core-shell synergy, and the impact strength is improved by 40% or above; the modified nano aluminum nitride-graphene composite filler constructs a heat conduction-antistatic network, and the modified nano aluminum nitride-graphene composite filler and the metallocene polyolefin are matched with the high-branching-degree polyolefin and the ethylene propylene diene monomer to enhance low-temperature toughness and creep resistance.

A borate compound-containing composition soluble in hydrocarbon solvents. A composition containing base A, or a compound having a total carbon number of not less than 8 and represented by the formula (5):wherein R and R′ are each independently an optionally substituted C1-30 alkyl group, an optionally substituted C3-15 cycloalkyl group, or an optionally substituted C6-14 aryl group; anda borate compound represented by the following formula (1):wherein R1, R2, R3 and R4 are each independently a C6-14 aryl group substituted by one or more fluorine atoms or fluoro C1-4 alkyl groups; and[A-H]+ is a base A-derived cation. A method for producing a polymer, by polymerizing at least one kind of monomer selected from the group consisting of olefins and dienes by using the composition A as a cocatalyst.

The invention relates to the technical field of cable accessories, in particular to a high-strength cable accessory and a preparation method thereof. The high-strength cable accessory comprises a semiconductor layer and an insulating layer, and the semiconductor layer is prepared from, by weight, 10-15 parts of low-density polyethylene, 75-85 parts of polyolefin thermoplastic elastomer, 8-12 parts of ethylene propylene diene monomer, 25-40 parts of silane coupling agent grafted graphene nanosheets and 4-6 parts of maleic anhydride grafted modified ethylene-octylene copolymer. The composition comprises the following components in parts by weight: 1.0-2.0 parts of zinc stearate, 1.0-2.0 parts of an antioxidant, 2.0-3.5 parts of trimethylolpropane trimethacrylate and 1.5-2.2 parts of dicumyl peroxide. According to the high-strength cable accessory provided by the invention, the overall mechanical property, thermal stability and conductivity of the composite material and the mechanical strength, breakdown field strength and insulating property of the insulating layer are improved.

Provided is an aqueous based styrene-diene polymer emulsion composition including: i) from 2 to 50 wt. % of one or more polymers including linear polymers characterized by the formula:star polymers characterized by the formula:or combinations thereof; wherein D′, PA, D″, n and X are defined herein; ii) from 0.05 to 5.0 wt. % of one or more surfactants; and iii) the remainder of the composition comprising water. Also provided are an electrode slurry composition for a secondary metal ion battery composition, a secondary metal ion battery anode, a method of improving the life of a secondary metal ion battery, a method of making an aqueous based styrene-diene polymer emulsion composition, and a method of making an electrode slurry composition for a secondary metal ion battery.

The invention provides a cable material as well as a preparation method and application thereof, and the cable material comprises the following components in parts by weight: 25-45 parts of polypropylene resin, 25-45 parts of elastomer, 80-100 parts of flame retardant, 1-3 parts of antioxidant and 1-2 parts of lubricant. The elastomer comprises any one or a combination of at least two of a styrene-butadiene-styrene block copolymer, an ethylene propylene diene monomer or an ethylene-vinyl acetate copolymer. The polypropylene resin and the elastomer are blended, so that the mechanical strength, the environmental adaptability and the aging resistance of the cable material are comprehensively improved while excellent electrical insulation performance of the cable material is maintained; the halogen-free flame retardant is added, so that the release of smoke and toxic gas is reduced, and an efficient and environment-friendly flame-retardant effect is realized.

The invention relates to a preparation method of a hydrolysis modified organic silicon high-temperature-resistant anticorrosive coating, and belongs to the technical field of anticorrosive coatings. The preparation method comprises the following steps: heating 1, 1 '-bis (dimethylsilyl) ferrocene, methylbenzene, chloroplatinic acid, 2, 2, 3, 3, 4, 4, 4-heptafluorobutyl acrylate and bis-(2-methylallyl) cyclooctyl-1, 5-diene ruthenium, and reacting to obtain an intermediate product 1; weighing methyltrimethoxysilane, phenyltrimethoxysilane and the intermediate product 1, uniformly stirring and mixing, slowly dropwise adding diluted hydrochloric acid, hydrolyzing, and heating to react, so as to obtain modified silicon resin; adding the modified silicon resin into petroleum ether, and adding silicone oil, an organic tin catalyst, a bis-ammonia coupling agent, filler and a curing agent to obtain the anticorrosive paint.

This invention discloses an ablation-resistant EPDM rubber insulation material, its preparation method, and its application. The ablation-resistant EPDM rubber insulation material, by weight, comprises the following components in parts: 100 parts EPDM rubber, 1-20 parts VPL-modified fibers, 10-50 parts reinforcing filler, 5-30 parts flame retardant, 0.5-5 parts vulcanizing agent, and 0.5-5 parts co-crosslinking agent. This invention improves the thermodynamic compatibility between the fibers and EPDM rubber by modifying the fibers with the interfacial compatibility agent VPL latex, thereby obtaining the ablation-resistant EPDM rubber insulation material.

A pressure-sensitive adhesive may comprise: about 18 wt % to about 90 wt % of a propylene-ethylene(-diene) (PE(D)M) copolymer; about 10 wt % to about 65 wt % of a tackifier; and 0 wt % to about 40 wt % of an oil. The PE(D)M copolymer may comprise: (a) about 60 wt % to about 99 wt % propylene, (b) about 1 wt % to about 40 wt % ethylene or a C4 to C22 alpha-olefin, and (c) 0 wt % to about 20 wt % diene, wherein the PE(D)M copolymer has a heat of fusion of about 15 J / g or less.

The invention relates to a flame-retardant and heat-conducting EPDM (Ethylene-Propylene-Diene Monomer) foaming sealing gasket and a preparation method thereof and belongs to the technical field of rubber materials. The sealing gasket takes ethylene propylene diene monomer as a matrix, and the core is that 8-25 parts of expandable graphene grafted and modified by an epoxy silane coupling agent is added as a functional filler, and 10-30 parts of epoxidized soybean oil is matched as a bio-based active plasticizer. In a peroxide cross-linking system, the three components form an integrated cross-linking network through chemical reaction, so that the sealing gasket has good heat conductivity, flame retardance and stability. The preparation method is controllable in process and suitable for industrial production. The sealing gasket is suitable for new energy automobile battery packs, energy storage equipment and other occasions with comprehensive requirements for sealing, heat dissipation and fire prevention.

The application relates to the technical field of shoe sole materials, in particular to a foamed composite material and application of the foamed composite material in shoe materials, which comprises EVA resin, ethylene-propylene-diene rubber, wear-resistant particles, a filler, a foaming agent, a crosslinking agent, a lubricant and an activator; wherein the wear-resistant particles are modified porous corundum, which is obtained by in-situ ring-opening polymerization of flexible PCL chains in and outside the pores of the porous corundum after surface activation; and the flexible PCL chains further have polyethylene glycol-stearic acid polymer brushes. Compared with the prior art, the application has the beneficial effects that: the EVA provides good processability and elasticity, the ethylene-propylene-diene rubber endows the material with excellent low-temperature performance and aging resistance; the corundum core of the modified porous corundum provides a high-hardness wear-resistant framework, significantly reduces the abrasion amount in a unit volume, the polycaprolactone main chain and the polyethylene glycol-stearic acid side chain compensate the rigidity of the corundum, and guarantee the high resilience, especially the low-temperature resilience, of the EVA material.

The application discloses an insulating EPDM composite material and a preparation method thereof, and belongs to the technical field of rubber preparation. First, boron nitride is dispersed in a dispersing agent, a coupling agent is added, and modified boron nitride is obtained by drying; the modified boron nitride is dispersed in polyisobutylene in a molten state, and polyisobutylene@boron nitride composite powder is obtained after freezing, crushing and sieving; EPDM, the polyisobutylene@boron nitride composite powder, a conductive agent and an antioxidant are mixed; finally, a vulcanizing agent is added to the S3 mixed system, and the insulating EPDM composite material is obtained after vulcanization is completed. The insulating EPDM composite material provided by the application has excellent electrical insulation performance and electrical resistance, can effectively prevent electrical tree aging, and prolongs the service life of the product.

The present invention relates to a thermoplastic resin composition including: a base resin including a diene-based graft polymer and a vinyl-based non-grafted polymer including an aromatic vinyl-based monomer unit and a vinyl cyanide-based monomer unit; and an additive including an olefin-based non-grafted polymer including an olefin-based monomer unit, a (meth)acrylate-based monomer unit, and a maleic acid-based monomer unit.

The application provides a dithiol modified copolymer and a preparation method and application thereof, and particularly relates to the technical field of lithium batteries. In the dithiol modified copolymer, the copolymer is a branched diene-vinyl pyridine copolymer, which is mainly obtained by copolymerization of branched diene and vinyl pyridine. The dithiol modified copolymer provided by the application has a main chain composed of flexible branched diene units, which endows the copolymer with a good elastic skeleton structure; vinyl pyridine is introduced as a functional monomer, so that a pyridine group is formed on the side chain of the copolymer; a dithiol compound introduces a thiol group (-SH) to the copolymer, and finally, the dithiol modified copolymer has a flexible main chain structure, and the side chain simultaneously contains a pyridine group and a thiol group, and has good elasticity and functional characteristics.

A rubber composition for tire side wall comprising, per 100 parts by mass of a rubber component containing at least a diene-based rubber, 0.2 to 7 parts by mass of a compound represented by the following general formula (1):wherein at least one of R1 to R5 is an —OH group or an —OCH3 group and others are each an —H group or a hydrocarbon group having 1 to 20 carbon atoms, A is an unsaturated bond or an alkylene group having 1 to 20 carbon atoms and optionally having an —H group, a —CH3 group, an —NH2 group, an —O— group, or an —OH group, n is an integer of 0 to 10, and B is a —COOH group, an —OH group, or an ═O group and optionally forms a ring structure with adjacent R1 or R5.

The invention relates to an anion exchange membrane containing a composite film of an ionomer and zirconium oxide particles of formula ZrO2, the ionomer being a block polymer of formula (AB)nA, the symbol A representing a polyvinylaromatic block bearing quaternary amine groups, the symbol B representing a hydrogenated block of a poly(1,3-diene) or a copolymer comprising monomer units of a 1,3-diene and a vinylaromatic monomer, n being an integer equal to or greater than 1, the zirconium oxide particle content of the composite film being greater than 40% by mass of the composite film mass, the zirconium oxide particles having a median volume size, D50, greater than 100 nm and less than 1 µm. The membrane exhibits good plasticity.

The present invention relates to a rubber composition based on at least one elastomeric matrix comprising predominantly a highly saturated diene elastomer, which highly saturated diene elastomer is a copolymer of ethylene and a 1,3-diene in which the ethylene units represent at least 50% by mole of the monomer units of the copolymer, a reinforcing filler, a vulcanizing system, a functional liquid butadiene polymer, which polymer is a liquid butadiene polymer functionalized along the chain by pendant alkoxysilyl functions, optionally totally or partially hydrolyzed, having a number-average molar mass (Mn) greater than or equal to 1000 g / mol, and a non-functional liquid butadiene polymer, having a number-average molar mass (Mn) greater than or equal to 1000 g / mol.

The present invention relates to a process for the preparation of polycyclic aliphatic dialdehydes by hydroformylation of polycyclic aliphatic diolefins in the presence of synthesis gas over an organophosphorus ligand modified metal catalyst system having a transition metal of the 8th-10th subgroup, wherein the hydroformylation is carried out by means of a water-soluble diphosphine or triarylphosphine complex catalyst at a pressure of greater than or equal to 0.5 MPa and less than or equal to 10 MPa and at a temperature of greater than or equal to 70° C. and less than or equal to 150°° C. in a homogeneous liquid reaction phase, the homogeneous liquid phase comprising at least one non-aqueous solvent, diolefin and / or mono- and / or dialdehydes thereof as reaction products and an aqueous catalyst solution, the proportions of these components in the solution being controlled so as to obtain a single-phase solution under the reaction conditions.

This rubber composition is characterized by comprising a diene-based rubber component and a filler containing recycled carbon black, and is characterized in that: the diene-based rubber component includes a butadiene-based rubber; when the recycled carbon black is measured using a grind gauge, 3 or more lines having a length of 10 mm or more are observed; and, among particles forming the lines having a length of 10 mm or more, the particle size of particles having the third largest size is 20 µm or less.

The present application relates to a kind of from androsta 1, 4-diene-3, 17-dione starting synthesis of estren and the method of a kind of compound thereof.Especially, the present application provides a kind of preparation method of estren shown in formula I, comprising the following steps: in inert solvent, androsta-1, 4-diene-3, 17-dione (II) with reagent R4VX carries out demethylation aromatization reaction step directly to obtain estren (I);Wherein, the definition of reaction substrate, reagent and reaction condition is as claimed in claim or specification.The method is simple in operation, and good in selectivity, and product purity is high, suitable for industrial production.

This invention relates to an EV cable material for charging piles. It comprises the following components and parts by weight: 45-55 parts polyvinyl chloride (PVC), 5-10 parts stabilizer, 35-50 parts plasticizer, 25-50 parts P83 rubber, 2-5 parts flame retardant, 10-20 parts propylene diene monomer (PPD) rubber, 10-25 parts TPU, 0.1-0.4 parts lubricant, 0.2-0.8 parts antioxidant, and 1-2 parts anti-aging agent. The EV cable material of this invention is soft to the touch, has good oil resistance, high tear strength, is lightweight, and has good flame retardancy. It does not require radiation cross-linking and can meet the long-term operating requirements of cables at 125°C, achieving a truly environmentally friendly flame-retardant material. Compared with thermosetting low-smoke halogen-free materials and other materials, it is a cost-effective alternative.