This invention discloses a crystalline
polyimide /
polyimide composite material, its preparation method, and its applications. The method involves first uniformly mixing phenylhexacarboxylic acid trihydride with a
diamine monomer, followed by a
solid-
phase reaction under
argon atmosphere protection. After the reaction, the product is immersed in a polar
solvent to obtain crystalline
polyimide. Then, the crystalline polyimide is added to an organic solution of
polyamic acid, subjected to ultrasonic treatment in an ice-water bath, and subsequently thermosetting to obtain the crystalline polyimide / polyimide
composite material. The crystalline polyimide in this
composite material has a layered two-dimensional COF structure, giving it relatively high
thermal conductivity,
heat resistance, and high-temperature mechanical properties. Introducing the crystalline polyimide into the
polyamic acid solution utilizes the special interfacial compatibility between the amino groups in the crystalline polyimide and the anhydrides in the
polyamic acid to react, solving the problem of difficult
processing and effectively expanding its application range.