266 results about "Trimesic acid" patented technology

The invention discloses self-adhesion-crosslinking double modified bamboo powder, a preparation method and application, and relates to the technical field of composites.The preparation method of the modified bamboo powder comprises the following steps that S1, bamboo powder, 2, 5-dihydroxyterephthalic acid, 4-aminobenzoyl hydrazine, N, N '-diisopropylcarbodiimide and tris (hydroxymethyl) aminomethane are mixed for a reaction; and S2, trimesic acid is added into the solution obtained after the reaction in the S1 for a reaction, filtering, washing and drying are conducted, and the self-adhesion-crosslinking double modified bamboo powder is obtained. The prepared modified bamboo powder is green and environmentally friendly, through a self-adhesion mechanism, a cross-linking mechanism, a branched-chain phenyl heterogeneous nucleation mechanism and the like, the interfacial compatibility of PBAT and the bamboo powder and the crystallinity of PBAT are improved, and therefore the mechanical property of PBAT / bamboo powder is enhanced.

The invention relates to the technical field of polymer electrolyte, in particular to a self-repairing type gel polymer electrolyte membrane, a preparation method and application in an energy storage battery, the self-repairing type gel polymer electrolyte membrane is prepared by the following steps: dissolving amino-terminated polyethylene glycol in an organic solvent, adding trimesic acid under the protection of an inert atmosphere, heating, stirring and reacting to form a pre-polymerized solution, cooling, and then adding trimesic acid into the pre-polymerized solution to prepare a self-repairing type gel polymer electrolyte membrane; the preparation method comprises the following steps: adding glyoxylic acid and glacial acetic acid, carrying out a constant temperature reaction to obtain a solution A, adding LiTFSI into the solution A, carrying out ultrasonic dispersion to a homogeneous phase, pouring the obtained slurry onto a template, and carrying out a drying curing reaction to obtain the self-repairing gel polymer electrolyte membrane. A rigid aromatic cross-linking agent is used for inhibiting polymer crystallization and improving mechanical integrity, an imine bond-based dynamic covalent network is introduced to realize an autonomous interface repairing function at the working temperature of the battery, and meanwhile, a polyethylene glycol ether oxygen chain is used for constructing an efficient lithium ion transmission channel; therefore, the technical boundary that the conductivity, the mechanical strength and the interface stability of the traditional GPE are difficult to collaboratively optimize is broken through.

The invention relates to the technical field of electro-catalysis and hydrogen energy, in particular to a modified LDH-based catalyst and a preparation method and application thereof. The preparation method comprises the following steps: mixing trimesic acid, water, an organic solvent, a nickel salt, a cobalt salt and an iron salt, carrying out electro-deposition, washing and drying to obtain a NiFeCo-LDH (TA) catalyst; the preparation method comprises the following steps: soaking a NiFeCo-LDH (TA) catalyst in a silver salt solution, washing and drying to obtain the modified LDH-based catalyst. The modified LDH-based catalyst provided by the invention can effectively resist chloride ion corrosion and inhibit dissolution of active metals in layered double hydroxides (LDH) under high current density in seawater, can reach industrial grade current density under relatively low overpotential, and can stably run for more than 1000 hours.

The invention discloses preparation of a high-performance carbon matrix embedded iron-based catalyst based on a metal organic framework precursor and application of the high-performance carbon matrix embedded iron-based catalyst in reverse water-gas shift reaction. In the preparation process, commercially available 1, 3, 5-trimesic acid iron (the chemical formula is C9H3FeO6, abbreviated as Fe-BTC) is selected as a raw material, pyrolysis treatment is carried out in an argon atmosphere, then air passivation is carried out, and finally the high-performance carbon matrix embedded iron-based catalyst based on the metal organic framework precursor is successfully prepared. The MOF-600 has excellent performance in many catalysts, the carbon dioxide production rate reaches 24.0 mmol CO.gcat <-1 >. S <-1 > at the temperature of 400 DEG C in a reverse water gas shift reaction, the performance is remarkably superior to that of an existing non-noble metal catalyst, and extremely high catalytic efficiency and application potential are shown.

The present invention provides a manganese metal-organic framework material with oxidase properties, a preparation method, and an application thereof. The material is prepared by the following method: using 1,3,5-trimethic acid as an organic ligand, manganese acetate tetrahydrate as a manganese source, and a water-ethanol solution as a solvent, to obtain a manganese metal organic framework (MOF) precursor via a solvothermal synthesis technique; the manganese MOF precursor is post-synthetically modified using an oxidant, wherein the oxidant is a mixed solution of an aqueous alkali metal hydroxide solution and H2O2, and the ratio of the manganese MOF precursor to the alkali metal hydroxide is (400-600) mg:(0.5-2) mmol. By using specific types and amounts of manganese MOF precursors and oxidants, the resulting metal-organic framework nanomaterial has specific enzyme-like properties, can exert the function of uricase, and has optimal and high uricase activity under neutral pH conditions.

The invention relates to the technical field of building materials, and particularly discloses interior wall waterproof putty powder and a preparation method thereof. Interior wall water-resistant putty powder is prepared from sulphoaluminate cement, nano heavy calcium powder, silica fume, a double-MOF composite nanotube, modified diatomite, polypropylene fiber, nano titanium dioxide, a defoaming agent, a dispersing agent and a mildew preventive, and the double-MOF composite nanotube is obtained by loading copper trimesic acid in an inner cavity of a halloysite nanotube and loading dimethyl imidazole cobalt on the outer wall of the halloysite nanotube; the modified diatomite is obtained by modifying diatomite with stearic acid. The interior wall waterproof putty powder provided by the invention adopts the double-MOF composite nanotube as a core functional material, and under the synergistic effect of multiple components, the water resistance and air permeability of a putty layer are effectively enhanced.

The invention relates to the technical field of electrocatalysts, and discloses a heterojunction catalyst composed of cobalt-copper co-doped ruthenium dioxide and metal ruthenium as well as a preparation method and application of the heterojunction catalyst. The preparation method comprises the following steps: carrying out hydrothermal reaction on cobalt salt and trimesic acid in a mixed solvent to prepare a cobalt metal organic framework precursor; a cobalt-copper bimetal organic framework is obtained through ion exchange of a copper salt solution; preparing a ruthenium-cobalt-copper ternary metal organic framework by adopting secondary ion exchange of a ruthenium salt solution; and carrying out air calcination treatment to obtain the cobalt-copper co-doped ruthenium dioxide and metal ruthenium heterojunction catalyst. According to the method, cobalt and copper atoms are uniformly doped in ruthenium dioxide crystal lattices through a step-by-step ion exchange strategy, and metal ruthenium nano-particles are grown on the surface in situ to form a heterogeneous interface. The obtained catalyst shows excellent performance in an acidic electrolyzed water anode oxygen evolution reaction, the overpotential is only 199 mV under the current density of 10 mA. Cm, and the stability can be maintained for 40 hours.

The invention discloses a copper-based MOF derived carbon-MgH2 composite solid hydrogen storage material and a preparation method thereof.The preparation method comprises the steps that 1, metal inorganic salt is dissolved in deionized water, stirring is conducted till reactants are dissolved, and a solution a is obtained; 2, trimesic acid is dissolved in a solution composed of N, N-dimethylformamide and methanol according to the volume ratio of 1: 1, ultrasonic treatment is conducted, and a solution b is obtained; 3, mixing and stirring the solution a and the solution b to obtain a mixed solution; step 4, adding the mixed solution into a reaction kettle for reaction, and after the reaction, performing furnace cooling overnight to room temperature; 5, a first product obtained after the reaction is washed with N, N-dimethylformamide and methyl alcohol for multiple times, and drying is conducted to obtain a Cu-based MOFs material; and 6, the dried Cu-based MOF material and MgH2 are mixed and subjected to ball milling, and the MOF catalyzed magnesium-based composite hydrogen storage material is obtained. The synthesis is simple, the reaction condition is mild, and the introduction of the copper-based MOF effectively improves the hydrogen absorption / desorption behavior of the MgH2 hydrogen storage material.

The invention discloses Pseudomonas putida, a bacterial agent thereof and an application of the Pseudomonas putida in chemical wastewater treatment, the Pseudomonas putida is named as PH-20 and preserved in the China General Microbiological Culture Collection Center on March 17, 2025, and the preservation number of the strain is CGMCC No. 33831. The invention further discloses a preparation method of the Pseudomonas putida. The pseudomonas putida disclosed by the invention can be used for rapidly degrading polybenzoic acid such as terephthalic acid, phthalic acid, isophthalic acid, trimellitic acid, trimellitic acid and pyromellitic acid in wastewater under the conditions of high salt and low temperature, and the degradation effect is still excellent under the condition that various pollutants coexist.

The present invention discloses a method for preparing a glass fiber diaphragm modified with a bismuth-based metal organic framework material, comprising: (1) using bismuth nitrate pentahydrate and trimesic acid as raw materials, and synthesizing a bismuth-based metal organic framework material by solvent thermal reaction; (2) adding the bismuth-based metal organic framework material prepared in step (1) and polyvinylidene fluoride to an N-methylpyrrolidone solution for mixing; (3) modifying the mixed solution obtained in step (2) onto a glass fiber diaphragm by a suction filtration method, and obtaining a glass fiber diaphragm modified with a bismuth-based metal organic framework material after drying. The present invention also discloses a glass fiber diaphragm modified with a bismuth-based metal organic framework material obtained by the above-mentioned preparation method and its application in a zinc ion battery. The glass fiber diaphragm modified with a bismuth-based metal organic framework material provided by the present invention can improve its electrochemical performance when applied to a zinc ion battery, thereby solving the problem of poor cycle performance of ordinary glass fiber diaphragms applied to aqueous batteries.

The invention discloses a BTCP-Ac-Eu-MOF double-fluorescence-emission fluorescent probe as well as a preparation method and application thereof, and belongs to the technical field of detection probes. The preparation method comprises the following steps: synthesizing BTCP from salicylic acid and 2-aminothiophenol to obtain a product 1, and reacting the product 1 with acetic anhydride and triethylamine to obtain BTCP-Ac; the preparation method comprises the following steps: mixing europium nitrate hexahydrate and trimesic acid, and performing high-temperature reaction to obtain Eu-MOF powder; and the BTCP-Ac and the Eu-MOF are mixed, such that the BTCP-Ac / Eu-MOF dual-fluorescence emission fluorescent probe is obtained. The europium metal organic framework has a clear structure, ultrahigh porosity and a designable function, the europium metal organic framework is combined with AIE fluorescent molecules to enhance the performance of the europium metal organic framework, and the fluorescence of the europium metal organic framework can be used as a colorimetric reference, so that the function of sensitively, quickly and conveniently indicating the freshness of meat products is realized.

The invention provides a DESs modified GO (at) MOF808 composite material, and the DESs modified GO (at) MOF808 composite material is prepared by the following steps: modifying the composite material GO (at) MOF808 with DESs to obtain GO (at) MOF-808 (at) DESs; the GO-coated MOF808 is prepared from the following raw materials in parts by weight: 56 to 84 parts of ZrCl4, 18.4 to 27.6 parts of trimesic acid (H3BTC) and 12 to 18 parts of graphene oxide (GO). The invention further discloses a preparation method of the GO-coated MOF808. The invention also provides a preparation method of the composite material, and a method for detecting the content of tolcapone and entacapone in an environment. According to the invention, the DES-modified GO-coated MOF808 composite material is used as an adsorption matrix, and the adsorption capacities of the adsorption material to entacapone and tolcapone can reach up to 86.50 + / -4.79 mg / g and 126.21 + / -2.72 mg / g; the method for removing and detecting entacapone and tolcapone in water by combining D-muSPE with DES (at) GO (at) MOF808 as an adsorption material with LC-MS / MS is simple to operate, high in sensitivity and high in removal rate.

The invention discloses a preparation method of a hydrophobic modified copper-based monatomic catalyst. The preparation method comprises the following steps: S1, dissolving Cu (NO3) 2 and L-alanine in deionized water; dissolving trimesic acid in an ethanol solution; s2, mixing the two solutions, and stirring at regular time at normal temperature to obtain a Cu-BTC precursor; s3, grinding and uniformly mixing the Cu-BTC precursor and dicyandiamide, and then putting the mixture into a tubular furnace for high-temperature pyrolysis treatment to obtain Cu-N-C-Pre powder; s4, the Cu-N-C-Pre powder is subjected to acid leaching impurity removal treatment in an acid solution, and the copper-based monatomic catalyst is obtained; and S5, dissolving the Cu-N-C catalyst and triacetylene benzene in an organic solvent, adding pyridine, uniformly stirring, and carrying out a hydrothermal reaction to obtain the hydrophobic modified copper-based monatomic catalyst. Hydrophobic modification is performed on the surface of the Cu-N-C monatomic catalyst, so that the hydrophobicity of the surface of the catalyst is enhanced, the catalytic activity of the catalyst in a reaction for preparing phenol by activating a benzene C-H bond by taking H2O2 as an oxidizing agent is improved, and the yield of phenol is increased.

The invention provides a manganese metal organic framework material with oxidase characteristics as well as a preparation method and application thereof, and the material is prepared by the following method: taking 1, 3, 5-trimesic acid as an organic ligand, manganese acetate tetrahydrate as a manganese source and a water-ethanol solution as a solvent, and obtaining a manganese MOFs precursor through a solvothermal method synthesis technology; the manganese MOFs precursor is subjected to post-synthesis modification with an oxidizing agent, the oxidizing agent is a mixed solution of an alkali metal hydroxide aqueous solution and H2O2, and the dosage ratio of the manganese MOFs precursor to the alkali metal hydroxide is (400-600) mg: (0.5-2) mmol. The manganese MOFs precursor and the oxidizing agent with specific types and using amounts are adopted, so that the obtained metal organic framework nano material has specific enzyme-like characteristics, can play a role of urate oxidase, has optimal urate oxidase activity under a neutral pH condition, and is relatively high in activity.

The invention discloses a fireproof composite material and a preparation method thereof, and belongs to the technical field of high polymer materials. The fireproof composite material comprises the following raw materials in parts by weight: 60-80 parts of epoxy resin, 20-30 parts of silicon dioxide, 10-18 parts of a flame retardant, 10-15 parts of a curing agent, 2-5 parts of a toughening agent, 1-2 parts of an accelerant and 1-3 parts of an antioxidant. The toughening agent is prepared by reacting trimesic acid with oleyl alcohol to generate a triester compound, reacting 1, 4-benzene diboric acid with 3-sulfydryl-1, 2-propylene glycol to generate a dioxaboroheterocyclic compound, and reacting the triester compound with the dioxaboroheterocyclic compound. The fireproof composite material prepared by the invention has good flame retardant property and impact resistance.

The invention relates to a fluoro-ligand regulated metal organic framework material and a preparation method and application thereof, the fluoro-ligand regulated metal organic framework material is prepared and synthesized by using zirconium oxychloride as a metal node and trimesic acid / 5-fluoroisophthalic acid as an organic ligand through a reflux method; the unit structural formula of the fluorinated ligand metal organic framework material is [Zr6O4 (OH) 4 (BTC) 2-x (F-BTC) x (AA) y (H2O) z], according to the preparation method, trimesic acid and part of 5-fluoroisophthalic acid are co-coordinated, a C-F bond is introduced to regulate and control the electronic environment around a Zr node through deletion of a connecting site, uniform nucleation of crystals is promoted, the grain size of the obtained material is remarkably reduced, and the dispersity is higher.

The invention relates to the technical field of electrocatalytic reduction of carbon dioxide, and provides a water-phase ultrafast green preparation method of a bismuth-based metal organic framework, and the preparation method of the bismuth-based metal organic framework material comprises the following steps: taking bismuth nitrate pentahydrate as a bismuth source, taking trimesic acid as a ligand, and preparing the bismuth-based metal organic framework material through a surfactant-mediated sonochemistry method. A complex topological bismuth-based metal organic framework (CAU-17) is synthesized in water under an environmental condition. The synthesis method is rapid, environmentally friendly, low in cost and easy to operate, cetyltrimethylammonium bromide (CTAB) amphiphilic molecules are used as a structure inducer, removal (dehydration) of non-coordinated water is controlled, the deprotonation degree of ligands is improved, therefore, coordination and crystallization in an aqueous solution are adjusted, and by adjusting the dosage of the added CTAB, the deprotonation degree of the ligands is increased. And the crystal structure evolution from a preferentially generated compact sheet structure to a porous rod-shaped structure is realized. Meanwhile, the synthesized CAU-17 catalyst shows relatively high current density and Faraday efficiency in electrocatalytic reduction of carbon dioxide into formic acid, and has relatively good selectivity.

The present application belongs to the technical field of the synthesis of chiral boron compounds, and in particular relates to an MOF-Cu(II) / CMC composite material, and a preparation method therefor and the use thereof. The preparation method for an MOF-Cu(II) / CMC composite material of the present application comprises: dropwise adding an aqueous solution of sodium carboxymethyl cellulose to an aqueous solution of a bivalent copper salt, performing solid-liquid separation, mixing obtained composite microspheres with an organic solution of trimesic acid, heating the resulting mixture, and subjecting same to solid-liquid separation, so as to obtain an MOF-Cu(II) / CMC composite material. The MOF-Cu(II) / CMC composite material is used in an asymmetric chiral boron addition reaction. The reaction is performed at room temperature, involves mild conditions, is applicable to a wide range of substrates and has a high yield and enantioselectivity. Moreover, the method can achieve the synthesis of a chiral organic boride in a solvent having simple components, providing an efficient new method for the preparation of drug molecules and active intermediates, and also broadening the range of substrates used for the preparation of chiral organic borides.

The invention discloses a ruthenium-doped cobalt metal oxide nanosheet electrocatalyst and a preparation method and application thereof, and relates to the technical field of electrocatalysts.The preparation method comprises the steps that cobalt salt and trimesic acid are weighed and jointly dissolved in a methanol solution, and a mixed solution A is obtained after primary ultrasonic mixing treatment; dropwise adding a methanol solution containing ruthenium salt into the mixed solution A, carrying out secondary ultrasonic mixing treatment to obtain a mixed solution B, and carrying out hydrothermal reaction on the mixed solution B to obtain a ruthenium-cobalt metal organic framework precursor; and calcining the ruthenium-cobalt metal organic framework precursor. Compared with the prior art, the ruthenium-doped cobalt metal oxide nanosheet electrocatalyst prepared by the method shows excellent hydrogen evolution electrocatalytic activity and stability in an alkaline water electrolysis reaction, the performance of the catalyst is superior to that of a commercial platinum-carbon catalyst, and stable potential output can be kept in a 100-hour continuous test without obvious attenuation.

The invention discloses a metal organic framework (MOF) derived Fe / Mn composite material and a preparation method and application thereof.The preparation method comprises the following steps that 1, Fe (NO3) 3.9 H2O, Mn (NO3) 2.4 H2O and trimesic acid C9H6O6 are mixed and stirred to be uniform according to a preset molar ratio, and mixed powder a is obtained; step 2, adding a preset volume of N, N-dimethylformamide (DMF) into the mixed powder a, and carrying out magnetic stirring reaction to obtain a solution b; step 3, putting the solution b into a reaction kettle, and reacting for 10 to 12 hours at the temperature of 160 to 180 DEG C, so as to obtain an organic framework material MIL-100 (Fe-Mn); and step 4, grinding the organic framework material MIL-100 (Fe-Mn) to a preset particle size, and calcining the organic framework material MIL-100 (Fe-Mn) in an N2 atmosphere at a temperature of 800 DEG C for 2-3 h to obtain the target MOF-derived Fe / Mn composite material. The invention aims to prepare a catalyst which can be used for degrading bisphenol A (BPA) in organic wastewater.

The invention provides a Z-type heterojunction material for synchronously removing phosphorus and tetracycline in sewage. The material is composed of a hexagonal flaky nano magnesium-aluminum-iron hydrotalcite matrix with the size of 30-100 nm and a metal oxide growing on the surface. The preparation method of the material comprises the following steps: carrying out hydrothermal treatment on magnesium-aluminum-iron hydrotalcite and trimesic acid in N-N dimethylformamide liquid, growing a metal organic framework compound on the surface of the magnesium-aluminum-iron hydrotalcite in situ through dissolved-out metal ions and trimesic acid, and roasting the metal organic framework compound to obtain the Z-type heterojunction material. The Z-type heterojunction material can synchronously and efficiently remove phosphorus and tetracycline in sewage, the synchronous removal rates of 50 mg of the material to phosphorus and tetracycline are 97.60% and 95.47% respectively in 100 mL of a phosphorus (concentration of 25 mg / L) water sample and a tetracycline (concentration of 50 mg / L) water sample, and the synchronous removal rates of phosphorus and tetracycline are still 87.62% and 85.57% after continuous circulation for five times. The Z-type heterojunction material can be applied to the aspect of phosphorus and tetracycline mixed sewage treatment in the breeding industry.

The invention provides metal organic framework loaded guanidyl polymer nanoparticles as well as a preparation method and application thereof. The nanoparticles comprise a copper-based metal-organic framework material and a guanidyl-containing polymer loaded on the surface of the copper-based metal-organic framework material; the copper-based metal-organic framework material comprises a copper trimesic acid complex, the copper trimesic acid complex has a porous structure and an octahedral structure, and the guanidyl-containing polymer is distributed in the porous structure and on the surface of the octahedral structure; the nanoparticles are insoluble in water, and the particle size of the nanoparticles is nanoscale. When the antibacterial agent is added into the resin, the non-dissolution antibacterial coating can be prepared, the guanidyl-containing polymer is not easy to dissolve out, the antibacterial coating is endowed with good antibacterial property, and the problems that the hydrophilic guanidyl-containing polymer and the coating resin are poor in compatibility and easy to leach out are solved.

The invention provides a preparation method of an environment-friendly two-dimensional high-strength coating and a raw material recycling method, and the preparation method comprises the following steps: preparing trimesic acid, melamine, a solution A and a solution B into a reaction solution according to a proportion in a glove box, and putting the reaction solution into a high-pressure reaction kettle to react to form gel; and mixing the gel with ethanol, carrying out ultrasonic treatment, filtering, washing and drying to obtain faint yellow polymer powder, dissolving the powder in trifluoroacetic acid, and preparing film coatings with different thicknesses by adjusting the concentration of the solution. According to the raw material recovery method of the coating, an acid catalyst is used for hydrolysis, trimesic acid and melamine are recovered, and the recovery rate reaches 88.9% or above. The prepared coating material has the advantages of high strength, low density, excellent leakproofness and chemical corrosion resistance, raw material recycling is realized, the production cost is reduced, the green and environment-friendly requirements are met, and the coating material is suitable for light high-strength materials, protective coatings and other high-performance application fields.

The invention discloses a metal oxide / carbon / nickel composite material, a preparation method and application of the metal oxide / carbon / nickel composite material to a magnesium-based hydrogen storage material, and belongs to the field of hydrogen storage energy. The problems that a single-component catalyst in the MgH2 hydrogen storage material is low in active site, the interface is inactivated in the circulation process and the like are solved. A metal nickel source and a cerium source are combined with an organic ligand trimesic acid to form bimetal MOF, CeO2 / C / Nix obtained after calcination inherits the high specific surface area of MOF, metal is evenly dispersed in a carbon matrix, CeO2 / C / Nix is introduced into MgH2, microscale efficient catalysis of MgH2 is achieved, when the doping amount of CeO2 / C / Ni20 is 8 wt.%, the initial dehydrogenation temperature is 188.23 DEG C, and when the doping amount of CeO2 / C / Ni20 is 8 wt.%, the initial dehydrogenation temperature is 188.23 DEG C, and the specific surface area of CeO2 / C / Nix is 27.8 wt.%. After 10 cycles, the capacity retention rate is 98.8%, excellent hydrogen storage performance is shown, and a unique insight is provided for large-scale production of the magnesium-based hydrogen storage material.

The invention discloses a manganese metal organic framework material preparation method, which comprises: dissolving an organic ligand trimesic acid in a solvent to form a solution A, and dissolving manganese acetate tetrahydrate and a surfactant in the solvent to form a solution B, the solvent being an aqueous solution of ethanol; slowly dropwise adding the solution B into the solution A, uniformly stirring, and standing for reaction, wherein the molar ratio of trimesic acid to manganese acetate tetrahydrate is 1: (1.5-3.2); and after the reaction is finished, cleaning a product and drying to obtain the manganese metal organic framework material. According to the application of the manganese metal organic framework material in the aqueous battery, the manganese metal organic framework material is prepared into electrode slurry, the surface of a titanium foil is coated with the electrode slurry, and the electrode slurry is dried to serve as an electrode plate of the aqueous battery. The manganese metal organic framework material with the uniform flower-ball shape is prepared, embedding and disengaging of Zn < 2 + > in the charging and discharging process are effectively promoted, and the electrochemical performance of the water-based zinc battery is improved.

The invention discloses polyester resin for a triglycidyl trimesic acid ester curing powder coating and a preparation method of the polyester resin. The polyester resin is obtained by esterification and condensation polymerization of trimesic acid, terephthalic acid, glycidyl methacrylate, glycidyl neodecanoate, palmitic acid, neopentyl glycol and behenyl alcohol. The cleaning agent comprises the following components in parts by mass: 5-15 parts of trimesic acid; 10 to 25 parts of terephthalic acid; 3 to 17 parts of glycidyl methacrylate; 8 to 12 parts of glycidyl neodecanoate; 3 to 7 parts of palmitic acid; 5 to 19 parts of neopentyl glycol; and 3 to 7 parts of behenyl alcohol. According to the invention, terephthalic acid and neopentyl glycol are used as framework monomers, and glycidyl methacrylate and glycidyl neodecanoate are used for modifying polyester resin, so that an obtained coating is higher in gloss and better in fineness; behenyl alcohol and palmitic acid are adopted to reduce the softening point of the polyester resin, reduce the difference between a curing agent and polyester in softening flow, increase the wettability of a film forming matter to pigments, fillers and a base material, and improve the gloss and fineness of a coating.

The present invention discloses a copper-containing hydrogen-bond organic framework material, a preparation method, and an application thereof. The method comprises the following steps: mixing trimesic acid, melamine, and a copper salt and dispersing them in a solvent to obtain a mixed suspension; transferring the mixed suspension to a reactor for reaction to obtain a copper-containing hydrogen-bond organic framework material solution; cooling the copper-containing hydrogen-bond organic framework material solution, centrifuging it, and then post-treating the copper-containing hydrogen-bond organic framework material solid obtained by centrifugation to obtain a copper-containing hydrogen-bond organic framework material with a one-dimensional rod-shaped structure. When used in the thermal decomposition catalysis of ammonium perchlorate, the copper-containing hydrogen-bond organic framework material prepared by the present invention can exhibit high catalytic activity and stability, thereby concentrating the exothermic temperature range and heat release of ammonium perchlorate.

The application belongs to the technical field of nanometer material preparation, and discloses a regulation method for synthesizing copper coordination polymers with different dimensions. The method is to obtain copper coordination polymers with different dimensional morphologies under room temperature conditions by controlling the reaction sequence of copper ion solution, uniform benzenetricarboxylic acid and 4,4-dipyridine and the molar ratio of uniform benzenetricarboxylic acid and 4,4-dipyridine. The synthesis process is simple, the cost is low, the dimension of the morphology is adjustable, large-scale industrial production is possible, and good economic benefits and environmental benefits are achieved.

The application relates to a preparation method of a composite semiconductor photocatalyst and application thereof, and comprises the following steps: preparing g-C3N4 nanosheets; dispersing the prepared g-C3N4 nanosheets into methanol at a mass fraction of 10% to 70%, then adding 750 mg of trimesic acid and 150 mg of bismuth nitrate, and ultrasonic treating for 10 min to obtain a mixed suspension; transferring the mixed suspension into a microwave reaction kettle for reaction, the reaction temperature is 90 to 130 DEG C, the reaction time is 30 to 60 min, and centrifugal drying is carried out after the reaction is completed; then g-C3N4 / Bi-MOF is obtained through anhydrous methanol washing and freeze drying; a heterostructure is constructed, the energy band structure is changed, the charge transmission resistance is reduced, the photocatalytic activity is improved, the photocatalyst has two different structure and property photocatalytic activity centers, and the photocatalytic activity is changed from the energy band structure and the catalytic activity.

The present application relates to the technical field of building materials, and specifically discloses a water-resistant putty powder for interior walls and a preparation method thereof. A water-resistant putty powder for interior walls, the raw materials of which include: sulphoaluminate cement, nano-heavy calcium powder, silica fume, double MOF composite nanotubes, modified diatomaceous earth, polypropylene fiber, nano-titanium dioxide, defoaming agent, dispersant and mildew inhibitor. The double MOF composite nanotubes are obtained by loading copper trimesic acid in the inner cavity of halloysite nanotubes and loading dimethylimidazole cobalt on the outer wall; the modified diatomaceous earth is obtained by modifying diatomaceous earth with stearic acid. The water-resistant putty powder for interior walls of the present application uses double MOF composite nanotubes as the core functional material, and under the synergistic effect of multiple components, it effectively enhances the water resistance and air permeability of the putty layer.