640 results about "Conversion reaction" patented technology

A direct air capture (DAC) of CO2 system includes a reaction reactor having a solid, amine-functionalized sorbent configured to sequester CO2 from air; an in-situ dual-function device configured as a CO2 conversion reactor and an exchange fluid regeneration device; and the exchange fluid, recirculating between the reaction reactor and the dual-function device, configured to capture the sequestered CO2 from the solid sorbent in the reaction reactor and release the captured CO2 in the conversion reactor, the exchange fluid including one or more amino acids.

The invention relates to an aqueous zinc-iodine battery electrolyte containing a phenolic additive, and a preparation method and application thereof, and belongs to the technical field of aqueous zinc-iodine batteries. The invention aims to solve the technical problems of serious multi-iodide shuttling and negative electrode by-products of the existing aqueous zinc-iodine battery. The preparation method of the aqueous zinc-iodine battery electrolyte containing the phenolic additive comprises the following steps: dissolving zinc salt and the phenolic additive in deionized water, and fully stirring and mixing to obtain the aqueous zinc-iodine battery electrolyte containing the phenolic additive. The phenolic additive used in the application can accelerate conversion from I3-to I-, accelerate iodine conversion reaction kinetics and reduce generation of polyiodide, so that shuttling of the polyiodide is effectively inhibited, a phenolic additive monomer is adsorbed on the surface of a zinc negative electrode, contact between Zn < 2 + > and water molecules is reduced, and generation of zinc negative electrode by-products is inhibited; the zinc-iodine battery also has the advantages of being easy to manufacture and low in cost.

A method is provided for synthesizing bio-based LPG from renewable sources via a bio-based synthetic gas feedstock, in a dual-stage reaction system comprising an oxygenate synthesis reaction zone and an oxygenate conversion reaction zone that are configured for producing and converting a methanol intermediate for reduced CO2 selectivity. The method includes recovering LPG from either the full reaction zone effluent or from a purge stream separated from the full reaction zone effluent for LPG recovery.

The invention belongs to the technical field of leguminous plants, and particularly discloses a soybean stem protoplast preparation and transformation method, which specifically comprises the steps of soybean aseptic seedling culture, soybean stem protoplast preparation and protoplast transformation. According to the method, the protoplast is prepared from the stem part of the first internode of the soybean, the formula of an enzyme solution is optimized, the protoplast cleaned and collected by W5buffer is utilized for conversion, and PEG instantaneous conversion reaction conditions are utilized, so that the yield and the conversion rate of the soybean protoplast are improved, and the method is more beneficial to identifying the soybean gene function.

Disclosed herein are methods, compositions, and kits related to the identification and / or quantification of target molecules. Furthermore, the disclosure relates to compositions, kits, and methods for detecting and quantifying molecular targets, and especially for detecting and quantifying DNA and RNA The apparatuses and methods. may find use in a variety of applications including prenatal testing detection of pathogens and screening of cancer.

A method is provided for synthesizing bio-based LPG from renewable sources via a bio-based synthetic gas feedstock, in a dual-stage reaction system comprising an oxygenate synthesis reaction zone and an oxygenate conversion reaction zone that are configured for producing and converting a methanol intermediate for reduced CO2 selectivity. The method includes recovering LPG from either the full reaction zone effluent or from a purge stream separated from the full reaction zone effluent for LPG recovery.

Electrochemical systems and methods for removing and recovering phosphorus in the form of phosphate from aqueous solutions are provided. Phosphate radical removal is performed in an electrochemical cell having an electrode containing bismuth (Bi), zinc (Zn), copper (Cu), iron (Fe), or an oxide thereof. During the removal of phosphate radicals from an aqueous solution, the metal (Bi, Zn, Cu or Fe) and / or metal oxide of the electrode is converted into its corresponding metal phosphate within the electrode by a reversible conversion reaction. The phosphate stored in the electrode during the removal step is subsequently released into the recovery solution by electrochemical reduction of the metal phosphate to a metal.

A novel synthetic crystalline molecular sieve material called boron SSZ-121 is provided. Boron SSZ-121 can be synthesized using 1,3-bis(1-adamantyl)imidazolium cation as a structure directing agent. Boron SSZ-121 can be used in organic compound conversion reactions and / or sorption processes.

The invention discloses lithium sulfide, a two-step double decomposition preparation method and application of the lithium sulfide in an all-solid-state battery, and belongs to the technical field of solid-state batteries. According to the preparation method, a two-step decomposition synthesis technology is adopted, lithium carbonate and ammonium thiocyanate are used as raw materials, the raw materials are uniformly mixed and then placed in a high-temperature reactor, a step heating sintering procedure is completed in an inert gas atmosphere, and the purpose of fully decomposing and converting the raw materials is achieved by accurately controlling the temperature and the time; after a product is obtained through reaction, the high-purity lithium sulfide material is obtained after the product is cooled to the room temperature. The method for preparing the lithium sulfide is low in raw material cost, simple in reactant formula and free of side reaction in the reaction process, and the finally generated product is few in impurity, high in purity and good in crystallinity.

The invention discloses a process for preparing synthesis gas by non-catalytic and catalytic coupling of hydrocarbon-containing raw material gas. The process comprises the following steps: (S1) dividing preheated raw material gas into first raw material gas and second raw material gas; (S2) introducing the first raw material gas, water vapor and preheated oxygen into a non-catalytic reactor, and carrying out a non-catalytic conversion reaction to generate first synthesis gas; (S3) introducing the second raw material gas and supplemented water vapor into a pre-catalytic reactor, and carrying out pre-catalytic conversion reaction to generate second synthesis gas; (S4) introducing the first synthesis gas and the second synthesis gas into a catalytic reactor, and carrying out catalytic conversion reaction to prepare third synthesis gas; and (S5) carrying out heat recovery on the prepared third synthesis gas to obtain the synthesis gas. According to the invention, the non-catalytic conversion reaction and the catalytic conversion reaction are coupled, so that the material consumption is greatly reduced, and meanwhile, heat is provided for the catalytic conversion reaction through the non-catalytic conversion reaction, so that the heat is recovered to a great extent.

The invention discloses a production process for preparing potassium sulfate from glauberite by an asymmetric balance method, which is characterized in that two asymmetries are designed, one is that an evaporation system adopts a mode of feeding more cold clear liquid and discharging more salt mother liquid, evaporation is carried out according to a fixed proportion, enough evaporation condensate water can be evaporated in unit time, and the evaporation efficiency is improved; the excessive part is used for digesting water from an external supplementing system; secondly, the secondary conversion reaction is a reaction of a potassium chloride solution and glauberite in an equal proportion, the glauberite containing the glauberite is matched with anhydrous sodium sulphate to produce potassium sulfate, and the core is that the potassium index of a primary conversion reaction system is controlled by using the proportion of the glauberite containing the glauberite, so that the production quantity of the glauberite is adjusted; the potassium sulfate is matched with the evaporation and condensation water amount consumed due to equal-proportion dissolution, so that the overall balance is maintained for production, and meanwhile, the quality of the prepared potassium sulfate meets the quality requirements of agricultural potassium sulfate national standard GB / T 20406-2017 powder crystalline superior products (K2O is greater than or equal to 52%) and first-grade products (K2O is greater than or equal to 50%).

A liquid fuel production system including: a gas-adsorbing / desorbing portion; a heating medium-supplying portion configured to supply, to the gas-adsorbing / desorbing portion, a heating medium for heating the gas-adsorbing / desorbing portion; a liquid fuel-synthesizing portion including a first gas flow path storing a catalyst that advances a conversion reaction from a raw material gas to a liquid fuel, and a second gas flow path through which a temperature-controlling gas that controls a temperature of the first gas flow path is flowed, the liquid fuel-synthesizing portion being configured to flow a first outflow gas out of the first gas flow path, and to flow a second outflow gas out of the second gas flow path; and a heat exchanger configured to perform heat exchange between the first outflow gas and the heating medium to heat the heating medium. The first outflow gas contains a condensable gas.

A method for preparing theasinensin A (TSA) by means of a low-temperature enzyme process. The method comprises using a plant polyphenol oxidase enzyme extract or polyphenol oxidase enzyme formulation as an enzyme source, using epigallocatechin gallate (EGCG) as a substrate, using as a reaction system a buffer solution having a certain pH value, and performing an enzymatic reaction at a low temperature and subsequent steps such as column chromatography, distillation and concentration, liquid phase preparation, and freeze drying, thereby synthesizing TSA in a directional enzymatic manner. The method achieves EGCG enzymatic oxidation at a low temperature and obtains dimeric TSA by means of a conversion reaction, laying a theoretical and practical basis for green, safe, efficient and large-scale industrial production and utilization of TSA.

The invention discloses a mutant and a genetically engineered bacterium for catalytic synthesis of D-chiral inositol by using the mutant, and relates to the technical field of biology, inositol dehydrogenase is subjected to site-directed saturation mutagenesis at N154 and C269 sites and then is subjected to combined mutagenesis at M123, V157, A171 and Y277 to obtain the inositol dehydrogenase mutant, so that a conversion reaction is carried out in a forward direction, and the conversion rate of D-chiral inositol is greatly improved.

The invention discloses a mixed waste plastic recovery and conversion reaction system which comprises a waste plastic raw material bin, a spiral feeder, a reaction furnace, a combustion chamber, a condensing device and an oil storage tank. The reaction furnace is sequentially provided with a feeding end, a reaction area and a discharging end, the reaction area comprises a plurality of reaction sections which are connected in series, the reaction sections are sequentially and continuously arranged along the length of a furnace body, and each reaction section is provided with a temperature control device which is independently opened and closed; the discharging end is communicated with a condensing device, and the condensing device is provided with a condensed kerosene outlet and a non-condensed pyrolysis gas outlet; the non-condensing pyrolysis gas outlet is divided into two paths, one path is communicated with the reaction furnace, and the other path is communicated with the combustion chamber. According to the invention, multiple reaction sections are combined and connected in series, multiple reaction mode combinations are provided, and high-value aviation kerosene can be produced. According to the invention, dechlorination can be effectively carried out before pyrolysis, and equipment corrosion, catalyst poisoning, secondary pollution and the like are prevented; according to the invention, the non-condensed gas is recovered for hydrogenation upgrading of products and self-heating of the system, so that energy is saved.

The invention belongs to the field of energy catalysis and carbon resource utilization, and particularly relates to a self-regeneration perovskite / alkaline earth metal oxide composite bifunctional material and preparation and application thereof. The invention provides a composite bifunctional component formed by Ce doped perovskite A (Ti1-x-yCexNiy) O3 and alkaline earth metal oxide, and an adsorption-catalysis bifunctional material obtained after the composite bifunctional component is subjected to thermal reduction can realize carbon dioxide capture under a high-temperature condition and is converted into synthesis gas (CO and H2) in situ. By introducing Ce, the controllable dissolution and re-embedding process of Ni in ICCU-DRM reaction is promoted, lattice self-repairing and catalytic activity self-regeneration are realized, the stability of carbon dioxide conversion reaction is effectively improved, and the problem of inactivation caused by easy sintering and carbon deposition of a traditional Ni-based catalyst in dry reforming reaction is solved.

The invention discloses an AxSDR (Adenosine Diphosphate Dehydrogenase Regulator) gene of an Algaea xinjiangensis source enzyme, a recombinant bacterium containing the gene and an application of the recombinant bacterium and the AxSDR gene of the Algaea xinjiangensis source enzyme. The nucleotide sequence of the enzyme AxSDR gene is as shown in SEQ ID NO. 1; the amino acid sequence of the enzyme protein coded by the enzyme AxSDR gene is SEQ ID NO. 2. The AxSDR gene is used for constructing a recombinant plasmid, and then the recombinant plasmid is introduced into E.coli BL21 (DE3) to obtain a gene recombinant bacterium containing the gene. Enzyme protein coded by the AxSDR gene or recombinant bacteria containing the gene can catalytically reduce 1500 mmol / L of m-trifluoromethyl acetophenone to prepare a chiral compound (R)-1-(3-trifluoromethyl phenyl) ethanol, conversion of a high-concentration (282g / L) substrate is achieved, the reaction lasts for 11 hours, the product yield is 99.6%, and the enantiomer excess value is 99% or above.

The invention relates to the technical field of catalysis, and particularly discloses a method for preparing pure biodiesel from kitchen waste oil through enzyme catalytic desulfurization. The method comprises the following steps: adding a Sm2O3 / ZrO2 solid acid catalyst into the kitchen waste oil for pretreatment to obtain pretreated waste oil, and then adding lipase into the pretreated waste oil for catalyzing transesterification to obtain the biodiesel. According to the method for preparing the pure biodiesel from the kitchen waste oil through enzyme catalytic desulfurization, in-situ esterification and synchronous desulfurization of free fatty acid can be completed in a single-step reaction, the stability of a conversion reaction is effectively improved, the production process is simplified, and the conversion efficiency of preparing the biodiesel from the kitchen waste oil is improved.

A catalyst suitable for use in carbon oxide conversion reactions is described, said catalyst in the form of a shaped unit formed from an oxidic catalyst powder, said catalyst comprising 30-70% by weight of copper oxide, combined with zinc oxide, alumina and silica, having a Si:Al atomic ratio in the range 0.005 to 0.15:1, and having a BET surface area ≥105 m2 / g and a copper surface area >37 m2 / g catalyst. The catalyst is prepared by a co-precipitation method using an alumina sol.

The invention belongs to the field of batteries, and particularly discloses a battery positive electrode and a zinc-iodine battery containing the battery positive electrode. The battery positive electrode comprises a positive electrode material layer, and the positive electrode material layer contains a positive electrode material; the positive electrode material contains an active substance and a polar organic catalyst; the polar organic catalyst contains at least one group selected from hydroxyl, carboxyl, aldehyde group, ketone group, ester group, ether group, amino, amide group, nitryl, nitrile group, sulfonic acid group and quaternary ammonium salt. The polar organic catalyst is introduced into the battery positive electrode, the contained polar group can efficiently catalyze the iodine positive electrode four-electron conversion reaction, the reaction kinetics of the battery system is obviously accelerated, the iodine positive electrode capacity multiplication is realized, the complete conversion of I0 / I + can be realized, and the high-voltage platform capacity ratio reaches 50%; and the iodine positive electrode capacity, the rate capability and the self-discharge capacity retention rate of the zinc-iodine battery containing the battery positive electrode are remarkably improved.

The present disclosure relates to a process for conversion of hydrocracked pitch into distillates in a slurry hydro-conversion reactor in presence of hydrogen gas with recycling of a hydrocracked pitch residue to achieve improved overall conversion and minimize fresh addition of catalyst. The slurry hydro-conversion of hydrocracked vacuum residue along with recycle of hydrocracked pitch residue (4d) provides improved overall conversion of >97% with very less yield of <3 wt. % pitch (>540° C.) along with distillates (C6+−370° C.) in a yield of 55 wt. % and VGO (370-540° C.) in a yield of 28.3 wt. %. The recycling of hydrocracked pitch residue back to slurry hydro-conversion reactor facilitates the minimization of the addition of fresh catalyst to the reactor section.

The invention relates to a method for recycling lead by treating lead plaster of a waste lead-acid storage battery, and belongs to the technical field of lead secondary resource recycling. The method comprises the following steps: (1) slurrying lead paste with water to obtain slurry; adding sodium carbonate and sodium sulfite into the slurry, heating and then carrying out reduction-conversion reaction under a certain temperature condition to obtain a reaction mixture containing a lead-containing solid and a liquid phase; (2) carrying out solid-liquid separation on the reaction mixture obtained in the step (1) under the condition that the temperature is not lower than 40 DEG C to obtain a lead-containing solid; (3) drying the lead-containing solid obtained in the step (2) to obtain a dried lead-containing material; and (4) the dried lead-containing material obtained in the step (3) is subjected to high-temperature reduction smelting, and metal lead is obtained. According to the method, a wet process and a pyrogenic process are adopted, the used raw materials such as sodium carbonate, sodium sulfite and pea coal are cheap and easy to obtain, the whole technological process is short, operation is easy, the lead recovery rate is high, and industrial large-scale application and popularization are facilitated.

The invention provides a pseudoxanthomonas wenibertii strain TY3-10 and application thereof in preparation of rare ginsenoside, and belongs to the technical field of biological medicine. The preservation number of the pseudoxanthomonas wenibertii strain TY3-10 disclosed by the invention is CGMCC (China General Microbiological Culture Collection Center) No.35238. The pseudoxanthomonas wenibertii The strain TY3-10 has the characteristic of producing beta-glucosidase and beta-xylosidase, and can be used for converting various ginsenosides and notoginsenoside into rare ginsenosides F2, Rd2, Fd, C-Mc1 and Rh1. The invention further provides a method for preparing the rare ginsenoside, and ginsenoside is subjected to a conversion reaction under the action of the pseudoxanthomonas wenibertii strain TY3-10 to obtain the rare ginsenoside. The invention provides a new process for preparing the rare ginsenoside, and has a wide application prospect.

To provide a technique for improving the utilization rate of carbon dioxide in a fuel gas production system.SOLUTION: The fuel gas production system includes a storage device including a recovery device configured to recover carbon dioxide, a recovery unit configured to recover carbon dioxide separately from the recovery device, and a storage unit configured to store the carbon dioxide recovered by the recovery unit, a fuelization device configured to supply hydrogen and at least one of the carbon dioxide recovered by the recovery device and the carbon dioxide stored by the storage device to a reactor to generate fuel gas, and a control unit configured to control the storage device to supply the carbon dioxide recovered by the recovery unit to the storage unit when a differential pressure becomes smaller than a differential pressure threshold.SELECTED DRAWING: Figure 4

The present invention belongs to the preparation of liquid fuels from syngas, and particularly relates to a method for directly converting syngas into liquid fuels. Using syngas as the reaction raw material, the conversion reaction is carried out in a fixed bed or a moving bed. The catalyst used includes Component I and Component II, and Component I and Component II are compounded together in a mechanical mixing manner; the active ingredient of Component I is a metal oxide, and Component II is a heteroatom ZSM-5 molecular sieve; the heteroatom in the heteroatom ZSM-5 molecular sieve is Fe or Ga. The reaction process of the present invention has a very high product yield and selectivity. The selectivity of the liquid fuel composed of C5-C 11 can reach 50-80%, the selectivity of aromatics in C5-C 11 is less than 40%, and at the same time, the selectivity of the by-product methane is less than 3%, having good application prospects.

The invention relates to a method for separating heavy metal cations and radionuclides from aqueous solutions. The method according to the invention can be used to separate dissolved and / or suspended naturally occurring ions or radioactive ions produced by radioactive decay, nuclear transformation reactions such as nuclear fission, or, for example, by activation with neutron radiation, from aqueous solutions.

The invention discloses a rapid conversion method for continuous production of diazonium salt, which comprises the following steps: dissolving an amide raw material in a polar solvent, adding acid to obtain an amide salt solution, and dissolving sodium nitrite in water to obtain a sodium nitrite aqueous solution; constructing a reaction system in the reaction kettle; synchronously dropwise adding the amide salt solution and the sodium nitrite aqueous solution into a reaction system according to a set proportion; enabling the amide salt solution and the sodium nitrite aqueous solution to be subjected to a conversion reaction in the reaction kettle through automatic control while dropwise adding in a certain proportion synchronously, so as to generate diazonium salt; after diazonium salt is generated in the reaction kettle, carrying out instant conversion reaction on the diazonium salt and a reaction system to obtain a rapid conversion reaction mixture; and treating the rapid conversion reaction mixture, and separating to obtain a target product. According to the invention, the safety problem of diazonium salt production, storage, transportation and use is solved, the yield of diazotization and next reaction is greatly improved, the automation degree is high, and the purpose of eliminating the danger of diazonium salt can be achieved.

The invention relates to a method and device for preparing low-carbon olefins, and the method comprises the following steps: S1, contacting raw oil with a catalytic conversion catalyst in a catalytic conversion reactor for catalytic conversion reaction to obtain a catalytic conversion reaction product; s2, separating the catalytic conversion reaction product to obtain ethylene and propylene as well as a first circulating olefin flow containing butene and / or a second circulating olefin flow containing C5 + olefin; s3, enabling the olefin material to enter an etherification unit, and contacting the olefin material with an alcohol raw material under an etherification condition to obtain a circulating ether material and etherified olefin; and S4, enabling at least one part of etherified olefin to enter an isomerization unit, and carrying out isomerization reaction in the presence of an isomerization catalyst to obtain isomerized olefin. According to the method disclosed by the invention, the conversion of ethers into low-carbon olefins can be realized, the yield and selectivity of ethylene and propylene are improved, the yield of methane is reduced, the content of methanol in the product is reduced to the greatest extent, and the conversion of low-cost methanol into low-carbon olefins is realized.

The invention belongs to the technical field of electrocatalytic carbon dioxide reduction catalysts, and discloses a silver-based catalyst suitable for fluctuating carbon dioxide electrolysis and a preparation method of the silver-based catalyst. The preparation method comprises the following steps: uniformly and continuously dropwise adding a potassium hydroxide solution into a silver nitrate solution to prepare a silver oxide catalyst, and further applying a constant reduction current to the silver oxide catalyst in the presence of carbon dioxide gas for in-situ reduction to prepare the quintuple twin crystal silver-based catalyst. The preparation method disclosed by the invention combines precipitation titration and in-situ electroreduction methods, and has the characteristics of simplicity in operation, greenness, high efficiency and suitability for mass production; meanwhile, the catalyst can maintain high selectivity to carbon monoxide products in an extremely wide potential window range of 3V when being used in an electro-catalysis carbon dioxide conversion reaction, and is very suitable for being directly matched and coupled with fluctuating renewable energy sources.

The invention discloses a catalytic cracking light naphtha processing method. The method comprises the following steps: (I) mixing catalytic cracking light naphtha with hydrogen, and then feeding the mixture into a hydrofining reaction zone for hydrofining reaction to obtain a refined naphtha material flow; (II) the refined naphtha material flow obtained in the step (I) enters a hydro-conversion reaction zone to be subjected to a hydro-conversion reaction, converted catalytic cracking light naphtha is obtained, and the temperature of the hydro-conversion reaction is 100-300 DEG C higher than that of the hydrofining reaction. According to the present invention, the olefin in the catalytic cracking light naphtha product is completely saturated, the normal hydrocarbon content is increased, and the triene yield can be substantially improved when the catalytic cracking light naphtha product is adopted as the ethylene raw material through steam cracking.