749 results about "Molybdenum sulfide" patented technology

The invention belongs to the technical field of ceramics, and discloses a preparation method of fracture-resistant and wear-resistant ceramics. The preparation method comprises the following steps: weighing the raw materials in parts by weight; the preparation method comprises the following steps: mixing 40 parts of potassium feldspar, 10 to 25 parts of albite, 1 to 10 parts of kaolin, 1 to 10 parts of serpentine, 5 to 25 parts of dolomite, 2 to 9 parts of nano zirconium oxide, 0.1 to 1 part of nano cerium oxide, 0.1 to 1 part of nano molybdenum disulfide, 0.1 to 0.8 part of silicon carbide fiber, 0.5 to 2.5 parts of polyethylene glycol, 0.1 to 0.6 part of fullerene trifluoromethyl derivative, 0.1 to 3 parts of sodium dodecyl sulfate, 0.1 to 2 parts of sodium tripolyphosphate and 10 to 60 parts of solvent to obtain slurry; and carrying out spray granulation to obtain a blank, carrying out compression molding to obtain a green body, and sintering to obtain the fracture-resistant and wear-resistant ceramic. The breaking strength of the breaking-resistant and wear-resistant ceramic can exceed 70 MPa, and the length of a grinding pit does not exceed 8.5 mm.

The present application relates to the technical field of catalysts and relates to a non-noble metal cathode hydrogen evolution catalyst for PEM water electrolysis and a use thereof. The present application provides a method for preparing a cathode hydrogen evolution catalyst. A nickel-molybdenum heteropoly acid having a specific structure is generated in situ on the surface of a porous carbon material carrier, and is used as a hydrogen evolution catalyst active component precursor, and an in-situ generated nickel-containing molybdenum sulfide active component is subjected to sulfidation treatment to prepare a non-noble-metal-supported cathode hydrogen evolution catalyst, wherein the in-situ generated nickel-containing molybdenum sulfide active component has a hydrogen adsorption free energy similar to that of Pt and catalytic hydrogen evolution activity, the dispersity is good, and the number of active sites is large, thereby reducing the costs of the catalyst; in addition, during the sulfidation treatment of the nickel-molybdenum heteropoly acid, nitrogen or phosphorus atoms in the carrier can be doped into the lattice of molybdenum disulfide, thereby reducing the hydrogen evolution Gibbs free energy of sulfur atoms on an MoS2 crystal basal surface, and more active sites are formed on a sulfur edge and a molybdenum edge, facilitating a hydrogen evolution reaction.

The invention discloses a carbon-doped titanium dioxide nanotube-molybdenum disulfide energy-storage antibacterial material and a preparation method thereof. The preparation method comprises the following steps: carrying out primary anodic oxidation on a clean titanium foil in a mixed electrolyte of ethylene glycol, water and ammonium fluoride; after ultrasonic treatment is carried out in a hydrochloric acid solution for set time, secondary anodic oxidation is carried out, and the mixed electrolyte of the secondary anodic oxidation is the same as that of the primary anodic oxidation; annealing the titanium foil subjected to anodic oxidation twice in an argon atmosphere, putting an annealed sample into a mixed solution of sodium molybdate, a sulfur source and glucose, and carrying out hydrothermal treatment; and the titanium foil subjected to hydro-thermal treatment is cleaned and dried, and the carbon-doped titanium dioxide titanium foil with the surface covered with molybdenum disulfide is obtained. The MoS2-coated carbon-doped titanium dioxide nanotube (TNT-C-atMoS2) with high biocompatibility developed by the invention has a synergistic effect of charge antibiosis and chemical sterilization, so that the problem of intractable biological fouling of a titanium-based metal material in ocean engineering equipment is effectively solved.

The invention is applicable to the technical field of nano material preparation, and provides a preparation method of a two-dimensional acetylene-rich carbon / molybdenum sulfide heterostructure hydrogen production catalyst, which comprises the following steps: adding molybdenum sulfide into a solution to prepare a suspension A; adding soluble cuprous salt into the turbid liquid A in an inert atmosphere to obtain a mixed liquid B; alkynyl benzene is added into an organic solvent, and a mixed solution C is obtained; dropwise adding the mixed solution C into the mixed solution B under a continuous stirring condition, and reacting to obtain a mixed solution D; centrifuging the mixed solution D to obtain a precursor E; and cleaning the precursor E, and carrying out vacuum drying to obtain the two-dimensional acetylene-enriched carbon / molybdenum sulfide heterostructure hydrogen production catalyst. No additive is needed in the preparation process, and the product purity is high; by constructing a special two-dimensional heterostructure, the problem of molybdenum sulfide is solved, and the intrinsic activity and stability of the material are remarkably improved. The preparation method has the advantages of easily available raw materials, simple process, low cost and environmental protection, and is suitable for industrial production.

The invention relates to the technical field of stainless steel pneumatic cylinder barrels, and particularly discloses a wear-resistant stainless steel pipe for a pneumatic cylinder barrel and a preparation process thereof.The wear-resistant stainless steel pipe for the pneumatic cylinder barrel comprises the steps that firstly, a powder metallurgy method is adopted, tungsten carbide, cerium oxide, chromium nitride and other components are added into stainless steel powder, and the performance of a steel pipe base body is enhanced; the corrosion-resistant alloy layer is deposited on the surface of the steel pipe, so that the corrosion resistance, wear resistance and other properties of the steel pipe are enhanced, finally, a silicon nitride wear-resistant ceramic layer is sintered on the surface of the corrosion-resistant coating, and two lubricants of graphite and molybdenum sulfide are synthesized in gaps and holes of the wear-resistant ceramic layer. The defects on the ceramic surface are blocked; and the ceramic coating is endowed with a self-lubricating function.

The invention relates to the field of design and preparation of powder metallurgy friction materials, in particular to a copper-based powder metallurgy friction material and a preparation method thereof. Raw materials used in the method comprise, by mass, 45%-55% of copper powder, 8%-20% of iron powder, 6%-15% of ferrochromium, 16%-22% of graphite, 0.5%-4% of molybdenum disulfide, 0.5%-4% of tin sulfide and 0.5%-4% of nickel-coated tungsten disulfide, and the mass ratio of the tin sulfide to the nickel-coated tungsten disulfide is (1-2): (1-2). In the nickel-coated tungsten disulfide, the content of nickel is 5-40%; the sum of the total amount of molybdenum disulfide, nickel-coated tungsten disulfide and tin sulfide is less than or equal to 5%. The preparation method comprises the following steps: weighing raw material powder according to the designed components, mixing, pressing and sintering to obtain the product. The composition design has the characteristics of scientificity, simple and controllable process and the like, and the obtained product has excellent tribological performance and completely meets the friction braking requirement of high-speed heavy-load equipment of 400km / h and above.

The invention discloses a method for synthesizing a Mn0. 43Cd0. 57S / Cu2MoS4 photocatalyst by adopting a solvothermal method, and belongs to the technical field of catalysts. The preparation method comprises the following steps: preparing copper molybdenum sulfide by using cuprous oxide as a template, synthesizing copper molybdenum sulfide with high purity and good crystallinity by combining a solvothermal method, preparing manganese cadmium sulfide by using manganese acetate, cadmium acetate, sodium hydroxide and thioacetamide as raw materials, adding copper molybdenum sulfide before a hydrothermal reaction, successfully modifying the manganese cadmium sulfide by constructing a heterojunction, and preparing the copper molybdenum sulfide modified manganese cadmium sulfide. The Mn0. 43Cd0. 57S / Cu2MoS4 photocatalyst is synthesized, and the photocatalytic hydrogen production rate of the cadmium manganese sulfide is improved. Moreover, the hydrogen production rate of the Mn0. 43Cd0. 57S / Cu2MoS4 photocatalyst prepared by the invention can reach 8233 mu mol / (g.h), which is 2.08 times of the hydrogen production rate of pure cadmium manganese sulfide, and 1.24 times of the hydrogen production rate of cadmium manganese sulfide loaded with 1% platinum.

The invention discloses anti-attrition lubricating oil suitable for minimal quantity lubrication and a preparation method thereof, and belongs to the technical field of lubricating oil, molybdenum disulfide is nucleated and grows on the surface of porous cerium oxide nanosphere powder to form a cerium oxide and molybdenum disulfide compound, then modified silicon dioxide and tannic acid are pre-polymerized to form silicon dioxide prepolymer powder, and the silicon dioxide prepolymer powder is subjected to ball milling to obtain the anti-attrition lubricating oil suitable for minimal quantity lubrication. The preparation method comprises the following steps: taking a cerium oxide molybdenum disulfide compound as a core material, taking silicon dioxide prepolymer powder and an N-isopropylacrylamide polymer as a shell to obtain a composite temperature-sensitive microcapsule, and mixing the composite temperature-sensitive microcapsule with other raw materials to prepare the composite temperature-sensitive microcapsule. The outer-layer shell polymer chain of the composite temperature-sensitive microcapsule in the anti-attrition lubricating oil shrinks, the cerium oxide molybdenum disulfide compound inside is released, and controllable release of the inner core material is realized by using the temperature sensitivity of the shell polymer of the composite temperature-sensitive microcapsule and the external temperature change during operation.

The invention discloses an infrared detector with a Van der Waals complementary barrier structure, a preparation method and an application. The structure of the detector is as follows: a P-type Si substrate is used as a substrate of the detector; growing a SiO2 dielectric layer on the P-type Si substrate; the black phosphorus layer covers the SiO2 dielectric layer and is used as a conducting channel; one end of the molybdenum disulfide layer covers one end of the black phosphorus layer, and the other end of the molybdenum disulfide layer is arranged on the SiO2 dielectric layer; the drain electrode is directly prepared on the other end of the black phosphorus layer and is in contact with the black phosphorus layer; the source electrode is prepared at the other end, not overlapped with the black phosphorus layer, of the molybdenum disulfide layer, and electric connection is achieved through overlapping of the molybdenum sulfide layer and the black phosphorus layer. According to the invention, high-sensitivity room temperature detection, ultra-fast response and sensing of multiple physical quantities such as light intensity, polarization and gas are realized, and the method has an application prospect in a miniaturized, low-power-consumption and multifunctional infrared detection system.

The invention discloses a monatomic-cluster double-active-site efficient ammonia cracking hydrogen production catalyst and a preparation method thereof, and belongs to the field of new energy catalytic materials. The catalyst comprises a 2-methylimidazole zinc derived nitrogen-doped carbon-loaded cobalt monatomic carrier, a molybdenum disulfide nanosheet-loaded iron cluster carrier, monatomic active metal, cluster active metal and an auxiliary agent. Wherein the 2-methylimidazole zinc derived nitrogen-doped carbon-loaded cobalt monatomic carrier is prepared by the following steps: stirring 2-methylimidazole, zinc acetate and cobalt nitrate hexahydrate in methanol to generate a ZIF-8 precursor, washing, drying, and calcining in an H2 / Ar mixed atmosphere, thereby obtaining the 2-methylimidazole zinc derived nitrogen-doped carbon-loaded cobalt monatomic carrier; the molybdenum disulfide nanosheet loaded iron cluster carrier is prepared by carrying out hydrothermal reaction on ammonium molybdate and thiourea to generate MoS2 nanosheets and then loading iron clusters. The catalyst prepared by the invention has high activity, long service life and industrial applicability.

The invention discloses an epoxy resin-based composite material with vibration damping performance and a preparation method and application thereof, and belongs to the technical field of carbon fiber reinforced composite materials. The carbon fiber reinforced epoxy resin matrix composite material is prepared from the following raw materials in parts by weight: 80-120 parts of epoxy resin, 10-50 parts of a curing agent and 5-10 parts of carbon nanotube / molybdenum disulfide and micron rubber co-embedded damping particles. The epoxy resin-based composite material disclosed by the invention is simple in raw materials, can be commercialized, and meets the low-altitude economic development requirements and the application requirements of aviation aircrafts; and the composite material has high specific strength, high damping vibration attenuation performance, electrical insulation performance and the like, and has a good application prospect in preparation of aircraft skin parts.

The invention provides a preparation method of a molybdenum disulfide material with a biological fine hierarchical structure form, and relates to the technical field of nano materials, and the preparation method comprises the following steps: preparing a biological wing as a biological template; pretreating the biological template by using an ethylenediamine tetraacetic acid solution; molybdenum disulfide grows on a pretreated biological template through a hydrothermal method, and the molybdenum disulfide material of the biomorphic fine hierarchical structure is obtained. Organisms with fine hierarchical structures existing in the nature in quantity serve as the template, and the molybdenum disulfide material of the fine hierarchical structure is prepared through the hydrothermal method; the prepared metal material inherits the fine structure characteristics of an original biological template and has wide application value in the fields of photoelectron, photocatalysis and magnetic performance, compared with the original biological template, the thickness of the molybdenum disulfide layer can be further controlled by adjusting the hydrothermal time and temperature of a hydrothermal method, and the preparation method is simple and easy to implement. The molybdenum disulfide material with the multi-scale graded fine structure and different biological morphological structures is prepared.

The invention provides a molybdenum mineral content measuring method, and belongs to the field of process mineralogy, and the method comprises the following steps: carrying out ore grinding, ore washing and desliming treatment on a to-be-measured sample to obtain slurry and ore washing concentrate; the ore washing concentrate is subjected to gravity separation, and gravity separation concentrate and gravity separation tailings are obtained through separation; mixing the slime and the gravity concentrate to obtain a mixed sample, and performing molybdenum phase analysis to obtain the content of molybdenum oxide; an automatic mineralogical analysis sample of the mixed sample and an automatic mineralogical analysis sample of the gravity separation tailings are prepared respectively, automatic mineralogical analysis is carried out, and a molybdenite content correction coefficient and a molybdenum oxide content correction coefficient are calculated; and calculating the content of various molybdenum minerals in the to-be-detected sample in combination with the correction coefficient and the mineral content data. By optimizing the sample preparation process, molybdenite oxidation is reduced, and the mineral recognition accuracy is improved. Molybdenum oxide and molybdenum sulfide are treated separately, different correction processes are adopted, and the accuracy of ore molybdenum mineral measurement is improved in a targeted mode.

The invention discloses a self-lubricating aluminum coating and a preparation method thereof.The preparation method comprises the steps that molybdenum disulfide is pretreated through a silane coupling agent, tetraethoxysilane mixed liquor is added, the pH is adjusted to be 9-10, a water bath reaction is conducted, and molybdenum disulfide-silicon dioxide microcapsules are obtained after high-temperature strengthening treatment; respectively adding a zinc nitrate solution and a hexamethylenetetramine solution, adjusting the pH value to 10-11, carrying out a high-temperature and high-pressure hydrothermal reaction to obtain zinc oxide nanorods, and carrying out ball milling treatment on the zinc oxide nanorods, microcapsules, stearic acid and zirconium oxide balls under the protection of argon to obtain doped microcapsules; after raw materials are pretreated, the raw materials and a dispersing agent solution are added into a mixer respectively, spraying powder, a pretreated base body and the spraying powder are obtained after mixing treatment, spraying treatment is conducted on the surface of the base body through a plasma spraying method, and the self-lubricating aluminum coating is obtained after vacuum annealing treatment. Therefore, the obtained self-lubricating aluminum coating is low in friction coefficient, high in performance and excellent in self-lubricating property.

The invention relates to the technical field of catalytic materials, in particular to a molybdenum sulfide-based electro-catalytic material and a preparation method and application thereof. The invention provides a molybdenum sulfide-based electro-catalytic material, which comprises a transition metal chalcogenide containing chalcogen element vacancies and titanium dioxide quantum dots containing oxygen vacancies compounded on the surface of the transition metal chalcogenide, and a composite interface of the transition metal chalcogenide and the titanium dioxide quantum dots has a heterojunction structure. According to the composite electrocatalytic hydrogen evolution catalyst containing the TiO2 quantum dots and coupled with the double vacancies and the preparation method of the composite electrocatalytic hydrogen evolution catalyst, through the quantum effect and the double vacancy defect effect of the TiO2 quantum dots, the conductivity and the active site density of transition metal chalcogenide catalysts are improved, and the electrocatalytic hydrogen evolution performance is synergistically enhanced.

The invention relates to the technical field of sliding materials for shock absorption and isolation supports, and particularly discloses a composite sliding plate containing ultra-high molecular weight polyethylene as well as a preparation method and application of the composite sliding plate. The composite sliding plate containing the ultra-high molecular weight polyethylene comprises a working layer material and a base layer material from top to bottom, the working layer material comprises the following raw material components: ultra-high molecular weight polyethylene, trimethylolpropane modified polytetrafluoroethylene, a lubricant, an inorganic filler, a compatilizer and a coupling agent; the base layer material comprises the following raw material components: ultra-high molecular weight polyethylene, molybdenum disulfide coated carbon fibers, graphene and a coupling agent. The prepared composite sliding plate has high compressive strength, excellent wear resistance and excellent creep resistance. By means of the technical scheme, the problems that in the prior art, a sliding material for a seismic mitigation and isolation support is low in compressive strength, poor in wear resistance and poor in creep resistance are effectively solved.

The invention discloses a miniature multi-ion sensing system based on a non-gate array and a preparation method thereof, and belongs to the technical field of electrochemical sensing, and the miniature multi-ion sensing system comprises a multi-ion sensing unit and a molybdenum disulfide non-gate array; the multi-ion sensitive unit comprises a metal electrode array, an ion sensitive film array and a liquid storage tank, multiple ions are detected through the ion sensitive film array at the same time and converted into electric signals, and the electric signals are transmitted to the molybdenum disulfide non-gate array through the metal electrode array; the molybdenum disulfide NOT gate array comprises a plurality of molybdenum disulfide NOT gates, and each molybdenum disulfide NOT gate comprises a metal electrode layer, a molybdenum disulfide layer, a NOT gate input end and a NOT gate output end, so that two field effect transistors are formed, received electric signals are amplified, the Nernst limit is broken through a NOT gate structure, and tiny changes of ion concentration are accurately detected. The sensitivity is higher; molybdenum disulfide is used as a channel material of the NOT gate, so that the size and power consumption of the NOT gate are effectively reduced, the integration level of the system is improved, and the service life of the system is prolonged.

The invention discloses a molybdenum disulfide acid leaching purification process, relates to the technical field of molybdenum disulfide purification, and aims to solve the problems of waste acid recycling, wastewater treatment and equipment corrosion in the molybdenum disulfide purification process. The molybdenum disulfide acid leaching purification process comprises the following steps: S1, acid purification: adding a molybdenum concentrate raw material into a reaction kettle; adding reaction acid into the reaction kettle according to a certain solid-to-liquid ratio, heating the reaction kettle to react for a period of time, and cooling to dissolve impurities in the molybdenum concentrate; s2, filter pressing and cleaning: conveying the acid-washed material to a plate frame for filter pressing to form a filter cake, cleaning the filter cake with clear water for 2-4 times until the wastewater is neutral, and conveying the filter cake to the plate frame for filter pressing again; s3, repeating acid purification and filter-pressing cleaning for several times until various acids are used up in the process; and S4, drying: putting the cleaned filter cake into a drying system for drying to obtain the high-purity molybdenum disulfide with the purity of more than or equal to 99%. According to the acid leaching purification process, impurities in molybdenum disulfide are selectively dissolved, the purity of molybdenum disulfide is remarkably improved, and the industrial application requirement is met.

The invention provides molybdenum sulfide powder, a heavy metal adsorbent, a photo-thermal conversion material, a distillation method, an oxygen reduction catalyst and catalyst ink. This molybdenum sulfide powder contains a 3R crystal structure of molybdenum disulfide. The heavy metal adsorbent according to the present invention contains molybdenum sulfide particles having a median diameter (D50) of 10-1000 nm as determined by a dynamic light scattering type particle size distribution measurement device. This photo-thermal conversion material contains a material containing molybdenum sulfide particles, and generates heat by absorbing light energy.

The application provides a preparation method of a self-coiled structure molybdenum disulfide / nitrogen-doped porous carbon composite material, a product and application, high-content nitrogen-doped porous carbon material is synthesized by inducing dicyandiamide molecules to undergo a supramolecular self-assembly process, and on this basis, a hydrothermal reaction is carried out to coat molybdenum sulfide sheet layer material on the surface, and finally, a self-heating coiling treatment is carried out to form a carbon-based electrocatalyst of the self-coiled structure molybdenum disulfide / nitrogen-doped porous carbon. Compared with a high specific surface area carbon-based catalyst, high doping concentration of nitrogen atoms can provide more electron-rich properties to facilitate the adsorption of substances, and the self-coiled carbon-based material can exhibit very excellent electrochemical performance, especially in the aspect of electrochemical hydrogen production. The preparation method is simple in operation, low in preparation cost and suitable for large-scale production.

The invention discloses tannic acid-oleylamine modified nano molybdenum disulfide as well as a preparation method and application thereof. The preparation method of the tannic acid-oleylamine modified nano-molybdenum disulfide comprises the following steps: 1) dispersing nano-molybdenum disulfide and tannic acid in a solvent, then adding ferric salt for reaction, and then carrying out product separation to obtain the tannic acid modified nano-molybdenum disulfide; and 2) dispersing the tannic acid modified nano molybdenum disulfide and oleylamine in a solvent for reaction, and then carrying out product separation to obtain the tannic acid-oleylamine modified nano molybdenum disulfide. The tannic acid-oleylamine modified nano molybdenum disulfide disclosed by the invention has the advantages of excellent friction reduction and wear resistance, good dispersity in ester oil, good compatibility with other additives and the like, the preparation raw materials are safe and non-toxic, the preparation method is simple, and the tannic acid-oleylamine modified nano molybdenum disulfide is suitable for large-scale industrial production and application.

The invention relates to a polypropylene foam material with a wave-absorbing function, and belongs to the technical field of wave-absorbing materials. The polypropylene foam material with the wave-absorbing function is prepared from the following components in parts by mass: 75 to 85 parts of polypropylene resin, 15 to 25 parts of wave-absorbing filler, 3 to 4 parts of nucleating agent, 3.5 to 4.5 parts of foaming agent and 0.2 to 0.8 part of antioxidant, the preparation method of the wave-absorbing filler comprises the following steps: plating nickel on molybdenum disulfide to obtain nickel-plated molybdenum disulfide; and then the surface of the nickel-plated molybdenum disulfide is coated with copper in situ, and the wave-absorbing filler is obtained. The surface of molybdenum disulfide is sequentially coated with metal nickel, polydopamine and metal copper, the metal copper and the metal nickel can be tightly and evenly distributed on the surface of molybdenum disulfide, the metal copper and the metal nickel are tightly combined together through the polydopamine, the synergistic effect can be achieved, and the electric conductivity, the magnetic conductivity and the wave absorbing capacity are improved.

The invention discloses application of a composite film with a multi-element and multi-phase structure in surface lubrication of an aerospace vehicle or a nuclear power bearing in a high-temperature environment. The composite film comprises a titanium transition layer, a titanium / molybdenum disulfide / tantalum / tungsten diboride gradient transition layer and a multi-element and multi-phase structure layer which are sequentially formed on the surface of a base body. The multicomponent multiphase structure layer comprises a molybdenum disulfide / tantalum / tungsten diboride composite layer, the molybdenum disulfide / tantalum / tungsten diboride composite layer comprises tantalum nanoparticles, a molybdenum disulfide layer and a tungsten diboride layer, and the tantalum nanoparticles are distributed between the molybdenum disulfide layer and the tungsten diboride layer. The composite film with the multi-element and multi-phase structure shows higher hardness and hardness / elasticity ratio and low friction coefficient and wear rate at the high temperature of 400 DEG C, and meanwhile, the composite film can meet stable lubrication and long-life reliable service of aerospace vehicles and nuclear power bearings under harsh and complex variable working conditions.

The invention discloses molybdenum disulfide nanosheet modified urea formaldehyde / melamine resin as well as preparation and application thereof. A preparation method of the molybdenum disulfide nanosheet modified urea formaldehyde / melamine resin comprises the following steps: (1) preparing molybdenum disulfide nanosheets from a sulfur source and a molybdenum source by adopting a hydrothermal synthesis method; (2) carrying out surface functional group modification on the molybdenum disulfide nanosheet by using a surface functional group modifier; (3) carrying out copolymerization reaction on aldehydes, a compound containing polyamido and the molybdenum disulfide nanosheet modified by the surface functional group in the step (2) to obtain molybdenum disulfide nanosheet urea formaldehyde / melamine resin; and (4) modifying the molybdenum disulfide nanosheet urea formaldehyde / melamine resin by using a silane coupling agent to obtain the molybdenum disulfide nanosheet modified urea formaldehyde / melamine resin. According to the method disclosed by the invention, the polymer is copolymerized and grafted onto the molybdenum disulfide nanosheet, so that the problems that urea formaldehyde / melamine resin is insufficient in temperature resistance and poor in pressure resistance after being solidified with a rock core are effectively solved.

A combined extrusion method for preparing high-performance grain-refined magnesium alloy comprises the following steps that a mold is cleaned, and a molybdenum disulfide solid lubricant is evenly sprayed to an extrusion channel to reduce friction force; the tightening mold is tightly wrapped with refractory cotton after being placed at a proper extrusion position of a workbench; induction heating plates are placed on the two sides of the mold, a thermocouple is placed in an extrusion channel for temperature measurement, and heat preservation is conducted for 30 min after heating is conducted to the experimental temperature; polishing the sample to remove an oxide layer, and then uniformly spraying a MoS2 solid lubricant; putting into a muffle furnace, heating to 300-350 DEG C along with the furnace, and preserving heat for 15 minutes; coordinating the heat preservation time of the sample and the mold; after the heat preservation time is finished, the heating and temperature measuring equipment is moved away, and the sample is put into an extrusion channel and extruded at the speed of 2-4 mm / s; after extrusion is finished, the sample and the mold are air-cooled together at the original position of a workbench; after cooling to room temperature, opening the mold and taking out the sample. The tensile strength, the ductility and the product of strength and elongation of the sample extruded by the method are 298.02 MPa, 23.42% and 6.98 GPa% respectively, and the performance of the magnesium alloy is greatly enhanced.

The invention belongs to the technical field of electro-catalytic materials, and particularly relates to a metal cation doped polymetallic sulfide nanosphere as well as a preparation method and application thereof. The metal cation doped polymetallic sulfide nanosphere is formed by polymetallic sulfide nanosheets, and polymetallic sulfide comprises molybdenum sulfide and metal cation doped cobalt sulfide; the metal cations comprise nickel ions and / or manganese ions. The material has excellent bifunctional catalytic performance of hydrogen evolution reaction (HER) and oxygen evolution reaction (OER), shows excellent water electrolysis performance, and can effectively improve the catalytic efficiency of water electrolysis.

The invention provides a molybdenum sulfide-molybdenum nitride heterojunction and a preparation method and application thereof.The preparation method comprises the following steps that molybdenum sulfide grows through a chemical vapor deposition method to obtain multi-layer molybdenum sulfide, and the number of the layers of the multi-layer molybdenum sulfide is at least two; and heating and nitriding the multilayer molybdenum sulfide and a nitrogen source to obtain the molybdenum sulfide-molybdenum nitride heterojunction. According to the preparation method, the multilayer molybdenum sulfide is adopted as the precursor for high-temperature nitridation, the formation process of the heterojunction can be accurately regulated and controlled, the catalytic activity at a microscopic heterojunction interface is accurately tested, and meanwhile the catalytic performance of the molybdenum sulfide-molybdenum nitride heterojunction can be improved.

The invention discloses application of a molybdenum disulfide nano material in crop cold damage regulation and control, and belongs to the technical field of anti-cold agents. The preparation method comprises the following steps: dispersing a molybdenum disulfide nano material in water to obtain a suspension; then the suspension is sprayed on corn and soybean leaves, the cold resistance of the corn and the soybean is regulated and controlled in a leaf surface spraying mode, the biomass of the cold-damaged corn and the soybean can be increased, and the application prospect is excellent.

The invention belongs to the technical field of photovoltaics, and particularly relates to a heterojunction crystalline silicon solar cell and a preparation method and application thereof. According to the heterojunction crystalline silicon solar cell provided by the invention, MoSz-QD is embedded in the SiOy layer, molybdenum sulfide (MoSz) has good electrical properties, and rapid migration of carriers is facilitated; meanwhile, the band gap of the MoSz-QD can be broadened to gt; 3.0 eV, so that high Ec is formed on an interface to prevent electron transport, and the blocking effect of non-selective carriers (electrons) can be realized; moOx is deposited on the surface of MoSz-QD, an impurity energy level is formed through defect engineering, and only holes are allowed to utilize traps to assist tunneling to form effective transportation, so that the heterojunction crystalline silicon solar cell provided by the invention is a high-performance heterojunction crystalline silicon solar cell; the technical problem that in the prior art, a solar cell with a transition metal oxide (TMO) selective contact layer is poor can be solved.

The invention discloses multifunctional nano-enzyme composite hydrogel as well as a preparation method and application thereof. The preparation method comprises the following steps: synthesizing molybdenum disulfide MoS2 by taking hexaammonium heptamolybdate tetrahydrate and thiourea as raw materials; the preparation method comprises the following steps: carrying out stirring reaction on MoS2 and cysteine to obtain MoS2-LC; the preparation method comprises the following steps: mixing galangin with MoS2-LC, carrying out ultrasonic treatment, and carrying out a stirring reaction to obtain MoS2-LC (at) Gal; the preparation method comprises the following steps: adding acetic anhydride into a carboxymethyl chitosan aqueous solution to obtain N-acetylated carboxymethyl chitosan N-CC; the preparation method comprises the following steps: adding 1-butyl-3-methylimidazole chlorine salt into N-CC to react, and carrying out alcohol precipitation to obtain N-CC-IL; a cross-linking agent, MoS2-LC (at) Gal and N-CC-IL are subjected to a blending reaction, and SNCI (at) MLG is obtained. Pharmacodynamic results show that the multifunctional nano-enzyme composite hydrogel prepared by the preparation method disclosed by the invention can play a role in inhibiting ferroptosis while having an antibacterial effect, and a new possibility is provided for periodontal local treatment.