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134results about How to "Narrow bandgap" patented technology

Nano-crystal fluorescent powder and preparation method thereof

ActiveCN102433124ALow toxicityLuminous wavelength adjustableLuminescent compositionsRare-earth elementIndium
The invention relates to nano-crystal fluorescent powder and a preparation method thereof. The invention belongs to the technical field of luminescent materials. The nano-crystal fluorescent powder is Cu-In-Znx-E/ZnS, wherein E=S or Se, and x is no smaller than 0. The preparation method comprises steps that: copper salt, indium salt, alkanethiol and octadecene are isolated from oxygen, mixed, andheated; long-chain alkyl organic acid is added to the product, the mixture is isolated from oxygen and is heated, such that a reaction source is obtained; zinc salt, long-chain alkyl organic amine and octadecene are isolated from oxygen, mixed, and heated, such that a zinc source is obtained; when E=S, the zinc source is added to the reaction source, and the mixture is heated, such that a colloidal solution 1 is obtained; when E=Se, selenium powder is dissolved, and an obtained selenium source is added to the reaction source; the mixture is heated, such that a colloidal solution 2 is obtained; the zinc source is added to the colloidal solution 2, and the mixture is heated, such that a colloidal solution 3 is obtained; the colloidal solution 1 or 3 is washed, and is subject to vacuum drying, such that the nano-crystal fluorescent powder is obtained. According to the invention, the nano-crystal fluorescent powder contains no rare earth element; the luminescence wavelength is adjustable;the nano-crystal fluorescent powder can be uniformly dispersed in an organic solvent; and the application range of the nano-crystal fluorescent powder is wide. The preparation method is advantaged inhigh yield, low cost, environment-friendliness, easy operation, and suitability for large-scaled productions.
Owner:ZHIJING NANOTECH CO LTD

Flexible molybdenum disulfide phototransistor and preparation method thereof

The invention discloses a flexible molybdenum disulfide phototransistor and a preparation method thereof, and mainly solves the problem that an existing flexible transistor is high in fabrication technique difficulty and poor in performance. The phototransistor structurally comprises a grid electrode (1), a dielectric layer (2) and a semiconductor layer (3) from bottom to top, a source electrode (4) and a drain electrode (5) are arranged at two ends of the semiconductor layer (3) and connected with the dielectric layer (2), flexible transparent materials such as PEN (polyethylene naphthalate)of an ITO (indium tin oxide) transparent electrode layer are evaporated on the surface of the grid electrode (1), and 5%-15% potassium hydroxide water solution is doped in the semiconductor layer (3).A device is transferred to a PEN substrate from a silicon substrate by the aid of a substrate transfer technology, molybdenum disulfide materials are doped in the substrate transfer process to reducethe contact resistance of the materials, fabrication technique is simplified, cost is reduced, the performance and the flexibility of the device are improved, and the phototransistor can be used forelectronic, communication and medical equipment.
Owner:XIDIAN UNIV

Thienyl polymer-containing polymer photocatalyst with high photocatalytic water splitting hydrogen production activity and preparation method thereof

The invention discloses a thienyl polymer-containing photocatalyst with high photocatalytic water splitting hydrogen production activity and a preparation method thereof. The photocatalyst is prepared by adopting a simple ternary copolymerization Suzuki coupling reaction, and the construction unit of the photocatalyst comprises pyrene, thiophene or thiophene derivative and dibenzothiophene sulfone. The pyrenyl monomer and the dibenzothiophene sulfuryl monomer for polymerization have the same polymerizable functional groups and can be subjected to Suzuki coupling reaction with thiophene or thiophene derivative monomers at the same time so as to ensure that pyrenyl units and dibenzothiophene sulfuryl units in the polymer structure are connected through thiophene or thiophene derivative units. The polymer photocatalyst has the characteristics of high photocatalytic hydrogen production activity, high apparent quantum efficiency, narrow optical band gap and continuous and adjustable structure and composition, is simple in preparation process, high in yield and stable in performance, can release hydrogen under sunlight, and can be used in the field of photocatalytic hydrogen production.
Owner:SHAANXI NORMAL UNIV

ZnO/Ag2O photocatalysis composite material, as well as preparation method and application thereof

The invention discloses a ZnO / Ag2O photocatalysis composite material, as well as a preparation method and application thereof. The ZnO / Ag2O photocatalysis composite material, as well as the preparation method and the application thereof have the following technical effects that 1, the ZnO / Ag2O photocatalysis composite material is prepared by one step by adopting a solid phase grinding method, andthe preparation method has the remarkable advantages of simplicity in operation, low energy consumption, high efficiency, high yield, green and environmental protection, and recyclability of substratesodium nitrate, and is suitable for mass production; 2, a p-n node formed between zinc oxide and silver oxide is beneficial to interface electron transfer, the recombination of a photo-induced electron hole pair is reduced, and the catalytic performance is remarkably improved compared with a single semiconductor catalyst; on the other hand, the silver oxide is provided with narrower band gaps compared with the silver oxide, so that silver oxide nanoparticles can be used as an effective photosensitizer under the irradiation of sunlight, so that the visible light catalysis performance of the zinc oxide is improved; 3, the ZnO / Ag2O photocatalysis composite material can be used for degrading organic dye wastewater containing methylene blue, methyl orange and rhodamine B, and can be used for degrading 80 percent or more of target degradation products within 20 minutes at the soonest, so that the degradation rate can be improved by 13 times compared with single zinc oxide, and the excellentphotocatalytic activity is realized.
Owner:XIANGTAN UNIV

3D chrysanthemum-like Z type Bi2S3@CoO heterojunction composite catalyst as well as preparation method and application thereof

The invention relates to a 3D chrysanthemum-like Z type Bi2S3@CoO heterojunction composite catalyst as well as a preparation method and application thereof. The preparation method of the 3D chrysanthemum-like Z type Bi2S3@CoO heterojunction composite catalyst comprises the following steps: adding CoO and Bi(NO3)3 into redistilled water, continuously stirring, dropwise adding a Na2S aqueous solution, stirring and reacting, then centrifuging and taking a solid product, repeatedly washing the solid product with redistilled water until the solid product is neutral, drying the solid product, then putting the product into a tubular furnace, and calcining for 2 hours under 250 DEG C to obtain a target product. The degradation rate on tetracycline of Bi2S3@CoO can reach up to 90%, and the degradation rate on aureomycin of Bi2S3@CoO can reach over 70%; the preparation method is simple, convenient and efficient and is low in cost; the prepared composite material has the characteristics of narrowband gap, large specific surface area and high catalytic activity, is excellent in visible light absorption performance, excellent in stability, high in photoelectric efficiency and excellent in photoelectrocatalysis degradation effect on organic matters, and can be applied to the fields of photoelectrocatalysis degradation organic matters and sensors.
Owner:LIAONING UNIVERSITY

Novel graphite phase carbon nitride polymer material, preparation method and applications thereof

The invention discloses a novel graphite phase carbon nitride polymer material, a preparation method and applications thereof, and belongs to the technical field of functional materials, wherein the carbon nitride material has a layered structure, has good crystallinity, and has a chemical formula of g-C3N3, and the polymer material can be peeled into a single-layer or few-layer two-dimensional material through a chemical or mechanical method. The preparation method of the graphite phase carbon nitride polymer comprises: under inert gas protection or air, using an appropriate amount of a monomer as a reactant, cutting to obtain a metal sheet with an appropriate size, ultrasonically cleaning with water and an organic solvent, drying, adding to a reactor, properly placing the metal sheet, heating to a temperature of 180-300 DEG C, maintaining for not more than 48 h, and cooling, wherein the sheet-like material loaded on the surface of the metal sheet is the CN polymer. According to the present invention, the preparation method has advantages of simple steps, high yield and cheap raw materials; and the obtained material can be used for a variety of purposes such as electrocatalytic hydrogen evolution, photocatalytic hydrogen evolution, water production and oxygen production through photolysis of water, decomposition of pollutants, and the like.
Owner:HUBEI UNIV
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