1158 results about "Electron donor" patented technology

The invention belongs to the technical field of sewage treatment, and particularly relates to an anaerobic ammonia oxidation-photoelectric denitrification deep nitrogen removal method. The method comprises the following steps: firstly, adopting a double-chamber reactor; introducing part of sewage into the cathode chamber, carrying out Anammox reaction under a dark state condition to remove ammonia nitrogen and part of nitrite nitrogen, and synchronously generating nitrate nitrogen; turning on a light source to irradiate the anode chamber, exciting photo-induced electrons by a photosensitizer, transmitting the photo-induced electrons to the cathode chamber through an external circuit, and driving the sulfur autotrophic denitrification sludge to reduce residual nitrite nitrogen and nitrate nitrogen generated by Anammox; the total nitrogen removal rate is close to 100%. According to the invention, photo-induced electrons are used as the only denitrification electron donor, so that the addition of a carbon source / sulfide is thoroughly avoided, and the risk of secondary pollution is eliminated. The method is suitable for green low-carbon deep treatment of sludge digestion liquid and pharmaceutical wastewater high-ammonia-nitrogen low-carbon-nitrogen-ratio sewage.

The invention provides a solid polymer electrolyte capable of working in a wide temperature range. The solid polymer electrolyte is obtained by carrying out in-situ polymerization on a precursor solution on the surface of a base material, wherein the precursor solution is prepared from a first type of polymeric monomer, a second type of polymeric monomer, an initiator and electrolyte salt; the first polymeric monomer is an electron donor, and the electron donor is at least one of cyclic ether and olefin monomers; the second polymeric monomer is an electron acceptor, and the electron acceptor is one or more of cyclic ester, olefin monomers and anhydride monomers. The solid polymer electrolyte keeps good mechanical performance and high ionic conductivity in a wide temperature range, and an assembled solid secondary battery has good electrical performance and cycling stability.

The invention discloses a compound containing a urea structure as well as a preparation method and application of the compound in a color developing agent, and relates to the technical field of color developing agents. The compound containing the urea structure is a # imgabs0 # structure as shown in a formula 1. The compound containing the urea structure is synthesized through multiple steps of Suzuki reaction, bromination reaction and substitution reaction. The compound is used as an electron donor to be applied to a thermosensitive color development system and forms a color development composition with a phenolic compound and an acidic material, and the activation temperature is as low as 60-120 DEG C. The ureido structure stabilizes a reaction intermediate through a hydrogen bond network, enhances the electron transfer efficiency, and significantly improves the color developing sensitivity; the aryl / heteroaryl substituent optimizes the color contrast through the conjugation effect, and meanwhile, the synergistic effect of the hot-melt filler ensures the stability of the system. Compared with a traditional color developing agent, the color developing agent has the advantages of low-temperature activation, high color developing intensity and excellent weather resistance, is suitable for the fields of thermal printing, anti-counterfeiting materials and the like, and overcomes the defects of high reaction temperature and insufficient stability in the prior art.

The invention discloses a device and a method for realizing low-carbon-nitrogen-ratio sewage autotrophic and heterotrophic coupled deep nitrogen and phosphorus removal based on a continuous flow membrane aeration bio-membrane reactor. A hollow fiber membrane is arranged in the continuous flow reactor, and an oxygen concentration gradient is formed through a bubble-free membrane aeration technology. In the biomembrane area, spatial partitions of functional bacteria such as nitrifying bacteria and anaerobic ammonium oxidation bacteria are established, and the two anoxic areas realize efficient nitrogen removal through short-cut denitrification coupling anaerobic ammonium oxidation (PD / A) and synchronous nitrification and denitrification. In the aspect of phosphorus removal, the system adopts an anaerobic-aerobic operation mode, phosphorus-accumulating bacteria release phosphorus anaerobically and absorb excessive phosphorus aerobically, and finally, phosphorus removal is realized through residual sludge discharge. The system integrates an internal carbon source extraction process, recovers a sludge carbon source and supplements an electron donor required by denitrification, and reduces the operation cost and carbon emission. The continuous flow MABR denitrification system enhances the denitrification efficiency of the PD / A system, is suitable for large-scale operation, and efficiently and stably realizes deep denitrification of a low-carbon-nitrogen-ratio urban sewage treatment plant.

The present application relates to the field of municipal wastewater treatment, and particularly relates to a highway service area wastewater treatment device and method based on AOOA-MBBR process. The device comprises a first anoxic tank, a first aerobic tank, a second aerobic tank and a second anoxic tank connected in sequence, and is filled with MBBR filler respectively, and the volume of the filled MBBR filler is taken as the effective volume; the first aerobic tank and the second aerobic tank are respectively provided with an aeration device; the first anoxic tank is used for inoculating hydrolytic bacteria and denitrifying bacteria; the first aerobic tank is used for inoculating hydrolytic bacteria, nitrifying bacteria and denitrifying bacteria; the second aerobic tank is used for inoculating nitrifying bacteria, and the second anoxic tank is used for inoculating hydrolytic bacteria and denitrifying bacteria; the second aerobic tank is connected with the first anoxic tank through a reflux pipe, and the reflux pipe is provided with a reflux power assembly. The present application solves the problems of existing highway service wastewater treatment with extremely low carbon-nitrogen ratio, such as the need for additional carbon source / electron donor, high operation cost, poor denitrification effect and high sludge yield.

The present disclosure provides an alignment method and application of a cyanobiphenyl liquid crystal composite doped with an organic donor material. The organic small molecule is doped in the host cyanobiphenyl liquid crystal, and the small molecule donor / cyanobiphenyl liquid crystal mixture is directionally induced to assemble by virtue of the large surface energy difference between the superhydrophobic structured substrate and the superhydrophilic flat substrate. The liquid crystal molecules form a uniform arrangement under the action of the liquid bridge, driving the self-assembly of the small molecule donor to be embedded in the cyanobiphenyl liquid crystal, forming a structure of electron donor-donor, enhancing the conductivity of the liquid crystal composite device, studying the influence of the surface tension of the solvent on the performance of the composite, and giving a direction for the selection of the solvent. Compared with the methods of inducing the alignment of liquid crystal molecules and donor small molecules by using electric fields, magnetic fields, photolithography, capillary methods, etc., this method is simpler and more feasible, easy to transfer, the circuit pattern is easy to design, and has good stability.

IR-sensitive lithographic printing plate precursors provide a stable print-out image using a unique IR radiation-sensitive composition in an infrared radiation-sensitive image-recording layer. This IR radiation-sensitive composition includes: (1) a free radical initiator composition that comprises an electron-donating agent; (2) a free radically polymerizable composition; and (3) a color-changing compound that is represented by the Structure (I) having a conjugated carbon chain between the aromatic terminal groups. The compound also has a —SO2—R3 group wherein R3 represents alkyl, aryl or heteroaryl groups. After IR imaging, these precursors exhibit desirable printout images both fresh and after dark storage. The precursors can be developed off-press or on-press.

The invention discloses preparation of a phenanthroline-based covalent organic framework photocatalyst and application of the phenanthroline-based covalent organic framework photocatalyst in photocatalytic production of hydrogen peroxide. According to the method, a hydrogen peroxide production experiment is carried out in a water-oxygen system or a benzyl alcohol-water-oxygen system by taking phenanthroline-based COF as a photocatalyst. According to the invention, through regulation and control of molecular flatness engineering, an electron-rich phenanthroline unit (Phen) anchored by a pyridine expansion plane and electron-deficient triazine (TTA) are integrated into a COF skeleton, and a novel electron donor-acceptor (D-A) type COF is synthesized. The COF has the advantages of proper energy band structure, excellent photo-induced electron and hole separation efficiency, strong D-A interaction, good hydrophilicity and the like, and the efficiency of photocatalytic hydrogen peroxide production reaction within a short time is greatly improved. The invention provides a use method of the COF photocatalyst which is cheap, convenient, rapid, efficient and environment-friendly, and has a potential application prospect.

The invention relates to the technical field of luminescent materials, and discloses an aggregation-induced emission material, nanoparticles as well as a preparation method and application thereof, the structural general formula of the aggregation-induced emission material is as follows: # imgabs0 #, R is selected from one of the following structures: # imgabs1 # aggregation-induced emission material takes a pyridine group as an acceptor unit, and the acceptor unit is selected from one of the following structures: 1 # imgabs2 # aggregation-induced emission material; a carbon-carbon double bond and a thiophene unit are used as pi bridges, and diphenylamine, bis (4-ethylphenyl) amine and bis (4-(tert-butyl) phenyl) amine are used as strong electron donors. The donors not only provide strong electron supply ability, but also become efficient rotors due to highly twisted molecular conformation, and endow the aggregation-induced emission material with long emission wavelength and aggregation-induced emission activity.

A long-persistent luminescence emitter containing a polymer that contains, relative to the total molar amount of an electron donor structural unit and an electron acceptor structural unit therein, 70 mol % or more of an electron donor structural unit and less than 30 mol % of an electron acceptor structural unit, or containing a polymer that contains, relative to the total molar amount of an electron donor structural unit and an electron acceptor structural unit therein. 70 mol % or more of an electron acceptor structural unit and less than 30 mol % of an electron donor structural unit. The emission decay after stopping light irradiation to the emitter is power law decay.

The application discloses a kind of synchronous denitrification and phosphorus removal light materials and its preparation and application method, belong to environmental functional materials and sewage treatment technical field.The application is obtained by fully melting and dispersing sulfur and iron-based component, and the iron-based component is a mixture of pyrite and calcium-magnesium carbonate.The molten mixture is foamed to form a synchronous denitrification and phosphorus removal light material.The synchronous denitrification and phosphorus removal light material has high porosity, large specific surface area, light weight and high reactivity.The light material is used as a microbial carrier and an electron donor for biochemical reactions, and is applied to fixed bed, fluidized bed and other reactors for sewage treatment.The light material has good microbial adhesion performance, high denitrification rate and good phosphorus removal effect.

According to the alkoxy magnesium carrier Ziegler-Natta catalyst and the preparation method thereof, alkoxy magnesium is activated and then loaded with titanium, fluorene diether is selected as an internal electron donor, the obtained catalyst is subjected to post-treatment, and finally the alkoxy magnesium carrier Ziegler-Natta catalyst with excellent performance is prepared. The raw material utilization rate is higher, the adding amount of required titanium tetrachloride is smaller, the steps are simpler, the preparation conditions are mild, the isotactic index of the prepared homo-polypropylene is higher, and the activity of the prepared catalyst is higher.

The denitrification filter tank comprises a tank body and sulfur autotrophic denitrification filler, a blending area and a filler area which are communicated with each other are arranged in the tank body, and the blending area and the filler area are sequentially distributed in the length direction or the width direction of the tank body; the blending area is provided with a water inlet; the filler area is provided with a water outlet; sewage to be treated flows in from the water inlet, sequentially passes through the blending area and the filler area and flows out of the tank body from the water outlet; the sulfur autotrophic denitrification filler is arranged in the filler area and is used for performing sulfur autotrophic denitrification treatment on the flowing sewage. When sewage flows through the sulfur autotrophic denitrification filler, nitrate nitrogen in the sewage is converted into nitrogen through the denitrification effect of sulfur autotrophic denitrification microorganisms and by taking sulfur or reduced sulfide as an electron donor, so that the denitrification treatment of the sewage is realized, the removal efficiency is high, an organic carbon source does not need to be added, and the operation cost is low.

The invention discloses a compound, a kit and application thereof, and relates to the technical field of biomedicine. The compound comprises an electron acceptor aromatic unit, an optional electron donor aromatic unit and a shielding unit, and the shielding unit shields intermolecular interaction of the electron acceptor aromatic unit and / or the electron donor aromatic unit. Wherein the electron acceptor aromatic unit, the electron donor aromatic unit and the shielding unit are connected through covalent bonds. The compound can be used as a molecular near-infrared-II fluorophore, and has higher quantum yield and good biocompatibility. The compounds emit fluorescence in the range of 900-1400 nanometers, the intermolecular and intramolecular interaction of the conjugated skeleton is weakened, and the quantum yield is improved. The high quantum yield, biocompatibility and near-infrared II emission of the compound provide opportunities for in-vivo application of near-infrared II imaging by using molecular fluorophores.

The invention discloses a membrane bio-membrane reactor and a method for efficiently coupling biogas recycling and denitrification by using the same, and relates to a reactor and a method for recycling and denitrifying biogas by using the same. The invention aims to solve the technical bottleneck problems that the traditional denitrification process depends on an external carbon source and is high in cost, and the existing methane-based membrane bio-membrane reactor cannot fully utilize biogas resources. The invention discloses a membrane bio-membrane reactor. Comprising a biogas high-pressure gas cylinder, a high-pressure gas pressure reducing valve, a reactor main body, a hollow fiber membrane assembly, a reactor main body water outlet, a reactor main body water inlet, a water inlet device, a reflux device, a circulating water outlet, a circulating water inlet, a gas sampling port, a reflux device water outlet, a liquid sampling port, a pH measuring instrument, a water outlet liquid sealing device and an atmosphere communication port. The mechanism of'one source and two purposes' (serving as an electron donor and converting into a carbon source in situ) of biogas methane is the core of realizing efficient denitrification and biogas resource utilization.

The present invention provides an autotrophic denitrification filter material, comprising three types of materials A, B, and C, and the weight ratio of each material is A: B: C = (10-15): (1-2): 1, wherein A is a composite denitrification ingredient, including ferrous sulfide, sulfur, sodium thiosulfate and iron powder; B is an adhesive; and C is a molecular sieve treated with a microbial culture solution. The high efficiency of the autotrophic denitrification filter material with high efficiency denitrification provided by the present invention is mainly based on the following two options: first, the filter material belongs to a multivalent composite sulfide-iron coupling denitrification scheme, and the diverse electron donors of the autotrophic denitrifying bacteria have synergistic synergy; second, the autotrophic denitrifying bacteria culture solution is pre-placed in the gap of the molecular sieve, which can be slowly released, ensuring that the autotrophic denitrifying bacteria can still maintain growth when the environment is subjected to various shocks. The autotrophic denitrification filter material provided by the present invention has a simple preparation process, is easy to operate during application, and can maintain high efficiency in denitrification capacity.

The invention discloses a carboxymethyl beta-cyclodextrin modified D-A COF material and a preparation method and application thereof.Benzotrithiophene is used as an electron donor, triazine is used as an electron withdrawing unit, imine-connected D-A COFs are successfully synthesized through a solvothermal method, the imino COFs and carboxymethyl beta-cyclodextrin are treated through a Ugi multi-component reaction, and the COF material is prepared. And the COFBTT-TAPT photoactive material containing the beta-cyclodextrin group is obtained through preparation. COFBTT-TAPT-beta-CD and Mxene form a heterojunction to further enhance the photoelectric conversion efficiency of the photoactive material, and the photoactive material is used for preparing a photoelectrochemical sensor, so that high-sensitivity field screening of PFOS (perfluorooctane sulfonate) can be carried out in a low concentration range.

The invention relates to a composite ecological filler for enhancing in-situ denitrification of a river water body, a percolation system and application. The composite ecological filler is composed of an anoxic denitrification filler and a transition regulation filler or composed of an aerobic nitrification filler, an anoxic denitrification filler and a transition regulation filler; the aerobic nitrification filler comprises an inorganic mineral matrix denitrification filler, biological ceramsite, a mineral-based slow-release functional material and a microbial immobilization functional carrier; the anoxic denitrification filler comprises a sulfur-based composite electron donor material, a slow-release organic carbon source material, a zero-valent iron-based environmental remediation material and denitrifying bacterium embedding gel; the transition regulation and control filler comprises a multifunctional water treatment filter material, activated carbon and an environment response type functional microbial carrier. The invention also provides application of the composite ecological filler and a percolation system, solves the problem that the traditional denitrification filler cannot cooperatively support nitrification / denitrification due to single function, and also solves the problem that the fixed ratio of the traditional denitrification filler is difficult to adapt to dynamic fluctuation of water quality.

The invention belongs to the technical field of photocatalysts, and particularly discloses a CoMo6 / Fe3O4 (at) ZnO composite material and a preparation method and application thereof.The photocatalytic mechanism of the prepared CoMo6 / Fe3O4 (at) ZnO composite material is as follows: after the composite material CoMo6 / Fe3O4 (at) CeO2 is excited by light, photo-induced electrons on CoMo6 are transferred to the surface of Fe3O4 (at) ZnO, meanwhile, photo-induced holes absorb an electron donor H2O on the surface of POM polyanions to react to generate. OH, and the CoMo6 / Fe3O4 (at) ZnO composite material is obtained. The. OH free radical with strong oxidation capability oxidizes eosin B to generate oxidation products such as CO2 and the like. In the experiment, a small amount of electrons absorb an electron acceptor O2 and reduce the electron acceptor O2 to generate. O2 <->, and the two free radicals act at the same time to promote the photocatalytic reaction. When a magnetic field is added outside, the oxidation capacity and rate of. OH are also accelerated, so that the degradation rate of eosin B is improved; the highest degradation rate on an eosin B dye can reach 92.21%; after an external magnetic field is applied, the degradation rate is obviously accelerated, and the reaction is almost complete 40 minutes after illumination is started.

The invention relates to the technical field of biological denitrification, in particular to a nitrogen-doped carbon dot-based microbial electronic control denitrification system and application thereof. The system comprises electron donor microorganisms, electron acceptor microorganisms and nitrogen-doped carbon dots, the nitrogen-doped carbon dots serve as electron mediators outside cells, an efficient extracellular electron transfer network is constructed, and interspecific electron transfer resistance is reduced; meanwhile, the nitrogen-doped carbon dots can regulate and control intracellular electron transport chains and the energy metabolism process, the improvement of the reducing power and the energy level is promoted, and the metabolism mode optimization is realized. By cooperatively regulating and controlling generation, transmission and utilization of electrons under an extreme electron donor limited oligotrophic condition, the system disclosed by the invention can realize efficient denitrification, avoid nitrite accumulation, remarkably inhibit generation of nitrous oxide (N2O), reduce dependence on an external organic carbon source and an electron source, and improve the denitrification efficiency. And a new technical approach is provided for improving the deep denitrification efficiency under the low-carbon condition.

The invention discloses a tetrathiomolybdate intercalated ternary iron-magnesium-zinc layered double hydroxide catalyst, a preparation method thereof and an application of the tetrathiomolybdate intercalated ternary iron-magnesium-zinc layered double hydroxide catalyst in degrading azo dyes by activating peroxymonosulfate. According to the method, a carbonate intercalated ternary LDH precursor is synthesized through a hydrothermal reaction, interlayer anions are replaced with nitrate and tetrathiomolybdate through ion exchange, and the target catalyst is obtained. In the catalyst, a unique Fe-Mg-Zn ternary metal laminate and a MoS < 2-> intercalation structure cooperatively construct a multi-active center, and MoS < 2-> is used as an electron donor to promote cyclic regeneration of Fe < 3 + > / Fe < 2 + >. The catalyst keeps ultrahigh activity in a wide range of pH (potential of hydrogen) of 3-9, can completely degrade 10 mg / L of acid orange 7 within 5 minutes, and is stable in structure and low in metal dissolution risk. The problems of low activity, slow Fe < 3 + > reduction, metal ion dissolution and the like under neutral and alkaline conditions in an advanced oxidation technology based on peroxymonosulfate are solved, and the method has important application value in the field of printing and dyeing wastewater treatment.

The invention relates to an electrocatalysis-biological fermentation coupling system as well as a construction method and application thereof. The electrocatalysis-biological fermentation coupling system comprises an electrocatalysis unit and a fermentation unit; the electro-catalysis unit is used for electrolyzing water to generate H2 and O2; the fermentation unit is used for producing succinic acid through fermentation by taking CO2 as a carbon source and taking H2 and O2 generated by the electro-catalysis unit as an electron donor and an electron acceptor; the fermentation unit comprises S.ovaata bacteria, E.coli bacteria and a culture medium, the S.ovaata bacteria are used for synthesizing acetate by taking CO2 as a carbon source, and the E.coli bacteria are used for synthesizing succinic acid by utilizing the acetate. According to the invention, an electro-catalysis-biological fermentation coupling system with a specific structure is designed, the system can stably operate for 5 days, and the average yield of succinic acid is as high as 30.70 mg.L <-1 >. Day <-1 >.

A compound having a structure of Formula I,is provided. In Formula I, Z1 to Z16 are each CR or N; three consecutive ones of Z1 to Z16 within the same ring cannot be N; each R is independently a hydrogen or a substituent selected from a variety of substituents; at least one R includes and electron donor substituent; at least one R includes an electron acceptor substituent; and any two Rs on the same ring can be joined or fused together to form a ring. Organic light emitting devices, consumer products, formulations, and chemical structures containing the compounds are also disclosed.

The invention provides a preparation method of composite degradable TIEL aerogel, and relates to the technical field of production of TIEL aerogel. The preparation method of the composite degradable TIEL aerogel comprises the following steps: S1, firstly, preparing a culture medium, and dissolving 20g / L of glucose, 5g / L of yeast extract, 5g / L of peptone, 2.7 g / L of Na2.HPO4, 0.5 g / L of MgSO4. 7H2O and 1.5 g / L of citric acid in deionized water; s2, adjusting the pH value of the culture medium with HCl, then performing high-temperature sterilization treatment on the culture medium, cooling the culture medium to room temperature, inoculating pre-cultured acetobacter aceti into the culture medium, performing static culture for 7 days at 30 DEG C, then repeatedly cleaning the harvested film with deionized water, and removing impurities with an alkaline solution to obtain a fresh bacterial cellulose film. According to the cellulose aerogel, chitosan is introduced as a natural electron donor, so that the triboelectric property of the cellulose aerogel is optimized, and meanwhile, the degradability is kept.

The invention discloses an acid mine pollution treatment method based on microbial regulation and control, and belongs to the technical field of environmental protection engineering, and the acid mine pollution treatment method comprises the following steps: S1, screening and domesticating acid-resistant and heavy metal-resistant functional microbial communities; s2, constructing a sectional bioreactor, and filling the sectional bioreactor with a corresponding composite biological carrier; s3, inoculating the functional microbial community obtained by domestication in the step S1 into the sectional reactor constructed in the step S2, and carrying out biofilm culturing in simulated AMD; and S4, introducing AMD to be treated into the reaction system in the step S3, and regulating and controlling microbial activity through pH gradient regulation and dynamic supply of electron donors to realize heavy metal precipitation and water quality remediation. According to the method, closed-loop treatment of sulfate reduction, heavy metal precipitation and acid neutralization is achieved through the synergistic effect of microbial regulation and control and the functionalized biological carrier, and the problems of efficiency, cost and secondary pollution of traditional AMD treatment are solved.

The invention belongs to the technical field of anaerobic fermentation of organic wastes, and discloses a method for producing medium-chain fatty acid by promoting anaerobic fermentation of excess sludge by using blue iron ore, which comprises the following steps: inoculating anaerobic sludge by using excess activated sludge from a municipal sewage treatment plant as a fermentation substrate, adding the blue iron ore and a methanogenesis inhibitor, adjusting the pH value, and fermenting to obtain the medium-chain fatty acid. Carrying out anaerobic fermentation in the presence of an electron donor to produce medium-chain fatty acid; due to the addition of the blue iron ore, the electron transfer capability of microorganisms in a carbon chain extension process can be enhanced, so that the yield of medium-chain fatty acid in a fermentation product is increased; the addition amount of the blue iron ore in the system is 2-20g / L. According to the method, the blue iron ore is introduced into a system for producing the medium-chain fatty acid from the sludge, the addition amount of the blue iron ore in the system is strictly controlled, the blue iron ore is used as an electron mediator, and the electron transfer efficiency of microbial fermentation in the process of producing the medium-chain fatty acid from the sludge is enhanced, so that the yield of the medium-chain fatty acid is increased; further, efficient utilization of sludge resources is realized.

The invention provides a sewage deep denitrification method and equipment based on polysulfide-assisted activated sludge, and relates to the technical field of sewage treatment. Activated sludge is inoculated into a fluidized bed reactor to serve as a biological denitrification flora; the polysulfide agent and the nitrogen-containing wastewater to be treated respectively flow into the fluidized bed reactor from the bottom of the fluidized bed reactor through peristaltic pumps; operating the fluidized bed reactor to perform sewage denitrification, wherein the activated sludge in the fluidized bed reactor is in a fluidized state; and after water is discharged from the fluidized bed reactor, calcium salt is added for SO4 < 2-> removal control. The technical problems of limited electron transfer rate and easy generation of by-product pollution caused by taking an organic carbon source or elemental sulfur as an electron donor in the prior art are solved, and the technical effects of improving the denitrification performance, effectively controlling the generation of by-products and improving the environmental protection benefit are achieved.

The invention discloses a sewage treatment equipment state supervision system, belongs to the technical field of sewage treatment, and solves the problems that the sewage contains reducing sulfides and competes with denitrifying bacteria for electron donors, so that the COD in an anoxic zone is sufficient, the nitrate reduction rate is low, a false carbon source sufficient trap with inhibited denitrification occurs, but the sulfide is easy to oxidize, and the potential safety hazard is caused. And a sampling detection result is distorted and is difficult to identify. According to the invention, sewage is measured in an anoxic zone through a probe interface module, under the scheduling of a time division control module, a constant potential rectifier module excites sulfide characteristic oxidation current in a DPV time period, a logarithmic current detection module captures a peak value and integrates a charge quantity, an impedance detection module measures phase offset in an EIS time period, a signal processing module fuses characteristic values, and a temperature compensation module eliminates errors. The reference electrode protection module ensures signal fidelity, outputs sulfide concentration and electron competition index, starts a dosing system when the concentration exceeds the limit, and prevents sampling oxidation distortion in the whole process.

The invention discloses a staged regulation and control sulfur cycle enhanced denitrification microbial community construction method, and belongs to the technical field of environmental biologication.The method comprises the three stages that in the first stage, low-carbon-nitrogen-ratio domestication culture is conducted, the carbon-nitrogen ratio is 1.5-2.5: 1, and domestication is conducted for 50-70 days; in the second stage, electron donor-acceptor ratio regulation culture is carried out, the / molar ratio is (4-6): 1, and culture is carried out for 15-25 days; in the third stage, pulse type sulfate is fed for enhanced culture, the single-time feeding concentration is 200-500 mg / L, culture is conducted for 8-15 days, real-time monitoring is conducted through the fluorescence in-situ hybridization technology, construction is completed when the abundance of sulfur autotrophic denitrifying bacteria reaches 28% or above, and when the microflora constructed through the method is used for treating low-carbon-nitrogen-ratio industrial wastewater, the sulfur conversion rate is 1.2-2.0 kg / (m.d), the system stability is good, and the application range is wide. And the impact load resistance is high.

A process for preparing a solid catalyst component containing Mg, Ti, and an internal electron donor formed in-situ is provided. The solid catalyst component is suitable for producing polyethylene and its copolymers, and said process shows a combination of high productivity and high bulk density of ethylene polymers, lower soluble fraction, uniform particle morphology, and adjustable control of molecular weight distribution to allow controlled improvement in product properties as per specific requirements.