2916 results about "Sulfide compound" patented technology

The invention relates to the technical field of batteries, in particular to a solid electrolyte material and a preparation method thereof, a solid electrolyte membrane and a battery. The solid electrolyte material has a core-shell structure, the core-shell structure comprises an inner core and a coating layer arranged on the surface of the inner core, the inner core comprises a sulfide electrolyte, and the coating layer comprises an amide compound. According to the solid electrolyte material disclosed by the invention, the coating layer containing the amide compound is arranged on the surface of the sulfide electrolyte, so that the air stability of the solid electrolyte material can be effectively improved, and meanwhile, the solid electrolyte material is ensured to have proper conductivity without influencing the charge-discharge performance of a battery.

The invention discloses high-purity lithium sulfide as well as a preparation method and application thereof. The preparation method comprises the step that lithium hydride, lithium hydroxide and a sulfur source are subjected to a heating reaction in a dry inert atmosphere, and the high-purity lithium sulfide is obtained. The molar ratio of lithium hydride to lithium hydroxide is X: (10-X), and X is 1-6. The invention also discloses the prepared high-purity lithium sulfide and application of the high-purity lithium sulfide in preparation of sulfide solid electrolyte. Lithium hydroxide and lithium hydride are mixed to serve as a lithium source in lithium sulfide preparation, the lithium hydroxide quickly and uniformly reaches the reaction temperature by means of the characteristic that the lithium hydride reacts with a sulfur source to release heat and produce gas, the lithium hydride reacts to produce gas, meanwhile, discharging of product water vapor is facilitated, and oxygen in the environment is isolated; and hardening and generation of a side reaction product lithium sulfate are prevented, the conversion rate of lithium hydroxide to lithium sulfide is improved, and the raw material and process cost for preparing lithium sulfide is remarkably reduced.

The invention discloses a single-ion conductor polymer, a ternary composite binder solution, high-solid-content sulfide electrolyte slurry and a wet film forming method and application thereof, and belongs to the technical field of all-solid-state lithium batteries. The key technical problems in the wet membrane preparation of the sulfide electrolyte are solved through an innovative solvent-binder synergistic system, and the method specifically comprises the steps that 1, through the synergistic effect of a non-polar solvent and a weak-polar solvent, low-viscosity coating of high-solid-content slurry is achieved while the chemical stability of the sulfide electrolyte is guaranteed; 2, a poly (lithium styrenesulfonate-butyl acrylate), styrene butadiene rubber and polyisobutene ternary composite binder is designed, a lithium ion transmission channel is provided through a lithium sulfonate group, a benzene ring structure in the styrene butadiene rubber enhances the mechanical strength, long-chain alkane in the polyisobutene improves the interface adhesive force, and the mechanical strength is improved; the three components cooperate to realize balance of mechanical and electrochemical properties of the electrolyte membrane, so that the prepared electrolyte membrane has low porosity, high ionic conductivity and mechanical strength.

The invention discloses a preparation method and application of a sulfide solid electrolyte membrane based on a gradient polymer / ionic liquid composite binder, and an all-solid-state battery, and belongs to the technical field of all-solid-state batteries. The method comprises the following steps: firstly coating a polymer / ionic liquid / sulfide electrolyte composite layer through a gradient coating process, filling particle gaps under low pressure by utilizing the plasticizing effect of ionic liquid, and reducing the porosity of an interface; and then coating a polymer / sulfide electrolyte surface layer to provide mechanical support and inhibit side reaction of the electrode. According to the design, the electrolyte membrane still keeps high ionic conductivity under the working pressure of a commercial power battery module, and the interface impedance is reduced compared with that of a traditional homogeneous membrane. Through the innovative gradient structure and material combination, the ion transmission bottleneck of the sulfide electrolyte under the low-pressure condition is solved, excellent interface stability and process compatibility are achieved, and a key technical scheme is provided for all-solid-state battery industrialization.

The invention discloses a desulfurizing tower and a desulfurizing method based on enhanced absorption of flat sheet membrane internals. The desulfurizing tower comprises a desulfurizing tower body, and a liquid distributor, the flat sheet membrane internals and fractal internals which are sequentially arranged in the desulfurizing tower body from top to bottom, according to the invention, high-concentration sulfur-containing gas is subjected to rapid pre-desulfurization at the tower bottom by utilizing the high turbulence characteristic of the fractal internals, so that the sulfide concentration can be instantly reduced, and the gas flow distribution is optimized; and the pre-desulfurized gas then enters a high-efficiency fine desulfurization area formed by the flat sheet membrane internals. According to the flat sheet membrane internal part, a plurality of vertically arranged flat sheets are utilized to form a fixed gas flowing channel, so that transverse movement of gas molecules is limited, and gas distribution is more uniform. And meanwhile, a layer of uniform and continuous absorbent liquid film is formed on the surface of the flat plate, so that the gas-liquid contact area is remarkably increased, and high efficiency and low energy consumption are achieved through full countercurrent contact and efficient gas-liquid mass transfer of gas and the absorbent liquid film under extremely low pressure drop.

The invention relates to the technical field of all-solid-state batteries, in particular to a halide sulfide double-layer coated positive electrode material and a preparation method and application thereof. The halide sulfide double-layer coated positive electrode material comprises a positive electrode material substrate, and a halide electrolyte coating layer and a sulfide electrolyte coating layer which sequentially coat the positive electrode material substrate. The halide electrolyte coating layer is located in the middle layer, compatibility with a positive electrode interface can be achieved by means of high oxidation resistance of the halide electrolyte coating layer, and the problem of the positive electrode interface occurring in sulfide electrolyte oxygenolysis is solved. The sulfide electrolyte coating layer is located on the outermost layer, air stability is excellent, processing in a dry environment can be met, and the problems that halide electrolyte is poor in chemical stability, cannot be processed and manufactured in an external environment and is high in density are solved. The halide sulfide double-layer coated positive electrode material has high interface stability and good chemical stability.

The invention discloses a sulfide-based composite solid-state electrolyte, a preparation method thereof and a lithium metal solid-state battery, sulfide is subjected to specific bifunctional surface grafting modification by using a silane coupling reagent with sulfydryl and epoxy bonds, then the sulfide is introduced into a polymer precursor liquid, and the sulfide-based composite solid-state electrolyte is prepared through light-heat curing reaction synergy. A flexible and rigid cross-linked network is formed, the sulfide-based composite solid-state electrolyte with high ionic conductivity and high mechanical strength is obtained, the interface stability of the sulfide-based composite solid-state electrolyte in the charge-discharge process is ensured, for example, the sulfide-based composite solid-state electrolyte in the embodiment 1 has high ionic conductivity (3.81 mS / cm), and the interface stability of the sulfide-based composite solid-state electrolyte in the embodiment 2 is ensured. The lithium-lithium symmetric battery prepared by the method has the advantages of excellent flexibility, high tensile strength (7.9 Mpa) and wide electrochemical window (5.1 V), the lithium-lithium symmetric battery can stably circulate for 2000h, and the whole battery can stably circulate for 2000 circles at the room temperature at the rate of 4C, so that the lithium-lithium symmetric battery has great industrial application value.

The invention provides a surface-modified sulfide electrolyte and a preparation method thereof, and an all-solid-state battery, the surface-modified sulfide electrolyte comprises a sulfide electrolyte and a modification layer coated on the surface of the sulfide electrolyte, the chemical general formula of the modification layer is LiaMbNcXd, 0 < = a < = 3, 0 < = b < = 1, 0 < = c < = 1, 0 < = d < = 6, and 0 < = c < = 1. M is at least one element of magnesium, aluminum, calcium, iron, zirconium, niobium, tantalum, tungsten, gadolinium, yttrium, indium, hafnium, lanthanum and ytterbium, and X is at least one element of oxygen, sulfur, fluorine, chlorine, bromine and iodine. According to the surface-modified sulfide electrolyte, the modification layer with high ionic conductivity and high oxidation potential is coated outside the sulfide electrolyte, so that when the surface-modified sulfide electrolyte is applied to a positive electrode of an all-solid-state battery, the modification layer can improve the oxidation potential of the electrolyte on the premise of not reducing the ionic conductivity of the electrolyte; the effects of improving the interface stability between the positive electrode active material and the sulfide electrolyte and further improving the cycle performance of the battery are achieved.

The invention discloses a mixed ion conductor layer for a lithium metal negative electrode, a preparation method of the mixed ion conductor layer and an all-solid-state battery, and belongs to the technical field of sulfide all-solid-state batteries. The preparation method comprises the following steps: synthesizing a sulfide electrolyte 70 (0.75 Li2S-0.25 P2S5)-30LiI through a liquid phase, introducing graphene oxide and a lithium salt precursor 2, 5-dihydroxy-1, 4-benzene diphosphate in the electrolyte preparation process, and carrying out heat treatment and pressing to obtain a mixed ion conductor layer; the graphene oxide can isolate the sulfide electrolyte layer from the lithium metal negative electrode, interface reaction is avoided, and a special porous and interlayer structure provides a transverse growth space for lithium metal deposition. And meanwhile, the lithium diphosphate-based MOF among the graphene layers ensures the rapid movement of lithium ions, enhances the bulk diffusion of lithium at the negative electrode end, reduces the local current density, plays a role in dredging the distribution of the lithium ions, and remarkably prolongs the cycle life of the sulfide all-solid-state battery.

The invention provides a composite sulfide solid electrolyte, a preparation method thereof and a lithium ion battery. The composite sulfide solid-state electrolyte comprises a sulfide solid-state electrolyte matrix and a composite layer coating the surface of the sulfide solid-state electrolyte matrix, the composite layer comprises an interface reaction layer and a coating layer from inside to outside, the coating layer comprises a halide material, and the interface reaction layer comprises an interface reactant obtained after the halide material and the surface of the sulfide solid electrolyte matrix are subjected to an interface reaction. According to the invention, under the action of the specific surface composite layer, the electrochemical window and mechanical property of the sulfide solid electrolyte are widened, the mechanical stability and electrochemical stability of the sulfide solid electrolyte and a positive electrode material are improved, and the interface reaction of the sulfide solid electrolyte is further inhibited.

The invention belongs to the technical field of petroleum processing, and particularly relates to a catalyst and a preparation method and application thereof. The raw materials of the catalyst comprise a metal active component, a carrier and an auxiliary agent, the metal active component is sulfides of Mo and Ni elements, the carrier is spherical gamma-Al2O3 of 0.5-1 mm, and the auxiliary agent is P; the carrier is modified by using the metal active component and the auxiliary agent to serve as the catalyst. The high-activity catalyst is synthesized by adopting the strategy of changing the roasting temperature, adding the additive for doping modification and changing the molar ratio of metal active components, the additive is combined with surface aluminum atoms, the framework strength is enhanced, pore channel collapse caused by acid / water erosion is reduced, the water resistance and acid resistance of the catalyst are improved, and the catalytic reaction activity is further improved. The catalyst disclosed by the invention is accurate and controllable in structure, can be synthesized in batches, and can be applied to the co-catalytic hydrogenation process of biomass pyrolytic oil and / or a model compound thereof and petroleum distillate oil and / or VR.

The invention discloses a preparation method for selectively oxidizing thioether into sulfoxide through photo-initiation, and belongs to the field of synthesis of medical compounds. The preparation method comprises the following steps that in the air atmosphere, a thioether compound is dissolved in an acetonitrile-water mixed solvent, inorganic metal salt catalysts such as ferric chloride and copper sulfate are added, the mixture reacts for 8-48 h at the temperature of 0-45 DEG C under illumination with the wavelength of 295-405 nm, selective oxidation is carried out, and the sulfoxide product is obtained, and the molar ratio of thioether to the catalysts is 5: 1. The method overcomes the problems of excessive oxidation risk, complicated operation, environmental pollution and the like caused by dependence of a noble metal catalyst and use of a strong oxidant in the existing thioether oxidation method, has the advantages of high catalytic efficiency, high yield and excellent selectivity, can greatly reduce the production cost, is suitable for later industrial synthesis and amplification, and has wide application prospects. The method has the advantages of no expensive metal catalyst or oxidant, simple preparation process, high efficiency, environmental protection, safety and cost saving.

The invention relates to the technical field of batteries, in particular to a composite solid electrolyte material as well as a preparation method and application thereof. A composite solid electrolyte material comprises a base material and a composite coating layer located on the surface of the base material, the composite coating layer comprises a first coating layer and a second coating layer, the first coating layer is located on the surface of the base material, and the second coating layer is located on the surface of the first coating layer; the matrix material comprises a sulfide electrolyte material; the first coating layer is prepared from Li3PS4 and LiCl; the second coating layer contains LiF and LiPO4. According to the composite solid electrolyte material disclosed by the invention, the first coating layer (Li3PS4 and LiCl) and the second coating layer (Li3PS4 and LiCl) are arranged on the surface of the base material and are coordinated and matched, so that the composite solid electrolyte material has high ionic conductivity and high chemical and electrochemical stability.

The invention discloses a composite sulfide solid-state electrolyte and a preparation method and application thereof, and relates to the technical field of solid-state batteries. The composite sulfide solid electrolyte comprises sulfide solid electrolyte particles and nano ion conductor particles which are stable to water vapor, wherein the nano ion conductor particles are uniformly distributed on the surfaces and gaps of the sulfide solid electrolyte particles to form a composite structure. Therefore, through the composite structure that the nano ion conductor particles are uniformly distributed on the surfaces of the sulfide particles and in the gaps, the surface coverage of the sulfide solid electrolyte can be increased, the hydrolysis reaction rate can be reduced, and the sulfide solid electrolyte is well protected while the reduction amplitude of the lithium ion conductivity is reduced; the stability to air is improved; and the electrochemical stability is also improved. In addition, the method is simple in process, has good mass production capacity, and has high application value for actual production.

The invention provides a composite sulfide solid electrolyte membrane, a preparation method thereof and a lithium ion battery. The composite sulfide solid electrolyte membrane comprises a halide layer and a sulfide layer which are sequentially arranged from top to bottom; the halide layer comprises a halide solid electrolyte material; the sulfide layer contains a sulfide solid electrolyte material with particle size grading, and sulfide particles with different particle sizes are uniformly mixed; a connecting surface is arranged between the sulfide layer and the halide layer, and the halide solid electrolyte material in the connecting surface is filled into a gap of the sulfide solid electrolyte material. The composite sulfide solid-state electrolyte membrane comprises the halide layer and the sulfide layer which are sequentially arranged from top to bottom, the compactness of the sulfide solid-state electrolyte membrane can be improved by grading sulfide solid-state electrolyte materials with different particle sizes, and a composite channel structure with high stability and high ionic conductivity is formed; the ion transmission efficiency and the interface long-term stability are both considered.

The invention relates to the technical field of electrochemistry, and provides a sulfide solid electrolyte, a preparation method thereof, a battery and application. The chemical formula of the sulfide solid electrolyte is Li7-aPS6-aXa, X is halogen, and a is greater than or equal to 1 and less than or equal to 2; wherein the peak area of a diffraction peak corresponding to a (111) crystal plane of the sulfide solid electrolyte is I1, the peak area of a diffraction peak corresponding to a (311) crystal plane of the sulfide solid electrolyte is I2, and I1 / I2 is larger than or equal to 0.2 and smaller than or equal to 0.3. The I1 / I2 of the sulfide solid electrolyte disclosed by the invention is within the range, a good crystal structure and a relatively large interface area can be provided, and ion movement is promoted, so that relatively high ionic conductivity is obtained. Furthermore, according to the method disclosed by the invention, the high ionic conductivity of the product is ensured by reducing the solvent dosage and optimizing the sintering step, and meanwhile, the environmental pollution, the energy consumption and the production cost are remarkably reduced.

Provided are: a negative electrode composite material for a negative electrode for a solid-state battery, the negative electrode composite material being capable of being used even when a high-capacity negative electrode active material having a large volume change rate and a sulfide-based solid electrolyte that is reactive with an ionic liquid are used in the negative electrode composite material; and a solid-state battery using the negative electrode composite material. As a result, it is possible to achieve a solid-state battery in which loss of an ion conduction path during charging and discharging of the solid-state battery is suppressed, and a decrease in capacity during a charging and discharging cycle is suppressed. The negative electrode composite material contains a specific ionic liquid. Specifically, in a negative electrode composite material containing a negative electrode active material, a solid electrolyte, and an ionic liquid, the negative electrode active material is a silicon-based negative electrode active material, the solid electrolyte is a sulfide-based solid electrolyte, and the ionic liquid contains an anion having a donor number of 9 or less as determined from the half-wave potential of a noble metal.

The invention relates to the technical field of microorganisms, and particularly discloses a nitrogen-fixing and cadmium-reducing microbial agent as well as a preparation method and application thereof. The microbial agent consists of bacillus pseudomycoides, lactococcus lactis, azotobacter chroococcum and biochar, wherein the biochar is obtained by pyrolyzing and carbonizing rice straws. The bacillus pseudomycoides can reduce the bio-availability of soil cadmium; lactococcus lactis can secrete a large number of biological active substances such as exopolysaccharides and enzymes, and the activity of other microorganisms is stimulated and improved; azotobacter chroococcum converts nitrogen in air into ammonium, amino acid and peptide which can be utilized by plants and promotes plant growth, and released metallothionein contains free sulfydryl which is combined with Cd ions, so that a stable sulfide compound is formed. The biological carbon adsorbs and fixes the three bacteria, so that the microorganisms can continuously and effectively play a role and have a mutual synergistic effect, the fixation of Cd in the soil is further enhanced, the availability of nitrogen is improved, and the plant growth is effectively promoted.

The invention belongs to the field of metal materials, and provides a 70MPa-grade low-temperature container steel plate for hydrogen energy storage and transportation and a manufacturing method of the 70MPa-grade low-temperature container steel plate, and the steel plate comprises the following components in percentage by weight: 0.15%-0.18% of C, 0.12%-0.16% of Si, 0.74%-0.98% of Mn, less than or equal to 0.01% of P, less than or equal to 0.01% of S, 1.12%-1.44% of Ni, 0.47%-0.75% of Cr, 0.01%-0.02% of V, 0.11%-0.19% of Mo, 0.022%-0.034% of N, 0.002%-0.0028% of La and the balance of Fe and inevitable impurities. The manufacturing method comprises the steps of smelting, continuous casting, four-stage efficient slab heating, two-stage rolling, two-stage cooling and heat treatment. The steel plate produced by the method has good obdurability matching and high and low temperature service performance, and the steel plate has excellent hydrogen-induced crack resistance, sulfide stress cracking resistance and stress corrosion resistance; and the steel plate has good wear resistance, and meets the manufacturing and application requirements of the high-performance steel plate for hydrogen energy storage and transportation.

The invention relates to a sulfide composite solid-state electrolyte membrane, a preparation method thereof and a solid-state battery, and belongs to the technical field of solid-state electrolyte materials. The preparation method comprises the following steps: mixing a component A, a component B and a solvent under anhydrous and anaerobic conditions, and carrying out a heating reaction to obtain a precursor solution containing a high-molecular polymer; mixing the sulfide solid electrolyte with the precursor solution, and adding a solvent to adjust the solid content to 25-60% to obtain electrolyte slurry; coating the electrolyte slurry on the surface of a base material, drying to form a film on the surface of the base material, and removing the base material to obtain a sulfide composite solid electrolyte film; wherein the mass ratio of the effective components in the sulfide solid electrolyte to the effective components in the precursor solution is (99.5-90): (0.5-10). The sulfide composite solid electrolyte membrane has relatively good flexibility, and good contact between the membrane and an electrode can be maintained, so that the interface resistance is reduced.

The invention provides a sulfide solid electrolyte and a preparation method and application thereof, and relates to the technical field of lithium ion batteries. The preparation method comprises the following steps: S1, carrying out dry ball milling treatment on raw materials Li2S, P2S5 and LiX according to a required stoichiometric ratio, so that the raw materials are amorphized; s2, adding a solvent into the non-crystallized raw material obtained in the step S1, and carrying out wet ball-milling treatment to obtain a precursor with the particle size of 0.05-0.5 mu m; s3, the solvent is removed from the precursor slurry, the sulfide solid electrolyte is obtained through solid-phase sintering, all the steps are carried out in an inert atmosphere, and X is a halogen element. According to the present invention, the non-crystallization of the raw material is achieved through the dry ball milling, the uniform precursor slurry with the small particle size is obtained by combining the wet ball milling, and the sub-micron / nano-scale pure phase electrolyte material can be obtained after the sintering treatment, such that the electrode / electrolyte interface contact is improved, the impedance is reduced, and the battery performance is significantly improved.

The invention discloses a polycrystalline positive electrode material for a sulfide all-solid-state battery, a preparation method of the polycrystalline positive electrode material and a secondary battery, the surface of a high-nickel polycrystalline positive electrode material is coated with a conductive polymer in a surface coating manner, and an inorganic electrolyte is dispersed in the conductive polymer. According to the polycrystal positive electrode material for the sulfide all-solid-state battery, the stress generated by expansion of the high-nickel polycrystal positive electrode material is effectively relieved by utilizing the elasticity of the conductive polymer, the mechanical strength and durability of the material are enhanced, and the problem that the high-nickel polycrystal positive electrode material is easy to crack in the circulating process is effectively solved. In addition, the interfacial compatibility between the high-nickel polycrystalline positive electrode material subjected to coating modification treatment and the electrolyte is improved, the coated conductive polymer also has excellent electronic conductivity, the inorganic electrolyte can realize lithium ion transmission on a polymer chain segment, and the combined action of the two can improve the internal grain boundary conductivity of the polycrystal, so that the rate performance is improved.

Solid electrolyte compositions and solid-state batteries are disclosed, which comprise a solid electrolyte layer including a sulfide-containing solid-state electrolyte material and a compound of Chemical Formula 1. The sulfide-containing solid-state electrolyte material includes but is not limited to Li6PS5Cl (“LPSC”), an LPS-based glass or glass ceramic of formula xLi2S·yP2S5, wherein x+y=1, or an argyrodite-based sulfide-based solid electrolyte or formula Li6PS5X, wherein X═Cl, Br, or I) or Li6-yPS5-yCl1+y, where y is <1. In some aspects, the compound of Chemical Formula 1 is sodium 3-mercapto-1-propanesulfonate (3M1P).

The invention discloses a preparation method of a W and Se co-doped sodium ion sulfide solid electrolyte, which comprises the following steps: weighing raw materials Na2S, Sb2S3, S and WS2 according to a stoichiometric ratio of Na3-xSb1-xWxS4-ySey, grinding and mixing uniformly, 0 < x < = 0.12, and 0 < y < = 0.15; carrying out ball milling to prepare electrolyte precursor powder, and adding a Se raw material according to a stoichiometric ratio in the ball milling process; pressing the electrolyte precursor powder into a sheet; sintering after vacuum sealing; and grinding the sintered product, and then carrying out ball milling again to obtain the product. The invention also discloses the W and Se co-doped sodium ion sulfide solid electrolyte prepared by the method and application. W and Se elements are introduced into Na3SbS4, W < 2 + > is oxidized into W < 6 + > by utilizing the oxidability of S, and the ionic conductivity is improved from 10 <-4 > order of magnitude to 10 <-2 > order of magnitude; therefore, the sodium ion sulfide solid electrolyte has ultrahigh ionic conductivity.

The invention discloses a composite positive electrode, a preparation method thereof and an all-solid-state battery. The composite positive electrode comprises a composite solid electrolyte and a positive electrode active material. The composite solid electrolyte comprises a first solid electrolyte and a second solid electrolyte, wherein the molecular structural formula of the first solid electrolyte is Li < 2 + > (4-a) < x > Zr < 1-x > A < x > Cl < 6-by > By; the second solid electrolyte is selected from one or more of sulfide solid electrolytes; the selection of the metal element A and the non-metal element B meets the condition that XIC * x + (1-x) * 1.687 is less than 1.6; and [(6-by) * 3.16 + y * Xp] / [(6-by + y) * (XIC * x + (1-x) * 1.687)] > = 1.9; wherein the valence state of the metal element A is + a, and the valence state of the non-metal element B is-b; xIC represents the electronegativity of the metal element A, and Xp represents the electronegativity of the non-metal element B. According to the invention, the material forming the composite positive electrode is selected based on the electronegativity of the contained elements, so that the stability and the electrical performance are improved.

The invention provides a pharmaceutical wastewater treatment process. The pharmaceutical wastewater treatment process comprises the following steps: A1, pretreatment, A2, adsorption treatment, A3, oxidation treatment and A4, filtration treatment. In the step A2, a composite adsorbent comprising the following raw materials: attapulgite, activated carbon, carbon nanotubes, 4-carboxyphenylboronic acid, polyethyleneimine, sodium dithiocarbamate, epoxy resin E-44, deionized water and modified nano zero-valent iron is used, and self-repairing is realized through dynamic chemical bonds such as boric acid ester bonds, imine bonds and thiol-disulfide bonds; the adsorbent can be self-repaired during microscopic damage, so that the service life is prolonged, and relatively high adsorption capacity is kept. In the step A3, a gel microsphere oxidant comprising the following raw materials: hydrogen peroxide, potassium persulfate, copper-iron sulfide, nitrogen-doped carbon quantum dots, sodium alginate powder, sodium polyacrylate and a phosphate buffer solution is used, and efficient degradation is realized through a synergistic mechanism of free radical oxidation, non-free radical oxidation and photocatalysis.

The invention belongs to the technical field of all-solid-state lithium batteries, and particularly relates to a densified sulfide all-solid-state battery composite positive electrode material and a preparation method and application thereof. The preparation method of the composite positive electrode material comprises the following steps: (1) raw material pretreatment: mixing a positive electrode active substance, a sulfide solid electrolyte and an additive according to a predetermined mass ratio under the protection of an inert atmosphere, and carrying out mechanical grinding to obtain composite positive electrode powder; the additive is Li3PO4 (lithium phosphate); (2) isostatic pressing pretreatment: performing hot isostatic pressing treatment on the composite positive electrode powder, and then controlling the cooling rate to cool to room temperature to obtain a densified composite positive electrode blank; (3) adding a conductive agent and a binder into the densified composite positive electrode blank, and mixing; the composite positive electrode material is obtained; the binder is formed by compounding nano-scale polytetrafluoroethylene and micron-scale polytetrafluoroethylene according to a mass ratio of 1: 2-1: 4.

The invention provides a method for measuring the oxidation rate of gold ore, and belongs to the technical field of process mineralogy. According to the method, the proportion of the unoxidized part (metal sulfide and crack) of the gold edge is obtained by measuring the contact length of the gold and the gold edge contact mineral, and the oxidation degree (the proportion of metal oxide and other gangue minerals) of the gold ore is obtained through conversion. Compared with traditional pretreatment modes such as crushing, ore grinding and ore dressing, the scheme does not destroy the original state of gold, and the test result is more accurate. Besides, the content proportion is represented by the proportion of the contact length of the edge contact mineral of the gold mineral and the gold, compared with the proportion of the test area, the error caused by the overlarge exposure area of the large-particle gold mineral can be weakened, the test result is more accurate, and the edge contact length of the gold and other minerals can also reflect the embedding state of the gold. The data measured by the testing method is closer to the actual production, and the definition of the gold ore oxidation rate is met.

The invention discloses a sulfide solid electrolyte-lithium-rich manganese-based interface construction method, a positive electrode material and an all-solid-state lithium battery, and the interface construction method comprises the following steps: 1) mixing a mixture containing a lithium-rich manganese-based layered oxide positive electrode, a niobium source and a boron source, and heating in an oxygen-containing atmosphere, the modified lithium-rich manganese-based layered oxide positive electrode material is obtained; and 2) ball-milling and mixing raw materials containing the modified lithium-rich manganese-based layered oxide positive electrode material and a sulfide solid electrolyte to obtain a sulfide solid electrolyte-surface modified lithium-rich manganese-based material, and forming a sulfide solid electrolyte-lithium-rich manganese-based interface. According to the sulfide solid electrolyte-lithium-rich manganese-based positive electrode interface constructed by the invention, boron and niobium elements are adopted for surface modification, and the lithium-rich manganese-based surface is modified, so that not only is the structural stability of the sulfide solid electrolyte-lithium-rich manganese-based positive electrode interface improved, but also the ionic conductivity of the interface is improved.

The invention discloses a sulfide solid electrolyte stable in wet air, a preparation method thereof and a battery, and belongs to the technical field of all-solid-state batteries, the sulfide solid electrolyte comprises the following raw materials in parts by weight: 20-100 parts of sulfide solid electrolyte and 1 part of metal halide component, the chemical formula of the sulfide solid electrolyte is Li < 6-x > PS < 5-x > Cl < 1 + x >, 0 < = x < = 0.6, the metal halide component comprises at least one metal halide, the chemical formula of the metal halide is MXn, n is greater than or equal to 2 and less than or equal to 4, M is one of Zr, Al, Zn, Sn, Sb and Bi, and X is one of F, Cl, Br and I. The metal halide and the sulfide solid electrolyte in a specific ratio are mixed, subjected to ball milling and then subjected to annealing treatment, and an in-situ doping coating layer is obtained on the surface of the sulfide solid electrolyte; and under the condition that the ionic conductivity of the sulfide solid electrolyte is slightly influenced, the wet air stability of the sulfide solid electrolyte is effectively improved.