The invention provides a laminated
cell and a preparation method thereof, and relates to the technical field of cells, and the laminated
cell comprises a substrate structure, a composite junction and a top
cell structure which are sequentially laminated; wherein the composite junction comprises a conductive film layer, an interface modification layer and a
hole transport layer which are sequentially stacked on the substrate structure, and the
work function of the material of the interface modification layer is smaller than the
work function of the material of the conductive film layer. The conductive film layer, the interface modification layer and the
hole transport layer form a composite junction, and the
work function of the material of the interface modification layer is smaller than the work function of the material of the conductive film layer. An interface modification layer made of a
low work function material is used for carrying out
surface modification on a conductive film layer material in the composite junction, an interface modification layer made of an ultrathin
low work function material is introduced into a composite junction interface, and a conductive film layer /
hole transport layer structure is designed, so that better energy
band bending is realized, the carrier tunneling efficiency of the composite junction can be improved, and the performance of the composite junction is improved. And the performance of the laminated cell is improved.