This invention relates to the field of battery technology, and more particularly to a positive
electrode lithium replenisher, its preparation method, a positive
electrode sheet, and a
lithium battery. The aforementioned positive
electrode lithium replenisher includes a core and a shell, with the shell covering the surface of the core to isolate the core from the
side reaction environment. The core is a lithium-rich material, specifically at least one of Li5FeO4, Li5ReO6, and Li6CoO4. The shell is
cobalt boride. This core-shell structured positive electrode lithium replenisher with
cobalt boride as the shell effectively coats the core material, improves the air stability of the positive electrode lithium replenisher, reduces residual alkali, and thus enhances the battery's
energy density and cycle performance.