1928 results about "Acetamide" patented technology

The invention relates to a preparation method of an amino-functionalized metal organic framework material and application of the prepared material to separation of CO2 / N2 and CO2 / CH4. The preparation method comprises the following steps: dissolving adenine and copper nitrate trihydrate in N, N '-dimethylacetamide to obtain a first mixed solution; dissolving carboxylic acid and potassium carbonate in deionized water to obtain a second mixed solution; and adding the second mixed solution into the first mixed solution, carrying out stirring reaction, and carrying out vacuum drying on an obtained solid product to obtain the amino-functionalized metal organic framework material. The amino-functionalized metal organic framework material prepared by the invention has high CO2 adsorption selectivity and adsorption capacity, and also has good acid-resistant, alkali-resistant and water-resistant stability. The amino-functionalized metal organic framework material prepared by the preparation method disclosed by the invention is applied to industrial CO2 adsorption separation and has an excellent separation effect.

The invention discloses a preparation method of a reverse osmosis membrane and the reverse osmosis membrane. The preparation method comprises the following steps: (1) adding polyethersulfone into N, N-dimethylacetamide in a heating and stirring state, and stirring for a period of time after charging is completed, so as to obtain a mixed solution; (2) cooling the mixed solution, continuing to add a pore-foaming agent, and stirring for a period of time after charging is completed to obtain a precursor solution; (3) performing vacuum defoaming treatment on the precursor solution to obtain a membrane casting solution; (4) loading the membrane casting solution on a carrier, and then carrying out gel bath treatment to obtain a base membrane; and (5) performing polyamide treatment on the surface of the base membrane to obtain the reverse osmosis membrane. The preparation method disclosed by the invention is simple in process and low in material cost, and the obtained reverse osmosis membrane has more uniform and more through-type pore structures, higher separation efficiency, more excellent chemical stability and better mechanical properties, can adapt to higher operation pressure, and can continuously and stably operate at higher flux under high pressure.

The invention belongs to the field of photocatalytic materials, and particularly relates to a high-entropy sulfide and a preparation method and application thereof. The high-entropy sulfide is granular, the molecular general formula is (MnaFebCocCudZe) xS, x is equal to 1, and the atomic ratio of Mn to Fe to Co to Cu to Zn is a: b: c: d: e of (1-2): (1-2): (1-2): (1-2): (1-2): (1-2): (1-2). The preparation method comprises the following steps: S1, dissolving metal salt in a mixed solvent of isopropanol and glycerol according to the atomic ratio of metal elements, and carrying out solvothermal reaction to obtain a precursor; and S2, dispersing the precursor in ethanol, adding thioacetamide as a sulfur source, and carrying out solvothermal reaction to obtain the high-entropy sulfide. The high-entropy sulfide disclosed by the invention is used as a photocatalytic material and shows excellent photocatalytic performance.

The invention discloses a photocatalytic preparation method of a deuterated acetamide compound, and belongs to the technical field of synthesis of deuterated acetamide compounds. According to the technical scheme, the method is characterized in that a dichloroacetamide compound is used as a raw material, D2O is used as a deuterium source, and the dideuterated acetamide compound is synthesized through reaction under the room-temperature nitrogen illumination condition; according to the method, dichloroacetamide compounds are taken as raw materials, D2O is taken as a deuterium source, deuterated dichloroacetamide compounds are synthesized through room-temperature reaction, and monodeuterated or trideuterated acetamide compounds are respectively obtained through photocatalytic reaction according to different solvents (H2O or D2O) added into a system. The preparation method provided by the invention has the advantages of simple and safe operation, mild reaction conditions, no transition metal participation, cheap and easily available deuterium source, high deuteration rate, controllable number and the like.

The invention discloses a synthesis method of a covalent organic framework crystal material at normal temperature, and belongs to the technical field of covalent organic framework synthesis. The synthesis method of the covalent organic framework crystal material at normal temperature comprises the following steps: S1, dissolving an ammonia monomer in a first solvent to obtain an ammonia monomer solution; dissolving an aldehyde monomer in a second solvent to obtain an aldehyde monomer solution; the first solvent or the second solvent is one or two of N, N-dimethylacetamide and dichloromethane; s2, mixing and reacting the ammonia monomer solution, the aldehyde monomer solution, a catalyst and a third solvent to obtain the covalent organic framework crystal material. According to the synthesis method provided by the invention, the covalent organic framework crystal material can be synthesized at a relatively low temperature within a short time.

The invention belongs to the field of photocatalysts, and discloses a MoS2 / CdS composite photocatalyst, which is a composite material prepared by taking cadmium acetate as a cadmium source, thioacetamide as a sulfur source and ethylenediamine as a reaction solvent, synthesizing a CdS nanorod through a one-step hydrothermal method, and growing a MoS2 promoter at one end of the CdS nanorod. The invention also discloses an application of the MoS2 / CdS composite photocatalyst in hydrogen production by decomposing water molecules under an illumination condition. The MoS2 cocatalyst with an electron harvesting agent function is grown at one end of the CdS nanorod, so that the performance is improved, and the use of noble metals is avoided. The MoS2 / CdS composite photocatalyst disclosed by the invention has excellent catalytic activity and stable hydrogen evolution activity under a simulated sunlight condition.

The invention discloses a fluralamide moxidectin drop and a preparation method thereof, and relates to the technical field of veterinary drugs. The drop is prepared from the following components in parts by weight: 26 to 26.5 parts of fluralan, 1.32 parts of moxidectin, 0.10 part of butylated hydroxytoluene, 29.5 to 30.5 parts of dimethylacetamide, 19.5 to 20 parts of tetrahydrofuran polyethylene glycol ether, 13 to 13.5 parts of diethyl toluamide, 8.5 to 9.3 parts of acetone and 1.0 to 1.5 parts of ethanol. The invention has the effects of improving the stability, permeability and lasting effect of the medicine.

The invention discloses a ternary chalcogenide heterojunction catalytic material as well as a synthesis method and application thereof, and belongs to the field of photocatalysts. The synthesis method comprises the following steps: dissolving ZnCl2 and InCl3. 4H2O in an ethanol water solution, stirring, adding thioacetamide into the mixed solution, continuously stirring, carrying out hydrothermal reaction, cooling, centrifuging and washing on the solution, and drying to constant weight to obtain a material Zn2In2S5; the preparation method comprises the following steps: dispersing Zn2In2S5, thiourea, 1-hexadecyl-3-methylimidazole bromide and Bi (NO3) 3.5 H2O in absolute ethyl alcohol, carrying out ultrasonic dispersion, carrying out a hydrothermal reaction on the mixture, cooling, centrifuging, washing, and drying to constant weight to obtain the powder material Zn2In2S5 / Bi19S27Br3. The photocatalytic activity is greatly improved by constructing the heterojunction, pollutant degradation is achieved, and the photocatalyst has the advantages of being good in stability and capable of being repeatedly used.

The invention discloses a microporous breathable fabric as well as a preparation method and application thereof, and relates to the technical field of fabric treatment. The invention discloses a preparation method of a microporous breathable fabric, which comprises the following steps: coating the surface of a base cloth with a polyurethane coating agent, and drying to obtain the microporous breathable fabric, the polyurethane coating agent is prepared from the following raw materials in parts by weight: 100 parts of organic silicon modified polyurethane emulsion, 8 to 11 parts of N, N-dimethylacetamide, 2 to 2.5 parts of n-caprylic alcohol, 5 to 8 parts of a foam homogenizing agent and 1 to 3 parts of a thickening agent PTF; the organic silicon modified polyurethane emulsion is obtained by crosslinking polyurethane with carboxymethyl cellulose through silica sol; the polyurethane coating agent prepared by taking the organic silicon modified polyurethane emulsion as the base material is coated on the surface of the base cloth, so that the fabric has high waterproof performance and also has high air permeability and moisture permeability; the microporous breathable fabric prepared by the invention is applied to the field of outdoor sportswear, and comfortable wearing experience is provided.

The invention discloses a preparation method of near-infrared response thermoelectric temperature-sensitive supramolecular injectable hydrogel. The preparation method comprises the following steps: dissolving bismuth nitrate pentahydrate and thioacetamide in deionized water to react to obtain Bi2S3 nano-particles, and putting the Bi2S3 nano-particles into a tannic acid TA aqueous solution to react to obtain Bi2S3 coated TA nano-particles; the preparation method comprises the following steps: adding NIPAM, VI, disulfiram and azodiisobutyronitrile into an organic solvent, dissolving to obtain a mixed solution, and heating to obtain a supramolecular temperature-sensitive polymer PNV; sA, TA, PNV and Bi2S3 at TA are dissolved in normal saline, an obtained mixed solution is injected into a mold, a metal salt solution is sprayed, and the thermoelectric temperature-sensitive supramolecular injectable hydrogel is obtained through a reaction. The invention also discloses application of the injectable hydrogel obtained by the preparation method in preparation of products for repairing skin wounds. The injectable hydrogel provided by the invention completes active contraction and thermal-electric stimulation under single near-infrared energy input, and can be used as a photo-thermal platform to relieve bacterial load and promote repair of infected wounds.

The invention relates to the field of photoelectrocatalysis, and provides a preparation method and application of a cerium-based double-layer composite material coated with indium zinc sulfide, and the preparation method comprises the following steps: dispersing Ce (IV)-MOF in DMF and methanol, adding a hydroxyl-containing organic ligand, carrying out room temperature ultrasonic treatment to obtain modified MOF, dispersing the modified MOF in water and glycerin, adding a zinc salt and an indium salt, stirring, adding thioacetamide, stirring, filtering, washing, and drying to obtain the cerium-based double-layer composite material coated with indium zinc sulfide. And heating to obtain the product indium zinc sulfide coated cerium-based double-layer composite material. According to the invention, an ultrasonic-assisted MOF ligand exchange technology is utilized, so that an MOF regular octahedral framework structure is well maintained; the ZnIn2S4 material is compounded through in-situ growth of ZnIn2S4, the compounding synthesis temperature and a solution system are optimized, a ZnIn2S4 double-layer coating structure is obtained, and the yield and dispersity of ZnIn2S4 are improved. And the prepared ZnIn2S4 / MOF composite material has excellent reaction efficiency and stability of photoelectrocatalytic hydrogen production.

The invention discloses a fluoride-free waterproof sound-transmitting film and a preparation method thereof, and the fluoride-free waterproof sound-transmitting film comprises the following components in percentage by mass: 30-40% of a fluoride-free polymer; 4.5%-11.5% of a fluoride-free waterproof agent; 0.5%-3.5% of a cross-linking agent and 45%-65% of a solvent; the solvent is a mixed solvent of N 'N-dimethylformamide, N' N-dimethylacetamide, acetone and ethyl acetate, and the mass ratio of the amide solvent in the mixed solvent is 60%-85%; the preparation method of the fluoride-free waterproof sound-transmitting film comprises the following steps: preparing a spinning solution; carrying out electrostatic spinning by utilizing electrostatic spinning equipment to obtain a continuous and uniform nano spinning membrane; the method comprises the following steps: uniformly depositing nanofibers on a nano spinning film base material, and carrying out post-treatment to obtain a finished product of the fluoride-free waterproof sound-transmitting film, the fluorine-free safe and healthy product with good water resistance and air permeability, high rebound resilience and excellent acoustic performance is successfully prepared through selection of raw materials, preparation of a spinning solution, spinning process parameters and fine regulation and control of post-treatment conditions.

The invention discloses a polyimide and epoxy resin composite modified fluorocarbon resin coating and a preparation method thereof, and the polyimide and epoxy resin composite modified fluorocarbon resin coating comprises the following components in percentage by weight: 0.4-0.8% of monomer diamine, 0.4-0.8% of monomer dianhydride, 60-70% of N, N-dimethylacetamide, 10-20% of epoxy resin, 0.2-0.5% of epoxy curing agent, 1-2% of fluorocarbon resin curing agent and 15-25% of fluorocarbon resin. The preparation method comprises the following specific steps: reacting monomer diamine and dianhydride in N, N-dimethylacetamide, sequentially compounding with epoxy resin and an epoxy curing agent to obtain a composite modifier, and adding the composite modifier and a fluorocarbon resin curing agent into a fluorocarbon resin solution to obtain the polyimide and epoxy resin composite modified fluorocarbon resin coating. Compared with an existing fluorocarbon resin coating, the performance of the fluorocarbon resin coating is greatly improved in the aspects of mechanical performance, heat resistance, adhesive force and the like.

The invention relates to a perovskite solution, a preparation method and application thereof, and a perovskite battery. The perovskite solution comprises a perovskite precursor and an additive, the additives are dibasic acid ester, nylon acid diisobutyl ester, iodobenzene diacetic acid, diisopropanolamine, diethanol amine, diisodecyl adipate, dibutyl adipate, dimethylacetamide, dioctyl adipate, diisobutyl glutarate, dimethyl sebacate, diisobutyl adipate, diisobutyl succinate and triethyl citrate; and at least one of tributyl citrate. According to the perovskite solution disclosed by the invention, the bromide ion-free or low-bromide ion perovskite precursor can form a black-phase film with good stability by adding the additive, so that the photoelectric conversion efficiency of a perovskite photovoltaic device is improved.

The invention relates to the technical field of layered composite fabrics, in particular to a bio-based antibacterial fiber fabric and a preparation method thereof. The preparation method comprises the following steps: carrying out a reaction on diisocyanate, polyether polyol, bio-based polyester polyol and hexamidine dihydroxyethyl sulfonate in N, N-dimethylacetamide, so as to obtain a polyurethane prepolymer solution; 2-(4-aminophenyl)-5-aminobenzimidazole and amino-modified nano-zinc oxide are sequentially added into the polyurethane prepolymer solution for a reaction, a prepared polyurethane spinning solution is subjected to dry spinning to prepare polyurethane fibers, and then the polyurethane fibers are sequentially spun into yarn and fabric; the bio-based nylon is subjected to melt spinning to obtain bio-based nylon fibers, and the bio-based nylon fibers are sequentially spun into yarns and fabrics; the bio-based antibacterial fiber fabric is prepared by taking a polyurethane fabric as an inner-layer fabric and taking a bio-based chinlon fabric as an outer-layer fabric, and the fabric is good in antibacterial performance and moisture absorption performance.

The invention provides a method for promoting acquisition of clean fuel by light / sound concerted catalytic degradation of waste plastics and upgrading and conversion thereof, which comprises the following steps: uniformly mixing g-C3N4, cadmium acetate and thioacetamide according to a predetermined proportion, pouring into a reaction kettle, placing in a high-temperature oven for a predetermined time, centrifuging, cleaning and drying to obtain a catalyst, the method comprises the following steps: loading a catalyst on the surface of aerogel, hydrogel or non-woven fabric to obtain an MTSJA-loaded catalyst, treating waste plastic with NaOH, adding the MTSJA-loaded catalyst, stirring under irradiation of a xenon lamp, starting ultrasound for reaction, and carrying out light / sound synergistic catalytic degradation on the waste plastic. According to the method, energy consumption is not needed, toxic and harmful gas is not generated, the purposes of energy conservation and environmental protection can be achieved, meanwhile, carbon dioxide in water can be catalytically reduced to generate clean energy such as methane in the process of degrading the waste plastic, and further obtaining of the energy is promoted.

The invention discloses a catalytic material for self-circulation photocatalytic Fenton and a preparation method thereof, and relates to the technical field of catalytic materials, the method comprises the following steps: adding thioacetamide into a manganese chloride solution, mixing, stirring, adding ammonia water, and reacting at 180-200 DEG C for 18-24 hours to obtain alpha-MnS; the preparation method comprises the following steps: dispersing alpha-MnS in an ethanol solution, then adding thiourea, stirring and mixing, then soaking the foam iron-nickel in the mixed solution, carrying out ultrasonic treatment, and finally reacting for 6-14 hours at 120-140 DEG C to obtain the catalytic material for self-circulation photocatalytic Fenton. The invention also discloses the catalytic material for the self-circulation photocatalytic Fenton, which is prepared by the method. The catalytic material has efficient self-circulation photo-Fenton performance, and has great application value in pollutant degradation and wastewater treatment.

The invention discloses a superfine high-strength meta-position aramid fiber and a preparation method thereof, and the superfine high-strength meta-position aramid fiber is obtained by adjusting the type of a wet spinning coagulating bath and reducing the temperature of the coagulating bath to realize super-stretching. Ethyl acetate and dimethylacetamide are used as a coagulating bath, and meanwhile, the temperature of the coagulating bath is reduced, so that the coagulating speed of the fiber in the coagulating bath is slowed down, the intermolecular force of the fiber is stronger, a more stable network gel state is formed, and very excellent stretchability is achieved. The meta-position aramid fiber prepared by the method has the advantages that the diameter is as small as 1.43 mu m, the tensile rate can reach 8000 times, the breaking strength reaches 1332 MPa, and the elongation at break is more than 20%.

The invention discloses a method for synthesizing a Mn0. 43Cd0. 57S / Cu2MoS4 photocatalyst by adopting a solvothermal method, and belongs to the technical field of catalysts. The preparation method comprises the following steps: preparing copper molybdenum sulfide by using cuprous oxide as a template, synthesizing copper molybdenum sulfide with high purity and good crystallinity by combining a solvothermal method, preparing manganese cadmium sulfide by using manganese acetate, cadmium acetate, sodium hydroxide and thioacetamide as raw materials, adding copper molybdenum sulfide before a hydrothermal reaction, successfully modifying the manganese cadmium sulfide by constructing a heterojunction, and preparing the copper molybdenum sulfide modified manganese cadmium sulfide. The Mn0. 43Cd0. 57S / Cu2MoS4 photocatalyst is synthesized, and the photocatalytic hydrogen production rate of the cadmium manganese sulfide is improved. Moreover, the hydrogen production rate of the Mn0. 43Cd0. 57S / Cu2MoS4 photocatalyst prepared by the invention can reach 8233 mu mol / (g.h), which is 2.08 times of the hydrogen production rate of pure cadmium manganese sulfide, and 1.24 times of the hydrogen production rate of cadmium manganese sulfide loaded with 1% platinum.

The invention provides a synthesis method of (S)-3-aminobutyronitrile, which specifically comprises the following steps: (1) addition of diketene and ammonia to prepare acetoacetamide; (2) performing an enzyme catalytic reaction on the acetoacetamide obtained in the step (1) in the presence of transaminase, and purifying after the reaction is completed to obtain (S)-3-aminobutanamide; and (3) dehydrating the (S)-3-aminobutanamide obtained in the step (2) to obtain the (S)-3-aminobutyronitrile. According to the synthesis method, the synthesis route is simplified, the production efficiency of the (S)-3-aminobutyronitrile is improved, industrial three wastes are reduced, the use of highly toxic substances is avoided, the cost reduction and benefit improvement in the industrial amplified production are facilitated, and the whole route embodies the value of green chemical synthesis.

The invention relates to the technical field of nano-generators, in particular to a triboelectric material of nano-porous composite fibers and a preparation method and application of the triboelectric material of the nano-porous composite fibers, and the preparation method comprises the following steps: adding polyvinylidene fluoride and perfluoroethylene propylene copolymer nanoparticles into a mixed solvent of N, N-dimethylacetamide / acetone; uniformly mixing to obtain a polyvinylidene fluoride / perfluoroethylene propylene copolymer nanoparticle spinning emulsion; and carrying out electrostatic spinning on the polyvinylidene fluoride / perfluoroethylene propylene copolymer nanoparticle spinning emulsion to obtain the triboelectric material. The triboelectric material prepared through the method is a high-charge-density super-hydrophobic nano-generator material based on electrostatic spinning, the electrostatic spinning porous composite fiber material is used as a friction medium layer, high surface charge, hydrophobicity and fouling resistance are achieved, and the performance of a flexible solid-liquid interface nano-generator is improved.

The present disclosure relates to pharmaceutically acceptable salts, cocrystals, and crystalline forms thereof, of a compound which is N—((S)-1-(3-(4-chloro-3-(methylsulfonamido)-1-(2,2,2-trifluoroethyl)-1H-indazol-7-yl)-6-(3-methyl-3-(methylsulfonyl)but-1-yn-1-yl)pyridin-2-yl)-2-(3,5-difluorophenyl)ethyl)-2- ((3bS,4aR)-5,5-difluoro-3-(trifluoromethyl)-3b,4,4a,5-tetrahydro-TH-cyclopropa[3,4]cyclopenta[1,2-c]pyrazol-1-yl)acetamide, which is useful in the treatment of a Retroviridae viral infection including an infection caused by the HIV virus.

The invention discloses an electrolyte additive, an aqueous electrolyte and a zinc-based energy storage device. The electrolyte additive comprises an azo organic matter with at least one functional group of carboxyl, acetamido, carbonyl, sulfonate radical, phenolic hydroxyl, ammonia radical or methoxyl and salt of the azo organic matter. The electrolyte additive can improve the stability and the service life of the zinc-based energy storage device.

To provide: a cleaning fluid having improved removability of stains due to impurities: and a cleaning method using the cleaning fluid.SOLUTION: Provided is a cleaning fluid, comprising a solvent and a metal remover. The cleaning fluid includes two or more kinds of solvents, the distance (HSP distance) between the Hansen solubility parameter of the cleaning fluid and the Hansen solubility parameter of dimethylacetamide is 1.0 or less, and the content of metal impurities is 0.1×10-9 pts.mass or more to 102×10-6 pts.mass or less relative to 100 pts.mass in total of the solvent and the metal remover.SELECTED DRAWING: None

The present invention relates to the field of the preparation of polyurethane elastic fibers, and relates to a preparation method for a bio-based polyurethane elastic fiber, comprising: preparing polyether polyol from sucrose, glycerol, dimethylamine and propylene oxide; adding a solvent, i.e., N,N-dimethylacetamide, and polyether polyol and polyisocyanate into a reaction tank, and adding p-Toluenesulfonyl semicarbazide and aluminum methylenebis(2,4-di-tert-butylphenoxy) phosphate to prepare a spinning solution; and subjecting the spinning solution to spinning and oil application by means of dry spinning technology to obtain the bio-based polyurethane elastic fiber. The present invention ensures that the properties of polyurethane elastic fibers do not deteriorate or are partially enhanced, while the cost and performance advantages are achieved.

The invention provides a method for preparing high-purity hafnium tetrachloride by wet extraction and separation, which comprises the following steps: stirring and leaching hafnium alloy waste serving as a raw material by using HNO3 and HF mixed acid, then adding thioacetamide, adjusting the pH value to 4-5, stirring and filtering; compounding tributyl phosphate, trioctylphosphine oxide and sulfonated kerosene to obtain a composite extracting agent, and stirring and mixing to form a homogeneous organic phase; in a hydrochloric acid medium, controlling the volume ratio of an organic phase to a water phase to be (2.5-3.5): 1, carrying out three-stage counter-current extraction, and standing for phase splitting; the extracted organic phase passes through an adsorption column filled with iminodiacetic acid modified silica gel; and carrying out reverse extraction by using a hydrochloric acid solution, and then carrying out reduced pressure evaporation concentration, cooling crystallization and dehydration to obtain hafnium tetrachloride. According to the method, the zirconium and hafnium separation efficiency in the hafnium tetrachloride preparation process is improved, and the problem that the content of zirconium and hafnium impurities in the product is too high is solved.

The invention discloses a preparation method of an MOF-on-MOF material, and belongs to the technical field of electrocatalysts.The preparation method comprises the steps that firstly, nickel acetate tetrahydrate and terephthalic acid are added into a mixed solvent composed of deionized water and N, N-dimethylacetamide, stirring reaction is conducted at the temperature of 140-160 DEG C, and Ni-MOF is synthesized; mixing and dissolving ferric nitrate nonahydrate and cobalt nitrate in a molar ratio of 1: 5 in deionized water, then adding a sodium acetate aqueous solution, and synthesizing a Fe2Co (mu3-O) cluster after stirring reaction; and then adding the Ni-MOF and the Fe2Co (mu3-O) cluster into deionized water, carrying out ultrasonic treatment, carrying out solid-liquid separation, and washing and drying a solid product to obtain the Ni-MOF / Fe2Co (mu3-O) cluster. Compared with an existing method, the method is easy to operate and low in cost, and the prepared MOF-on-MOF material has excellent electrocatalytic activity and stability in an electrocatalytic oxygen evolution reaction and is particularly suitable for being used in the field of hydrogen production through water electrolysis.

The invention relates to a nitrogen-containing heterocyclic compound as well as a preparation method and application thereof, belongs to the technical field of heterocyclic compound synthesis, and solves the problems of low reaction efficiency and high energy consumption caused by the fact that an existing method for synthesizing an indole maleimide derivative needs to be carried out step by step. The preparation method comprises the following steps: step 1, adding indoleacetamide and a nucleophilic reagent into a mixed solution, and reacting; 2, performing post-treatment to obtain a nitrogen-containing heterocyclic compound; the mixed solution comprises alkali, an additive and an organic solvent; the alkali comprises one of triethylamine (Et3N), N, N-diisopropylethylamine, pyridine and 1, 8-diazabicyclo [5.4. 0] undec-7-ene, and the alkali comprises one of 1, 8-diazabicyclo [5.4. 0] undec-7-ene.

The invention relates to a nickel sulfide / cadmium sulfide / sulfur-doped graphite-like carbon nitride double-heterojunction composite photocatalyst and a preparation method thereof, and belongs to the technical field of photocatalysis. S-doped g-C3N4 nanosheet powder, nickel chloride hexahydrate, cadmium acetate, thioacetamide, cetyltrimethylammonium bromide and polypyrrole are uniformly mixed in ammonia water; the molar ratio of the nickel chloride hexahydrate to the cadmium acetate to the thioacetamide is (1-5): (1-6): (2-12); the precursor solution is subjected to heat preservation treatment at the temperature of 120-180 DEG C to obtain a reaction solution, precipitates in the reaction solution are washed and then dried, separation and transmission of photogenerated charges are effectively promoted, a rapid charge transfer way is provided for rapid migration of electrons-holes in the catalysis process through a double-heterogeneous interface, and therefore the purpose of accelerating separation of the photogenerated charges is achieved; finally, the photocatalytic hydrogen evolution activity of the g-C3N4 can be obviously improved.