Method for preparing antibacterial and wear-resistant stainless steel permeation layer

A technology of stainless steel and permeation plating, applied in coating, sputtering plating, ion implantation plating, etc., can solve the problems of unqualified stainless steel workpieces, uncontrollable process, peeling, etc., achieve good bonding strength, improve uniformity, The effect of response enhancement

Inactive Publication Date: 2011-01-26
王鹤峰
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

The former can transform the existing stainless steel products, that is, to coat the stainless steel with bactericidal metal materials or other inorganic materials with bactericidal effects, but the disadvantage is that it is easy to wear, aging, peeling off, and changes with temperature difference and external environment. The stainless steel loses its antibacterial properties; the latter is to add some antibacterial metal elements (usually silver, copper, etc.) The addition of low melting point silver and copper alloy elements can easily lead to the deterioration of the overall mechanical properties of stainless steel
[0003] At present, the use of double-layer glow ion infiltration metallization technology has been used to infiltrate nitrogen-doped TiO on the surface of metal substrates. 2 The film method, such as the Chinese patent CN200810055484.4, but this technology first generates a Ti film in a double-layer glow ion metallization furnace, and then reacts with nitrogen and oxygen in the air by heating to generate nitrogen-doped TiO 2 film, the disadvantage of this approach is that the resulting nitrogen-doped TiO 2 The distribution on the metal substrate is uneven, and the reaction process of nitrogen and oxygen with the titanium film is uncontrollable, and unqualified nitrogen-doped TiO is prone to occur. 2 Membrane stainless steel workpiece

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] Embodiment 1: a kind of preparation method of antibacterial wear-resisting stainless steel percolation coating, prepares according to following steps;

[0018] Step 1: Put the metallographic structure of the austenitic stainless steel substrate workpiece into the double-layer glow ionization metallization furnace, use the pure titanium plate as the sputtering target, the working gas is argon, the reaction gas is nitrogen, and perform the infiltration , the distance between the stainless steel substrate workpiece and the sputtering target is 15cm, the air pressure is 35Pa, argon gas and nitrogen gas are passed into the double-layer glow ion infiltration metal furnace according to the flow ratio of 1:1, the sputtering target voltage is 1000V, and the stainless steel substrate workpiece voltage is 550V , the temperature of the stainless steel substrate workpiece is 950°C, and the infiltration time is 3 hours, and a titanium nitride infiltration layer is formed on the surfac...

Embodiment 2

[0020] Embodiment 2: a kind of preparation method of antibacterial wear-resisting stainless steel percolation coating, prepares according to following steps;

[0021] Step 1: Put the metallographic structure of the austenitic stainless steel substrate workpiece into the double-layer glow ionization metallization furnace, use the pure titanium plate as the sputtering target, the working gas is argon, the reaction gas is nitrogen, and perform the infiltration , the distance between the stainless steel substrate workpiece and the sputtering target is 16cm, the air pressure is 40Pa, argon gas and nitrogen gas are passed into the double-layer glow ion infiltration metal furnace according to the flow ratio of 1:1, the sputtering target voltage is 1100V, and the stainless steel substrate workpiece voltage is 600V , the temperature of the stainless steel base workpiece is 1000°C, and the plating time is 2 hours, and a titanium nitride plating layer is formed on the surface of the stain...

Embodiment 3

[0023] Embodiment 3: a kind of preparation method of antibacterial wear-resisting stainless steel percolation coating, prepares according to following steps;

[0024] Step 1: Put the metallographic structure of the austenitic stainless steel substrate workpiece into the double-layer glow ion metallization furnace, use the pure titanium plate as the sputtering target, the working gas is argon, and the reaction gas is a mixture of nitrogen and methane When the gas is used, the distance between the stainless steel base workpiece and the sputtering target is 16cm, the air pressure is 40Pa, argon, nitrogen, and methane are fed into the double-layer glow ion metal infiltration furnace according to the flow ratio of 1:1:2, and the sputtering target voltage is 1100V , The voltage of the stainless steel base workpiece is 600V, the temperature of the stainless steel base workpiece is 1000°C, and the permeation time is 2h, and a titanium carbonitride coating layer is formed on the stainle...

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Abstract

The invention provides a method for preparing an antibacterial and wear-resistant stainless steel permeation layer, belongs to the technical field of stainless steel surface protective coatings, and provides a method for diffusion coating of a uniformly distributed antibacterial and wear-resistant stainless steel permeation layer on a stainless steel matrix workpiece. The reaction process is controllable. The technical scheme comprises the following steps of: 1, putting the stainless steel matrix workpiece into a double-layer metallic glow ion cementation furnace, taking a pure titanium plate as a sputtering target, argon as working gas, and nitrogen or mixed gas of nitrogen and methane as reaction gas for diffusion coating; and 2, putting the stainless steel matrix workpiece subjected to diffusion coating into a vacuumized muffle furnace, introducing oxygen to react with the permeation layer of the stainless steel matrix workpiece, controlling the heating temperature range to be between 400 and 600 DEG C, keeping the temperature for 1.5 to 2 hours, and cooling to room temperature. The method is applied to the technical field of stainless steel surface diffusion coating.

Description

technical field [0001] The invention provides a method for preparing an antibacterial and wear-resistant stainless steel permeable coating, which belongs to the technical field of stainless steel surface protective coatings. Background technique [0002] Antibacterial stainless steel is divided into two types according to the antibacterial production method: coating type and self-antibacterial type. The former can transform the existing stainless steel products, that is, to coat the stainless steel with bactericidal metal materials or other inorganic materials with bactericidal effects, but the disadvantage is that it is easy to wear, aging, peeling off, and changes with temperature difference and external environment. The stainless steel loses its antibacterial properties; the latter is to add some antibacterial metal elements (usually silver, copper, etc.) The addition of low melting point silver and copper alloying elements can easily lead to the deterioration of the ove...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23C14/34C23C14/06C23C14/58
Inventor 王鹤峰李秀燕唐宾
Owner 王鹤峰
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