618 results about "Molybdenum sulfide" patented technology

The present application relates to the technical field of catalysts and relates to a non-noble metal cathode hydrogen evolution catalyst for PEM water electrolysis and a use thereof. The present application provides a method for preparing a cathode hydrogen evolution catalyst. A nickel-molybdenum heteropoly acid having a specific structure is generated in situ on the surface of a porous carbon material carrier, and is used as a hydrogen evolution catalyst active component precursor, and an in-situ generated nickel-containing molybdenum sulfide active component is subjected to sulfidation treatment to prepare a non-noble-metal-supported cathode hydrogen evolution catalyst, wherein the in-situ generated nickel-containing molybdenum sulfide active component has a hydrogen adsorption free energy similar to that of Pt and catalytic hydrogen evolution activity, the dispersity is good, and the number of active sites is large, thereby reducing the costs of the catalyst; in addition, during the sulfidation treatment of the nickel-molybdenum heteropoly acid, nitrogen or phosphorus atoms in the carrier can be doped into the lattice of molybdenum disulfide, thereby reducing the hydrogen evolution Gibbs free energy of sulfur atoms on an MoS2 crystal basal surface, and more active sites are formed on a sulfur edge and a molybdenum edge, facilitating a hydrogen evolution reaction.

The invention discloses a carbon-doped titanium dioxide nanotube-molybdenum disulfide energy-storage antibacterial material and a preparation method thereof. The preparation method comprises the following steps: carrying out primary anodic oxidation on a clean titanium foil in a mixed electrolyte of ethylene glycol, water and ammonium fluoride; after ultrasonic treatment is carried out in a hydrochloric acid solution for set time, secondary anodic oxidation is carried out, and the mixed electrolyte of the secondary anodic oxidation is the same as that of the primary anodic oxidation; annealing the titanium foil subjected to anodic oxidation twice in an argon atmosphere, putting an annealed sample into a mixed solution of sodium molybdate, a sulfur source and glucose, and carrying out hydrothermal treatment; and the titanium foil subjected to hydro-thermal treatment is cleaned and dried, and the carbon-doped titanium dioxide titanium foil with the surface covered with molybdenum disulfide is obtained. The MoS2-coated carbon-doped titanium dioxide nanotube (TNT-C-atMoS2) with high biocompatibility developed by the invention has a synergistic effect of charge antibiosis and chemical sterilization, so that the problem of intractable biological fouling of a titanium-based metal material in ocean engineering equipment is effectively solved.

The invention is applicable to the technical field of nano material preparation, and provides a preparation method of a two-dimensional acetylene-rich carbon / molybdenum sulfide heterostructure hydrogen production catalyst, which comprises the following steps: adding molybdenum sulfide into a solution to prepare a suspension A; adding soluble cuprous salt into the turbid liquid A in an inert atmosphere to obtain a mixed liquid B; alkynyl benzene is added into an organic solvent, and a mixed solution C is obtained; dropwise adding the mixed solution C into the mixed solution B under a continuous stirring condition, and reacting to obtain a mixed solution D; centrifuging the mixed solution D to obtain a precursor E; and cleaning the precursor E, and carrying out vacuum drying to obtain the two-dimensional acetylene-enriched carbon / molybdenum sulfide heterostructure hydrogen production catalyst. No additive is needed in the preparation process, and the product purity is high; by constructing a special two-dimensional heterostructure, the problem of molybdenum sulfide is solved, and the intrinsic activity and stability of the material are remarkably improved. The preparation method has the advantages of easily available raw materials, simple process, low cost and environmental protection, and is suitable for industrial production.

The invention relates to the technical field of stainless steel pneumatic cylinder barrels, and particularly discloses a wear-resistant stainless steel pipe for a pneumatic cylinder barrel and a preparation process thereof.The wear-resistant stainless steel pipe for the pneumatic cylinder barrel comprises the steps that firstly, a powder metallurgy method is adopted, tungsten carbide, cerium oxide, chromium nitride and other components are added into stainless steel powder, and the performance of a steel pipe base body is enhanced; the corrosion-resistant alloy layer is deposited on the surface of the steel pipe, so that the corrosion resistance, wear resistance and other properties of the steel pipe are enhanced, finally, a silicon nitride wear-resistant ceramic layer is sintered on the surface of the corrosion-resistant coating, and two lubricants of graphite and molybdenum sulfide are synthesized in gaps and holes of the wear-resistant ceramic layer. The defects on the ceramic surface are blocked; and the ceramic coating is endowed with a self-lubricating function.

The invention relates to the field of design and preparation of powder metallurgy friction materials, in particular to a copper-based powder metallurgy friction material and a preparation method thereof. Raw materials used in the method comprise, by mass, 45%-55% of copper powder, 8%-20% of iron powder, 6%-15% of ferrochromium, 16%-22% of graphite, 0.5%-4% of molybdenum disulfide, 0.5%-4% of tin sulfide and 0.5%-4% of nickel-coated tungsten disulfide, and the mass ratio of the tin sulfide to the nickel-coated tungsten disulfide is (1-2): (1-2). In the nickel-coated tungsten disulfide, the content of nickel is 5-40%; the sum of the total amount of molybdenum disulfide, nickel-coated tungsten disulfide and tin sulfide is less than or equal to 5%. The preparation method comprises the following steps: weighing raw material powder according to the designed components, mixing, pressing and sintering to obtain the product. The composition design has the characteristics of scientificity, simple and controllable process and the like, and the obtained product has excellent tribological performance and completely meets the friction braking requirement of high-speed heavy-load equipment of 400km / h and above.

The invention discloses a method for synthesizing a Mn0. 43Cd0. 57S / Cu2MoS4 photocatalyst by adopting a solvothermal method, and belongs to the technical field of catalysts. The preparation method comprises the following steps: preparing copper molybdenum sulfide by using cuprous oxide as a template, synthesizing copper molybdenum sulfide with high purity and good crystallinity by combining a solvothermal method, preparing manganese cadmium sulfide by using manganese acetate, cadmium acetate, sodium hydroxide and thioacetamide as raw materials, adding copper molybdenum sulfide before a hydrothermal reaction, successfully modifying the manganese cadmium sulfide by constructing a heterojunction, and preparing the copper molybdenum sulfide modified manganese cadmium sulfide. The Mn0. 43Cd0. 57S / Cu2MoS4 photocatalyst is synthesized, and the photocatalytic hydrogen production rate of the cadmium manganese sulfide is improved. Moreover, the hydrogen production rate of the Mn0. 43Cd0. 57S / Cu2MoS4 photocatalyst prepared by the invention can reach 8233 mu mol / (g.h), which is 2.08 times of the hydrogen production rate of pure cadmium manganese sulfide, and 1.24 times of the hydrogen production rate of cadmium manganese sulfide loaded with 1% platinum.

The invention discloses anti-attrition lubricating oil suitable for minimal quantity lubrication and a preparation method thereof, and belongs to the technical field of lubricating oil, molybdenum disulfide is nucleated and grows on the surface of porous cerium oxide nanosphere powder to form a cerium oxide and molybdenum disulfide compound, then modified silicon dioxide and tannic acid are pre-polymerized to form silicon dioxide prepolymer powder, and the silicon dioxide prepolymer powder is subjected to ball milling to obtain the anti-attrition lubricating oil suitable for minimal quantity lubrication. The preparation method comprises the following steps: taking a cerium oxide molybdenum disulfide compound as a core material, taking silicon dioxide prepolymer powder and an N-isopropylacrylamide polymer as a shell to obtain a composite temperature-sensitive microcapsule, and mixing the composite temperature-sensitive microcapsule with other raw materials to prepare the composite temperature-sensitive microcapsule. The outer-layer shell polymer chain of the composite temperature-sensitive microcapsule in the anti-attrition lubricating oil shrinks, the cerium oxide molybdenum disulfide compound inside is released, and controllable release of the inner core material is realized by using the temperature sensitivity of the shell polymer of the composite temperature-sensitive microcapsule and the external temperature change during operation.

The invention discloses an infrared detector with a Van der Waals complementary barrier structure, a preparation method and an application. The structure of the detector is as follows: a P-type Si substrate is used as a substrate of the detector; growing a SiO2 dielectric layer on the P-type Si substrate; the black phosphorus layer covers the SiO2 dielectric layer and is used as a conducting channel; one end of the molybdenum disulfide layer covers one end of the black phosphorus layer, and the other end of the molybdenum disulfide layer is arranged on the SiO2 dielectric layer; the drain electrode is directly prepared on the other end of the black phosphorus layer and is in contact with the black phosphorus layer; the source electrode is prepared at the other end, not overlapped with the black phosphorus layer, of the molybdenum disulfide layer, and electric connection is achieved through overlapping of the molybdenum sulfide layer and the black phosphorus layer. According to the invention, high-sensitivity room temperature detection, ultra-fast response and sensing of multiple physical quantities such as light intensity, polarization and gas are realized, and the method has an application prospect in a miniaturized, low-power-consumption and multifunctional infrared detection system.

The invention discloses a monatomic-cluster double-active-site efficient ammonia cracking hydrogen production catalyst and a preparation method thereof, and belongs to the field of new energy catalytic materials. The catalyst comprises a 2-methylimidazole zinc derived nitrogen-doped carbon-loaded cobalt monatomic carrier, a molybdenum disulfide nanosheet-loaded iron cluster carrier, monatomic active metal, cluster active metal and an auxiliary agent. Wherein the 2-methylimidazole zinc derived nitrogen-doped carbon-loaded cobalt monatomic carrier is prepared by the following steps: stirring 2-methylimidazole, zinc acetate and cobalt nitrate hexahydrate in methanol to generate a ZIF-8 precursor, washing, drying, and calcining in an H2 / Ar mixed atmosphere, thereby obtaining the 2-methylimidazole zinc derived nitrogen-doped carbon-loaded cobalt monatomic carrier; the molybdenum disulfide nanosheet loaded iron cluster carrier is prepared by carrying out hydrothermal reaction on ammonium molybdate and thiourea to generate MoS2 nanosheets and then loading iron clusters. The catalyst prepared by the invention has high activity, long service life and industrial applicability.

The invention provides a preparation method of a molybdenum disulfide material with a biological fine hierarchical structure form, and relates to the technical field of nano materials, and the preparation method comprises the following steps: preparing a biological wing as a biological template; pretreating the biological template by using an ethylenediamine tetraacetic acid solution; molybdenum disulfide grows on a pretreated biological template through a hydrothermal method, and the molybdenum disulfide material of the biomorphic fine hierarchical structure is obtained. Organisms with fine hierarchical structures existing in the nature in quantity serve as the template, and the molybdenum disulfide material of the fine hierarchical structure is prepared through the hydrothermal method; the prepared metal material inherits the fine structure characteristics of an original biological template and has wide application value in the fields of photoelectron, photocatalysis and magnetic performance, compared with the original biological template, the thickness of the molybdenum disulfide layer can be further controlled by adjusting the hydrothermal time and temperature of a hydrothermal method, and the preparation method is simple and easy to implement. The molybdenum disulfide material with the multi-scale graded fine structure and different biological morphological structures is prepared.

The invention provides a molybdenum mineral content measuring method, and belongs to the field of process mineralogy, and the method comprises the following steps: carrying out ore grinding, ore washing and desliming treatment on a to-be-measured sample to obtain slurry and ore washing concentrate; the ore washing concentrate is subjected to gravity separation, and gravity separation concentrate and gravity separation tailings are obtained through separation; mixing the slime and the gravity concentrate to obtain a mixed sample, and performing molybdenum phase analysis to obtain the content of molybdenum oxide; an automatic mineralogical analysis sample of the mixed sample and an automatic mineralogical analysis sample of the gravity separation tailings are prepared respectively, automatic mineralogical analysis is carried out, and a molybdenite content correction coefficient and a molybdenum oxide content correction coefficient are calculated; and calculating the content of various molybdenum minerals in the to-be-detected sample in combination with the correction coefficient and the mineral content data. By optimizing the sample preparation process, molybdenite oxidation is reduced, and the mineral recognition accuracy is improved. Molybdenum oxide and molybdenum sulfide are treated separately, different correction processes are adopted, and the accuracy of ore molybdenum mineral measurement is improved in a targeted mode.

The invention discloses a self-lubricating aluminum coating and a preparation method thereof.The preparation method comprises the steps that molybdenum disulfide is pretreated through a silane coupling agent, tetraethoxysilane mixed liquor is added, the pH is adjusted to be 9-10, a water bath reaction is conducted, and molybdenum disulfide-silicon dioxide microcapsules are obtained after high-temperature strengthening treatment; respectively adding a zinc nitrate solution and a hexamethylenetetramine solution, adjusting the pH value to 10-11, carrying out a high-temperature and high-pressure hydrothermal reaction to obtain zinc oxide nanorods, and carrying out ball milling treatment on the zinc oxide nanorods, microcapsules, stearic acid and zirconium oxide balls under the protection of argon to obtain doped microcapsules; after raw materials are pretreated, the raw materials and a dispersing agent solution are added into a mixer respectively, spraying powder, a pretreated base body and the spraying powder are obtained after mixing treatment, spraying treatment is conducted on the surface of the base body through a plasma spraying method, and the self-lubricating aluminum coating is obtained after vacuum annealing treatment. Therefore, the obtained self-lubricating aluminum coating is low in friction coefficient, high in performance and excellent in self-lubricating property.

The invention relates to the technical field of catalytic materials, in particular to a molybdenum sulfide-based electro-catalytic material and a preparation method and application thereof. The invention provides a molybdenum sulfide-based electro-catalytic material, which comprises a transition metal chalcogenide containing chalcogen element vacancies and titanium dioxide quantum dots containing oxygen vacancies compounded on the surface of the transition metal chalcogenide, and a composite interface of the transition metal chalcogenide and the titanium dioxide quantum dots has a heterojunction structure. According to the composite electrocatalytic hydrogen evolution catalyst containing the TiO2 quantum dots and coupled with the double vacancies and the preparation method of the composite electrocatalytic hydrogen evolution catalyst, through the quantum effect and the double vacancy defect effect of the TiO2 quantum dots, the conductivity and the active site density of transition metal chalcogenide catalysts are improved, and the electrocatalytic hydrogen evolution performance is synergistically enhanced.

The invention discloses a miniature multi-ion sensing system based on a non-gate array and a preparation method thereof, and belongs to the technical field of electrochemical sensing, and the miniature multi-ion sensing system comprises a multi-ion sensing unit and a molybdenum disulfide non-gate array; the multi-ion sensitive unit comprises a metal electrode array, an ion sensitive film array and a liquid storage tank, multiple ions are detected through the ion sensitive film array at the same time and converted into electric signals, and the electric signals are transmitted to the molybdenum disulfide non-gate array through the metal electrode array; the molybdenum disulfide NOT gate array comprises a plurality of molybdenum disulfide NOT gates, and each molybdenum disulfide NOT gate comprises a metal electrode layer, a molybdenum disulfide layer, a NOT gate input end and a NOT gate output end, so that two field effect transistors are formed, received electric signals are amplified, the Nernst limit is broken through a NOT gate structure, and tiny changes of ion concentration are accurately detected. The sensitivity is higher; molybdenum disulfide is used as a channel material of the NOT gate, so that the size and power consumption of the NOT gate are effectively reduced, the integration level of the system is improved, and the service life of the system is prolonged.

The application provides a preparation method of a self-coiled structure molybdenum disulfide / nitrogen-doped porous carbon composite material, a product and application, high-content nitrogen-doped porous carbon material is synthesized by inducing dicyandiamide molecules to undergo a supramolecular self-assembly process, and on this basis, a hydrothermal reaction is carried out to coat molybdenum sulfide sheet layer material on the surface, and finally, a self-heating coiling treatment is carried out to form a carbon-based electrocatalyst of the self-coiled structure molybdenum disulfide / nitrogen-doped porous carbon. Compared with a high specific surface area carbon-based catalyst, high doping concentration of nitrogen atoms can provide more electron-rich properties to facilitate the adsorption of substances, and the self-coiled carbon-based material can exhibit very excellent electrochemical performance, especially in the aspect of electrochemical hydrogen production. The preparation method is simple in operation, low in preparation cost and suitable for large-scale production.

The invention discloses tannic acid-oleylamine modified nano molybdenum disulfide as well as a preparation method and application thereof. The preparation method of the tannic acid-oleylamine modified nano-molybdenum disulfide comprises the following steps: 1) dispersing nano-molybdenum disulfide and tannic acid in a solvent, then adding ferric salt for reaction, and then carrying out product separation to obtain the tannic acid modified nano-molybdenum disulfide; and 2) dispersing the tannic acid modified nano molybdenum disulfide and oleylamine in a solvent for reaction, and then carrying out product separation to obtain the tannic acid-oleylamine modified nano molybdenum disulfide. The tannic acid-oleylamine modified nano molybdenum disulfide disclosed by the invention has the advantages of excellent friction reduction and wear resistance, good dispersity in ester oil, good compatibility with other additives and the like, the preparation raw materials are safe and non-toxic, the preparation method is simple, and the tannic acid-oleylamine modified nano molybdenum disulfide is suitable for large-scale industrial production and application.

The invention provides a molybdenum sulfide-molybdenum nitride heterojunction and a preparation method and application thereof.The preparation method comprises the following steps that molybdenum sulfide grows through a chemical vapor deposition method to obtain multi-layer molybdenum sulfide, and the number of the layers of the multi-layer molybdenum sulfide is at least two; and heating and nitriding the multilayer molybdenum sulfide and a nitrogen source to obtain the molybdenum sulfide-molybdenum nitride heterojunction. According to the preparation method, the multilayer molybdenum sulfide is adopted as the precursor for high-temperature nitridation, the formation process of the heterojunction can be accurately regulated and controlled, the catalytic activity at a microscopic heterojunction interface is accurately tested, and meanwhile the catalytic performance of the molybdenum sulfide-molybdenum nitride heterojunction can be improved.

The invention relates to a normal-temperature curing high-corrosion-resistance self-lubricating composite coating which is prepared from the following components in parts by weight: 25 to 35 parts of modified epoxy resin, 12 to 22 parts of waterborne polyurethane-acrylate copolymer, 6 to 14 parts of lubricating filler, 4 to 9 parts of corrosion-resistant filler, 10 to 18 parts of composite curing agent, 1 to 4 parts of dispersing agent, 0.5 to 3.5 parts of flatting agent, 0.8 to 2.5 parts of defoaming agent and 35 to 55 parts of auxiliary solvent. According to the coating disclosed by the invention, an interpenetrating network matrix is constructed through modified epoxy resin and a waterborne polyurethane-acrylate copolymer, and is matched with components such as a nano molybdenum disulfide / graphene composite lubricating filler and a nano titanium dioxide-zinc oxide composite corrosion-resistant filler, and a photoinitiator-amine composite curing agent is combined, so that dual curing is realized. The coating has excellent properties of rapid curing at normal temperature, high corrosion resistance, self-lubrication and the like, is low in VOC content and wide in application range, and provides an innovative solution for the field of surface protection.

The invention relates to a wear-resistant modified glass fiber and a preparation method thereof, and belongs to the technical field of high polymer materials. The wear-resistant modified glass fiber is prepared from the following components in parts by weight: 40 to 60 parts of SiO2, 10 to 15 parts of Al2O3, 20 to 30 parts of CaO, 1 to 3 parts of Fe2O3, 1 to 3 parts of CeO2, 2 to 10 parts of modified toughening agent and 2 to 10 parts of wear-resistant filler, the flexibility and elasticity of polydopamine in the modified toughening agent can reduce the generation and expansion of cracks, and polydopamine cooperates with modified silicon nitride to increase the toughness and the adhesiveness and bonding performance of polyethyleneimine, so that the material is not easy to damage when bearing an external force; graphite oxide in the wear-resistant filler endows strength and heat resistance, molybdenum disulfide provides lubricity, a pre-product contributes to improvement of interface performance, and polytetrafluoroethylene and molybdenum disulfide synergistically improve wear resistance and lubricity; the wear-resistant modified glass fiber prepared by the invention not only has a good toughening effect, but also has an excellent wear-resistant effect.

The invention relates to the technical field of catalysts, in particular to a desulfurization catalyst and application thereof in hydrodesulfurization. The desulfurization catalyst adopts a hollow core shell, a weak acid site is constructed on a shell surface, and a boron-containing polymerization network is formed through surface-initiated polymerization; and linear / branched polyethyleneimine complexation is used for synergistically introducing Ni and Mo, in-situ vulcanization is performed after inert atmosphere pretreatment, and a dispersed nickel molybdenum sulfide active phase and shallow and deep double-peak metal distribution are obtained. The structure inhibits excessive hydrogenation while ensuring diffusion and structural stability, promotes a direct desulfurization path, and shows high conversion and high selectivity to 4, 6-dimethyl dibenzothiophene. The catalyst has low hydrogen consumption, high aromatic hydrocarbon retention and cycling stability, and is suitable for deep desulfurization of diesel oil and preparation of ultralow-sulfur fuel.

The invention relates to the technical field of lubricating materials, and provides a super-lubricating amorphous carbon-based thin film as well as a preparation method and application thereof. The super-lubricating amorphous carbon-based thin film comprises a bonding transition layer, a carbide gradient layer and a composite hydrogen-containing amorphous carbon-based film layer which are sequentially arranged from bottom to top, the composite hydrogen-containing amorphous carbon-based film layer is a sulfide-doped hydrogen-containing amorphous carbon thin film, and sulfide is one or two of tungsten sulfide and molybdenum sulfide. The structure of the carbon-based thin film is regulated and controlled by doping a small amount of sulfide, compared with a traditional hydrogen-containing amorphous carbon-based thin film, the obtained super-lubricating amorphous carbon-based thin film shows more stable super-lubricating performance and more excellent wear resistance, a new solution is provided for surface protection of tribological parts, and the method is suitable for popularization and application. The method has important industrial application value.

The invention belongs to the technical field of composite material preparation, and discloses oriented pore channel interconnected dual-network xerogel and a preparation method and application thereof.The method comprises the steps that firstly, acrylamide monomers, molybdenum sulfide nanosheets and sodium alginate powder are mixed and then dispersed in 35 mL of ultrapure water, and a homogeneous transparent precursor solution is formed; injecting the precursor solution into a mold to prepare molded hydrogel, loading the molded hydrogel into a brass mold, and performing directional freezing treatment to prepare PSM; the preparation method comprises the following steps: dipping PSM in a lithium chloride solution, carrying out directional freezing treatment, and then carrying out freeze-drying treatment to prepare the dual-network xerogel PSML. The dual-network xerogel PSML provided by the invention not only solves the problems of easy deliquescence, slow adsorption-desorption rate, poor cycle stability and high regeneration energy consumption of a moisture absorbent after moisture absorption, but also has excellent moisture absorption capability, photothermal conversion efficiency, water desorption performance and cycle stability; and high-efficiency low-energy-consumption indoor dehumidification and solar-driven atmosphere water collection can be realized synchronously.

The invention provides polymer foam with high photothermal conversion efficiency and a preparation method of the polymer foam. The polymer foam with high photothermal conversion efficiency comprises a melamine three-dimensional foam skeleton and a single-layer MoS2 nanosheet which is polymerized on the melamine three-dimensional foam skeleton in situ, according to the scheme, single-layer molybdenum disulfide is uniformly introduced into a three-dimensional polymer skeleton based on an in-situ polymerization process, so that the three-dimensional structured evaporator with high photothermal conversion efficiency, excellent salt crystallization resistance and a simple processing process is constructed.

The invention belongs to the technical field of lubricating oil manufacturing, and relates to composite lubricating oil used in an aluminum rolling process, which comprises the following components in parts by mass: 94-96 parts of base oil, 0.5-1.5 parts of an oiliness agent, 0.5-0.8 part of an extreme pressure anti-wear agent, 0.5-1.5 parts of a wear-resistant antioxidant, 0.5-2 parts of oleic acid diethanolamide and 0.5-1 part of an antirust agent. On the basis of the prior art, nano-sheet molybdenum disulfide is introduced and added into 2-aminoterephthalic acid and nickel nitrate to react to prepare a modified metal organic framework, then carnosic acid is grafted through an amide reaction to prepare the wear-resistant antioxidant, and a protective film can be formed on a friction interface through a sheet structure of molybdenum disulfide, so that the friction coefficient is reduced; the wear resistance is improved; a compact passive film is formed on the surface of aluminum metal through the synergistic effect of the extreme pressure anti-wear agent and the wear-resistant antioxidant, and the corrosion resistance and wear resistance of the composite lubricating oil used in aluminum plate rolling are improved.

The application discloses a preparation method of a two-dimensional rhenium sulfide-molybdenum sulfide vertical heterostructure. The method is chemical vapor deposition, and Si / SiO2 is used as a substrate, a metal rhenium foil (Re) is used as a rhenium source, and a metal molybdenum foil (Mo) is used as a molybdenum source. The metal rhenium foil is laid on one end surface of the metal molybdenum foil, the substrate is inverted on the metal molybdenum foil, and the substrate is reacted with sulfur vapor to prepare a two-dimensional ReS2 / MoS2 vertical heterostructure with a multilayer ReS2 as a bottom layer and a double-layer MoS2 as a top layer. The obtained two-dimensional ReS2 / MoS2 vertical heterojunction material is a crystal stacked by two crystals with different sizes, presents obvious luminescent properties, can be used as a channel material of a transistor and applied to the field of ultrathin electronic devices, and has potential application in the field of high-efficiency light detectors.

The invention belongs to the technical field of electronic components, and relates to a photoelectric transistor, in particular to a polarization sensitive photoelectric transistor with a MoS2 / In2Se3 heterojunction as a conducting layer. The MoS2 / In2Se3 heterojunction phototransistor comprises a Si / SiO2 substrate, a semiconductor MoS2 nanosheet, a semiconductor In2Se3 nanosheet, a source electrode and a drain electrode, the MoS2 nanosheet and the In2Se3 nanosheet form a vertical heterojunction located on the substrate, and the source electrode and the drain electrode are located at the two ends of the MoS2 / In2Se3 heterojunction. According to the invention, the MoS2 / In2Se3 heterojunction structure with intrinsic anisotropy is adopted to carry out polarized photoelectric detection, complicated optical components such as an additional optical polarizer and an optical filter are not needed, and the problems that a traditional polarized photoelectric detector is complicated in structure and cannot be integrated are solved; the two-dimensional material heterojunction with excellent photoelectric property is used as the conductive layer, so that the power consumption of the phototransistor is effectively reduced.

The invention relates to the technical field of solar photovoltaic backboards, in particular to a high-water-resistance solar cell backboard and a preparation method thereof. The solar cell backboard structurally comprises a weather-proof layer, a nano-composite waterproof layer, a substrate supporting layer and a bonding layer from bottom to top in sequence, the preparation raw materials of the nanometer composite waterproof layer comprise a nanometer material, multilayer graphene, saturated aliphatic polyester polyol and a curing agent. The nano material comprises at least one of nano silicon dioxide, nano clay, single-walled carbon nanotubes, multi-walled carbon nanotubes, nano aluminum oxide, nano boron carbide, nano cellulose, nano zinc oxide, nano titanium oxide and nano molybdenum disulfide. The invention has the advantages of better water resistance and weather resistance and simpler preparation process.

The invention relates to the technical field of catalysts, in particular to a graphene-based desulfurization catalyst and a preparation method thereof. Graphene oxide is used as a carrier, an initiating group is introduced firstly, a short-brush amphoteric polymer gradient modification layer and a long-brush amphoteric polymer gradient modification layer are sequentially constructed through atom transfer radical polymerization, ammonium molybdate-urea complex deposition is fused, and uniform nucleation of a metal precursor is achieved. Two-stage vulcanization is adopted in the preparation process, the crystallization process of a precursor is controlled step by step at different temperatures, and the size and dispersity of a molybdenum disulfide sheet layer are optimized. The catalyst is high in conversion rate under a hydrodesulfurization model system, low in total sulfur of discharged materials, and excellent in activity retention rate after multiple cycles. The method can be widely applied to the field of fuel oil deep desulfurization, and the efficient and environment-friendly industrial catalysis requirement is met.

Provided in the present application are a two-dimensional 1T-phase molybdenum disulfide nano material, a preparation method therefor, and the use thereof. The two-dimensional 1T-phase molybdenum disulfide nano material satisfies the following conditions: the monolayer ratio of the molybdenum disulfide is 97% or above, the content of the 1T-phase molybdenum disulfide represented by X-ray photoelectron spectroscopy is 90% or above, and the surface has defects. The monolayer ratio of the two-dimensional molybdenum disulfide nano material being 97% or above indicates that the proportion of monolayer molybdenum disulfide nanosheets in the nano material is very high; the mass content of the 1T-phase molybdenum disulfide being 90% or above indicates that the nano material has good metallicity; and meanwhile, the presence of defects on the surface of the nano material indicates that the nano material has good dispersibility in solvents and also has good electrocatalytic performance, especially having excellent electrocatalytic hydrogen evolution performance under an industrial current density; the catalytic performance of the nano material is better than that of commercial Pt / C and even can be kept stable for 100 h without deterioration; thus, the nano material is one of the most superior non-precious-metal hydrogen evolution catalysts at present.

The invention belongs to the field of lubricants, and relates to a composite solid lubricant for a sprocket shaft group and a preparation method thereof. The composite solid lubricant for the sprocket shaft group is prepared from the following raw materials in percentage by weight: 2-15% of graphite fluoride, 1-4% of terbium-thulium co-doped molybdenum disulfide, 1-3% of organic graphene, 0.07-0.4% of tin powder, 1-11% of polyethylene glycol, 1-7% of a thickening agent and the balance of basic lubricating oil. According to the preparation method, molybdenum disulfide is co-doped with rare earth thulium and terbium, thulium and terbium ions are embedded into molybdenum disulfide layers or replace molybdenum sites through electrostatic adsorption in the hydrothermal reaction process, the layered structure is more compact, oxygenolysis of molybdenum disulfide at high temperature is effectively inhibited, and better oxidation resistance is achieved. The talcum powder is introduced to modify the lithium-based soap, and zinc ions are adopted to modify the talcum powder, so that the dispersibility of the talcum powder is improved, and the thermal stability, wear resistance and water resistance of the lubricant are improved after the talcum powder is compounded with the lithium-based soap.