The invention relates to a preparation method of an orientation LTL type molecular sieving membrane for
gas separation. The preparation method comprises the following steps: (1) mixing an alkali source, an aluminum source, a
silicon source and deionized water to obtain gel and performing hydrothermal
crystallization for preparing a
seed crystal; (2) performing acidic treatment on the
seed crystal prepared in the step (1) so as to remove aluminum from the grain surface, and then preparing a suspension in sec-butyl
alcohol, and stirring for modifying; (3) dropwise adding the LTL type molecular sieving suspension acquired by modifying in the step (2) into an LB
liquid tank for forming a membrane, and then transferring the acquired membrane onto the surface of a carrier; (4) mixing an alkali source, an aluminum source, a
silicon source and deionized water to obtain a
secondary growth synthetic solution; (5) contacting the product from the step (3) with the
secondary growth synthetic solution from the step (4), performing hydrothermal
crystallization and acquiring the LTL type molecular sieving membrane on the carrier. According to by the invention, the simple, controllable, efficient and repeatable LB method is adopted for preparing the orientation LTL type
molecular sieve seed crystal layer and the high c-axis orientation LTL type molecular sieving membrane is prepared through
secondary growth; the operation is simple, the degree of orientation is easily controlled, and the
repeatability is high.