587 results about "Carbodiimide" patented technology

The invention discloses a preparation method of a cell inflammatory factor adsorbent, which comprises the following steps: mixing styrene, divinyl benzene and hydroxyethyl acrylate, and adding a pore-foaming agent and mesoporous SiO2 nano powder to prepare a porous microsphere carrier; the preparation method comprises the following steps: mixing chitosan and poly (N-isopropylacrylamide) in an acetic acid solution to obtain a temperature-sensitive chitosan hydrogel precursor solution; the preparation method comprises the following steps: activating the surface of a porous microsphere carrier by using 1-ethyl-(3-dimethylaminopropyl) carbodiimide and N-hydroxysuccinimide, mixing the activated porous microsphere carrier and a temperature-sensitive chitosan hydrogel precursor solution to obtain a water phase, and assembling, washing and drying in an oil phase to obtain the cell inflammatory factor adsorbent. Through the design of the core-shell structure and the addition of the mesoporous SiO2 nano powder, the temperature response characteristic and the recyclable characteristic are given to the cell inflammatory factor adsorbent, the adsorption capacity of cell factors is also improved, and a new solution is provided for physical adsorption of the cell inflammatory factors.

An adhesive composition (100) comprises: a polyester resin (A) that includes an ester bond which bonds repeating units together and one or more functional groups selected from the group consisting of carboxy groups and carboxylic acid anhydride structures; an epoxy compound (B) in the amount of 1-50 parts by mass with respect to 100 parts by mass of the polyester resin (A); and a cyclic carbodiimide (C) in the amount of 0.1-20 parts by mass with respect to 100 parts by mass of the polyester resin (A).

The invention discloses a synthesis method of oxyalkyl isourea and application of the oxyalkyl isourea as a free radical alkylation reagent. According to the synthesis method, cheap and rich alcohol compounds and carbodiimide are used as raw materials, oxygen alkyl isourea is synthesized in one step under the mild condition of metal catalysis, the synthesis process is simple and convenient, the yield is high, and hectogram-level large-scale preparation can be achieved. The synthesized oxyalkyl isourea can be used as a free radical alkylation reagent to be applied to a coupling reaction of metal catalysis, so that different alkylate products rich in saturated carbon sequence structures are prepared, and the method has a good application prospect.

The invention belongs to the technical field of high polymer materials, and discloses a two-component polyurethane pouring sealant and a preparation method thereof.The two-component polyurethane pouring sealant comprises a component A and a component B. The component A comprises, by weight, 40-60 parts of bio-based polyether polyol, 10-15 parts of boron nitride nanosheets, 5-10 parts of graphene modified epoxy resin, 1-3 parts of a silane coupling agent and 0.5-1.5 parts of a supercritical fluid foaming agent; the component B is prepared from 30 to 50 parts of carbodiimide modified MDI (methylene diphenyl diisocyanate), 10 to 20 parts of dendritic polyurethane cross-linking agent and 2 to 5 parts of nano aluminum hydroxide filler; the mixing ratio of the component A to the component B is (2-3): 1; the invention aims to provide the two-component polyurethane pouring sealant and the preparation method thereof, and through material innovation and process integration, the two-component polyurethane pouring sealant which is high in heat conductivity, environment-friendly, weather-resistant and low in internal stress is provided.

The invention belongs to the technical field of probiotic protection, and discloses a preparation method and application of probiotic-loaded sulfydryl hyaluronic acid-based hydrogel, sulfydryl hyaluronic acid is prepared by taking cysteamine hydrochloride as a substrate, and connection of L-glutamine is further catalyzed through a cross-linking agent, so that the sulfydryl hyaluronic acid-based hydrogel is obtained. The cross-linking agent is a mixture of N-hydroxysuccinimide and 1-ethyl-(3-dimethylaminopropyl) carbodiimide or a mixture of N-hydroxysuccinimide and 1-hydroxybenzotriazole (HOBT), and the cross-linking agent is a mixture of N-hydroxysuccinimide and 1-ethyl-(3-dimethylaminopropyl) carbodiimide and 1-hydroxybenzotriazole (HOBT). The hydrogel prepared by the preparation method disclosed by the invention is used as a probiotic carrier, so that the influence of complex gastrointestinal tracts is effectively resisted, the hydrogel accurately reaches an intestinal injury part and is split, and the targeted intestinal controllable release of probiotics is realized; meanwhile, the L-glutamine is introduced and has a synergistic effect with the probiotics to relieve specific intestinal diseases, so that the L-glutamine can be used as a probiotic supplement for the specific intestinal diseases.

The preparation method comprises the following steps: by taking natural chitosan, epsilon-polylysine and polyphenol as raw materials, firstly, respectively preparing polyphenol modified chitosan and carboxyphenylboronic acid modified polylysine through a carbodiimide coupling method, then, mixing single-component solutions of the polyphenol modified chitosan and the carboxyphenylboronic acid modified polylysine, and then, preparing the antibacterial and antioxidant glycopeptide hydrogel based on the polyphenol. And the antibacterial and antioxidant glycopeptide hydrogel is obtained by virtue of the synergistic effect of the phenolic hydroxyl group-boric acid group dynamic bond and the amino group-carboxyl group. The hydrogel disclosed by the invention has broad-spectrum antibacterial property and glucose response oxidation resistance, has self-healing capability and strong wound adhesion, is excellent in biocompatibility and can be naturally degraded; and the process is simple, convenient and controllable, large-scale production is easy to realize, the hydrogel can be used as a wound dressing for treating chronic difficult-to-heal wounds such as diabetes mellitus in a targeting manner, and integrated nursing of antibiosis, antioxidation, wound adhesion and self-repairing is realized.

The invention discloses a preparation method of a new energy battery pack cover plate flame-retardant PP material, and relates to the technical field of polymer flame-retardant materials. The preparation method comprises the following steps: sequentially adding phosphate esterified polypropylene, a maleic anhydride grafted polyolefin elastomer, polyether block amide, modified nano clay, a B-P-triazinyl charring agent, a carbodiimide type anti-hydrolysis agent, a hindered phenol antioxidant, short carbon fibers, polytetrafluoroethylene micro powder and modified hollow glass beads into a mixing mill; and adding the obtained premix into a twin-screw extruder, extruding, pelletizing, and carrying out injection molding to obtain the flame-retardant PP material for the cover plate of the new energy battery pack. The prepared new energy battery pack cover plate flame-retardant PP material has excellent mechanical performance, flame retardance, thermal stability, dimensional stability and antistatic performance, is light in weight, and has wide application prospects in the fields of new energy automobiles, energy storage systems, consumer electronics, aerospace and industrial equipment.

The invention discloses a functional hydrogel microsphere and a preparation method and application thereof, and relates to the technical field of medicines.The preparation method comprises the steps that a hyaluronic acid methacrylic acid precursor solution and an IL-1beta shRNA adenovirus stock solution are mixed to obtain an Ad-atHAMA precursor solution; preparing the Ad (at) HAMA precursor solution through an oil-in-water micro-fluidic technology to obtain an Ad (at) HAMA microsphere; and sequentially adding the Ad (at) HAMA microspheres, 1-ethyl-3-(3-dimethylaminopropyl) carbodiimide and N-hydroxysuccinimide into a 2-morpholinoethanesulfonic acid buffer solution, carrying out activating treatment, adding E selectin, and incubating to obtain the functionalized hydrogel microspheres. The functionalized hydrogel microspheres can inhibit a related mechanism of acute spinal cord injury pathological progress and promote neural function repair by targeting adsorption of neutrophil to regulate Nets-triggered innate immune inflammation cascade.

The invention relates to the technical field of batteries, in particular to a low-hydrogen-evolution graphene material for a lead-acid battery and a preparation method thereof.The method comprises the steps that firstly, ethidene diamine is grafted to the surface of graphene oxide through a carbodiimide / active ester method, and aminated graphene is obtained; performing heat treatment in a nitrogen / ammonia gas atmosphere to realize nitrogen doping; compounding with titanium dioxide, and carrying out hydrothermal reaction to form a stable structure; then, sequentially grafting imidazolium silane and perfluorodecyl silane to carry out hydrophobic modification; and finally, stabilization and low-temperature re-nitridation curing are carried out through titanium tetrabutoxide. The graphene material prepared by the method endows the battery with excellent performance, and is low in direct-current internal resistance and high in capacity retention ratio.

The invention provides synthesis of a T-2 toxin antigen and preparation and application of a monoclonal antibody. Relates to the technical field of biotoxin detection. The preparation method of the T-2 toxin antigen comprises the following steps: step 1, synthesizing an immunogen T-2-BSA by adopting a carbodiimide method, dissolving 2mg of T-2 adipic acid with 0.5 mL of dimethylformamide, and recording as a solution A; 5 mg of bovine serum albumin and 3 mg of EDC are dissolved with a 2-morpholine ethanesulfonic acid buffer solution with the pH being 5.5, and the solution is marked as a solution B; step 2, under the condition of stirring, dropwise adding the solution A into the solution B, stirring for 18 hours in a dark place at 4 DEG C, then dialyzing for 3 days by using a phosphate buffer solution, changing the solution once a day, centrifuging the dialysate for 10 minutes at 3,500 r / min, and discarding the precipitate; the adipic acid is coupled with the T-2 toxin through a chemical method, and the unique step enriches the structural characteristics of the hapten, so that the prepared T-2 toxin complete antigen is excellent in immune effect, can efficiently excite immune response of an organism, and shows high specificity and sensitivity.

The invention relates to the technical field of removal of carbon dioxide in oil gas, in particular to a preparation method of carbon dioxide PAMAM grafted ionic liquid for oil gas purification. Comprising the following steps: 1) activating carboxyl: dissolving 1-butyl-3-methylimidazole carboxylic acid in a solvent, adding dicyclohexylcarbodiimide and 4-dimethylaminopyridine, and stirring at room temperature to generate active ester; 2) grafting PAMAM: adding PAMAM dendrimer into the solution, and reacting under the protection of nitrogen; and 3) purification: removing the dicyclohexylurea precipitate through centrifugation, and dialyzing the filtrate to remove the unreacted ionic liquid and small molecule byproducts to obtain the PAMAM grafted ionic liquid. The stability and durability of the absorbent are remarkably improved, the CO2 absorption efficiency is improved, the energy consumption of the absorbent per unit mass is reduced, and the preparation method is simple and controllable, mild in reaction condition and easy for large-scale production.

The invention relates to the technical field of resin composite materials, in particular to a layer-adding adhesive film for an FC-BGA packaging carrier plate, a preparation method of the layer-adding adhesive film and an adhesive-coated copper foil. The layer-adding adhesive film is prepared from the following raw materials in parts by mass: 50 to 60 parts of epoxy resin, 180 to 200 parts of inorganic filler, 30 to 36 parts of curing agent, 4 to 6 parts of modified phenoxy resin, 3 to 5 parts of carbodiimide resin and 0.2 to 0.4 part of 4-dimethylaminopyridine. Modified phenoxy resin and carbodiimide resin are added on the basis of main components such as epoxy resin, inorganic filler and a curing agent, meanwhile, 4-dimethylaminopyridine is used as a curing accelerator, and through the synergistic effect of all the components, the dielectric loss angle tangent of a layer-adding adhesive film can be effectively reduced, the glass-transition temperature of a layer-adding adhesive layer is increased, and the bonding strength of the layer-adding adhesive film is improved. Good flame retardance of the layer-adding adhesive film is ensured, and the layer-adding adhesive film is applied to the adhesive-coated copper foil.

The invention is suitable for the technical field of MCA, and provides an MCA / PA6 flame-retardant composite material and a preparation method thereof. Comprising the following components in parts by weight: 50-60 parts of MCA, 15-20 parts of PA6, 15-25 parts of long glass fiber, 3-8 parts of metal hydroxide, 0.5-1.5 parts of titanium dioxide, 0.3-0.6 part of an antioxidant, 1-2 parts of nano silicon dioxide, 1-3 parts of zinc molybdate, 2-5 parts of aluminum hypophosphite, 1-2 parts of silicone resin, 0.5-1 part of carbodiimide and 5-8 parts of a toughening agent. The MCA / PA6 flame-retardant composite material disclosed by the invention combines the flame-retardant property of MCA and the excellent physical property of PA6, so that the flame-retardant property of the material is remarkably improved, and meanwhile, the original characteristics of light weight, good toughness, chemical resistance, good durability and the like of PA6 are maintained. By adding the long glass fiber, the metal hydroxide, the titanium dioxide, the antioxidant, the nano silicon dioxide, the zinc molybdate, the aluminum hypophosphite, the silicone resin, the carbodiimide, the flexibilizer and other components, the strength, the heat resistance and the flame retardant effect of the composite material are further enhanced.

The present invention relates to a microneedle-based transdermal delivery patch fabricated from a hydrogel composed of polyvinyl alcohol (PVA), arginine-modified chitosan, and a crosslinker. The arginine-modified chitosan is prepared by reacting a chitosan solution with an arginine solution preactivated with N-hydroxy succinimide and 1-Ethyl-3-(3-dimethylaminopropyl)carbodiimide at a specific pH. The hydrogel's formulation further comprises a PVA concentration ranging from 10% to 12% (w / v). arginine-modified chitosan and PVA solution are mixed in a 1:2 ratio by volume and are crosslinked using trimethyl orthoformate (TMOF). The patch is further loaded with curcumin, with a concentration of 120μg per patch, demonstrating a 70% release over 48 hours in a controlled manner. This invention represents the first application of PVA crosslinked arginine-modified chitosan hydrogel loaded with curcumin specifically for animal wound healing, providing enhanced wound healing and antibacterial efficacy.

The invention discloses a nano-drug delivery system for treating myocardial fibrosis as well as a preparation method and application of the nano-drug delivery system, and belongs to the technical field of biological medicines. According to the system, ZIF-8 is taken as a core carrier, the loading efficiency of pirfenidone is improved through high specific surface area and adjustable aperture, PCM myocardial targeting peptide is covalently coupled on the surface, and the limitation of tissue selectivity is broken through. Through coordination complexation, pi-pi conjugate accumulation and electrostatic interaction synergy, stable drug loading and microenvironment response release are guaranteed; a one-pot method and a carbodiimide method are adopted to wrap PFD and modify PCM on the surface of ZIF-8 to form a nano-drug delivery system; according to the system, the fibrosis process is intervened through multiple mechanisms, the enrichment degree and the acting time of the medicine at the diseased region are improved, the prepared medicine integrates the carrier structure advantage and the targeting peptide function, efficient medicine carrying, precise delivery and controllable release are achieved, a new scheme is provided for myocardial fibrosis treatment, and the system has wide application prospects.

The invention provides a porphyrin functionalized carbon nanotube compound. Medium-tetra (4-carboxyphenyl) porphyrin is covalently connected to the surface of an aminated carbon nanotube through an amido bond to form the compound. Stable amido bond connection is formed through amino-carboxyl condensation, and the bond energy is obviously higher than that of an ester bond. The invention also provides a preparation method of the porphyrin functionalized carbon nanotube compound, which comprises the following steps: carrying out carboxyl activation treatment on the meso-tetra (4-carboxyl phenyl) porphyrin by adopting a catalytic system consisting of N, N '-dicyclohexylcarbodiimide and N-hydroxysuccinimide; the preparation method comprises the following steps: performing ultrasonic treatment on aminated carbon nanotubes in N, N-dimethylformamide, adding the aminated carbon nanotubes into an activated meso-tetra (4-carboxyphenyl) porphyrin solution prepared in the step 1, performing stirring reaction at room temperature, and performing suction filtration and freeze drying to obtain a target product, namely the porphyrin functionalized carbon nanotube compound. A mild room-temperature stirring process is adopted, so that the dependence of a solvothermal method on high-temperature and high-pressure equipment is completely avoided, and the production cost is remarkably reduced.

The invention discloses preparation and application of bacteriophage-loaded sericin microgel, and belongs to the technical field of food preservation. The sericin microgel capable of loading the bacteriophage is prepared from a sericin solution extracted by using 1-ethyl-(3-dimethylaminopropyl) carbodiimide (EDC) in combination with a mechanical shearing method and a high-temperature and high-pressure method. The sericin protein microgel loaded with bacteriophage, which is obtained by soaking the microgel into bacteriophage proliferation liquid after freeze-drying, can significantly improve the storage stability of the bacteriophage and can effectively prolong the shelf life of beef, and the preparation method is green, simple and safe, has a wide application prospect, and is suitable for industrial production. Meanwhile, a new field is opened up for efficient application of the bacteriophage.

The invention relates to the technical field of waterproof gas-permeable membranes, in particular to a waterproof gas-permeable membrane with heat preservation performance and a preparation method thereof.The waterproof gas-permeable membrane with the heat preservation performance comprises a bio-based polymer, an ultraviolet light absorber, heat preservation filler, a plasticizer and a cross-linking agent.The bio-based polymer is selected from one or more of polylactic acid (PLA), polyhydroxyalkanoate (PHA) and cellulose ester; the ultraviolet light absorber is a mixture of nano-zinc oxide and nano-titanium dioxide, the thermal insulation filler is a combination of aerogel microspheres and hollow glass beads, the plasticizer is tributyl citrate or acetyl tributyl citrate, the cross-linking agent is a carbodiimide compound, and the filler is a mixture of nano-zinc oxide and nano-titanium dioxide. The materials are subjected to drying, blending, melt extrusion, stretching forming and heat treatment to finally obtain a waterproof breathable film with a heat preservation effect, and meanwhile, the waterproof breathable film also has an ultraviolet-proof function.

The invention discloses a lignin / gelatin / alginate composite hydrogel material and a preparation method thereof, and belongs to the field of biomass materials and environmental materials. The preparation method comprises the following steps: respectively preparing a gelatin solution A, a modified lignin solution B and a soluble alginate and carbodiimide solution C, mixing the gelatin solution A, the modified lignin solution B and the soluble alginate and carbodiimide solution C with a slow-release ionic cross-linking agent, pouring the mixture into a mold, and reacting for 2-48 hours to obtain the hydrogel. According to the hydrogel, a stable three-dimensional network structure is constructed through crosslinking of covalent bonds among three components of modified lignin, gelatin and alginate. Meanwhile, full biomass modification is adopted, and natural high polymer materials and renewable resources are used; the prepared hydrogel has good crosslinking controllability, is basically recoverable under 70% compressive strain, has excellent performance through 1000 times of compression resilience tests under 30% compressive strain, has excellent fatigue resistance and mechanical stability, also has the advantages of low toxicity, low cost and simple and convenient preparation process, and has wide application potential in the fields of medical treatment, electronics and the like.

The invention provides a polyurethane waterproof coating and a preparation method thereof. The polyurethane waterproof coating comprises a polyurethane prepolymer, polymerized carbodiimide and a latent curing agent, wherein the polyurethane prepolymer comprises a first group, and the first group is-N = C = O; the polymerized carbodiimide comprises a second group, and the second group is-N = C = N-; the latent curing agent comprises a third group, and the third group is Ar-C = N-R; r is alkyl of C2-C15; in the polyurethane waterproof coating, the molar ratio of the first group to the second group to the third group is (1.5-2.1): (1-1.5): 1. According to the polyurethane waterproof coating provided by the invention, the problem that the strength is reduced or the coating is sticky after curing can be avoided, and the effects that the polyurethane waterproof coating is rapidly cured and a formed film is free of pinholes / bubbles are achieved, so that a long-acting and durable waterproof effect is provided for buildings.

The invention discloses a supporting layer suitable for a composite current collector, a corresponding composite current collector and a battery. Wherein the supporting layer is formed by curing insulating adhesive liquid; the insulating adhesive liquid comprises a component A and a component B which are mixed, wherein the component A is at least one of polyurethane resin, acrylic resin, epoxy resin, polyester resin, polyimide, an organosilicon polymer and a modified compound thereof; the liquid B is at least one of amino resin, isocyanate, an aziridine cross-linking agent, carbodiimide, a silane coupling agent and an organic silicon tackifier; wherein the ratio of the component A to the component B is (90-99): (1-5). Compared with an existing supporting layer and an existing composite current collector, the viscous insulating layer structure can replace common PET, PP, PI and other types of base film middle supporting layer structures, the adhesive strength of the metal layer and the supporting layer is improved, and meanwhile additional hierarchical structures are avoided. And the production process is simplified, so that mass production is realized.

The invention discloses a folic acid modified active oxygen response type sodium alginate nano-carrier and application thereof, and the preparation method comprises the following steps: firstly synthesizing-Se-Se-FA: stirring dicyclohexylcarbodiimide, 4-dimethylaminopyridine, dimethyl sulfoxide / pyridine, a double-selenium fragment and folic acid at room temperature for 18-22 hours in an argon environment; and carrying out acetone precipitation, centrifugation, washing, rotary evaporation concentration and freeze-drying. The preparation method comprises the following steps: preparing an ALG-Se-FA carrier, stirring sodium alginate, 1-ethyl-3-(3-dimethylaminopropyl) carbodiimide hydrochloride and hydroxysuccinimide in a 2-morpholinoethanesulfonic acid buffer solution, adding DMSO, dissolving a double-selenium fragment and a-Se-Se-FA fragment in DMSO and deionized water, adding the dissolved double-selenium fragment and-Se-Se-FA fragment into a system, stirring, dialyzing, and freeze-drying to obtain the product. According to the carrier, a double-selenium bond ROS response unit and folic acid targeting molecules are introduced through covalent bonds, astaxanthin can be efficiently entrapped and protected, and after the carrier is stable in gastrointestinal environment and reaches a colitis disease part, high ROS level can be responded, and intelligent drug slow release is achieved through folic acid receptor targeting.

The invention discloses a low dimer modified isocyanate composition and a preparation method thereof. The content of dimers in the modified isocyanate is reduced to 0.9 wt% or below mainly by controlling the reaction temperature of carbodiimide, the cooling rate after the reaction and the curing temperature. Through the method, the storage time of the modified isocyanate can be prolonged, and the stability of the modified isocyanate product is improved.

This invention discloses a method and sensor for adiponectin detection using a polyaniline and polyacrylic acid-modified wire mesh carbon electrode, relating to the field of adiponectin detection technology. The method involves electrochemically activating the wire mesh carbon electrode, electropolymerizing it to form a polyaniline-polyacrylic acid composite modification layer, immobilizing adiponectin monoclonal antibody after activation with N-hydroxysuccinimide and 1-ethyl-3-(3-dimethylaminopropyl)carbodiimide, blocking the antibody with bovine serum albumin, and reacting it with a serum sample. The adiponectin concentration is determined based on the peak potential shift and peak current change. This invention simultaneously achieves both conductive transport and antibody immobilization, reduces non-specific adsorption and serum interference, and improves detection sensitivity, repeatability, and quantitative accuracy.

The invention discloses a preparation method of surface-modified degradable polymer microspheres, which comprises the following steps: (1) preparing dry microsphere powder: putting an oil-phase solution and a water-phase solution into emulsifying equipment for mixing and emulsifying to obtain emulsion; carrying out temperature rise and pressure reduction curing on the emulsion to obtain biodegradable microsphere dry powder; (2) dissolving the modification material: dissolving the modification material containing the amino group to obtain a solution containing the modification material; (3) swelling: dispersing the biodegradable microsphere dry powder in a third solvent and stirring to swell the surface structure of the biodegradable microsphere; (4) activation: adding a carbodiimide compound and an N-hydroxyl activator into the swollen biodegradable microsphere solution for activation, so that an O-acyl isourea intermediate is formed on the surface of the microsphere, and a surface-activated microsphere precipitate is obtained; and (5) modification: mixing the microsphere precipitate with a solution containing a modification material, and stirring to obtain the surface-modified degradable polymer microsphere. Compared with the prior art, the hydrogel has good hydrophilicity and biocompatibility.

This invention provides a method for preparing dibenzoyl-p-benzoquinone dioxime using a microchannel reactor. The method includes the following steps: 1,3-dicyclohexylcarbodiimide and a catalyst are mixed uniformly and preheated to obtain a premix; a chloroform solution of p-benzoquinone dioxime, a chloroform solution of benzoic acid, and the premix are simultaneously introduced into the microchannel reactor for reaction; the resulting reaction solution is subjected to vacuum distillation, washing, filtration, and drying to obtain dibenzoyl-p-benzoquinone dioxime. The synthesis method of this invention features high reaction conversion rate, high production efficiency, few side reactions, and high safety. The obtained dibenzoyl-p-benzoquinone dioxime product has stable quality. Furthermore, the organic solvent used can be recovered and reused after vacuum distillation, overcoming the problems of inaccurate temperature control, poor safety, numerous side reactions, and difficult waste treatment in traditional processes. This provides a new approach for the synthesis of dibenzoyl-p-benzoquinone dioxime.

Provided is a method for producing a blow-molded article, whereby it is possible to prevent a wax-derived component from migrating to the surface of the blow-molded article. The method for producing a blow-molded article includes a step of obtaining a blow-molded article by blow-molding a resin mixture containing at least a wax, a polyethylene or polypropylene, and a carbodiimide compound.

A thermoplastic composition comprises a non-fluorinated hydrophobic additive comprising a fatty acid ester, a hydrolytic stabilizer comprising at least one of a polycarbodiimide and a polyester-modified siloxane, and a thermoplastic polymer. The combination of the non-fluorinated hydrophobic additive and the hydrolytic stabilizer results in the thermoplastic composition having improved hydrophobicity and / or enhanced hydrophobic durability while being free of fluorine and fluoride.

To improve the adhesion of the coating film to the resin and the resistance of the coating films to blocking each other. [Solution] The polyurethane aqueous dispersion according to the embodiment comprises a polyurethane resin (A) containing a polyester polyol as a constituent component dispersed in an aqueous dispersion medium, and includes a carbodiimide group-containing compound (B) and a salt (C) of an acid and an alkali metal. The polyurethane resin (A) has carboxyl groups, and the salt (C) is at least one selected from the group consisting of bicarbonates, carbonates, monocarboxylates, dicarboxylates, tricarboxylates, and phosphates, and the salt (C) exists in an ionized state in the aqueous dispersion medium.

The application belongs to the field of metal corrosion protection, and discloses a preparation method of graphene oxide-polyaspartic acid nanomaterial, which comprises the following steps: dispersing nano graphene oxide in a solvent to obtain a nano graphene oxide dispersion; dissolving polyaspartic acid, 4-dimethylaminopyridine and N,N-dicyclohexyl carbodiimide in an organic solvent to obtain a polyaspartic acid mixture; uniformly mixing the nano graphene oxide dispersion and the polyaspartic acid mixture according to a mass ratio of 1:1-1.5 of the nano graphene oxide and the polyaspartic acid, and performing a reaction under the protection of a certain temperature and an inert atmosphere; and after the reaction is completed, performing solid-liquid separation and collecting a solid product, namely, graphene oxide-polyaspartic acid nanomaterial. The corrosion inhibitor of the application can achieve efficient corrosion inhibition effect by adding a small amount of the corrosion inhibitor into water, and the operation is simple and the cost is low.