9715results about How to "Raw materials are cheap and easy to get" patented technology

The invention relates to a preparation method of a metal organic framework based composite phase-change material. The method comprises the steps that a metal organic framework material substrate is prepared selectively; hole diameter size design and hole channel polarity regulation and control are performed on the substrate according to the size and the kind of a core material, so that a phase-change core material to be loaded is matched better; the soluble phase-change core material is prepared into a solution; a metal organic framework material is dispersed in the prepared phase-change material solution; a phase-change material is adsorbed by utilizing an extra-large specific surface area and a nano hole channel structure of the metal organic framework material; drying is performed; and then the metal organic framework composite phase-change material with a shaping effect is obtained. According to the method, a novel metal organic framework based composite phase-change material is developed; the prepared metal organic framework based composite phase-change material can effectively avoid leakage and the like, and has the advantages of adjustable nano hole structure and wide core material selection range; the method is simple in technology and mild in reaction condition, and is suitable for scale production; and a raw material is cheap and easy to obtain.

The invention discloses a hydrothermal synthesis method of lithium-ion battery anode material of lithium iron phosphate, relating two kinds of metal phosphate. The steps are as follows: lithium source and phosphorus source are dissolved in water or mixed with water, and added into the reaction autoclave, the quaternary cationic surfactants and the alkylphenols polyoxyethylene ethers nonionic surfactant is also added into the reaction autoclave, the air in the dead volume of the autoclave inside is purged by the inert gas, the autoclave is sealed and heated to 40-50 DEG C with stirring, a feed valve and an exhaust valve are opened, pure ferrous salting liquid is added into the autoclave, and then the autoclave is sealed for the reaction of the material at 140 to 180 DEG C for 30 to 480 minutes; the mixture ratio of the invention is set as follows: the molar ratio of Li, Fe and P is 3.0-3.15:1:1.0-1.15, and then the resultant is filtered, washed, dried and carbon-coated, thus the lithium iron phosphate is obtained. The lithium iron phosphate which is produced by the invention has the advantages that: the electrochemical performance is excellent, the particle size distribution of which the D50 is between 1.5 um to 2 um is even, the phase purity is above 99 percent and the electronic conductivity of the material is improved.

By using the soluble salt of transition metalz Zn, Cd, Pb, Mn, Co, Ni, Cu, Ag, Sb and Bi, selenious acid or its solutl salt, or antimonous acid or its soluble salt as raw material, and hydrazine hydrate, sodium borohydride, potassium borohydride, hydroxylamine or hydrazine sulfate as reductant, and through hydrothermal reduction reaction at 100-200 deg.c in a sealed container for 2 hr to 5 days, selenides or tellurides of the said metals as semiconductor material may be synthesized. Unlike available synthesis process, which needs high temperature, toxic feedstock and complex technological course, the present invention has the advantages of low-cost material, simple apparatus, easy control, good technological reproducibility, stable product quality, etc.

The invention belongs to the field of material science and particularly relates to a graphene oxide/cellulose compound material as well as a preparation method and application of the material. The compound material is prepared by mixing graphene oxide suspension and alkaline solution of cellulose, and forming a compound structure of the graphene oxide and the cellulose under the action of mechanical stirring, shearing, ultrasonic or the like. In the preparation method, raw materials are cheap and easy to obtain, a water system is simple and free of pollution, equipment is simple and low in cost, and the industrial preparation is easy to realize; and the prepared compound material has the properties of fiber and the graphene oxide and is widely applied.

The invention provides a method for preparing normal propyl alcohol by glycerol hydrogenation, wherein glycerite or biodiesel byproduct glycerol which is diluted by glycerol or solvent reacting with hydrogen or gaseous mixture containing hydrogen to generatenormal propyl alcohol, which provides a new way for synthesizing normal propyl alcohol. The present invention can enhance activity of glycerol hydrogenation and selectively generates normal propyl alcohol, also can make normal propyl alcohol united generating with 1,2-propanediol, ethandiol, methylic alcohol and ethyl hydrate, thus its product process program is very flexible. The present invention is characterized in that its technological condition is geniality, raw material is cheap and can be obtained easily and the cost of manufacture is low, which belongs to environment friendly green chemical industry technique.

The invention discloses a modified silica sol and application thereof in preparation of aqueous painting. The inventive modified silica sol is prepared from aqueous silica sol by regulate pH value of raw material to 3-6; charging organosilane with a mass ratio with SiO2 in silica sol of 1:1 - 5:1, water bathing at temperature of 50-80 DEG C., waiting for 0.5-5 hours, vaporizing by-products generated in hydrolysis to obtain transparent sol, which is final product. The modified silica sol has cheap raw material, simple preparation. When used as matrix in preparation of paint, the sol uses only water as solvent, without need of adding any organism such as alcohol. The preparation is simple, economic, environmental protecting. The prepared aqueous paint not only has high decorative, great adhesion and toughness of organic paint, but also has high rigidity, chemical resistance of inorganic paint, which can be used on surface of substrates of metal, glass, wood, plastic and in construction industry.

The invention relates to porous concrete and a preparation method thereof, in particular to novel nano porous concrete which is prepared by taking thixotropic colloid as a template agent to form a uniform-water-phase three-dimensional network nano porous structure and adding cementing materials, fine aggregate, coarse aggregate, an admixture and an additive. The nano porous concrete has the characteristics of being light, high in strength and low in heat conductivity, can be prefabricated into bricks, building blocks, plates, and assembly type stairs, wallboards, balcony slabs and roof panel parts in a factory, can be also cast on a construction site, and further can be prepared into mortar, thereby having remarkable practical significance on promotion of development of housing industrialization and green building concrete material in our country.

The invention discloses a composite catalyst for purifying indoor formaldehyde and a preparation method of composite catalyst. The catalyst consists of 99 to 90 weight percent of carrier and 1 to 10 weight percent of metal ion doped MnO2 powder, wherein the carrier comprises active carbon powder, active carbon fiber powder or molecular sieve porous superfine particles; and the doped metal ions are silver, copper or zinc ions. The preparation method comprises the following steps of: preparing MnO2 powder by using KMnO4 and MnSO4 as raw materials; adsorbing KMnO4 solution on the carrier under the actions of immersion and adsorption, and reacting the MnSO4 solution serving as a reducing agent with the KMnO4 on the carrier so that the MnO2 powder generated by reaction is directly deposited onthe surface and the interior of the carrier; and soaking the carrier into 0.5 to 2.0 percent of metal ion doped solution, performing rotary evaporation, and drying at the temperature of 100 DEG C to prepare the MnO2/carrier composite catalyst containing doped ions.

The invention discloses a self-healing polymer material and a preparation method thereof. The self-healing polymer material comprises at least one polyurethane polymer prepared by random copolymerization reaction of a low polymer dihydric alcohol, a chain extender and a first diisocyanate, wherein the chain extender comprises at least one multiple hydrogen bond chain extender. The invention further provides a preparation method of the self-healing polymer material. The method comprises the following steps: preparing a ureido pyrimidone type end-capping reagent or chain extender, and preparing the low-temperature rapid self-healing polymer material containing quadruple hydrogen bond groups on side chains and end groups by utilizing the random copolymerization reaction of the low polymer diglycol, the chain extender and the first diisocyanate. Compared with the traditional self-healing material, the self-healing material disclosed by the invention can realize repeated self-healing at the same position at a low temperature without adding a repair agent to the damaged part, and the self-healing polymer material is high in healing ability, excellent in mechanical property, excellent in material film-forming property and transparency, simple in process and low in cost.

The invention provides a method for extracting carbon quantum dots from activated carbon, which comprises the following steps of: adding dry activated carbon powder to salpeter solution and stirring for backflow; performing reduced pressure distillation for evaporating suspension obtained by backflow to dryness; dispersing obtained black solids in water, and neutralizing obtained solution with sodium hydroxide; and finally, centrifugating neutralized black suspension for removing precipitation, separating supernatant fluid by using an ultrafiltration centrifugal tube or an ultrafiltration membrane, collecting filtrate, and drying the filtrate to obtain carbon quantum dots. The method uses cheap and available activated carbon as carbon sources, and can obtain a large number of carbon quantum dots by simple chemical oxidation process and simple subsequent processes of evaporation, saturation, centrifugation and ultrafiltration. The carbon quantum dots are graphite structure nanocrystals with the grain diameter of 3 to 5 nm, the surfaces of which have a large amount of hydroxide radicals. The carbon quantum dots have good fluorescence and electrochemiluminescence.

The invention discloses a current collector carbon coated aluminum foil and its preparation method. A carbon-containing composite layer is arranged on the substrate of the current collector carbon coated aluminum foil, and is combined with the substrate through a binder, wherein the thickness of the carbon-containing composite layer is 1-100mum; the carbon-containing composite layer comprises granular conductive carbon black pre-dispersed by a dispersant, and fibrous conductive carbon; the granular conductive carbon black and the fibrous conductive carbon filled between the layers of the granular conductive carbon black form a netted node form conductive network. The composite layer is tightly combined with the substrate of the aluminum foil, so the conductivity and the corrosion resistance of the aluminum foil are improved, and the aluminum foil is protected from oxidation or chemical corrosion. The preparation method of the aluminum foil comprises the following operations: mixing the conductive carbon black with the dispersant in an organic solvent to pre-disperse, adding the fibrous conductive carbon, uniformly mixing, adding the binder to prepare a slurry, coating on the aluminum foil, and carrying out vacuum drying. The current collector carbon coated aluminum foil enables the interface impedances of the current collector and an active layer to be reduced, the internal resistance of a battery to be reduced, and the cycle life and the ratio performances of the battery to be improved when the aluminum foil is used as a lithium ion battery anode current collector. The aluminum foil has the advantages of simple technology, low cost and wide application prospect.

The invention provides a biodiesel-based alcoholic fuel oil, which consists of the following substances in percentage by mass: 20 to 50 percent of refined biodiesel, 40 to 80 percent of industrial methanol and 5 to 30 percent of additive, wherein the additive comprises 5 to 20 percent of solvent aid, 1 to 15 percent of cosurfactant, 0.2 to 2 percent of stabilizer and 0.1 to 1 percent of corrosion inhibitor. A preparation method comprises the following steps of: mixing the substances in percentage by mass, and stirring the mixture uniformly at normal temperature to obtain the fuel oil. The fuel oil has the advantages of low cost, high heat value and stable performance; the preparation method has the advantages of simple process, convenience and safety of use and good adaptability to the boiler; and compared with diesel oil, the fuel oil is economic and energy-saving, has low environmental pollution, is regenerative energy, and can be used as commercial oil for great popularization and use.

The invention provides a method for preparing an SiO2/TiO2 hollow microsphere by a sol-gel method. The method is mainly characterized in that cation polystyrene microsphere (PS) is used as a formwork; ethyl silicate and butyl titanate are respectively used as raw material and diluted ammonia is taken as regulator of pH value; a multi-layer organic-inorganic hybrid composite microsphere is obtained by the sol-gel reaction under the temperature of 70-80 DEG C. Formwork particle of the obtained deposition is removed by a calcining process to obtain the SiO2/ TiO2 hollow microsphere. By changing the consistency of reactant, content of surfactant and calcining temperature, the SiO2/ TiO2 hollow microsphere with different spherical shell thickness, density and grain size can be obtained. The hollow microsphere prepared by the method has high photo-catalytic activity, overcomes the shortage that existing preparation method of hollow microsphere can only prepare single shell layer microsphere; the multi-layer hollow microsphere can be prepared, the technique is simple, the cost is low and the preparation method of the invention is suitable for industrialized production.

The manufacture method of a kind of zirconia fibre cotton relates to the field of resistance of fire fibre material. We compose van-style acetamide acetone zirconium polymer according to chloridze zirconia, acetamide acetone and three-ethylamine. We use methanol as the dilute impregnant, we mix round them to let hloridize zirconia, acetamide acetone and three-ethylamine react at 40-20 deg.C, and we can receive poly-acetamide acetone zirconium van-substance. Four-hydrogen furan filtrate and remove the outgrowth hydrochloric three-ethylamine. The offspring dissolve in the filature liquid made of methanol. After centrifugal swing, we can receive van-substance fibre. After we do special hear treatment, the zirconia fibre cotton we receive has the characteristic of good filature ability, high content of zirconium, equality andclarity and jarles capability. It can be used as industrial stove, roomage fusion stove, atomic energy reactor and the high temperature heat insulation material used in aviation and military. The material of the invention cost low, the method is easy, the impregnant can be recycled, the preparation of fibre cost low.

The invention discloses a preparation method of a high-liquid absorbing rate micro-nano structure polymer electrolyte membrane, wherein the membrane is prepared by polymer material being packed on a support frame. The method comprises the following steps of: by being processed, the polymer membrane has a micro-nano structure, forms holes with micron level and nanometer level, and forms a netty distribution hole structure with the nanometer holes of the support frame; and the polymer which is crossly linked layer by layer is packed on the special support frame to form a special netty micro-nano structure polymer electrolyte membrane. The polymer membrane of the micro-nano structure can absorb large numbers of electrolyte, greatly increase liquid-absorption rate, and improve the affinity of diaphragm to the electrolyte; the netty micro-nano structure leads the electrolyte to be kept in the membrane well, leads lithium ion in the polymer electrolyte membrane to be evenly distributed, leads the concentration to be to balanced, and lead the current density in the battery to be evenly when discharging electricity; and the special support frame guarantees the mechanical capability of the membrane. The preparation technology of the polymer electrolyte membrane has simple route and easily obtained raw material, can be operated under a normal condition, and does not need harsh production environment. The polymer lithium ion battery prepared by the membrane has good electrochemistry capability.

The invention discloses a preparation method of vilazodone or its hydrochloride, which comprises the following steps: the compound of formula (I) is mixed with the compound of formula (II) 5-(1 -piperazinyl)-benzofuran-2-formamide reaction, then collect vilazodone shown in formula 1 from the reaction product; Gained vilazodone 1 is in a solvent, and hydrochloric acid is salified to prepare formula (A ) shown vilazodone hydrochloride. The present invention overcomes the defects and deficiencies in the existing preparation methods of vilazodone and its intermediates, is more suitable for the large-scale industrial preparation of vilazodone hydrochloride, has obvious creativity, and has a relatively large positive progress effect and practical application value. The reaction formula is as follows:

The invention discloses a mesosulfuron-methyl synthetic method. The mesosulfuron-methyl synthetic method is characterized in that mesosulfuron-methyl is prepared from raw materials such as paratoluic acid by adopting the seven steps of chlorosulfonation-ammonolysis, oxidation, dehydration, reduction, alcoholysis, methyl sulfone chloride acylation and condensation. The mesosulfuron-methyl synthetic method provided by the invention has the advantages of being low in cost of the raw materials, easy in availability of the raw materials, simple in operation and mild in conditions, having low requirements on equipment, high yield and strong practicability and being suitable for industrial production.

A copper mine tailing slag porous ceramic material comprises copper mine tailing slag, a pore-foaming agent, an adhesion agent and a fluxing agent. A preparation method comprises the steps of using the copper mine tailing slag as aggregate, adding the pore-foaming agent, the adhesion agent, the fluxing agent and water to be stirred evenly, using a mold to perform compression molding to obtain a blank, controlling the temperature and sintering through a high-temperature procedure after drying, and obtaining porous ceramics. Raw materials used by the copper mine tailing slag porous ceramic material are cheap and easy to obtain, the compression strength of the porous ceramic material can be remarkably improved and can reach to 5-25 MPa only by adding the copper mine tailing slag and a small amount of additives, and the apparent porosity can reach to 40%-65%. A large amount of beneficiation tailing slag can be utilized effectively, the environmental pollution is reduced, wastes are turned into wealth, and the prepared porous ceramic material can be used as an excellent adsorbing material and a filter material. The technical process is simple, the utilization amount of the copper mine tailing slag is large, secondary pollution is not caused, the porous ceramic material is high in compression strength and porosity, and the resource utilization of the copper mine tailing slag is achieved. The copper mine tailing slag porous ceramic material is suitable for industrial production.

The invention discloses a high-resilience self-repair high-polymer aquagel and a preparation method thereof. The high-resilience self-repair high-polymer aquagel is prepared from the following raw materials in parts by mass: 15-20 parts of polyisocyanate, 40-75 parts of hydrophilic polyester polyol or hydrophilic polyether glycol, 1-5 parts of acrylate monomer, 10-15 parts of acrylamide monomer, 0.5-2 parts of chain extender, 1-3 parts of surfactant, 0.1-1 part of alkyl acrylate monomer and 0.5-2 parts of catalyst. The preparation method comprises the following steps: preparing an acrylate-monomer-terminated hydrophilic polyurethane high-polymer monomer self-assembly and an alkyl acrylate micelle; and carrying out radical copolymerization with acrylamide monomer under the photoinitiation action. The obtained self-repair high-polymer aquagel can complete self repair on self damage without any repair agent or specific environment, and has excellent resilience and physical and mechanical properties.

The invention relates to a preparation method of diatomite ceramic particles or diatomite ceramic plates. The preparation method of the diatomite ceramic particles comprises the following steps: grinding diatomite, adding cosolvent, mineral powder and vegetable fiber powder to mix evenly and grind; and adding water to mix, shaking to obtain diatomite ceramic particles, and roasting to obtain the finished diatomite ceramic particles. The preparation method of the ceramic plates comprises the following steps: using evenly mixed powder to perform dry pressing with a pressure forming machine, or using mud with the water content of 15-25wt% to perform extrusion forming; and roasting to obtain the diatomite ceramic plates. The formed and dried diatomite ceramic plates or diatomite ceramic particles are soaked in slurry prepared from anatase titanium dioxide nanometer powder or metatitanic acid powder and then dried and roasted to obtain diatomite ceramic particles or diatomite ceramic plates with photochemical activity. In the invention, the low temperature sintering method is adopted to prepare the diatomite diatomite ceramic plates and ceramic particles which have high diatomite content and good adsorption property and water resistance and can be combined with various functional components on the surface. The diatomite ceramic products in the invention are convenient to use and have simple production technology and cheap and easy available raw materials.

The invention relates to a preparation method of covalent organic framework composite microspheres with core-shell structures. The method comprises the following steps: dissolving silicon dioxide microspheres, a first construction element and a second construction element in an organic solvent; and after adding a catalyst, rapidly synthesizing into the composite microspheres with core-shell structures at a certain temperature. In a preparation process, reaction conditions are gentle, the method is simple, and the yield is high; the prepared covalent organic framework composite microspheres have the advantages of good core-shell morphology, high specific surface area, ordered pore structures, good mechanical stability, thermal stability, chemical stability and the like, if the microspheres are used as a chromatographic stationary phase, the chromatographic mass transfer resistance can be reduced effectively, the theoretical plate height is improved, and finally, column efficiency and degree of separation are improved; and if the microspheres are used as solid-phase extracting filler, the enrichment effect can be improved remarkably. The covalent organic framework composite microspheres with core-shell structures have good application prospects in the aspect of separation and enrichment of small organic molecules.

The invention provides preparation of a carbon nanotube material embedded with a quantum-dot modified metal organic framework. The preparation comprises the following steps of firstly, adding a certain amount of powder quantum dots to a formed metal organic framework precursor solvent so that the quantum dots of which the diameters are matched with the sizes of pore passages are embedded into the pore passages of the formed metal organic framework; secondly, uniformly mixing the obtained quantum-dot modified metal organic framework and melamine powder, and performing high-temperature processing to obtain a composite material (QD/UMCM-1@CNT) in a carbon nanotube embedded with the quantum-dot modified metal organic framework; and finally, enabling Pt to be loaded on a surface of the composite material carbon nanotube (Pt/QD/UMCM-1@CNT) by microwave radiation heating to be used as a positive electrode catalyst of a methanol fuel cell. Compared with a traditional hydrothermal method for synthesis of the carbon nanotube, the quantum-dot modified metal organic framework obtained by high-temperature processing is embedded into the composite material in the carbon nanotube, the structural aspects such as the length and the diameter of the carbon nanotube are more consistent, and a catalyst substrate with a unified structure is easier to form.

The invention discloses a preparation method of polydopamine modified alginic acid microspheres, which comprises the following steps of: under the protection of nitrogen, grafting dopamine to alginic acid by use of N-hydroxysuccinimide and 1-ethyl-3-(3-dimethylaminopropyl)carbodiimide hydrochloride; polymerizing the synthesized dopamine modified alginic acid under the slight alkaline condition to obtain a polydopamine modified alginic acid solution; dropwise adding the polydopamine modified alginic acid solution into a CaCl2 solution by a syringe; and aging to obtain polydopamine modified alginic acid microspheres. The method disclosed by the invention is simple in process, and the prepared modified alginic acid microspheres have higher swelling resistance and good mechanical properties.

The invention discloses a method for preparing gypsum-based self-leveling material for use in building material industry. The main material of the gypsum-based self-leveling material is desulfurized gypsum which is a desulfurization product from power plants. The method comprises: firstly, calcining the desulfurized gypsum in a calcining kiln; and secondly, mixing calcined gypsum powder accountingfor 50 to 78 percent of the total weight of the material, a water reducer accounting for 0.1 to 1 percent of the total weight of the material, a retarder accounting for 0.01 to 0.5 percent of the total weight of the material, a water-retaining agent accounting for 0.02 to 5 percent of the total weight of the material, a reinforcing agent accounting for 0 to 10 percent of the total weight of the material, re-dispersible emulsion powder accounting for 0.2 to 1.5 percent of the total weight of the material, a defoamer accounting for 0.05 to 0.2 percent of the total weight of the material, riversand accounting for 25 to 45 percent of total weight of the material and a filler accounting for 0 to 20 percent of the total weight of the material to obtain a the high-performance gypsum-based product. The invention provides a new method for producing high-quality gypsum-based self-leveling material characterized by high strength, high flowability, small contraction deformation and low cost by using the desulfurized gypsum, which provides a new way of comprehensively using desulfurized gypsum that is a solid waste and fills the blank that the preparation of gypsum-based self-leveling materials from desulfurized gypsum lacks in China.