The invention relates to a novel
hydrogen adsorption and
desorption method, which aims at providing a reversible
hydrogen adsorption and
desorption method using
piperidine as a media and a device. The method uses
hydrogen storage
alloy as a catalyst, and the reversible
hydrogen adsorption and
desorption process comprises the
hydrogen desorption process and the
hydrogen adsorption process, wherein in the
hydrogen desorption process, under the temperature condition of 120 to 350 DEG C, the
piperidine is converted into
pyridine under the effect of the
hydrogen storage alloy, and at the same time, the hydrogen gas is released out; and in the
hydrogen adsorption process, under the temperature condition of 95 to 115 DEG C, the hydrogen gas is introduced into the
pyridine, and the
pyridine and the hydrogen gas generate the
piperidine under the effect of the
hydrogen storage alloys. The piperidine is used as the
hydrogen storage media, so the hydrogen storage quantity which is much higher than that of the
metal hydrogen storage
alloy can be provided, and the invention is hopeful to become a hydrogen source of a fuel battery for generating
electricity and to be used as
motive power of a fuel battery vehicle. The hydrogen gas through the
decomposition of the piperidine is pure, does not contain CO, can be directly used for the fuel battery, and does not need the purification like the hydrogen gas obtained through the
methanol modification, so the
system is simple, and the operation is convenient.