4031 results about "Impurity" patented technology

The invention discloses a steel wire rod for a 2400-2460 MPa grade stress corrosion resistant prestressed steel strand, the steel strand and a production method. The steel wire rod comprises the following chemical components in percentage by weight: 0.90-0.97% of C, 0.6-1.2% of Si, 0.2-0.8% of Mn, 0.15-0.45% of Cr, 0.02-0.05% of V, 0.01-0.05% of Nb, less than 0.30% of Ni, less than 0.30% of Cu, less than 0.30% of Mo, less than or equal to 0.008% of S, less than or equal to 0.010% of P, less than or equal to 0.004% of N, less than or equal to 0.0020% of O and the balance of Fe and other inevitable impurities. By optimizing the chemical components and the production process of the wire rod, the strength of the prepared steel strand meets 2400-2460 MPa, the minimum stress corrosion value is 2.5 hours, the median value is 5 hours, and the stress corrosion resistance is obviously superior to that of an existing steel strand.

The invention discloses a steel wire rod for a 2300-2360 MPa grade stress corrosion resistant steel strand, the steel strand and a preparation method. The steel wire rod comprises the following chemical components in percentage by mass: 0.85-0.91% of C, 0.3-1.0% of Si, 0.2-0.8% of Mn, 0.15-0.45% of Cr, 0.02-0.05% of V, less than or equal to 0.008% of S, less than or equal to 0.010% of P, less than or equal to 0.004% of N, less than or equal to 0.0020% of O and the balance of Fe and other inevitable impurities. The steel wire rod has excellent strength and plasticity, the ultrahigh strength of 2300 MPa or above can be obtained through drawing with a small area reduction rate, surface damage and internal defects of the steel wire rod during subsequent drawing machining are reduced, and the stress corrosion index of the steel strand is improved.

The invention discloses a steel wire rod for a 2500-2560 MPa grade stress corrosion resistant prestressed steel strand, the steel strand and a production method. The steel wire rod comprises the following chemical components in percentage by mass: 0.95-1.02% of C, 0.8-1.5% of Si, 0.5-1.0% of Mn, 0.25-0.45% of Cr, 0.02-0.08% of V, 0.01-0.05% of Nb, less than 0.30% of Ni, less than 0.30% of Cu, less than 0.30% of Mo, less than or equal to 0.008% of S, less than or equal to 0.010% of P, less than or equal to 0.004% of N, less than or equal to 0.0020% of O and the balance of Fe and other inevitable impurities. By optimizing the chemical components and the production process and refining the microscopic structure, the steel strand prepared from the steel wire rod has high tensile strength, the minimum stress corrosion value is 2.5 hours, the median value is more than 5 hours, and the steel strand shows excellent stress corrosion resistance.

The invention discloses a 340MPa grade P-containing hot-dip galvanized iron alloy high-strength IF steel, the chemical composition of which is as follows by weight: C: ≤0.003%, Si: ≤0.03%, Mn: 0.35-0.65%, P: 0.03-0.075%, S≤0.010%, Als: 0.020-0.045%, Nb: 0.008-0.015%, Ti: 0.02-0.03%, B: 0.0004-0.0010%, N≤0.0035%, and the remainder is Fe and unavoidable impurities; The elements also meet the following restrictions: calculated according to the corresponding weight percentage of each element, 10C+3N+2S≤Ti+2Nb≤12C+3N+2S, 60B≤P≤80B; the present invention adds P element to IF steel, and through composition and process optimization control, obtains a P-containing hot-dip galvanized iron alloy high-strength IF steel with a yield strength of 180-320 MPa, a tensile strength of 340-440 MPa, an elongation of 35-46%, a value (average plastic strain ratio) ≥1.8, high surface quality, high formability, and good cold brittleness.

The high-steel-grade low-cost hot-rolled coil plate comprises the following chemical components: 0.040 to 0.065 percent of C, 0.20 to 0.35 percent of Si, 1.48 to 1.75 percent of Mn, less than or equal to 0.02 percent of P, less than or equal to 0.003 percent of S, 0.012 to 0.025 percent of Ti, 0.035 to 0.055 percent of Nb, 0.005 to 0.008 percent of RE, 0.15 to 0.20 percent of Cr, 0.0005 to 0.0020 percent of B, 0.002 to 0.004 percent of Mg, 0.025 to 0.050 percent of Als, less than or equal to 0.003 percent of Ca, less than or equal to 0.008 percent of N and the balance of Fe and inevitable impurities. The technological process comprises the steps of smelting, slab continuous casting, slab heating, rolling, cooling and coiling. Rt0.5 of the steel is 580-660 MPa, Rm is 650-750 MPa, A50 mm is larger than or equal to 28%, Rt0.5 / Rm is smaller than or equal to 0.90, the impact energy mean value Akv at the temperature of-40 DEG C is larger than or equal to 200 J, the drop weight DWTT mean value at the temperature of-20 DEG C is larger than or equal to 90%, the hardness value HV10 is smaller than or equal to 220, and the cold bending performance is qualified. The product provided by the invention has high strength and toughness and good welding performance, so that the product is more suitable for various complex and extreme service environments, and has higher safety in pipeline engineering.

The invention discloses an alloy for a 2230 MPa-grade high-corrosion-resistance steel strand, a wire rod, the steel strand and a method, and the alloy comprises the following components in percentage by mass: 0.89-0.93% of C, 1.20-1.40% of Si, 0.50-0.70% of Mn, 0.30-0.40% of Cr, 0.01-0.04% of V, less than or equal to 0.008% of S, less than or equal to 0.010% of P, less than or equal to 0.0040% of N, less than or equal to 0.0020% of O and the balance of Fe and other inevitable impurities. By optimizing the chemical component design and controlling the production process, the homogeneity of the steel is improved, the homogeneity of the wire rod is improved, the purity is improved, meanwhile, surface damage and internal defects during steel wire drawing machining are reduced, and therefore the stress corrosion index of the steel strand is improved.

The invention discloses 700Mpa-grade hot-rolled wheel steel and a preparation method thereof, and belongs to the technical field of metallurgy. The steel for the wheel comprises the following chemical components in percentage by mass: less than or equal to 0.1% of C, 0.05-0.10% of Si, less than or equal to 1.65% of Mn, less than 0.015% of P, less than 0.005% of S, less than 0.060% of Nb, less than 0.020% of Ti, less than 0.03% of Cr, less than 0.045% of A1s, less than 0.005% of N, less than 0.003% of O and the balance of iron and inevitable impurities. The production method comprises the procedures of molten iron pretreatment, converter smelting, LF refining, RH refining, slab continuous casting, heating, rolling, laminar cooling and coiling. Under the condition that expensive Mo element is not added, through reasonable component design and a controlled rolling and controlled cooling process, the yield strength of the wheel steel is larger than or equal to 500 MPa, the tensile strength is larger than or equal to 680 MPa, the ductility is larger than 18%, and the wheel steel has good welding performance and machining performance.

The invention relates to a P690QL2 steel plate with ultrahigh die welding and low-temperature performance and a manufacturing method of the P690QL2 steel plate. The P690QL2 steel plate comprises the following chemical components in percentage by weight: 0.04%-0.12% of C, 0.02%-0.08% of Si, 1.0%-1.2% of Mn, 1.5%-2.5% of Ni, 0.3%-0.7% of Cr, 0.7%-0.9% of Mo, 0.07%-0.12% of V, 0.02%-0.04% of Ti, less than or equal to 0.002% of S, less than or equal to 0.002% of P, 0.03%-0.06% of Als and the balance of Fe and inevitable impurity elements. The steel plate is applied to the liquid cargo tank of the LCO2 transport ship, has high strength and low-temperature toughness requirements, is easy to weld and has ultrahigh die welding performance, the V-type impact energy of the steel plate at-60 DEG C is larger than or equal to 150 J, the CTOD at-55 DEG C is larger than 0.2 mm, and the machining and welding use requirements of pressure-bearing equipment are met.

The invention relates to the technical field of HB450-grade thick-specification wear-resistant steel plates, in particular to a flame cutting delayed crack-free HB450-grade thick-specification wear-resistant steel plate and a production method thereof. The steel is composed of the following chemical components in percentage by weight: 0.18%-0.22% of C, 1.00%-1.10% of Si, 0.8%-1.0% of Mn, 0.015%-0.03% of Nb, 0.6%-0.70% of Cr, 0.06%-0.09% of Al, 0.0005%-0.0020% of B, more than or equal to 1.4% and less than or equal to 1.6% of Mn and Cr, and the balance of Fe and inevitable impurities. The production process flow comprises the steps of smelting, refining, slab continuous casting, casting blank heating and slow cooling, slab heating, controlled rolling, stacking and slow cooling, quenching and tempering heat treatment, flame cutting with temperature and slow cooling with hot water. The surface hardness is larger than or equal to HB450, the thickness ranges from 40 mm to 80 mm, the tensile strength is larger than or equal to 1250 MPa, the retained austenite content is 5%-7%, delayed cracks do not exist after fire cutting, the trimming hardness is larger than or equal to HB410, AKV at the temperature of-40 DEG C is larger than or equal to 40 J, and A is larger than or equal to 12%.

The invention discloses high-performance modified calcium carbonate and application thereof in a breathable film. The modified calcium carbonate is prepared by combining a three-element composite modification system composed of stearic acid, titanate and a silane coupling agent with a disc-nest mill three-stage gradient grinding process and antibacterial-hydrophobic dual-functionalization treatment of silver-loaded hydroxyapatite and a fluorinated modifier. The indexes of the prepared modified calcium carbonate are as follows: the median particle size (D50) is 1.8-2.2 mu m, the particle size (D97) of 97% particles is less than 6.5 mu m, the particles with the particle size of 1-5 mu m account for more than 60%, and the particles with the particle size of more than 10 mu m are less than 100 ppm; the content of calcium carbonate exceeds 97%, and the content of harmful impurities such as Fe is less than 200ppm; the whiteness is higher than 95; the oil absorption value is less than 12.5%, and the water content is less than 0.18%. When the composite material is applied to the breathable film in the medical field, the mechanical property, the antibacterial property and the hydrophobic property of the breathable film can be remarkably improved, the special requirements of the medical field on the breathable film are effectively met, and the composite material has good application prospects and industrial value.

The invention belongs to the technical field of magnetite beneficiation, and particularly relates to a method for removing iron impurities in minerals through manual and automatic three-stage combination in magnet beneficiation, a three-stage iron removal system is arranged, the iron impurities and ferromanganese are detected step by step according to the size of the iron impurities and the property of magnets or ferromanganese, and a detected magnetic field is cooperatively calibrated step by step; and iron impurities in the ores are removed in a classified manner. Compared with the prior art, the system has the beneficial effects that a manual and automatic three-stage combined iron removal solution is adopted, large magnetic iron impurities, small magnetic iron impurities and ferromanganese impurities in the process are efficiently classified and removed in a targeted manner, damage of the iron impurities to equipment such as an ore crusher and a belt conveyor is avoided, the operation efficiency of the process is improved, and the production cost is reduced. And the problem of removing iron impurities in magnet beneficiation is solved.

The invention relates to the technical field of impurity gas detection control, and discloses an impurity detection control method and system for high-purity oxygen, and the method comprises the steps: arranging a plurality of groups of TDLAS detection probes and temperature vibration monitoring units, and obtaining a spectrum harmonic signal and temperature and vibration data; the concentration is inverted through wavelength modulation spectrum demodulation and temperature and pressure disturbance compensation; pCA fusion denoising processing is executed through the edge calculation unit, and correction concentration is output; and abnormity is judged through a multi-scale dynamic threshold mechanism and linkage control is carried out. Compared with a common single-point probe or traditional low-pass filtering in the prior art, the technical problem that interference between impurity concentration change and environmental disturbance cannot be effectively handled especially in a high-vibration and high-temperature-difference environment is solved. According to the invention, through multi-channel cooperative weighting, PCA fusion compensation and a dynamic threshold determination mechanism, accurate detection control of the high-purity oxygen conveying pipeline in an industrial environment is realized, and the automation level of pipeline impurity gas detection control is improved.

The invention discloses a heat supply pipeline welding seam detection device, and relates to the technical field of heat supply pipeline processing, the heat supply pipeline welding seam detection device comprises a transmission mechanism 1 and a detection bin, the transmission mechanism 1 is provided with an inverted U-shaped support, the bottom wall of the horizontal section of the inverted U-shaped support is slidably connected with magnetization members in a front-back symmetrical manner, and the inverted U-shaped support is provided with a clamping member and a pretreatment mechanism; a detection bin is arranged on the left side of the first conveying mechanism, and a transferring mechanism, a marking mechanism and a second conveying mechanism are arranged on the detection bin. Through cooperation of the driving assembly and the brushing assembly, the outer wall of the to-be-detected pipe fitting is brushed, the situation that magnetic powder, oxide skin, burrs and the like adhere to the surface of the pipe fitting, the magnetic powder gathering phenomenon caused by non-defect factors is caused, and misjudgment occurs in the detection process is avoided, through cooperation of the driving assembly and the flushing assembly, the pipe fitting is flushed, and the detection efficiency is improved. The scraped impurities are prevented from being attached to the outer wall of the to-be-detected pipe fitting, and meanwhile, the pre-wetting treatment can be carried out, so that the fluorescent magnetic suspension is helped to cover the surface of the pipe fitting more uniformly.

The invention relates to the technical field of high-hardness thick-specification high-wear-resistance steel plates, in particular to a high-hardness 30-80mm thick-specification flame-cutting-delayed-crack-free high-wear-resistance steel plate and a production method thereof. New flame cutting delayed crack preventing components and process design are adopted, the chemical components of the steel plate are mainly characterized by medium carbon, high silicon and niobium microalloying, and the wear-resistant steel plate with low impurity content, uniform and fine martensite and a certain amount of retained austenite structures is obtained after refining, continuous casting, controlled rolling and heat treatment. And formation and expansion of delayed cracks during flame cutting can be inhibited. And during flame cutting, thermal stress and structural stress formed in the cutting process of the thick steel plate are reduced through the cutting process of cutting with temperature and slow cooling with hot water after cutting, and the effect of no delayed crack after cutting is achieved. The surface hardness is larger than or equal to HB500, the tensile strength is larger than or equal to 1350 MPa, AKV at-40 DEG C is larger than or equal to 30 J, A is larger than or equal to 10%, retained austenite is 4%-6%, delayed cracks do not exist after flame cutting, and the flame cutting edge hardness is larger than or equal to HB460.

The invention provides a sorbite steel wire for a high-strength aluminum-clad steel wire, the chemical composition of the steel wire comprises, by mass, 0.75%-0.82% of C, 0.25%-0.35% of Si, 0.50%-0.60% of Mn, 0.20%-0.35% of Cr, 0.25%-0.45% of Ni, 0.10%-0.20% of Cu, 0.0005%-0.010% of B, 0.0007%-0.010% of P, 0.005%-0.008% of S, 0%-0.1% of Nb, 0%-0.10% of V, 0%-0.10% of Ti, 0%-0.01% of rare earth components and the balance Fe and inevitable impurities, the sorbite percentage of the sorbite steel wire for the high-strength aluminum-clad steel wire is larger than or equal to 97%, the the strength of the steel wire can be improved on the premise of not reducing the plasticity and toughness of the steel wire.

The invention discloses a V-B-Ti microalloyed 690 MPa grade steel for engineering machinery, and belongs to the field of metal processing. The steel comprises the following chemical components in percentage by weight: 0.13%-0.17% of C, 0.15%-0.25% of Si, 1.55%-1.7% of Mn, less than or equal to 0.02% of P, less than or equal to 0.015% of S, 0.017%-0.0250% of Ti, 0.1%-0.2% of Cr, 0.015%-0.045% of Als, 0.05%-0.08% of V, 0.0015%-0.0020% of B, 0.005%-0.0095% of N, 3.4%-3.8% of Ti / N and the balance of Fe and inevitable impurities, the total amount of other impurity elements is less than 0.05%, and the problems of low steel plate toughness and plate shape unevenness are solved.

The invention relates to an air pre-impurity-removal control method and system for enrichment and separation of Kr, and relates to the technical field of gas separation and purification, and the air pre-impurity-removal control method comprises the following steps: removing impurity components in air through an impurity removal device to obtain air subjected to impurity removal treatment; carrying out multi-stage enrichment and separation treatment on the air subjected to impurity removal treatment to obtain enriched Kr gas; and introducing the enriched Kr gas into a chromatographic separation device, and separating krypton from other inert gases to obtain a target krypton component. The problems that in the traditional Kr enrichment and separation process, due to the fact that air impurities are prone to icing, the device is blocked, the multi-stage separation parameter adaptability is poor, and the enrichment efficiency is low are solved, and through pre-impurity removal of intelligent parameter configuration and multi-stage enrichment of gradient temperature control, the Kr separation stability, the enrichment efficiency and the target component purity are improved.

The invention relates to a preparation method of a silicon single crystal rod and a silicon wafer. Comprising a melting stage, a temperature adjusting stage, a welding stage, a seeding stage, a shouldering stage, an equal-diameter stage, an ending stage and a breaking stage which are carried out in sequence, in the equal-diameter stage, the pulling speed is controlled to be within a first pulling speed range, and the solid-liquid interface temperature gradient is controlled to be within a first gradient range; wherein the range of the first pulling speed ranges from 0.5 mm / min to 1.1 mm / min; the first gradient range is 3 DEG C / cm to 5 DEG C / cm. By reducing the temperature gradient of a solid-liquid interface and lowering the crystal pulling rate, the stability of a thermal field is enhanced, and sufficient conditions are provided for the composite reaction of Sii and V, so that the impurity capturing efficiency is improved, the internal purity of the crystal is improved, and the impurities are effectively removed.

The invention relates to a high-hardenability gear steel bar for a new energy automobile and a manufacturing method of the high-hardenability gear steel bar. The high-hardenability gear steel bar comprises the following chemical components in percentage by mass: 0.17-0.25% of C, less than or equal to 0.37% of Si, 0.50-0.90% of Mn, 0.85-1.25% of Cr, less than or equal to 0.025% of P, less than or equal to 0.030% of S, less than or equal to 0.30% of Cu, 0.02-0.06% of Ti, 0.02-0.05% of Al, less than or equal to 0.30% of Ni, 0.15-0.45% of Mo, 0.0005-0.0020% of B, 0.020-0.080% of Nb, less than or equal to 0.0030% of Ca, 0.0090-0.0150% of N, less than or equal to The production and manufacturing process comprises the steps of converter treatment, external refining, vacuum degassing, continuous casting, continuous rolling, shearing or saw cutting, stack cooling and finishing flaw detection. According to the invention, fine Nb (C, N) and (Nb, Ti) (C, N) particles are precipitated by microalloying Nb and Ti, the growth of crystal grains is effectively inhibited, and meanwhile, the hardenability of the material is improved by adding a proper amount of B element. According to the invention, Nb, Ti and B are adopted for composite microalloying at the same time, so that the fine-grain and high-hardenability gear steel material is obtained.

The invention discloses a method for step-by-step impurity removal in crude copper fire refining, and belongs to the technical field of metallurgical technologies. The method comprises the following steps: (1) removing As and Sb in an oxidation stage: heating and melting crude copper, blowing oxygen, and adding an impurity remover to remove As and Sb impurities in the crude copper; (2) removing Pb and Ni in an oxidation stage: after the impurity removal agent is added in the step (1) for reaction, adding a composite impurity removal agent, continuously blowing oxygen, stopping blowing oxygen until the oxygen content in the melt is 0.6-0.8% by mass, and slagging off to remove Pb and Ni impurities; and (3) deoxidation in a reduction stage: after slagging-off in the step (2), adjusting the temperature of the melt to a reduction temperature, adding high-sulfur pulverized coal in twice, and removing oxygen in the melt to complete impurity removal. According to the method, the impurity removal agent and the impurity removal process are optimized, and the impurity removal effect of the crude copper is remarkably improved through the synergistic effect.

The invention relates to the technical field of low-carbon microalloyed steel production, in particular to economical thin L450M pipeline steel and a method for controlling a banded structure, the steel comprises the following chemical components in percentage by weight: 0.07%-0.09% of C, 0.10%-0.25% of Si, 1.70%-1.80% of Mn, less than or equal to 0.020% of P, less than or equal to 0.015% of S, 0.01%-0.02% of Nb, 0.008%-0.015% of Ti, 0.015%-0.04% of Al, 0.05%-0.15% of Cr, 0.003%-0.006% of N and the balance of Fe and inevitable impurities, and the total amount of impurity elements is less than 0.05%; the steel plate produced by the invention has the advantages of low cost, high strength and toughness, low yield ratio and high straightness, and can ensure the service safety of the gas transmission pipeline.

The invention provides a method for measuring and calculating the article position of continuous silver ore with the particle size of 0.037 mm or above, and belongs to the technical field of mineral grade detection. The silver grade in the sample is measured and calculated through screening; leaching and measuring the content of silver monomers and continuous silver minerals, and reselecting to obtain a heavy sand product; carrying out fluorescent dyeing on the heavy sand product, and selecting monomer silver minerals; analyzing the color of the silver mineral through point scanning data of a scanning electron microscope, melting the monomer silver mineral to obtain the volume of the monomer silver mineral, and calculating the content of the monomer silver mineral; and carrying out conversion to obtain the continuous silver ore article position with the size of more than 0.037 mm. According to the method, the target mineral is rapidly and accurately obtained by adopting density medium reselection and fluorescent dye tracing; introducing a scanning electron microscope to measure and calculate the actual density of the silver mineral to replace the theoretical density, smelting the silver mineral in a mold, and carrying out volume measurement and calculation to obtain the actual metal amount closer to the actual silver mineral; measuring and calculating errors caused by impurities and irregular shapes of mineral particles are reduced; and the calculated grade of the silver mineral is more accurate.

The invention relates to the technical field of high-strength steel production, in particular to 780MPa-grade forming-enhanced cold-rolled dual-phase steel and a preparation method thereof.The 780MPa-grade forming-enhanced cold-rolled dual-phase steel comprises the chemical components of 0.09%-0.11% of C, 0.25%-0.45% of Si, 1.9%-2.1% of Mn, smaller than or equal to 0.012% of P, smaller than or equal to 0.006% of S, 0.03%-0.05% of Als, smaller than or equal to 0.005% of N, 0.25%-0.35% of Cr, 0.015%-0.025% of Nb, 0.08%-0.12% of Cu and 0.05%-0.09% of Ni, and the ratio of Nb to Cr is 1: 10-1: 12; ceq is equal to 0.38%-0.42%, and the balance is Fe and impurities; the core objective of the invention is to enable the work hardening index n value to be greater than or equal to 0.24 through component collaborative optimization and process precise regulation and control, so that the industrial pain points of insufficient reaming performance and poor formability of the existing 780MPa-grade cold-rolled dual-phase steel are fundamentally solved, and meanwhile, the alloy cost is reduced, and the manufacturability is improved.

The invention discloses a wafer etching auxiliary device, and relates to the technical field of semiconductor processing, the wafer etching auxiliary device comprises an operation table, two liquid outlet pipes, two nozzles and a clamping assembly, the periphery of each liquid outlet pipe is provided with a liquid discharge groove, each nozzle is provided with a main hole and a plurality of side holes which are communicated with the liquid outlet pipe, and an auxiliary hole which can be communicated with the liquid discharge groove, when the clamping assembly clamps the edge of the wafer, the main hole and the side hole wash the surface of the wafer, the main hole is closed, the side hole washes the surface of the wafer, and after the side hole is closed, residual impurities at the original clamping position are removed; according to the wafer cleaning device, the wafer is alternately clamped through the nozzle and the clamping piece, so that impurity particles on the periphery of the wafer can be thoroughly removed, meanwhile, the wafer can still be washed after being clamped through the nozzle, and when the particles cannot be thrown out by centrifugal force, the effect of thoroughly cleaning the periphery of the wafer is achieved through combination of pushing force of liquid and the centrifugal force.

The invention belongs to the technical field of chemical analysis of metallurgical standard samples, and discloses a super duplex stainless steel spectrum standard sample with high quality, high uniformity, high stability and accurate fixed value and a development method thereof. The method comprises the following steps: component design and raw material proportioning, smelting and casting, forging and homogenization treatment, primary inspection of uniformity and sample processing, uniformity inspection, constant value analysis and mathematical statistics, determination of characteristic values of standard samples, stability analysis of the standard samples after long-term storage, and traceability guarantee measures. The super duplex stainless steel spectrum standard sample comprises the following components in percentage by mass: 25%-26% of Cr, 6.50%-7.50% of Ni, 3.50%-4.50% of Mo, 0.23%-0.27% of N, 0.5%-1.0% of Cu, 0.5%-1.0% of W, and the balance of iron and inevitable impurities, and the content of trace elements including sulfur, aluminum and boron is controlled in a specific ppm level range.

The invention discloses medium-entropy MAB-phase ceramic powder and a preparation method thereof, and belongs to the technical field of ceramic material preparation. The chemical formula of the ceramic powder is (Cr1 / 3Mn1 / 3Fe1 / 3) 2AlB2, and the ceramic powder is structurally characterized in that three transition metal atoms of Cr, Mn and Fe are in random solid solution distribution at an M position. The preparation method of the material comprises the following steps: taking Cr powder, Mn powder, Fe powder, Al powder and B powder as raw materials, burdening according to a stoichiometric molar ratio in a chemical formula (Cr1 / 3Mn1 / 3Fe1 / 3) 2AlxB2 (wherein x is equal to 1.0-1.3), uniformly mixing, and sintering in a non-pressure tube furnace by adopting a two-stage heating sintering process. And crushing, drying and sieving the sintered product to obtain the ceramic powder. According to the invention, excessive aluminum powder is added to compensate high-temperature volatilization, and a two-stage sintering process is combined, so that the generation of an impurity phase is effectively inhibited, and a high-purity target product is successfully prepared. The synthesis method is simple in process, low in equipment requirement and suitable for large-scale production, and a material basis is provided for application of the medium-entropy MAB phase ceramic in the fields of electromagnetic functions, high-temperature environments and the like.

The invention relates to the technical field of metallurgy, in particular to a hot galvanizing low-alloy high-strength steel plate which comprises the following chemical components in percentage by mass: 0.06%-0.08% of C, 0.20%-0.25% of Si, 1.20%-1.35% of Mn, less than or equal to 0.015% of P, less than or equal to 0.005% of S, 0.020%-0.060% of Alt, 0.035%-0.050% of Nb, 0.010%-0.020% of Ti, less than or equal to 0.0050% of O, less than or equal to 0.0060% of N and the balance of Fe and inevitable impurities. The contents of C, Si and Mn in the chemical components are controlled, the welding performance of the hot-dip galvanizing low-alloy high-strength steel and the surface quality of a finished product are considered, Nb microalloying is mainly adopted, a proper amount of microalloy element Ti is added to form TiN, austenite grain coarsening is limited in the slab heating and heat preservation process, and fine and dispersed precipitated phases are finally obtained in combination with process control; the hot-dip galvanized low-alloy high-strength steel finished product is good in structure form and excellent in comprehensive performance.

The invention belongs to the field of thin films, and particularly discloses an atomic layer deposition method and a thin film prepared through the atomic layer deposition method. According to the deposition method, the reaction cavity, the two input pipeline systems, the outlet valve and the vacuum pump in the atomic layer deposition system are used for controlling precursor pulse deposition and inert gas purging conditions in the atomic deposition process, and the film deposition state is improved; the efficiency of purging and removing substances and impurity residues such as a precursor and a reaction product thereof is improved, the problem that the quality of a deposited film is affected by the impurity residues in a reaction system or on the surface of a sample in the film deposition process is avoided, the uniformity and compactness of film deposition and the coverage rate and conformal rate of a film on the surface of a base material hole are improved, the defects of the film are reduced, and the yield is improved. And the method can be applied to a substrate with a high aspect ratio structure to deposit the film, so that the purpose of manufacturing a large-size complicated special-shaped structure device is achieved.

The invention relates to a high-performance non-quenched and tempered steel bar for a fan shaft and a manufacturing method of the high-performance non-quenched and tempered steel bar, and belongs to the field of iron-based alloys. The steel comprises the following chemical components in percentage by weight: 0.37 to 0.43 percent of C, 0.30 to 0.60 percent of Si, 1.20 to 1.70 percent of Mn, less than or equal to 0.025 percent of P, 0.030 to 0.070 percent of S, less than or equal to 0.50 percent of Cr, 0.10 to 0.30 percent of Ni, less than or equal to 0.30 percent of Mo, less than or equal to 0.30 percent of Cu, 0.010 to 0.030 percent of Al, 0.005 to 0.025 percent of Ti, 0.05 to 0.15 percent of V, 0.0100 to 0.0200 percent of N, less than or equal to 0.0002 percent of H, less than or equal to 0.0015 percent of O and the balance of Fe and inevitable impurity elements. The manufacturing process comprises the steps of converter / electric furnace smelting, LF furnace refining, RH / VD furnace vacuum degassing, continuous casting, casting blank reheating, cogging rolling, flame cleaning, intermediate blank finishing, intermediate blank heating, bar rolling, cooling and stress relief tempering. The total cross-section structure of the bar is a ferrite and pearlite structure. The bending degree per meter is smaller than or equal to 0.5 mm, the surface defect depth is smaller than or equal to 0.10 mm, and the internal quality meets the A-level requirement of the GB / T4162 standard.

Disclosed is a specific Ni-base superalloy, preferably in powder form, comprising at least 7.00 to 24.00 wt.-% Cr, 5.00 to 20.00 wt.-% Co, 0.00 to 5.00 wt.-% Fe, 0.00 to 10.00 wt.-% W, 0.00 to 3.00 wt.-% Nb, 0.00 to 10.00 wt.-% Mo, 0.00 to 6.00 wt.-% Ti, 0.50 to 6.00 wt.-% Al, 0.00 to 9.00 wt.-% Ta, 0.00 to 0.20 wt.-% C, 0.00 to 0.20 wt.-% Zr, 0.00 to 2.00 wt.-% Hf, 0.00 to 0.50 Si wt.-% and 0.00 to 0.20 wt.-% B, wherein the balance is Ni and unavoidable impurities. Further disclosed are processes for the manufacture of such Ni-base superalloy powders, processes and devices for the manufacture of three-dimensional objects, three-dimensional objects prepared by such processes and devices and the use of such a Ni-base superalloy in powder form for minimizing and / or suppressing microcrack formation in a three-dimensional object and / or for providing improved ductility and rupture life in creep conditions.