The invention discloses near ultraviolet laser blue luminescent glass ceramic, which is oxyfluoride glass ceramic doped by bivalent europium ion comprising the following components in mol percentage: 45 to 60 percent of SiO2, 0 to 25 percent of Al2O3, 0 to 10 percent of Na2O, 0 to 10 percent of NaF, 0 to 20 percent of ZnF2, 10 to 50 percent of BaF2, 0.5 to 10 percent of EuF3, and 0 to 3 percent of clarificant and/or fluxing agent. A preparation method comprises processes of high-temperature melting in a reducing atmosphere and crystallization heat treatment, wherein trivalent europium ion is reduced to the bivalent europium ion. The method is simple, has no pollution and has low cost. The glass ceramic has wide excitation spectra in a near ultraviolet region (between 350 and 420 nanometers), can produce blue luminescence under excitation of GaInN near ultraviolet light LED, and has the characteristics of high luminosity, ultraviolet radiation resistance, and good chemical stability and thermal stability.