The invention relates t a phosphate base optical glass mixed with ytterbium and bismuth and a manufacturing method of the phosphate base optical glass. The compositions and mol percentage of the glass is that: P2O5(50-80), Al2O3(5-30), Ta2O3(0-5), Ga2O3(0-5), Y2O3(0-5) , Li2O(0-30), Na2O(0-15), K2O(0-5), ZnO(0-15), MgO(0-40), CaO(0-30), SrO(0-15), BaO(0-15), TiO2(0-5), ZrO2(0-5), SiO2(0-20), Bi2O3(0.01-5), Yb2O3(0.01-15); wherein the figures in the bracket refer to the selection range of mol percentage of the corresponding oxide of the compositions. Under the pump of 405nm, 532nm, 808nm and 980nm, higher near infrared ultra wideband fluorescence can be obtained; and under the pump of 980nm, the glass fluorescence emission has a remarkable reinforced effect and is hopeful to be applied in fields such as optical amplifier, superpower laser and tunable laser.