2786 results about "Metal-organic framework" patented technology

An isoreticular metal-organic framework (IRMOF) and method for systematically forming the same. The method comprises the steps of dissolving at least one source of metal cations and at least one organic linking compound in a solvent to form a solution; and crystallizing the solution under predetermined conditions to form a predetermined IRMOF. At least one of functionality, dimension, pore size and free volume of the IRMOF is substantially determined by the organic linking compound.

The growth of continuous MOF membranes on porous polymeric supports is reported, wherein a dip-coating procedure is used to deposit a layer of seed MOF nanocrystals on the surfaces of porous polymers, preferably in the form of hollow fibers, and polycrystalline MOF membranes are subsequently grown at temperatures as low as 65° C. from precursor solutions. The present work opens the road to inexpensive and scalable fabrication of MOF membranes for large-scale separation applications.

A carbon dioxide storage system includes a container and a conduit attached to the container for introducing or removing a carbon dioxide-containing composition from the container. A carbon dioxide storage material is positioned within the container. The carbon dioxide-storage material includes a metal-organic framework, which has a sufficient surface area to store at least 10 carbon dioxide molecules per formula unit of the metal-organic framework at a temperature of about 25° C.

The invention relates to a porous metal organic framework material based on transition metal cobalt and a preparation method thereof. The metal organic framework material is a compound with supramolecular porous network structure and formed by self-assembly of metal ions and organic ligands through coordination complexation. The porous cobalt-based metal organic framework material contains one or more metal ions, and one or more organic ligands; and at least one of the metal ions is Co (II). The porous cobalt-based organic framework material has excellent selective adsorption on CH4 in a separation process of CH4 and N2; and the advantage of adsorption selectivity on CH4 is particularly evident under low pressure. The material is particularly suitable for development and recovery of oil field gas, coal bed methane and biogas.

The invention relates to a preparation method of a metal organic framework based composite phase-change material. The method comprises the steps that a metal organic framework material substrate is prepared selectively; hole diameter size design and hole channel polarity regulation and control are performed on the substrate according to the size and the kind of a core material, so that a phase-change core material to be loaded is matched better; the soluble phase-change core material is prepared into a solution; a metal organic framework material is dispersed in the prepared phase-change material solution; a phase-change material is adsorbed by utilizing an extra-large specific surface area and a nano hole channel structure of the metal organic framework material; drying is performed; and then the metal organic framework composite phase-change material with a shaping effect is obtained. According to the method, a novel metal organic framework based composite phase-change material is developed; the prepared metal organic framework based composite phase-change material can effectively avoid leakage and the like, and has the advantages of adjustable nano hole structure and wide core material selection range; the method is simple in technology and mild in reaction condition, and is suitable for scale production; and a raw material is cheap and easy to obtain.

The invention relates to solids made of a porous crystalline metal-organic framework (MOF) loaded with at least one gas of biological interest, and to a method for preparing the same. The MOF solids of the present invention are capable of adsorbing and releasing in a controlled manner gases having a biological interest. They can be used in the pharmaceutical field and/or for applications in the cosmetic field. They can also be used in the food industry.

The invention provides a metal organic framework/polymer nanofiber composite membrane material and a preparation method thereof. The metal organic framework/polymer nanofiber composite membrane material is characterized by being prepared from a polymer nanofiber membrane; a metal organic framework layer grows on the surfaces of nanofibers in the polymer nanofiber membrane. The preparation method is characterized by comprising the steps of firstly preparing the polymer nanofiber membrane, hydrolyzing the polymer nanofiber membrane, and putting the hydrolyzed polymer nanofiber membrane into a precursor solution of a metal organic framework to enable the metal organic framework to grow on the polymer nanofiber membrane so as to obtain the metal organic framework/polymer nanofiber composite membrane material. The metal organic framework/polymer nanofiber composite membrane material has great application potential in the fields such as gas adsorption and separation, catalysts, sensors and electrode materials.

The invention discloses a metal catalyst based on a metal organic framework as well as a preparation method and application thereof. Metal salt and organic ligand are used for preparing the metal organic framework (MOF), and then the MOF is used as a precursor to be reduced to obtain the metal catalyst. The catalyst based on the MOF in the invention has high catalytic activity, good circularity and excellent catalytic property while being used as the catalyst of NH3BH3 hydrolysis hydrogen discharging reaction, thus having significant application value and wide application prospect in the field of catalyst and hydrogen storage technology.

The invention relates to a preparation method of a thermal conduction enhanced metal organic framework gas storage material and belongs to the field of nanocomposites. The preparation method comprises the following steps: firstly selectively preparing a metal organic framework material with a large surface area and a high micropore proportion; performing synthesis post-modification on the metal organic framework material by a 'one-pot' method, regulating the polarity and contained functional groups of pores, immobilizing metal nanoparticles inside the pores to enhance the thermal conduction property of the metal organic framework material; adsorbing industrial gas by utilizing the ultra-large specific surface area and the nano duct structure of the metal organic framework material, wherein the thermal conduction enhanced adsorption material can be used for quickly transmitting the heat generated in the adsorption and desorption process of the industrial gas. The metal organic framework industrial gas adsorber prepared by the invention can be used for efficiently adsorbing and desorbing the industrial gas and effectively improving the thermal conduction property of the adsorber, and avoiding the influence of the heat effect on the adsorption quantity in the adsorption and desorption process. The preparation method provided by the invention has the advantages of use of readily available and inexpensive raw materials, simple process, and mild reaction conditions and is suitable for large-scale production.

The present invention provides a metal-organic framework (“MOF”) comprising a plurality of metal clusters and a plurality of multidentate linking ligands. Each metal of the plurality of metal clusters comprises one or more metal ions. Each ligand of the plurality of multidentate linking ligands connects adjacent metal clusters. The present invention also provides a method of forming the metal-organic framework. The method of the invention comprises combining a solution comprising one or metal ions with a multidentate linking ligand having a sufficient number of accessible sites for atomic or molecular adsorption that the surface area of the resulting metal-organic framework is greater than 2,900 m²/g.

The invention provides a method for preparing a multilevel porous carbon base composite phase change material, and belongs to the field of composite phase change materials. The method comprises the following steps: at first, preparing an organic metal skeleton material by using such methods as a solution method, a solvothermal method or a stirring synthesis method; with the organic metal skeleton material as a template, high temperature carbonizing under the protection of an inert gas, and changing the carbonizing temperature and the post treatment manner to obtain a multilevel porous carbon material with a super-large specific surface area and a super-large pore volume; selecting proper solvents according to different kinds of phase change core materials, preparing the phase change core materials to a solution, dispersing the porous carbon material into the solution, removing the solvent by such manners as heating, and meanwhile the phase change core materials are adsorbed and limited in the porous carbon material. The composite phase change material prepared by the method provided by the invention has good thermal storage property, can effectively avoid the leakage problem of the phase change core material, and has the advantages of excellent heat transfer property, good cycling stability and wide application range, and the process is simple and is suitable for large-scale production.

The invention discloses an application of a metal-organic framework functional material, and belongs to the technical field of water processing. A metal-organic framework material is subjected to pre-modification and post-modification, and a series of different functional groups are introduced to an organic ligand or an inorganic metal cluster of the material. The metal-organic framework functional material is used as an adsorbent for removing radioactive ions from nuclear waste. The metal-organic framework material containing sulfate radicals and sulfonate radicals has a preferable adsorption effect on 133Ba<2+>; the maximum removal rate can reach 99.9%; and adsorption equilibrium can be achieved in 5min. By using the functionalized metal-organic framework material, a simple, easy, efficient, and fast novel method is provided for removing 133Ba<2+> from the nuclear waste. The metal-organic framework functional material has significant industrial application value with respect to nuclear pollution management.

The invention discloses a preparation method of an aromatic polyamide film modified by a ZIF-8 type metal-organic framework material. A ZIF-8 filling polyamide composite film is prepared on an ultrafiltration bottom film by an interfacial polymerization method, wherein nano-grade ZIF-8 particles are added into an m-phenylenediamine aqueous solution and/or a trimesoyl hexane solution; a polyamide ultrathin skin layer, to which ZIF-8 is added, is formed through interfacial polymerization. The preparation method has the advantages that by the use of a ZIF-8 nano-grade aperture and a three-dimensional multi-hole structure, the selectivity or the permeability of the aromatic polyamide film is improved; the prepared ZIF-8 filling polyamide composite film can serve as a nanofiltration or reverse osmosis film for removing organic matters from the aqueous solution; when the adding ratio of an organic phase or water phase solution, to which ZIF-8 is added, is 0.05-0.15% (w/v), the performance of the film is the highest, and the permeation flux and the retention rate can be increased at the same time; furthermore, the nanofiltration or reverse osmosis performance of the two-phase adding film is higher than that of a single-phase adding film.

The invention discloses a method for rapidly synthesizing a BTC (1,3,5-benzenetricarboxylic acid)-based nanoscale organometallic framework material at room temperature. The nanomaterial is prepared by the following steps: mixing metal acetate aqueous solution with BTC solution at room temperature, and reacting to obtain BTC-based organometallic framework nanoparticles. The method is rapid, simple and energy-saving; the yield is high; the used raw materials and solvents are inexpensive and easily available; the safety problem of commonly used nitrate is not caused; the method is favorable to the industrial production and has wide application prospects in the fields of catalysis, adsorption, drug carriers, building of nano devices and the like.

The invention discloses an MOFs (metal-organic frameworks) based carbon dioxide adsorbent, which includes MOFs and organic amine loaded in the pore channels and on the surface of MOFs. The mass ratio of the MOFs to the organic amine is 0.1-10:1. The MOFs based carbon dioxide adsorbent provided by the invention realizes the combined action of physical adsorption and chemical adsorption and can adsorb and store carbon dioxide at medium and low temperature, and regeneration and reutilization of the adsorbent can be realized under certain condition. The MOFs based carbon dioxide adsorbent has good adsorption capacity, high selectivity and cycling stability on carbon dioxide, and can overcome the disadvantages of easy volatilization and easy corrosion of equipment in organic amine so as to meet the industrial processing requirements. The invention also discloses a preparation method of the MOFs based carbon dioxide adsorbent and application of the adsorbent in adsorption of carbon dioxide in flue gas.

Microwave assisted synthesis may be used to produce water-repellent metallic organic frameworks (MOFs) molecules. The water-repellent MOFs contain non-polar functional groups, such as a trifluoromethoxy group, which has a strong water repellent effect. The water-repellent MOF, when exposed to water vapor for one week does not result in a significant X-ray power pattern change. The water-repellent MOFs may be suitable as an adsorbent in many industrial applications, such as gas chromatography.

The invention aims to provide a preparation method and application of a porous nano metal organic framework material, and is characterized in that the preparation method comprises the steps: adding a metal ion, an organic ligand, a surfactant and a nanocrystalline guide agent or a reagent forming the nanocrystalline guide agent into a growth medium, forming a framework structure through chemical complexation, crystallizing, filtering, washing, drying, and finally obtaining the porous nano metal organic framework material. The addition amount of the surfactant is 0-30% of the molar concentration of the metal ion; the metal ion is one or more of Cu<II>, Al<III>, Mg<II>, Fe<III>, Ni<II>, Co<II> and Zn<II>; the organic ligand has at least one atom independently selected from oxygen, sulfur and nitrogen and can be subjected to coordinated complexation to the metal ion through the atom. The method not only can effectively suppress the size of MOFs materials, but also easily improves size homogeneity and synthetic efficiency of the product.

The invention discloses a solid electrolyte for lithium ion battery and an application thereof. The electrolyte comprises a polyoxyethylene and/or polyoxyethylene derivative, an inorganic-organic hybrid framework and lithium salt. The inorganic-organic hybrid framework is one selected from a metal organic framework (MOF), a covalent-organic framework (COF) and a zeolite imidazole framework (ZIF). The prepared lithium ion cell electrolyte can be used to avoid safety problems such as cell combustion, even explosion and the like which are caused by leakage of traditional lithium ion batteries and has high lithium ion conductivity. By the use of the solid electrolyte, thinning of lithium ion batteries can be realized, so as to extend their application range.

The invention discloses a preparation method of a composite diaphragm of a lithium-sulphur battery. The composite diaphragm is formed by modifying a coating on a diaphragm matrix. The preparation method comprises the following steps: mixing a metal organic framework material and a conductive agent according to a mass ratio of 3:1 to 1:1 to obtain a uniformly-mixed coating material; uniformly mixing the coating material with an adhesive according to a mass ratio of 9:1 to 5:1, dispersing in a solvent by adopting a mechanical mixing or ultrasonic dispersing method to obtain a uniformly dispersed coating slurry; coating the surface of the diaphragm matrix by the slurry, and drying to obtain the composite diaphragm, wherein the content of a solid material in the slurry is 60-90 mg/mL. The preparation method of the composite diaphragm of the lithium-sulphur battery is simple; large-scale production is easily realized, and strong practical value is achieved; by adopting the diaphragm in conjunction with a high-capacity electrode material, the commercialized application of the lithium-sulphur battery is effectively promoted.

Metal-organic framework (MOF)-polymer mixed matrix membranes (MOF-MMMs) can be prepared by dispersing high surface area MOFs into a polymer matrix. The MOFs allow the polymer to infiltrate the pores of the MOFs, which improves the interfacial and mechanical properties of the polymer and in turn affects permeability. These mixed matrix membranes are attractive candidates for practical gas separation applications such as CO₂ removal from natural gas.

The invention relates to a method for preparing a metal organic frame supported film. The method comprises the following steps of: reacting a metal source provided by an inorganic supporting body with an organic ligand so as to generate a layer of crystal seeds on the surface of the supporting body; and preparing a continuous film layer through a secondary reaction. The method integrates a synthetic process and a coating process of the crystal seeds, and the crystal seeds generated through an in-situ chemical reaction are evenly distributed on the surface of the supporting body and have strong bonding force with the supporting body, and thus, a metal organic frame supported film with good integrity and high stability can be prepared successfully. The method can effectively solve the problem that a metal organic frame material can hardly form a film on the inorganic supporting body. The filming method of the invention has important meaning to the mass preparation and the practical application of the metal organic frame supported film.

The invention relates to the field of materials, in particular to a MOFs material as well as a preparation method and use thereof. The MOFs material comprises an organic metal framework base materialwhich comprises a grafting group; and the grafting group is grafted with linear polymer through a covalent bond. Mechanical tensile property of the MOFs material provided by the invention is greatly improved, and a membrane containing grafted MOF is obviously improved in anti-plasticizingplasticization performance resistance in comparison with a membrane containing un-modified MOF on the premiseof same MOF load amount; and moreover, the membrane containing grafted MOF is obviously improved in gas selectivity in comparison with athe membrane containing un-modified MOF.

The invention discloses a method for preparing a two-dimensional MOFs material, which includes the following steps: organic molecules and a metal organic framework material are mixed under normal temperature, the mixture is then milled or ball-milled, and after washing, centrifuging and drying, the two-dimensional metal organic framework material is obtained. the reaction conditions for the preparation of the two-dimensional MOFs are mild, reaction is fast, yield is high, solvent does not need to be added, moreover, the reaction process is simple, needed equipment is simple, and a ball mill can be used for implementing large-scale production.

The invention discloses a method for preparing a metal-organic framework material film, and belongs to the technical field of preparation of inorganic-organic hybrid films. The method comprises the following specific steps: enabling a ZrC14 solution to react with a 2-aminaterephthalic acid solution to prepare UiO-66-NH2; adding methacrylic anhydride to obtain modified UiO-66-NH2; adding modified UiO-66-NH2 in an acrylate organic monomer, adding a photoinitiator, and irradiating under UV light to obtain the metal-organic framework material film. The method is a simple and fast MOF film processing method, self-supported MOFs hybrid films of different polymer systems are synthetized, MOFs particles and the polymer systems are bonded, and the MOF particles are dispersed uniformly in the polymer systems. The method is simple, fast, and low in raw material cost, and has industrialized advantages.

The invention relates to a method for rapidly preparing a metal-organic framework (MOF) compound having a controllable structure by using an electrochemical method. After the method is adopted, an MOF material can be electrically synthesized on a variety of macroscopic and microcosmic conductive substrates by means of a simple and rapid one-step electrical synthesis method. Furthermore, the directional growth of multiple MOFs materials can be realized on different types of macroscopic and microcosmic conductive substrates by regulating and controlling the types, concentrations, proportions, electrical synthesis voltages, time and the like of organic ligands and metal ions in an electrolyte solution; the particle sizes and morphologies of the MOFs materials can be artificially regulated and controlled. The electrochemical synthesis method has the advantages of short synthesis time and simple operation process, synthesis can be completed under the condition of room temperature, and a condition for subsequent extensive preparation and industrial application is provided. In addition, the prepared novel MOFs thin-film material has a very wide application prospect in the aspects of electrolytic water oxygen evolution reaction (OER), supercapacitor electrode materials (SCs), lithium ion battery electrode materials, biosensing and the like.

An electrolyte membrane for a lithium battery, the electrolyte membrane including: a matrix including a polymerization product of a (meth)acrylate monomer composition; and a porous metal-organic framework dispersed in the matrix, wherein the metal-organic framework includes a crystalline compound including a metal ion or metal ion cluster which is chemically bound to an organic ligand, and a liquid electrolyte including a lithium salt and a nonaqueous organic solvent.

The invention relates to a preparation method and application method of a titanium dioxide nanosheet supported MIL-100 (Fe) composite photocatalysis material, belongs to the field of titanium dioxide photocatalysis, and especially relates to the field of titanium dioxide nanosheet supported porous metal organic skeleton (MOFs) composite materials. The preparation method comprises the following steps: 1, uniformly stirring tetrabutyl titanate and hydrofluoric acid at normal temperature, putting the obtained mixture in a hydrothermal reaction kettle, carrying out a reaction, separating the obtained material, washing the separated material, and drying the washed material to obtain titanium dioxide nanosheets; and 2, uniformly dispersing the titanium dioxide nanosheets in an anhydrous ethanol solution of iron trichloride, carrying out magnetic stirring at normal temperature for 15 min, carrying out suction filtration separation to obtain a product, dispersing the product in an anhydrous ethanol solution of trimesic acid, carrying out a 50-80 DEG C water bath reaction for 20-50 min, carrying out suction filtration separation to obtain a product, and repeating above processes in step 2 2-50 times to obtain the titanium dioxide nanosheet supported MIL-100 (Fe) composite photocatalysis material. The catalyst prepared through the method is especially suitable for catalytic degradation of high-concentration organic dyes (such as methylene blue) under visible light irritation) to reach a very high degradation rate.

The invention relates to a multifunctional rare earth metal-organic framework of which the chemical formula is {[Ln(FDA)1.5(DMF)].DMF}n, wherein Ln is Eu or Tb, the FDA is furyl-2,5-dicarboxylic acid, and the DMF is N,N-dimethylformamide; and the rare earth metal framework structure has an Eu<3+>/Tb<3+> ion in a coordination environment, and forms a three-dimensional framework structure containing one-dimensional honeycomb channels. The preparation method comprises the following steps: by using europium nitrate hexahydrate or terbium nitrate hexahydrate as a metal salt, H2FDA as a ligand and DMF as a solvent, stirring the mixed solution, baking, separating and washing the solid to obtain the multifunctional rare earth metal-organic framework. The multifunctional rare earth metal-organic framework provided by the invention has an fluorescent identification function on cancerigenic organic solvents, such as methylbenzene, benzene and acetone, has excellent selective adsorptivity for gas and high acting force with H2, contains high adsorptive enthalpy, and thus, is a multifunctional novel-structure microporous MOF (metal-organic framework) material.

The present invention discloses a method for preparing a metal organic framework film. The method comprises a step of contacting a metal source with an organic ligand to form the metal organic framework film on a substrate by a hot-pressing method. By means of the method provided by the present invention, a large number of metal organic framework films with quite high purity can be obtained conveniently and rapidly, so that industrialized production and application are implemented, and the method has the advantages of low costs, simplicity in operation, rapid production, mass production of products, high purity and the like.

The invention belongs to the technical field of metal organic skeletal materials, and discloses a Cu-based organic skeleton-graphene oxide composite porous material and a preparation method and application thereof. The preparation method particularly comprises the following steps of uniformly mixing copper acetate, 1,3,5-benzene tricarboxylic acid and graphene oxide; carrying out ball milling; washing; centrifugalizing; and drying to obtain the Cu-based organic skeleton-graphene oxide composite porous material. The preparation method disclosed by the invention has the advantages of short reaction time (only 30 minutes), no solvent, large preparation quantity, low energy consumption, simple operation method, and the like, is a high-efficiency, clean and environment-friendly novel green synthetic method. The obtained Cu-based organic skeleton-graphene oxide composite porous material greatly increases the adsorption capacity on hydrocarbon VOCs (Volatile Organic Compounds) and achieves the purposes that the adsorption capacity on methanol is 2.06 times of the adsorption capacity on the methanol caused by a Na-ZSM molecular sieve, 2.54 times of the adsorption capacity on the methanol caused by flexible-MOF(E), and 1.79 times of the adsorption capacity on the methanol caused by HKUST-1 under the same condition.