3494 results about "Sulfide compound" patented technology

The invention discloses a sulfide coated particle as well as a preparation method and an application thereof. The sulfide coated particle comprises a core and a shell coating the core, wherein the core is prepared from at least one of metal, oxide, metal hydroxide, metal inorganic salt, elemental carbon or oxysome thereof, carbide, nitride, semiconductor and organic matter; the shell is prepared from metal sulfide. The to-be-coated core is mixed with the metal salt, a reducing agent and a sulfur source with a liquid phase method, metal sulfide is precipitated to the particle surface through in-situ reduction, and uniform, continuous and controllable coating of the core surface with metal sulfide is realized. The coating method is simple, reaction conditions are mild, universality is high,a coating layer is controllable in thickness, complete and uniform, and the sulfide coated particle has quite broad practical application prospect in the fields of electrocatalysis, lithium ion batteries, biomedicine and the like.

A preloaded cathode layer, comprising: (A) An integral porous structure having massive surfaces greater than 100 m²/g or pores with a size from 1.0 nm to 100 nm, wherein multiple conductive particles, platelets or filaments, without a conductive filler, form a 3-D conductive network; and (B) a metal polysulfide preloaded in the pores or deposited on the massive surfaces, selected from: (a) an M_xS_y, (x=1-3 and y=1-10) wherein M is a metal element selected from a non-lithium alkali metal, an alkaline metal selected from Mg or Ca, a transition metal, a metal from groups 13 to 17, or a combination thereof, or (b) Li₂S₆, Li₂S₇, Li₂S₈, Li₂S₉, or Li₂S₁₀, wherein the metal polysulfide contains a thin coating or small particles with a thickness or diameter less than 20 nm and occupies a weight fraction of from 1% to 99%.

The present invention provides a process for making silica-filled rubber masterbatch using silica hydrophobated with a trimethoxy silane coupling agent that is soluble in an alcohol-water solution containing at least about 70 wt % water. One embodiment uses a mixture of trimethoxy silanes, one or more of which react with rubber to bond the silica to the rubber, and one or more of which do not react with rubber, but do hydrophobate the silica. Hydrophobated silica is mixed with latex polymer and incorporated into rubber during coagulation of the latex, which is preferably coagulated with calcium chloride. The present invention further provides a process for making the trimethoxy silane coupling agents. Preferred trimethoxy silane coupling agents include bis-(3-trimethoxysilylpropyl)-disulfide and bis-(3-trimethoxysilylpropyl)-tetrasulfide. Rubber products, particularly tires, compounded with the inventive silica masterbatch can be processed for a long time before scorching because the silica masterbatch provides a long scorch time.

Provided is a rechargeable alkali metal-sulfur cell comprising an anode active material layer, an electrolyte, and a cathode active material layer containing multiple particulates of a sulfur-containing material selected from a sulfur-carbon hybrid, sulfur-graphite hybrid, sulfur-graphene hybrid, conducting polymer-sulfur hybrid, metal sulfide, sulfur compound, or a combination thereof and wherein at least one of the particulates is composed of one or a plurality of sulfur-containing material particles being embraced or encapsulated by a thin layer of a high-elasticity polymer having a recoverable tensile strain no less than 10% when measured without an additive or reinforcement, a lithium ion conductivity no less than 10⁻⁵ S/cm at room temperature, and a thickness from 0.5 nm to 10 μm. This battery exhibits an excellent combination of high sulfur content, high sulfur utilization efficiency, high energy density, and long cycle life.

This invention relates to: a molding material comprising a bundle of continuous reinforcing fibers (A), a polyarylene sulfide prepolymer (B) comprising at least 50% by weight of cyclic polyarylene sulfide and having the weight average molecular weight of less than 10,000 or polyarylene sulfide (B′) having the weight average molecular weight of 10,000 or greater and the degree of dispersion of 2.5 or lower, and thermoplastic resin (C); a prepreg comprising a resin composition comprising the polyarylene sulfide prepolymer (B) impregnated into a reinforcing fiber; and a method for producing a fiber-reinforced molding substrate comprising step (I) of continuously feeding a bundle of continuous reinforcing fibers, step (II) of combining cyclic polyarylene sulfide with the reinforcing fiber bundle, step (III) of heating the composite obtained in step (II) to subject the cyclic polyarylene sulfide to ring-opening polymerization to convert into polyarylene sulfide, and step (IV) of cooling the composite obtained in step (III) and withdrawing the same.

The invention relates to a carbon-sulfur-shell matter composite material having a network dual-core shell structure and a preparation method thereof. The carbon-sulfur-shell matter composite material has a carbon-sulfur-shell three layer structure, a central core (inner core) is nano carbon particles, sulfur elemental or a polysulfide containing-Sm-structure (m>2) is directly deposited on the nano carbon particles, or functional groups are introduced onto the nano carbon particles by use of polycyclic aromatic hydrocarbon like reaction capacity of the carbon material and through an irreversible chemical reaction, polymeric chains are introduced in, a crosslinked network structure is formed through stretching, bending and crosslinking of the polymeric chains on the surface of the nano carbon particles, the sulfur elemental or the polysulfide containing the-Sm-structure (m>2) is composited onto the crosslinked network structure to form a nano sulfur layer having a network structure, then a mono-core shell nano composite material having a network structure is obtained and is used as a second layer (outer core) of the carbon-sulfur-polymer composite material having the network dual-core shell structure, an outermost layer is a shell matter layer, electronic and/or ionic conductivity of the material are/is improved, dissolving loss of discharge products can be further inhibited, and structural stability of the material is improved. The material is suitable for positive poles of lithium sulfur batteries, and has a prominent effect on improvement of cycle stability of the lithium sulfur batteries.

Disclosed are thioethers, methods for preparing such thioethers, and curable compositions, such as coating and sealant compositions, that include such thioethers. The thioethers can be the reaction product of (a) an alpha, omega dihalo organic compound, (b) a metal hydrosulfide and (c) a metal hydroxide.

The invention discloses an MXene-based flexible composite negative electrode material and a preparation method thereof. According to the MXene-based flexible composite negative electrode material andthe preparation method thereof, a transition metal sulfide is loaded on a two-dimensional layered structure of the MXene material through a hydrothermal method. The agglomeration effect of the MXene material is overcome, and the collapse of a layered structure is prevented. Meanwhile, the energy density of the composite material is improved. The MXene material with high conductivity acts as a three-dimensional conductive network skeleton, so that the conductivity and the mechanical strength of the composite material are enhanced. The volume expansion of the transition metal polysulfide material in the charging process is buffered. Meanwhile, the material has good charge-discharge cycle stability. The composite material and expanded graphite are combined to prepare a self-supporting high-flexibility negative electrode material. In the charging and discharging process, the hydrophilic MXene material has high affinity to polysulfides. The electrochemical performance and the capacitive deionization performance of the composite negative electrode material can be further improved. Sulfides generated by transition metal sulfides are eliminated. The shuttle effect of the polysulfides is limited, and the service life of the negative electrode material is prolonged.

The invention provides a bioremediation composition for in situ bioremediation of soil and/or groundwater contaminated with hydrocarbons, comprising an adsorbent capable of adsorbing said hydrocarbons, a mixture of facultative anaerobes capable of metabolizing said hydrocarbon under sulfate-reduction conditions, a sulfate-containing compound that releases sulfate over a period of time, and a nutrient system for promoting growth of said anaerobes, wherein said nutrient system includes a sulfide scavenging agent.

The invention relates to a desulfurizing agent for reforming stock oil and a preparation method thereof, in particular to the desulfurizing agent used for desorbing sulfides in the reforming stock oilsuch as H2S and the like. The desulfurizing agent is characterized by consisting of 10%-40% of ZnO, 15%-22% of NiO, 10%-17% of Al2O3, 5%-22% of SiO2 and the balance inevitable impurities. The desulfurizing agent takes zinc and nickel as active components and bentonite (or diatomite, or white clay, or zeolite, or high-alumina cement and or common cement) as a carrier, and active components thereofare directly present in the form of oxides of zinc and nickel or oxides transformed by corresponding carbonate (basic carbonate) and nitrate. In the invention, the desulfurizing agent has enlarged raw material range, thus effectively reducing raw material cost, simplifying production process of the desulfurizing agent, lowering production cost, improving strength to more than twice, and prolonging service life of the desulfurizing agent.

The invention discloses a detection method of metal ions. In the method, based on a gold nanoparticles-sulfide system, by virtue of the interaction among the gold nanoparticles, a hydrolysate of a sulfide and the detected metal ions or the interaction among the gold nanoparticles, a sulfhydryl compound and the detected metal ions, resonance absorption of plasmas on the surface of the gold nanoparticles changes so that the color and the ultraviolet visible absorption strength of the gold nanoparticles changes. By adopting the method, the detected metal ions in the solution system can be rapidly detected by directly distinguishing change of solution color through eyes or a simple apparatus. The detection method has the advantages of simple and convenient operation, low detection cost, high detection sensitivity, small sampling quantity and wide application scope.

The present invention provides methods and compositions for the chemical conversion of syngas to alcohols. The invention includes catalyst compositions, methods of making the catalysts, and methods of using the catalysts including techniques to maintain catalyst stability. Certain embodiments teach compositions for catalyzing the conversion of syngas into products comprising at least one C₁-C₄ alcohol, such as ethanol. These compositions generally include cobalt, molybdenum, and sulfur, and avoid metal carbides both initially and during reactor operation.

The invention provides a method for unhairing leather and loosening leather fiber without sodium sulfide and lime in a leather production process and the application of the method. The method is characterized in that a method for combining unhairing by non-sulfur (sodium sulfide) depilatory under the alkaline condition and enzyme fiber loosening under the under the non-lime (lime) alkaline swelling condition are adopted, the enzyme unhearing and the enzyme fiber loosening take protease, lipase, amylase and glucoamylase as a compound enzyme system. The method achieves the effects for unhairing and loosening the leather fiber through adopting the method for combining compound enzyme water immersion, compound enzyme unhairing, unhairing with sodium sulfide depilatory, expansion regulator-sodium hydroxide expansion and the enzyme unhairing under the alkaline condition and eliminates the pollution which is brought by the sodium sulfide and the lime in animal unhairing or leather fiber loosening procedures in the leather production process. The method of the invention is suitable for unhairing and leather fiber dispersed processing of various animal leather of leather with various usages.

The invention discloses a low-temperature oxidation preparation method of different carbon-coated nanocrystallines. The method comprises the steps of 1. preparing reaction raw materials: evenly mixing organic metal pi complex and a strong oxidant which are selected as raw materials, wherein the molar ratio of the strong oxidant to the organic metal pi complex is (1-5):1; 2. arranging the evenly mixed raw material into a pressure-resistant closed reaction container, heating up to 100-240 DEG C, and carrying out heat preservation for 0.5-2h; after the reaction, carrying out aftertreatment to obtain the different carbon-coated nanocrystallines, wherein nanocrystallines are any one or combinations of more than two of metal sulfide, metal oxide and elemental sulfur. The preparation method has the characteristics of simple equipment, easiness in operation, low cost, high efficiency, environmental protection and the like, thus facilitating industrial production; the prepared carbon-coated nanocrystallines have multiple varieties, controllable composition and form and good stability, and have wide application prospect in the fields of a lithium ion battery, a lithium sulphur battery, a supercapacitor, environmental cleaning, drug targeting, wave-absorbing material, etc.

The invention discloses a polydicyclopentadiene composite material, which consists of the following components in percentage by weight: 0.1 to 2 percent of inorganic nano filler, 0 to 5 percent of auxiliary polymer particles and the balance of polydicyclopentadiene and inevitable impurities, wherein the inorganic nano filler is nano inorganic salt, nano oxide, nano carbide or nano sulfide containing Si, Al, Ca, Zn, Ti, Zr or Mo metal or carbon-containing nonmetallic nano compound; and the auxiliary polymer particles are particles of polyethylene, polytetrafluoroethylene or polyamide, the particle diameter of which is 0.5 to 15 microns. The inorganic nano material and the auxiliary polymer particles are blended into the polydicyclopentadiene to prepare the polydicyclopentadiene composite material; and the abrasion resistance of the nano composite material is improved at the same time of improving the modulus and the impact strength, and the erosion and abrasion resistance of the nano composite material can reach 5 to 9 times that of low-chromium cast iron.

The invention provides a preparation method of an S/TiO2 composite material for an anode of a sodium-sulfur battery. The preparation method comprises the following steps: dissolving butyl titanate, a template agent and a hydrolysis inhibitor into absolute ethyl alcohol; adding a mixed solution of de-ionized water and the absolute ethyl alcohol to form semi-transparent sol; transferring the sol into a high-pressure reaction kettle to react; calcining a solid product in air to remove the template agent to obtain meso-porous titanium dioxide; dispersing the meso-porous titanium dioxide into a sodium thiosulfate solution dissolved with a surfactant; adding hydrochloric acid to react; washing the solid product by a lot of the de-ionized water and drying; and eating under the protection of an inert atmosphere to obtain the S/TiO2 composite material. The meso-porous titanium dioxide prepared by the preparation method is large in specific surface area, high in porosity and strong in adsorption capability; the electrical conductivity of sulfur can be improved and a lot of nano sulfur and polysulfide can be contained; the polysulfide can be effectively prevented from being dissolved and diffused in electrolyte, and the utilization rate of the sulfur is improved; meanwhile, the structure of the meso-porous titanium dioxide is stable and a pore channel cannot be easily damaged, so as to have buffering effects on volume expansion and retraction in a charging/discharging process of a sulfur electrode.