2107 results about "Chemical measurement" patented technology

Fuel management system for enhanced operation of a spark ignition gasoline engine. Injectors inject an anti-knock agent such as ethanol directly into a cylinder. It is preferred that the direct injection occur after the inlet valve is closed. It is also preferred that stoichiometric operation with a three way catalyst be used to minimize emissions. In addition, it is also preferred that the anti-knock agents have a heat of vaporization per unit of combustion energy that is at least three times that of gasoline.

An absorber layer may be formed on on a substrate using atomic layer deposition reactions. An absorber layer containing elements of groups IB, IIIA and VIB may be formed by placing a substrate in a treatment chamber and performing atomic layer deposition of a group IB element and/or one or more group IIIA elements from separate sources onto a substrate to form a film. A group VIA element is then incorporated into the film and annealed to form the absorber layer. The absorber layer may be greater than about 25 nm thick. The substrate may be coiled into one or more coils in such a way that adjacent turns of the coils do not touch one another. The coiled substrate may be placed in a treatment chamber where substantially an entire surface of the one or more coiled substrates may be treated by an atomic layer deposition process. One or more group IB elements and/or one or more group IIIA elements may be deposited onto the substrate in a stoichiometrically controlled ratio by atomic layer deposition using one or more self limiting reactions.

The invention provides crystalline nanoscale particles and tubes made from a variety of stoichiometries of BxCyNz where x, y, and z indicate a relative amount of each element compared to the others and where no more than one of x, y, or z are zero for a single stoichiometry. The nanotubes and nanoparticles are useful as miniature electronic components, such as wires, coils, schotky barriers, diodes, etc. The nanotubes and nanoparticles are also useful as coating that will protect an item from detection by electromagnetic monitoring techniques like radar. The nanotubes and nanoparticles are additionally useful for their mechanical properties, being comparable in strength and stiffness to the best graphite fibers or carbon nanotubes. The inventive nanoparticles are useful in lubricants and composites.

A new method for the removal of environmental compounds from gaseous streams, in particular, flue gas streams. The new method involves first oxidizing some or all of the acid anhydrides contained in the gas stream such as sulfur dioxide (SO₂) and nitric oxide (NO) and nitrous oxide (N₂O) to sulfur trioxide (SO₃) and nitrogen dioxide (NO₂). The gas stream is subsequently treated with aqua ammonia or ammonium hydroxide which captures the compounds via chemical absorption through acid-base or neutralization reactions. The products of the reactions can be collected as slurries, dewatered, and dried for use as fertilizers, or once the slurries have been dewatered, used directly as fertilizers. The ammonium hydroxide can be regenerated and recycled for use via thermal decomposition of ammonium bicarbonate, one of the products formed. There are alternative embodiments which entail stoichiometric scrubbing of nitrogen oxides and sulfur oxides with subsequent separate scrubbing of carbon dioxide.

Ambient air is compressed into a compressed ambient gas flow with a main air compressor. The compressed ambient gas flow having a compressed ambient gas flow rate is delivered to a turbine combustor and mixed with a fuel stream having a fuel stream flow rate and a portion of a recirculated gas flow to form a combustible mixture. The combustible mixture is burned and forms the recirculated gas flow that drives a turbine. The recirculated gas flow is recirculated from the turbine to the turbine compressor using a recirculation loop. At least one emission level is measured by at least a first emission sensor in the recirculated gas flow and at least a first control signal is generated. The fuel stream flow rate is adjusted based on the at least a first control signal to achieve substantially stoichiometric combustion.

A system for an engine, comprising of a cylinder located in the engine; a first injector for injecting a first fuel into said cylinder; a second injector for injecting a second fuel into said cylinder; and a controller configured to vary an amount of said first and second fuel injection during engine operation based on operating conditions, where amounts of variation of said first and second fuels are set to maintain desired engine output and provide a substantially stoichiometric mixture.

A method of growing an AlGaN semiconductor material utilizes an excess of Ga above the stoichiometric amount typically used. The excess Ga results in the formation of band structure potential fluctuations that improve the efficiency of radiative recombination and increase light generation of optoelectronic devices, in particular ultraviolet light emitting diodes, made using the method. Several improvements in UV LED design and performance are also provided for use together with the excess Ga growth method. Devices made with the method can be used for water purification, surface sterilization, communications, and data storage and retrieval.

Methods and devices are provided for transforming non-planar or planar precursor materials in an appropriate vehicle under the appropriate conditions to create dispersions of planar particles with stoichiometric ratios of elements equal to that of the feedstock or precursor materials, even after selective forces settling. In particular, planar particles disperse more easily, form much denser coatings (or form coatings with more interparticle contact area), and anneal into fused, dense films at a lower temperature and/or time than their counterparts made from spherical nanoparticles. These planar particles may be nanoflakes that have a high aspect ratio. The resulting dense films formed from nanoflakes are particularly useful in forming photovoltaic devices.

A method for forming an electrolytic capacitor is disclosed. The method includes forming a conductive polymer coating by polymerizing a monomer in the presence of less than a stoichiometric amount of an oxidative polymerization catalyst. The present inventor has found that the use of less than the stoichiometric amount of the oxidative polymerization catalyst per mole of monomer can slow the polymerization of the monomer, creating oligomers that are shorter in length than if fully polymerized into a polymer. Without wishing to be bound by theory, it is believed that these shorter oligomers provide better penetration into the porous anode. Thus, the resulting conductive polymer layer can be more intimately positioned with respect to the anode. As a result, the formed capacitor can exhibit better performance.

Metal silicates or phosphates are deposited on a heated substrate by the reaction of vapors of alkoxysilanols or alkylphosphates along with reactive metal amides, alkyls or alkoxides. For example, vapors of tris-(ter-butoxy)silanol react with vapors of tetrakis(ethylmethylamido)hafnium to deposit hafnium silicate on surfaces heated to 300° C. The product film has a very uniform stoichiometry throughout the reactor. Similarly, vapors of diisopropylphosphate react with vapors of lithium bis(ethyldimethylsilyl)amide to deposit lithium phosphate films on substrates heated to 250° C. supplying the vapors in alternating pulse produces these same compositions with a very uniform distribution of thickness and excellent step coverage.

The present invention relates to methods for robust controlled auto-ignition and spark ignited combustion controls in gasoline direct-injection engines, including transients, using either exhaust re-breathing or a combination of exhaust re-compression and re-breathing valve strategy. These methods are capable of enabling engine operation with either lean of stoichiometric or stoichiometric air/fuel ratio for oxides of nitrogen (NOx) control, with varying exhaust gas recirculation (EGR) rates and throttle valve positions for knock control, and with a combination of homogeneous charge compression ignition (HCCI) and spark ignition (SI) combustion modes to optimize fuel economy over a wide range of engine operating conditions.

The invention is directed at a mullite-aluminum titanate porous diesel particulate filter constituting a porous ceramic body containing, expressed in terms of weight percent of the total body, of 60-90%, preferably 70-80%, most preferably 70% iron-aluminum titanate solid solution having a stoichiometry of Al2(1-x)Fe2xTiO5, where x is 0-0.1, and 10-40%, preferably 20-30%, most preferably 30% mullite (3Al2O3.2SiO2), and consists essentially, expressed in terms of weigh percent on the oxide basis, of 3 to 15% SiO2, 55 to 65% Al2O3, 22 to 40% TiO2, and 0 to 10% Fe2O3, and being useful for filtration of diesel exhaust. The inventive diesel particulate filter exhibits high interconnected open porosity and large median pore size, in combination with high permeability when fired to a temperature of between 1650° to 1700° C., along with high thermal shock resistance and good filtration capability.

This invention relates to methods for reacting a hydrocarbon, molecular oxygen, and optionally water and/or carbon dioxide, to form synthesis gas. The preferred embodiments are characterized by delivering a substochiometric amount of oxygen to each of a multitude of reaction zones, which allows for optimum design of the catalytic packed bed and the gas distribution system, and for the optimization and control of the temperature profile of the reaction zones. The multitude of reaction zones may include a series of successive fixed beds, or a continuous zone housed within an internal structure having porous, or perforated, walls, through which an oxygen-containing stream can permeate. By controlling the oxygen supply, the temperatures, conversion, and product selectivity of the reaction can be in turn controlled and optimized. Furthermore the potential risks of explosion associated with mixing hydrocarbon and molecular oxygen is minimized with increased feed carbon-to-oxygen molar ratios.

A diesel engine (1) provided with a NOx catalyst (28A) and a diesel particulate filter (28B) performs lean burn operation during normal running, rich burn operation during regeneration of the NOx catalyst (28A), operation under the stoichiometric air-fuel ratio during desulphating of the NOx catalyst (28A), and operation under a slightly lean air-fuel ratio to regenerate the filter after desulphating of the NOx catalyst (28A). When the lean burn operation is applied, a controller (31) first controls the fuel injection amount, and controls an air supply amount based on the fuel injection amount. When rich burn operation is applied, the controller (31) first controls the air supply amount and controls the fuel injection amount based on the air supply amount. Due to this control, the response of the excess air factor control is enhanced while preventing torque fluctuation accompanying the variation of the target excess air factor.

Systems, methods, and apparatus are provided for controlling the oxidant feed in low emission turbine systems to maintain stoichiometric or substantially stoichiometric combustion conditions. In one or more embodiments, such control is achieved by diverting a portion of the recirculating exhaust gas and combining it with the oxidant feed to maintain a constant oxygen level in the combined oxidant-exhaust stream fed to the combustion chamber.

The invention provides a controller and cylinder deactivation system to regenerate an exhaust aftertreatment device for a multicylinder engine that operates primarily at an air/fuel ratio that is lean of stoichiometry. The invention uses the cylinder deactivation system to control temperature and air/fuel ratio of an exhaust gas feedstream going into an aftertreatment device. The invention also increases the amount of fuel delivered to each non-deactivated cylinder by an amount sufficient to maintain operating power of the engine. The regeneration action includes desorbing NOx from a NOx adsorber catalyst, desulfating the NOx adsorber catalyst, and purging a diesel particulate trap.