The present application relates to the medical field, specifically is crosslinking type
polylactic acid material and its preparation method and application, the present application is through the ATIPA bond to the
polymer main chain, gives the material intrinsic, stable and throughout the whole life cycle
X ray visibility, through the HEDS as the
structural unit integration into the hard segment, constructs the dynamic
exchange network, makes the material when microcosmic damage occurs can realize self-repair through the reversible fracture and recombination of
disulfide bond, significantly improves its anti-fatigue performance and long-term service reliability, through the adoption of the degradation rate different PLA and PCL double
soft segment copolymerization, constructs the
time sequence degradation model, wherein the PLA of fast degradation provides the initial support and the PCL of slow degradation forms the secondary network, together ensures that the material
mechanical strength presents gentle attenuation along with the
blood vessel remodeling process, effectively avoids the risk of "
cliff type" mechanical loss. Three kinds of functions integrated in the
molecular level mutually coordinate, systematically solves the key
bottleneck of the prior art.