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2126 results about "Chemical measurement" patented technology

Chemical measures can be used to directly detect pollutants such as lead or mercury. Chemical measures can also be used to detect imbalances within the ecosystem. Such imbalances may indicate the presence of certain pollutants. For example, elevated acidity levels may indicate the presence of acid mine drainage.

Solid electrolytic capacitor containing a conductive polymer

A method for forming an electrolytic capacitor is disclosed. The method includes forming a conductive polymer coating by polymerizing a monomer in the presence of less than a stoichiometric amount of an oxidative polymerization catalyst. The present inventor has found that the use of less than the stoichiometric amount of the oxidative polymerization catalyst per mole of monomer can slow the polymerization of the monomer, creating oligomers that are shorter in length than if fully polymerized into a polymer. Without wishing to be bound by theory, it is believed that these shorter oligomers provide better penetration into the porous anode. Thus, the resulting conductive polymer layer can be more intimately positioned with respect to the anode. As a result, the formed capacitor can exhibit better performance.
Owner:KYOCERA AVX COMPONENTS CORP

Cobalt-molybdenum sulfide catalyst materials and methods for ethanol production from syngas

The present invention provides methods and compositions for the chemical conversion of syngas to alcohols. The invention includes catalyst compositions, methods of making the catalyst compositions, and methods of using the catalyst compositions. Certain embodiments teach compositions for catalyzing the conversion of syngas into products comprising at least one C1-C4 alcohol, such as ethanol. These compositions generally include cobalt, molybdenum, and sulfur. Preferred catalyst compositions for converting syngas into alcohols include cobalt associated with sulfide in certain preferred stoichiometries as described and taught herein.
Owner:ALBEMARLE CORP

Coated nanoparticles and quantum dots for solution-based fabrication of photovoltaic cells

CIGS absorber layers fabricated using coated semiconducting nanoparticles and / or quantum dots are disclosed. Core nanoparticles and / or quantum dots containing one or more elements from group IB and / or IIIA and / or VIA may be coated with one or more layers containing elements group IB, IIIA or VIA. Using nanoparticles with a defined surface area, a layer thickness could be tuned to give the proper stoichiometric ratio, and / or crystal phase, and / or size, and / or shape. The coated nanoparticles could then be placed in a dispersant for use as an ink, paste, or paint. By appropriate coating of the core nanoparticles, the resulting coated nanoparticles can have the desired elements intermixed within the size scale of the nanoparticle, while the phase can be controlled by tuning the stochiometry, and the stoichiometry of the coated nanoparticle may be tuned by controlling the thickness of the coating(s).
Owner:AERIS CAPITAL SUSTAINABLE IP

Method for gas-solid contacting in a bubbling fluidized bed reactor

The present invention relates to a method for gas-solid contacting in a bubbling fluidized bed reactor by:(a) introducing into a reactor with bed length to bed diameter ratio below about 5.0, a primary gas consisting essentially of reactant(s) of the reaction to be carried out in the bed of solid particles through a primary gas distributor located at the reactor bottom at a superficial gas velocity Up, which is very close or equivalent to the minimum fluidization velocity Umf, required for achieving the incipient fluidization of the solid particles in the bed to obtain an emulsion phase consisting essentially of the solid particles and the primary gas with little or no formation of gas bubbles to achieve incipient fluidization or liquid-like behavior of fluidizable solid particles;(b) forming gas bubbles in the incipiently fluidized bed by introducing through a secondary gas distributor located immediately above the primary gas distributor a secondary gas, selected from one of the reactants which is used in excess of that required for the reaction stoichiometry, steam, an inert or a mixture of two or more thereof at a superficial gas velocity, Us, which is related to the superficial velocity of the primary gas such that a ratio of the superficial velocity of the secondary gas to the superficial velocity of the primary gas Us / Up, is in the range from about 0.5 to about 10.0, preferably from about 1 to about 5.
Owner:COUNCIL OF SCI & IND RES

Optimized fuel management system for direct injection ethanol enhancement of gasoline engines

Fuel management system for enhanced operation of a spark ignition gasoline engine. Injectors inject an anti-knock agent such as ethanol directly into a cylinder. It is preferred that the direct injection occur after the inlet valve is closed. It is also preferred that stoichiometric operation with a three way catalyst be used to minimize emissions. In addition, it is also preferred that the anti-knock agents have a heat of vaporization per unit of combustion energy that is at least three times that of gasoline.
Owner:MASSACHUSETTS INST OF TECH

Formation of CIGS absorber layer materials using atomic layer deposition and high throughput surface treatment

An absorber layer may be formed on on a substrate using atomic layer deposition reactions. An absorber layer containing elements of groups IB, IIIA and VIB may be formed by placing a substrate in a treatment chamber and performing atomic layer deposition of a group IB element and / or one or more group IIIA elements from separate sources onto a substrate to form a film. A group VIA element is then incorporated into the film and annealed to form the absorber layer. The absorber layer may be greater than about 25 nm thick. The substrate may be coiled into one or more coils in such a way that adjacent turns of the coils do not touch one another. The coiled substrate may be placed in a treatment chamber where substantially an entire surface of the one or more coiled substrates may be treated by an atomic layer deposition process. One or more group IB elements and / or one or more group IIIA elements may be deposited onto the substrate in a stoichiometrically controlled ratio by atomic layer deposition using one or more self limiting reactions.
Owner:AERIS CAPITAL SUSTAINABLE IP

Multi-component removal in flue gas by aqua ammonia

InactiveUS7255842B1Regeneration process is less-costlyIncrease load capacityGas treatmentNitrogen compoundsNitric oxideSlurry
A new method for the removal of environmental compounds from gaseous streams, in particular, flue gas streams. The new method involves first oxidizing some or all of the acid anhydrides contained in the gas stream such as sulfur dioxide (SO2) and nitric oxide (NO) and nitrous oxide (N2O) to sulfur trioxide (SO3) and nitrogen dioxide (NO2). The gas stream is subsequently treated with aqua ammonia or ammonium hydroxide which captures the compounds via chemical absorption through acid-base or neutralization reactions. The products of the reactions can be collected as slurries, dewatered, and dried for use as fertilizers, or once the slurries have been dewatered, used directly as fertilizers. The ammonium hydroxide can be regenerated and recycled for use via thermal decomposition of ammonium bicarbonate, one of the products formed. There are alternative embodiments which entail stoichiometric scrubbing of nitrogen oxides and sulfur oxides with subsequent separate scrubbing of carbon dioxide.
Owner:THE UNITED STATES AS REPRESENTED BY THE DEPARTMENT OF ENERGY

Mullite-aluminum titanate diesel exhaust filter

The invention is directed at a mullite-aluminum titanate porous diesel particulate filter constituting a porous ceramic body containing, expressed in terms of weight percent of the total body, of 60-90%, preferably 70-80%, most preferably 70% iron-aluminum titanate solid solution having a stoichiometry of Al2(1−x)Fe2xTiO5, where x is 0-0.1, and 10-40%, preferably 20-30%, most preferably 30% mullite (3Al2O3.2SiO2), and consists essentially, expressed in terms of weigh percent on the oxide basis, of 3 to 15% SiO2, 55 to 65% Al2O3, 22 to 40% TiO2, and 0 to 10% Fe2O3, and being useful for filtration of diesel exhaust. The inventive diesel particulate filter exhibits high interconnected open porosity and large median pore size, in combination with high permeability when fired to a temperature of between 1650° to 1700° C., along with high thermal shock resistance and good filtration capability.
Owner:CORNING INC

Method of controlling an engine exhaust gas system and method of detecting deterioration of catalyst/adsorbing means

In a method of controlling an exhaust gas system of an internal combustion engine including a nitrogen oxide reducing catalyst capable of adsorbing nitrogen oxide under a lean atmosphere and a nitrogen oxide sensor disposed downstream of the nitrogen oxide reducing catalyst, the nitrogen oxide reducing catalyst and the nitrogen oxide sensor are disposed in the exhaust gas system operated mainly under a lean condition, respectively. An output value of the nitrogen oxide sensor is compared with a predetermined value, and an operation condition of the internal combustion engine is temporarily changed into a stoichiometric condition or a rich condition, or a fuel is injected upstream of the nitrogen oxide reducing catalyst, so that the nitrogen oxide adsorbed to the nitrogen oxide reducing catalyst is detached or decomposed, and again the internal combustion engine is operated under the lean condition. Deterioration of the catalyst is determined based on Nox amount which is calculated from the sensor output, exhaust has flow amount and vehicle running distance.
Owner:NGK INSULATORS LTD

Power plant and control method

Ambient air is compressed into a compressed ambient gas flow with a main air compressor. The compressed ambient gas flow having a compressed ambient gas flow rate is delivered to a turbine combustor and mixed with a fuel stream having a fuel stream flow rate and a portion of a recirculated gas flow to form a combustible mixture. The combustible mixture is burned and forms the recirculated gas flow that drives a turbine. The recirculated gas flow is recirculated from the turbine to the turbine compressor using a recirculation loop. At least one emission level is measured by at least a first emission sensor in the recirculated gas flow and at least a first control signal is generated. The fuel stream flow rate is adjusted based on the at least a first control signal to achieve substantially stoichiometric combustion.
Owner:GENERAL ELECTRIC CO

Production of hydrogen and removal and sequestration of carbon dioxide from coal-fired furnaces and boilers

Methods for reducing and eliminating carbon dioxide from the emissions of solid fuel fired power plants, particularly coal fired power plants, and to sequester the carbon dioxide, typically by using existing equipment. In some embodiments, the methods involve pyrolyzing the solid fuel to remove volatile matter and using the volatile matter to produce hydrogen. Additionally, the methods may involve burning the solid fuel or pyrolized solid fuel at very fuel rich stoichiometric conditions. Sequestration may include the production of a carbon dioxide-containing solution and the pumping of the solution into the ground, particularly in areas high in limestone.
Owner:ZAUDERER BERT

Engine output control system and method

A system for an engine, comprising of a cylinder located in the engine; a first injector for injecting a first fuel into said cylinder; a second injector for injecting a second fuel into said cylinder; and a controller configured to vary an amount of said first and second fuel injection during engine operation based on operating conditions, where amounts of variation of said first and second fuels are set to maintain desired engine output and provide a substantially stoichiometric mixture.
Owner:FORD GLOBAL TECH LLC

Power plant and control method

Ambient air is compressed into a compressed ambient gas flow with a main air compressor. The compressed ambient gas flow having a compressed ambient gas flow rate is delivered to a turbine combustor and mixed with a fuel stream having a fuel stream flow rate and a portion of a recirculated gas flow to form a combustible mixture. The combustible mixture is burned and forms the recirculated gas flow that drives a turbine. The recirculated gas flow is recirculated from the turbine to the turbine compressor using a recirculation loop. At least one emission level is measured by at least a first emission sensor in the recirculated gas flow and at least a first control signal is generated. The fuel stream flow rate is adjusted based on the at least a first control signal to achieve substantially stoichiometric combustion.
Owner:GE INFRASTRUCTURE TECH INT LLC

High efficiency ultraviolet light emitting diode with band structure potential fluctuations

A method of growing an AlGaN semiconductor material utilizes an excess of Ga above the stoichiometric amount typically used. The excess Ga results in the formation of band structure potential fluctuations that improve the efficiency of radiative recombination and increase light generation of optoelectronic devices, in particular ultraviolet light emitting diodes, made using the method. Several improvements in UV LED design and performance are also provided for use together with the excess Ga growth method. Devices made with the method can be used for water purification, surface sterilization, communications, and data storage and retrieval.
Owner:TRUSTEES OF BOSTON UNIV

Valve and fueling strategy for operating a controlled auto-ignition four-stroke internal combustion engine

Part load operating point for a controlled auto-ignition four-stroke internal combustion engine is reduced without compromising combustion stability through load dependent valve controls and fueling strategies. Optimal fuel economy is achieved by employing negative valve overlap to trap and re-compress combusted gases below a predetermined engine load and employing exhaust gas re-breathing above the predetermined engine load. Split-injection fuel controls are implemented during low and intermediate part load operation whereas a single-injection fuel control is implemented during high part load operation. Split-injections are characterized by lean fuel / air ratios and single-injections are characterized by either lean or stoichiometric fuel / air ratios. Controlled autoignition is thereby enabled through an extended range of engine loads while maintaining acceptable combustion stability and emissions at optimal fuel economy.
Owner:GM GLOBAL TECH OPERATIONS LLC

High-throughput printing of semiconductor precursor layer from nanoflake particles

Methods and devices are provided for transforming non-planar or planar precursor materials in an appropriate vehicle under the appropriate conditions to create dispersions of planar particles with stoichiometric ratios of elements equal to that of the feedstock or precursor materials, even after selective forces settling. In particular, planar particles disperse more easily, form much denser coatings (or form coatings with more interparticle contact area), and anneal into fused, dense films at a lower temperature and / or time than their counterparts made from spherical nanoparticles. These planar particles may be nanoflakes that have a high aspect ratio. The resulting dense films formed from nanoflakes are particularly useful in forming photovoltaic devices.
Owner:AERIS CAPITAL SUSTAINABLE IP

Solid electrolytic capacitor containing a conductive polymer

A method for forming an electrolytic capacitor is disclosed. The method includes forming a conductive polymer coating by polymerizing a monomer in the presence of less than a stoichiometric amount of an oxidative polymerization catalyst. The present inventor has found that the use of less than the stoichiometric amount of the oxidative polymerization catalyst per mole of monomer can slow the polymerization of the monomer, creating oligomers that are shorter in length than if fully polymerized into a polymer. Without wishing to be bound by theory, it is believed that these shorter oligomers provide better penetration into the porous anode. Thus, the resulting conductive polymer layer can be more intimately positioned with respect to the anode. As a result, the formed capacitor can exhibit better performance.
Owner:KYOCERA AVX COMPONENTS CORP

Method for making thin-film semiconductors based on I-III-VI2 compounds, for photovoltaic applications

The invention concerns a method for making thin-film CIGS which consists in: electrochemically depositing on a substrate a layer of stoichiometry close to CuInSe2; then rapidly annealing said layer from a light source with pulses of sufficient power to recrystallize CIS. Advantageously, the electrodeposited elements are premixed. Thus, after the deposition step, a homogeneous matrix is obtained which can support sudden temperature increases during the rapid annealing.
Owner:ELECTRICITE DE FRANCE +1

Vapor deposition of metal oxides, silicates and phosphates, and silicon dioxide

Metal silicates or phosphates are deposited on a heated substrate by the reaction of vapors of alkoxysilanols or alkylphosphates along with reactive metal amides, alkyls or alkoxides. For example, vapors of tris-(ter-butoxy)silanol react with vapors of tetrakis(ethylmethylamido)hafnium to deposit hafnium silicate on surfaces heated to 300° C. The product film has a very uniform stoichiometry throughout the reactor. Similarly, vapors of diisopropylphosphate react with vapors of lithium bis(ethyldimethylsilyl)amide to deposit lithium phosphate films on substrates heated to 250° C. supplying the vapors in alternating pulse produces these same compositions with a very uniform distribution of thickness and excellent step coverage.
Owner:PRESIDENT & FELLOWS OF HARVARD COLLEGE

Method of HCCI and SI combustion control for a direct injection internal combustion engine

The present invention relates to methods for robust controlled auto-ignition and spark ignited combustion controls in gasoline direct-injection engines, including transients, using either exhaust re-breathing or a combination of exhaust re-compression and re-breathing valve strategy. These methods are capable of enabling engine operation with either lean of stoichiometric or stoichiometric air / fuel ratio for oxides of nitrogen (NOx) control, with varying exhaust gas recirculation (EGR) rates and throttle valve positions for knock control, and with a combination of homogeneous charge compression ignition (HCCI) and spark ignition (SI) combustion modes to optimize fuel economy over a wide range of engine operating conditions.
Owner:GM GLOBAL TECH OPERATIONS LLC

Mullite-aluminum titanate diesel exhaust filter

The invention is directed at a mullite-aluminum titanate porous diesel particulate filter constituting a porous ceramic body containing, expressed in terms of weight percent of the total body, of 60-90%, preferably 70-80%, most preferably 70% iron-aluminum titanate solid solution having a stoichiometry of Al2(1-x)Fe2xTiO5, where x is 0-0.1, and 10-40%, preferably 20-30%, most preferably 30% mullite (3Al2O3.2SiO2), and consists essentially, expressed in terms of weigh percent on the oxide basis, of 3 to 15% SiO2, 55 to 65% Al2O3, 22 to 40% TiO2, and 0 to 10% Fe2O3, and being useful for filtration of diesel exhaust. The inventive diesel particulate filter exhibits high interconnected open porosity and large median pore size, in combination with high permeability when fired to a temperature of between 1650° to 1700° C., along with high thermal shock resistance and good filtration capability.
Owner:CORNING INC

Synthesis gas process comprising partial oxidation using controlled and optimized temperature profile

This invention relates to methods for reacting a hydrocarbon, molecular oxygen, and optionally water and / or carbon dioxide, to form synthesis gas. The preferred embodiments are characterized by delivering a substochiometric amount of oxygen to each of a multitude of reaction zones, which allows for optimum design of the catalytic packed bed and the gas distribution system, and for the optimization and control of the temperature profile of the reaction zones. The multitude of reaction zones may include a series of successive fixed beds, or a continuous zone housed within an internal structure having porous, or perforated, walls, through which an oxygen-containing stream can permeate. By controlling the oxygen supply, the temperatures, conversion, and product selectivity of the reaction can be in turn controlled and optimized. Furthermore the potential risks of explosion associated with mixing hydrocarbon and molecular oxygen is minimized with increased feed carbon-to-oxygen molar ratios.
Owner:PHILLIPS 66 CO

Excess air factor control of diesel engine

A diesel engine (1) provided with a NOx catalyst (28A) and a diesel particulate filter (28B) performs lean burn operation during normal running, rich burn operation during regeneration of the NOx catalyst (28A), operation under the stoichiometric air-fuel ratio during desulphating of the NOx catalyst (28A), and operation under a slightly lean air-fuel ratio to regenerate the filter after desulphating of the NOx catalyst (28A). When the lean burn operation is applied, a controller (31) first controls the fuel injection amount, and controls an air supply amount based on the fuel injection amount. When rich burn operation is applied, the controller (31) first controls the air supply amount and controls the fuel injection amount based on the air supply amount. Due to this control, the response of the excess air factor control is enhanced while preventing torque fluctuation accompanying the variation of the target excess air factor.
Owner:NISSAN MOTOR CO LTD

Systems and Methods For Controlling Stoichiometric Combustion In Low Emission Turbine Systems

Systems, methods, and apparatus are provided for controlling the oxidant feed in low emission turbine systems to maintain stoichiometric or substantially stoichiometric combustion conditions. In one or more embodiments, such control is achieved by diverting a portion of the recirculating exhaust gas and combining it with the oxidant feed to maintain a constant oxygen level in the combined oxidant-exhaust stream fed to the combustion chamber.
Owner:EXXONMOBIL UPSTREAM RES CO

Engine cylinder deactivation to improve the performance of exhaust emission control systems

The invention provides a controller and cylinder deactivation system to regenerate an exhaust aftertreatment device for a multicylinder engine that operates primarily at an air / fuel ratio that is lean of stoichiometry. The invention uses the cylinder deactivation system to control temperature and air / fuel ratio of an exhaust gas feedstream going into an aftertreatment device. The invention also increases the amount of fuel delivered to each non-deactivated cylinder by an amount sufficient to maintain operating power of the engine. The regeneration action includes desorbing NOx from a NOx adsorber catalyst, desulfating the NOx adsorber catalyst, and purging a diesel particulate trap.
Owner:DELPHI TECH IP LTD

Method of operating a stoichiometric exhaust gas recirculation power plant

At least one main air compressor makes a compressed ambient gas flow. The compressed ambient gas flow is delivered to a turbine combustor at a pressure that is greater than or substantially equal to an output pressure delivered to the turbine combustor from a turbine compressor as at least a first portion of a recirculated gas flow. A fuel stream is delivered to the turbine combustor, and a combustible mixture is formed and burned, forming the recirculated gas flow. A turbine power is produced that is substantially equal to at least a power required to rotate the turbine compressor. At least a portion of the recirculated gas flow is recirculated through a recirculation loop. An excess portion of the recirculated gas flow is vented or a portion of the recirculated gas flow bypasses the turbine combustor or both.
Owner:GENERAL ELECTRIC CO
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