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413 results about "Optical stability" patented technology

Quantum dots having composition gradient shell structure and manufacturing method thereof

Provided are quantum dots having a gradual composition gradient shell structure which have an improvedluminous efficiency and optical stability, and a method of manufacturing the quantum dots in a short amount of time at low cost. In the method, the quantum dots can be manufactured in a short amount of time at low cost using a reactivity difference between semiconductor precursors, unlike in uneconomical and inefficient conventional methods where shells areformed after forming cores and performing cleaning and redispersion processes. Also, formation of the cores is followed by formation of shells having a composition gradient. Thus, even if the shells are formed to a large thickness, the lattice mismatch between cores and shells is relieved. Furthermore, on the basis of the funneling concept, electrons and holes generated in the shells are transferred to the cores to emit light, thereby obtaining a high luminous efficiency of 80% or more. The quantum dot structure is not limited to Group II-IV semiconductor quantum dots but can be applied to other semiconductors quantum dots, such as Group III-V semiconductors quantum dots and Group IV-IV semiconductors quantum dots. Also, the manufacturing method can be utilized in the development of semiconductor quantum dots having different physical properties, and in various other fields.
Owner:SEOUL NAT UNIV R&DB FOUND

Method for preparing polyacrylate/nano-SiO2 compound coating agent by using reactive emulsifier

The invention relates to a method for preparing polyacrylate/nano-SiO2 compound coating agent which is suitable for bottom layer coating in clothing leathers and instep leathers, by using a reactive emulsifier. The polyacrylate has excellent optical stability, chemical resistance and favorable adhesive property and is widely used as an adhesive, a coating film-forming agent, a functional film, and a medical polymer and in the fields of water treatment and the like, but polyacrylate emulsion has the defects of embrittlement at low temperature, stickiness and strength loss at high temperature, easy after tack and the like, which restrict the application range and the use value of the polyacrylate emulsion. In the invention, the polyacrylate/nano-SiO2 compound coating agent is prepared by substituting conventional emulsifier with reactive emulsifier by utilizing the nanometer effect of an inorganic nanometer material and synchronously adopting a conventional emulsion polymerization method and a sol-gel method. The compound coating agent prepared by the invention has fine granules, excellent adhesive force, good filling capacity, strong water resistance and flexible and transparent formed film, and meanwhile, the damages to the human body and the environment, which are caused by the use of large amount of emulsifiers, are reduced.
Owner:SHAANXI UNIV OF SCI & TECH

Process for producing fluorescent composite microgel hypersensitive to temperature and pH

The invention discloses a preparation method of fluorescent complex microgel which is sensitive to temperature and pH. The method comprises the technical steps of preparing a mixed surface active agent, preparing the oil phase of a template, preparing an emulsive liquid, preparing a water phase, preparing N-isopropyl acryl amide copolymerized methacrylic acid microgel, preparing turgid N-isopropyl acryl amide copolymerized methacrylic acid microgel, preparing a mixed liquid of Gamma-aminopropyl triethoxy silane and normal heptane, preparing a silicon dioxide polymer complex microballoon decorated by a surface deposited amino group, preparing a mixed liquid of fluorescein isothiocyanate and absolute ethyl alcohol as well as preparing the fluorescent complex microgel. In the invention, the fluorescein isothiocyanate with high quantum yield and good optical stability is adopted as fluorescent matter; the prepared fluorescent complex microgel is sensitive to temperature and pH; and the size of the prepared fluorescent complex microgel is in a micron range and is hard to be aggregated. The method has the advantages of reasonable design, practical technique and easy operation; moreover, reactions are carried out under normal temperature and the like; the method can be applied to the fields of controlled release of medicament, biological probe, chemical separation, and the like.
Owner:SHAANXI NORMAL UNIV

Ultrahigh-sensitivity fluorescent probe for detecting nitrogen monoxide

The invention relates to an ultrahigh-sensitivity fluorescent probe for detecting nitrogen monoxide. The ultrahigh-sensitivity fluorescent probe has the structural general formula in the original text. During preparation, firstly, 4-bromine-1, 8-anhydride naphthalene and o-nitro p-phenylenediamine with equal molar weights are used as raw materials, dissolved in ethylene glycol monomethyl ether and heated for reaction to obtain light yellow solid. Secondly, the light yellow solid is dissolved in anhydrous DMSO, primary amine is added into the anhydrous DMSO, the anhydrous DMSO is heated and refluxed, and reaction liquid is filtered in a sucking manner, depressurized and dried to obtain yellow solid. The yellow solid is dissolved in mixed liquid of tetrahydrofuran and methanol, and a yellow probe is obtained under catalysis of hydrogen and catalysts. Probe molecules have fine chemical and optical stability, good solubility and biological compatibility and high nitric oxide selectivity, and are free of interference of other active oxygen, active nitrogen and the like. Laser confocal imaging experiments indicate that the probe has fine cellular permeability, has no toxic and side effects on cells and organisms, and can be used for detecting protogenetic nitrogen monoxide in a high-sensitivity manner.
Owner:DALIAN UNIV OF TECH

Temperable three-silver low radiation coated glass and production technology thereof

The invention relates to temperable three-silver low radiation coated glass. The coated glass which comprises a glass body and a coating film is characterized in that: the glass body is a substrate; and the film structure of the coating film comprises, from inside to outside, a first dielectric combination layer, a first block protection layer, a first dielectric layer, a first silver layer, a second block protection layer, a first interval dielectric combination layer, a third block protection layer, a second dielectric layer, a second silver layer, a fourth block protection layer, a second interval dielectric combination layer, a fifth block protection layer, a third dielectric layer, a third silver layer, a sixth block protection layer and a second dielectric combination layer. The temperable three-silver low radiation coated glass disclosed in the invention adopts the unique film structure and a unique production technology, so a problem that middle and low radiation coated glass in the prior art cannot be well tempered is solved, and the coated glass which has the advantages of high visible light transmissivity, good photo-thermal ratio and optical stability, and good thermal insulation can satisfy various requirements of subsequent processing.
Owner:林嘉宏

Doped semiconductor nanocrystalline quantum dots having core-shell structure and preparation method thereof

The invention provides a doped semiconductor nanocrystalline quantum dot having a core-shell structure and a preparation method thereof. The quantum dot comprises a nanocrystalline core doped with Mn and a shell layer; the composition of the nanocrystalline core is MnzZn[1-z]SexS[1-x], and the composition of the shell layer is ZnSeyS[1-y], wherein x is greater than 0 or less than or equal to 1, y is greater than or equal to 0 and less than 1 and z is greater than 0 or less than or equal to 0.5; the dimension of the nanocrystalline core is 2-15 nm, and the dimension of the shell layer is 2-15 nm; the emission wavelength of the nanocrystalline quantum dot ranges from 590 to 630 nm. The fluorescence emission wavelength of the quantum dots is continuously adjustable in the range from 590 to 630 nm; as a result, the quantum dots cover the shortage of non-cadmium-doped nanocrystalline in emission wavelength, and have high fluorescence and quantum efficiency, as well as good air, temperature and optical stability; the quantum dots are good in absorption in blue and purple zones and have no self-absorption within other visible light wavelengths; the quantum dots contain no toxic metal and can be widely applied to the fields such as solid-stable lighting, solar cell, biological-medical detection and the like.
Owner:NANJING TECH CORP LTD

Preparation method of polyacrylic ester/hollow silicon dioxide nanometer composite leather finishing agent

The invention relates to a preparation method of a polyacrylic ester/hollow silicon dioxide nanometer composite leather finishing agent. The polyacrylic ester is a kind of film forming matters most extensively applied in the leather finishing material, the polyacrylic ester has excellent optical stability, chemical resistance, extensibility and good cohesiveness, while the polyacrylic ester forms a layer of dense thin film on the leather surface to severely block the passage through which the water vapor emitted by a human body disperses to outside, so that the sanitary performance of a leather product is greatly affected. According to the invention, polystyrene microspheres are used as a template to prepare hollow silicon dioxide nanometer particles, and the hollow silicon dioxide nanometer particles are mixed with the polyacrylic ester to prepare the polyacrylic ester/hollow silicon dioxide nanometer composite leather finishing agent. Compared with the pure polyacrylic ester leather finishing agent, the composite leather finishing agent prepared by the preparation method has the advantages that the water vapor permeability is improved by 82.6%, the tensile strength is increased by 37.72% and the elongation at break is increased by 11.09%.
Owner:SHAANXI UNIV OF SCI & TECH

Donor-acceptor type fluorenyl nanometer grid material, preparation method and application thereof

The invention discloses a donor-acceptor type fluorenyl nanometer grid material, a preparation method and application thereof. The nanometer grid material is of a square-ring-shaped rigid structure formed through alternative arrangement of fluorenyl ramification regarded as electron donor units and electron acceptor units. The preparation method comprises the following steps that a precursor with tertiary alcohol and aromatic nucleus terminal based hydrogen inhibitor dual binding sites is dissolved in organic solvent; at the room temperature, a catalyst is added, and stirring and reacting are conducted; and the reaction is conducted for 5 min-12 h, and products are obtained through chromatogram column separation. The donor-acceptor type fluorenyl nanometer grid material has the advantages that the compounding method is modularized, extensibility and stability of thermology, electrochemistry and photology are high; dependency of thin film solvent is reduced; large-area soluble processing is achieved; the size of apertures is accurately regulated and controlled; and accurate regulation an control of band gaps and energy level arrangement are achieved. The donor-acceptor type fluorenyl nanometer grid material has potential application prospects in the fields of photoelectric function materials of organic solar cells, storage and memory resistor, sensing, detecting and the like.
Owner:NANJING UNIV OF POSTS & TELECOMM

Phosphorescent dye parent materials with tetrahedral structure, and application thereof in electroluminescent device

The invention belongs to the technical field of organic electroluminescence material, in particular to a series of phosphorescent dye parent materials with a tetrahedral structure, and the application of the materials in an electroluminescent device. The phosphorescent dye parent materials can be used for a panel display device, a light-emitting diode (LED) and an electronic imaging device. The phosphorescent dye parent material has excellent electronic and hole transmission properties, can be independently used as a luminous layer and a current carrier transmission layer, and can be used as matrix and doped with other fluorescent or phosphorescent dyes. The compound has stronger fluorescent property in a state of solution or solid, can be used for forming an even film, and has better optical stability and thermal stability. R1, R2, R3 and R4 are respectively connected with phenyl group by a single bond, and are respectively selected from one of hydrogen, alkyl group, alkoxy, nitryl, hydroxyl, cyano-group, benzene cyano-group, amino, sulfydryl, halogen, diphenyl phosphoryl, furan, thiophene, pyrrole, pyridina, diazine, triazine, pyran, quinoline, benzpyrole, carbazole, aniline or phenothiazine, and X is C or Si.
Owner:JILIN UNIV
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