1259 results about "Solvothermal reaction" patented technology

The invention belongs to the field of photocatalytic materials, and particularly relates to a high-entropy sulfide and a preparation method and application thereof. The high-entropy sulfide is granular, the molecular general formula is (MnaFebCocCudZe) xS, x is equal to 1, and the atomic ratio of Mn to Fe to Co to Cu to Zn is a: b: c: d: e of (1-2): (1-2): (1-2): (1-2): (1-2): (1-2): (1-2). The preparation method comprises the following steps: S1, dissolving metal salt in a mixed solvent of isopropanol and glycerol according to the atomic ratio of metal elements, and carrying out solvothermal reaction to obtain a precursor; and S2, dispersing the precursor in ethanol, adding thioacetamide as a sulfur source, and carrying out solvothermal reaction to obtain the high-entropy sulfide. The high-entropy sulfide disclosed by the invention is used as a photocatalytic material and shows excellent photocatalytic performance.

The invention belongs to the technical field of adsorbent preparation, and relates to a preparation method of a series of M-TCBB metal organic framework materials and application of the M-TCBB metal organic framework materials to adsorption of sulfur dioxide and ammonia gas. The preparation method comprises the following steps: dispersing [9, 9 '-dicarbazole]-3, 3', 6, 6 '-tetracarboxylic acid (H4TCBB) serving as an organic ligand and any one or more of yttrium salt, zirconium salt, hafnium salt, cerium salt and thorium salt in a solution according to a certain mass ratio, and carrying out solvothermal reaction at 100-120 DEG C; and after the reaction is finished, centrifuging to take a precipitate, washing and drying to obtain a series of M-TCBB metal organic framework materials. The series of M-TCBB metal organic framework materials prepared by the invention have relatively good adsorption acting force on sulfur dioxide and ammonia gas, and are high in adsorption cycle stability; under a humid condition, capture of sulfur dioxide and ammonia gas shows a humidity enhancement characteristic, namely, water vapor promotes enhancement of the adsorption capacity of sulfur dioxide and ammonia gas.

The invention belongs to the technical field of organic electro-oxidation electrode materials, and particularly relates to a fullerene modified transition metal hydroxide nano array material as well as a preparation method and application thereof. A transition metal hydroxide nano array grows in situ on a current collector through solvothermal reaction, surface amino modification is achieved by means of grafting of a silane coupling agent with amino, and finally the transition metal hydroxide nano array material with the surface modified by fullerene is obtained through addition reaction of amino and fullerene carbon-carbon double bonds. The strong electron-withdrawing capability of the fullerene is beneficial to optimizing the surface electron structure of the material, so that the intrinsic catalytic activity is improved; meanwhile, fullerene can promote adsorption and enrichment of an organic substrate on the surface of the material through a conjugated pi bond, a hydrophobic effect and the like, so that the mass transfer efficiency is improved. Benefited from the lifting mechanism, the obtained nano array material has the advantages of high electrocatalytic activity and high mass transfer efficiency, and can be widely applied to a series of organic electrooxidation reactions.

The invention discloses preparation of a high-uniformity cerium oxide abrasive material and application of the high-uniformity cerium oxide abrasive material in a chemical mechanical polishing solution. According to a method, cerium nitrate or cerium oxalate is used as a cerium source, a cationic or nonionic surfactant is used as a structure-directing agent, and the high-uniformity cerium oxide abrasive material is prepared in a mixed solvent system formed by water and isopropanol or water and diethylene glycol according to a specific volume ratio. The preparation method comprises the following steps: regulating the particle size and the morphology structure through a solvothermal reaction, carrying out cleaning, drying and high-temperature calcination treatment on a reaction product to obtain sphere-like cerium oxide nano-particles with high particle size concentration ratio, moderate surface roughness and good dispersity, adding cerium oxide powder into deionized water, and carrying out ultrasonic dispersion to obtain the spherical cerium oxide nano-particles. And sequentially adding a dispersing agent and amino acid while stirring, uniformly stirring, fixing the volume, and adding a pH regulator to enable the solution to be weakly acidic, thereby obtaining the chemical mechanical polishing solution. The cerium oxide submicron powder which is different in surface appearance, particle size and distribution uniformity is prepared by adjusting the solvent ratio and other reaction conditions.

The invention belongs to the technical field of photocatalysis, and particularly discloses a diatomic metal complex / CdS nanorod composite photocatalyst as well as a preparation method and application thereof. The specific preparation method comprises the following steps: synthesizing a pure CdS nanorod by using an EDA assisted solvothermal reaction; then carrying out Schiff base reaction, heating in an oil bath, and condensing and refluxing to synthesize a diatomic metal complex; and putting the diatomic metal complex and the CdS nanorod into a beaker, adding ethanol, uniformly stirring and drying to obtain the diatomic metal complex and CdS nanorod photocatalytic composite material, namely the target product. The CdS nanorod is of a rod-shaped hexagonal crystal structure, the diatomic metal complex is blocky and is loaded on the wall of the CdS nanorod after being compounded with the CdS nanorod, and the main morphology of the CdS nanorod is not changed. According to the invention, the diatomic metal complex is compounded with the CdS nanorod, so that photo-induced electrons and holes can be effectively separated, and the activity of photocatalytic formic acid decomposition to prepare synthesis gas (H2 + CO) is improved.

The invention discloses a macrocyclic covalent organic polymer material for inhibiting a pi-pi stacking effect and application of the macrocyclic covalent organic polymer material, and belongs to the technical field of biological medicines. The preparation method comprises the following steps: adding 5, 10, 15, 20-tetra (4-ethynylphenyl) copper porphyrin and a macrocyclic monomer into an organic solvent in a protective atmosphere, and carrying out solvothermal reaction in the presence of a catalyst and alkali to obtain the macrocyclic covalent organic polymer material. According to the invention, 5, 10, 15, 20-tetra (4-ethynylphenyl) copper porphyrin and a macrocyclic monomer form a porous polymer MCP-CU-POP, the material utilizes the photo-thermal capability to combine the effects of simulated photo-thermal (PTT), photodynamic (PDT), peroxidase (PODs) and glutathione peroxidase (GSH-Px) to perform synergistic antibiosis, and the inherent characteristics of an infected microenvironment can also be utilized to induce death of bacteria, so that the antibacterial property of the material is greatly improved, and the antibacterial property of the material is greatly improved. And the microenvironment of the bacterial infection part can be adjusted, so that the recovery of the bacterial infection wound can be obviously accelerated.

The invention provides an amphiphilic carbon dot, a carbon nanofluid and application of the amphiphilic carbon dot and the carbon nanofluid, and belongs to the technical field of nanomaterial oil displacement, and the amphiphilic carbon dot is prepared by taking alkylphenol polyoxyethylene ether and glucose as raw materials to perform solvothermal reaction; the alkylphenol polyoxyethylene ether comprises octylphenol polyoxyethylene ether and / or nonylphenol polyoxyethylene ether; the mass ratio of the alkylphenol polyoxyethylene ether to the glucose is 1: (0.1-2). According to the invention, alkylphenol polyoxyethylene ether and glucose are taken as raw materials, and simple preparation of the amphiphilic carbon dots with high surface and interface activity is realized. The amphiphilic carbon dots provided by the invention show good surface and interface activity at high temperature and high salinity. According to the carbon nanofluid provided by the invention, the amphiphilic carbon dots and the zwitterionic surfactant are compounded, so that the stability of a carbon nanofluid oil displacement system at high temperature and high salt can be further improved, the crude oil recovery rate is increased, and efficient yield-increasing development of high-temperature and high-salt deep oil reservoirs is realized.

The invention provides a thioether oxidation catalyst, a preparation method thereof and a preparation method of pyroxasulfone. The preparation method comprises the following steps: S1, preparing a selenium source and a first solvent into a first solution; s2, adding a Lewis acid source into the first solution, and performing first mixing to obtain a second solution; s3, adding an organic alkali ligand source into the second solution, and performing second mixing to obtain a third solution; and S4, carrying out solvothermal reaction on the third solution at 100-150 DEG C to obtain the thioether oxidation catalyst. A selenium source, a Lewis acid source and an organic alkali ligand source are subjected to a combined reaction according to a specific sequence and conditions, and finally the inorganic-organic hybrid selenite catalyst with a special structure is formed under a solvothermal condition. The obtained catalyst is high in active atom utilization rate and strong in reactant molecule adsorbability, is beneficial to deep oxidation of reactants, accelerates oxidation of thioether into sulfone, and improves reaction selectivity and production efficiency.

The invention relates to an alkynyl-modified acyl covalent organic framework (COF) material and application thereof, and relates to the field of preparation of crystalline porous materials and fuel cells. The material is a covalent organic framework material which is synthesized by taking 1, 3, 5-triformyl phloroglucinol and 2, 5-bis (2-propynyloxy) terephthaloyl hydrazine as raw materials through solvothermal reaction under specific conditions, and has relatively high crystallinity. The material has good performance in the aspect of proton conductivity, the highest proton conductivity can reach 6.16163 * 10 <-4 > S / cm, and the mechanical property is enhanced due to introduction of alkynyl. Alkynyl is used as an active functional group, and various chemical reactions can be derived, so that the potential application value of the material is greatly improved.

The invention discloses an inorganic-organic hybrid compound crystal and a preparation method thereof, and belongs to the technical field of organic-inorganic hybrid materials. The preparation method comprises the following steps: mixing raw materials containing hydroiodic acid, organic cage molecules RCC3 and a lead source with a solvent, and carrying out solvothermal reaction to obtain the inorganic-organic hybrid compound crystal. The chemical formula of the prepared inorganic-organic hybrid compound crystal is ({H18 [C72H108N12] 2 [(Pb10I36)]}. 2I), wherein [C72H108N12] is RCC3 acidified by hydroiodic acid, the crystal has a supramolecular three-dimensional structure assembled by a [Pb5I8] 3-anion cluster unit and a protonated RCC3 molecular cage through electrostatic and hydrogen-bond interaction, and belongs to a monoclinic system, and the space group is P21. The crystal structure is a metal halide-based organic-inorganic hybrid crystal constructed by taking an organic molecular cage as nitrogen-containing cations and lead iodide for the first time.

The invention discloses a bimetal MOFs-loaded electrostatic spinning fiber membrane for oil-water separation and a preparation method thereof, and belongs to the technical field of membrane separation, and the preparation method comprises the following steps: (1) preparing a hydroxyl-modified metal organic framework material MIL-53 (Al)-OH through a solvothermal reaction; (2) preparing an MIL-53 (Fe) precursor solution by using ferric salt, terephthalic acid, polyvinylpyrrolidone and an organic solvent, ultrasonically dispersing MIL-53 (Al)-OH in the MIL-53 (Fe) precursor solution, uniformly mixing, and soaking the electrostatic spinning fiber membrane in the MIL-53 (Fe) precursor solution for 1-3 hours; and (3) transferring the system in the step (2) into a reaction kettle, reacting at 130-150 DEG C for 10-15 hours to enable the bimetallic MOFs to grow on the surface of the electrostatic spinning fiber membrane, washing, and drying to obtain the bimetallic MOFs-loaded electrostatic spinning fiber membrane for oil-water separation. The bimetal MOFs-loaded electrostatic spinning fiber membrane has the advantages of good oil-water separation performance, strong antifouling ability and strong dye degradation ability.

The invention discloses a self-supporting Co / CoO / Co3O4 catalytic electrode rich in oxygen vacancy as well as preparation and application of the self-supporting Co / CoO / Co3O4 catalytic electrode. The preparation method of the catalytic electrode comprises the following steps: step 1, dissolving Co (NO3) 3.6 H2O and dimethylimidazole in ethanol, uniformly mixing, adding a foamy copper substrate, putting into a drying oven, carrying out solvothermal reaction to generate a Co-ZIF precursor, and drying after the reaction is finished to obtain foamy copper containing the Co-ZIF precursor; and 2, putting the foamy copper containing the Co-ZIF precursor into a tubular furnace, introducing hydrogen-argon mixed gas, and carrying out reduction calcination at 300-500 DEG C to obtain the catalytic electrode. The invention provides application of the catalytic electrode as a cathode in a reaction of synthesizing ammonia through nitrate electroreduction. The process conditions are simple, the prepared catalytic electrode can effectively promote the electroreduction process of nitrate radicals, and high ammonia yield and high Faraday efficiency are achieved.

The invention discloses a Cu-metal phthalocyanine heterojunction catalyst, a preparation method thereof and application of the Cu-metal phthalocyanine heterojunction catalyst in preparation of 2, 5-furandimethanol through electro-catalytic hydrogenation of 5-hydroxymethylfurfural. A CuO nanowire is used as a carrier, metal phthalocyanine nanoparticles are effectively loaded through the coordination effect of 3, 4-dihydroxybenzonitrile by utilizing solvothermal reaction, and then the Cu and metal phthalocyanine heterojunction catalyst is prepared through electroreduction. The preparation method is simple, the raw materials are low in price, no precious metal is used, the production cost is effectively reduced, and the industrial application prospect is good; the catalyst has excellent electro-catalytic hydrogenation performance: at room temperature and normal pressure, the selectivity of 2, 5-furandimethanol can reach 100%, the conversion rate of 5-hydroxymethylfurfural reaches 95%, and the Faraday efficiency reaches 89%.

Clean version of Abstract A catalyst and anode for hydrogen production by electrolysis as well as a preparation method, activation method and use thereof are provided. The anode for hydrogen production by electrolysis includes a catalyst which is nickel iron barium hydrotalcite with a nano hexagonal sheet structure and a thickness of 100-200 nm. The catalyst can be prepared by a one-step solvothermal reaction method. Alkaline-earth metal ions are evenly doped in the nickel iron barium hydrotalcite and are in atomic level dispersion, so that the anode for hydrogen production by electrolysis based on the catalyst, when being applied to a process for hydrogen production by electrolysis of an aqueous solution containing chlorine ions, not only can maintain good catalytic performance, but also has greatly improved chlorine ion corrosion resistance, leading to significant improvement of working stability and service life.

The invention discloses a long-life phosphorescent sulfur quantum dot, a multicolor long-life phosphorescent sulfur quantum dot composition and a preparation method and application thereof, and belongs to the technical field of phosphorescent materials and information encryption. The preparation method comprises the following steps: carrying out solvothermal reaction on a sulfur source and ethylenediamine to obtain sulfur quantum dots, and adding a sulfur quantum dot aqueous solution into a boric acid matrix to react to prepare long-life phosphorescent sulfur quantum dots (SQDs-MA); the long-life phosphorescent sulfur quantum dots and a rhodamine B aqueous solution are blended and dried to prepare the multicolor long-life phosphorescent sulfur quantum dot composition (RhB / SQDs-MA). When excited by ultraviolet light, the SQDs-MA shows a wide absorption range of 200 to 700 nm. When excitation is carried out at 362 nm, the SQDs-MA shows a blue fluorescence emission peak at 436 nm. The SQDs-MA powder emits bright green phosphorescence after the irradiation of an ultraviolet lamp is turned off, and under the optimal excitation of 373 nm, the maximum phosphorescence emission value is displayed at 526 nm. Under the irradiation of ultraviolet light, the RhB / SQDs-MA can emit yellow, orange and red phosphorescence at the wavelength of 584 nm, 600 nm and 620 nm.

The invention discloses a two-dimensional metal oxide composite reduced graphene oxide burning rate catalyst, which is prepared by the following steps: uniformly grinding glucose, ammonium nitrate and transition metal nitrate, calcining at high temperature to generate a two-dimensional metal oxide nanosheet, mixing the two-dimensional metal oxide nanosheet with surfactant modified reduced graphene oxide powder, and sintering at high temperature to obtain the two-dimensional metal oxide composite reduced graphene oxide burning rate catalyst. And transferring into a high-pressure hydrothermal kettle for solvothermal reaction, so that the reduced graphene oxide and the two-dimensional metal oxide nanosheet are compounded to form the composite burning rate catalyst with a 2D-2D structure. Two two-dimensional materials are compounded through a solvothermal method, the defects of accumulation of reduced graphene oxide and aggregation of the two-dimensional metal oxide due to high surface energy are effectively avoided, meanwhile, the high conductivity of the reduced graphene oxide is utilized, the synergistic catalysis effect of the metal oxide and the carbon material is enhanced, and the performance of the composite material is improved. The composite material has a good catalytic effect on the thermal decomposition process of ammonium perchlorate.

The invention relates to the technical field of water pollutant removal, in particular to a UiO-66 / sodium carboxymethyl cellulose / polyvinyl alcohol / melamine sponge composite material and a preparation method and application thereof.The preparation method comprises the steps that zirconium chloride and terephthalic acid are dissolved in an organic solvent to obtain a mixed solution, the mixed solution is transferred into a reaction kettle, and through solvothermal reaction, the UiO-66 / sodium carboxymethyl cellulose / polyvinyl alcohol / melamine sponge composite material is obtained; the preparation method comprises the following steps: preparing UiO-66 powder; putting UiO-66 powder into the sodium carboxymethyl cellulose solution, and uniformly stirring the UiO-66 powder and the sodium carboxymethyl cellulose solution to obtain a UiO-66 / CMC mixed solution; placing the UiO-66 / CMC mixed solution in a polyvinyl alcohol solution, and uniformly stirring the UiO-66 / CMC / PVA mixed solution to obtain a UiO-66 / CMC / PVA mixed solution; the preparation method comprises the following steps: dipping a melamine sponge in a UiO-66 / CMC / PVA mixed solution to obtain an adsorption saturated melamine sponge; the UiO-66 / CMC / PVA / coated MS composite material is obtained by repeatedly freezing and thawing the adsorption saturated melamine sponge for multiple times and then freeze-drying, the composite material can be used for rapidly, efficiently and selectively removing phosphate or fluorine ions and the like in water and is convenient to separate and recycle, and a new thought is provided for development of efficient water treatment adsorbent materials.

The invention discloses a bimetallic MOFs mediated morphology-controllable catalyst, a preparation method and application thereof, and the preparation method comprises the following steps: respectively adding an iron salt, a cobalt salt and an organic ligand into an organic solvent, and then adding an alkaline regulator and a surfactant; transferring the stirred solution into a reaction kettle to carry out solvothermal reaction, and centrifuging, washing and drying the suspension after the reaction to obtain a bimetal organic framework (MOFs) precursor; and carrying out heat treatment in a gas atmosphere to obtain the catalyst. The bimetallic MOFs are obtained through a one-step solvothermal method, the size and morphology of the product are regulated through the alkaline regulator, agglomeration of catalyst nanoparticles can be reduced by adding the surfactant, the preparation method is simple, the specific surface area of the product is high, and when the catalyst is used for preparing high-carbon hydrocarbon through catalytic hydrogenation of carbon dioxide, the yield of the product is high. The conversion rate of carbon dioxide reaches up to 47.82%, the selectivity of high-carbon hydrocarbon reaches 59.68%, the selectivity of by-products carbon monoxide and methane is low, and the catalytic activity is good.

The invention relates to the technical field of preparation of lithium ion battery positive electrode materials, in particular to a double-coated modified positive electrode material and a preparation method and application thereof. The preparation method of the double-coated modified positive electrode material comprises the following steps: obtaining a positive electrode material and a high-entropy oxide; uniformly mixing the positive electrode material with the high-entropy oxide, and carrying out first sintering treatment to obtain a high-entropy oxide coating material; and mixing the high-entropy oxide coating material, a carbon source and a solvent, and sequentially carrying out solvothermal reaction and secondary sintering treatment to obtain the double-coating modified positive electrode material. On the basis of carrying out high-entropy oxide solid-phase sintering coating modification on the positive electrode material, wet-process carbon coating is further carried out, so that the lithium-hydrogen exchange side reaction caused by long-time contact between positive electrode particles and a solution can be effectively reduced, and the defects of low specific capacity and low first-circle efficiency of the solid-phase sintering coating high-entropy oxide positive electrode material can be overcome.

The invention belongs to the field of electro-catalytic materials, and particularly relates to a preparation method of a RuxCr1-xO2 bimetallic electro-catalytic material, which comprises the following steps: carrying out solvothermal reaction on a raw material solution containing a Ru source, a Cr source, a # imgabs0 # regulator with a structure as shown in a formula 1 and alkali, and calcining a solvothermal product at 300-500 DEG C to obtain the RuxCr1-xO2 bimetallic electro-catalytic material, wherein the Ru / Cr molar ratio in the Ru source and the Cr source is x / 1-x; x is in a range of 0.5 to 0.7; the pH value of the raw material solution is more than 10. The invention also comprises the material prepared by the preparation method and application of the material in OER catalysis. The preparation method is simple, the use amount of the noble metal is reduced due to the use of the transition metal, the production cost of the electrocatalyst is effectively reduced, and the catalytic material shows lower reaction overpotential and higher stability in an electrochemical test.

The invention discloses an ethylene chain-based ferrocenyl covalent organic polymer and application thereof, and belongs to the technical field of biological medicines. The covalent organic polymer based on the ethylene chain ferrocenyl is a covalent organic polymer which is obtained by taking 1, 1 '-ferrocenedicarboxaldehyde, bromoethane and 2, 4, 6-trimethyl-1, 3, 5-triazine as monomers through polymerization and has a completely conjugated structure. The method comprises the following steps: adding 1, 1 '-ferrocenedicarboxaldehyde, bromoethane and 2, 4, 6-trimethyl-1, 3, 5-triazine into a mixed solvent under a protective atmosphere, uniformly stirring, carrying out solvothermal reaction in a closed environment, and washing and drying a product obtained by filtering to obtain the covalent organic polymer based on ethylene chain ferrocenyl. The novel COP material ITAFc-COP with a completely conjugated structure is synthesized, the photo-thermal activity of the novel COP material ITAFc-COP is enhanced by the completely conjugated structure of ITAFc-COP, and the novel COP material has a photo-thermal effect and pod-like activity at the same time.

The invention discloses a zirconium-based MOF material and a preparation method and application thereof, in the zirconium-based MOF material, metal ions are Zr < 4 + >, an organic ligand is ellagic acid, a conditioning agent is gallic acid, and the material has an oxygen vacancy structure and a hierarchical pore structure; the preparation method comprises the following steps: (1) mixing ellagic acid, gallic acid, zirconium oxychloride octahydrate and a solvent, and carrying out solvothermal reaction; and (2) washing and drying the solid after the reaction in the step (1) to obtain the zirconium-based MOF material. According to the invention, renewable and low-cost ellagic acid and gallic acid are respectively used as an organic ligand and a conditioning agent, and an oxygen vacancy structure is constructed in a competitive coordination manner, so that more hydroxyl and unsaturated metal Zr active sites are exposed, the interaction with formaldehyde (HCHO) is enhanced, and meanwhile, the oxygen vacancy structure can be used as an oxygen vacancy catalyst. And the existence of the hierarchical pore structure can effectively promote mass transfer, so that the HCHO adsorption capacity is improved.

The invention provides a method for accurately regulating and controlling pores of an MXene material by utilizing a phosphonic acid ligand, which mainly comprises the following key steps of: directionally removing a main group element (A) layer of an MAX precursor by wet etching to obtain lamellar MXene, and then introducing a protonated quaternary amine compound intercalator to strip the MXene. And finally, carrying out functional modification and conversion by adopting a phosphonic acid ligand, and stably introducing phosphonic acid groups between layers and on the surface of MXene through solvothermal reaction to realize accurate regulation and control of interlayer spacing. The prepared material can realize efficient adsorption of uranyl in an acidic environment, shows high selectivity, high adsorption capacity and good acid stability and regeneration capacity to uranyl, provides a stable and efficient selective adsorption solution for treating high-acidity uranium-containing nuclear wastewater, and has a remarkable industrial application prospect.

The invention discloses a multilayer nanostructure metal hydride and a preparation method thereof.The preparation method comprises the steps that transition metal ion salt and a carbon material are added into a polar solvent to be mixed, heating and stirring are conducted to obtain solid powder, and the solid powder is subjected to a hydrogen thermal reduction reaction to obtain a functionalized carbon material; a metal hydride raw material and a functionalized carbon material are added into an organic solvent, ultrasonic treatment and mixing are carried out, a mixed solution is obtained, and the metal hydride raw material is a mixture of an alkyl metal Mg compound or an alkyl metal Li compound and a borane compound; and in a hydrogen atmosphere, carrying out solvothermal reaction on the mixed solution, and then centrifuging, washing, filtering and drying to obtain the multilayer nanostructure metal hydride. The multilayer nano-structure metal hydride prepared by the preparation method has relatively high hydrogen absorption and hydrogen storage capacity.

The invention discloses a sodium alginate embedded iron-carbon microcapsule material for repairing cadmium and arsenic polluted soil and a preparation method of the sodium alginate embedded iron-carbon microcapsule material, and belongs to the technical field of soil heavy metal pollution repairing materials. The material comprises straw biochar, high-iron steel slag powder, a sulfydryl acetylated chitosan-iron monatomic cluster compound, a boron-doped graphitized carbon coated cobalt ferrite nanosheet, sodium alginate, calcium chloride and sodium carbonate. Wherein the sulfydryl acetylated chitosan is prepared by reacting chitosan with sulfydryl acetic anhydride, dialyzing and drying, and performing solvothermal reaction with ferric nitrate under high pressure. The preparation method comprises the following steps: pyrolyzing and drying the straw biochar, reacting the high-iron steel slag with sulfuric acid, adding the biochar, adjusting the pH value, adding sodium carbonate, mixing to obtain an iron-carbon-based passivation material, mixing with two modified compounds, mixing with a sodium alginate solution, dropwise adding a calcium chloride solution, and stirring and curing. The material can be applied to remediation of cadmium and arsenic polluted soil.

The invention relates to an MOF (Metal Organic Framework)-derived Cu-In2O3 / C composite catalyst. The Cu-In2O3 / C composite catalyst is prepared by a two-step method of solvothermal reaction and high-temperature annealing treatment. The invention also provides a preparation method of the MOF-derived Cu-In2O3 / C composite catalyst. The Cu-In2O3 heterostructure can endow the catalyst with abundant catalytic active sites and an optimized surface electron structure, and the existence of the carbon carrier can enhance the conductivity and stability of the catalyst, so that the obtained Cu-In2O3 / C composite catalyst can efficiently catalyze the co-reduction reaction of carbon dioxide and nitrate under the electrochemical condition to generate urea. The synthesis method of the Cu-In2O3 / C composite catalyst is simple, easy to operate and suitable for large-scale production and application.

Disclosed in the present invention are an oxygen-enriched carbon quantum dot composite bismuth oxybromide nanosheet material, and a preparation method therefor and the use thereof. The preparation method comprises: sequentially uniformly dissolving Bi(NO3)3·5H2O and oxygen-enriched carbon quantum dots in a mannitol solution, then adding KBr thereto, stirring the mixture, then subjecting same to a solvothermal reaction, and then subjecting same to washing, suction filtration and drying, so as to obtain an oxygen-enriched carbon quantum dot composite bismuth oxybromide nanosheet material. The preparation method of the present invention is simple, and the bismuth oxybromide nanosheet is more easily and uniformly modified with the oxygen-enriched carbon quantum dots. The oxygen-enriched carbon quantum dots provide more active sites for bismuth oxybromide, thereby overcoming the defects of monomer bismuth oxybromide having a limited visible-light response and few active sites, optimizing the electron transmission performance of monomers, enhancing the light absorption intensity of the material, effectively guiding the charge flow, accelerating the separation and transfer of photo-generated charges, and achieving efficient visible light catalytic activity.

The invention discloses a modification method and application of a modified amorphous alumina defluorination adsorbent, and belongs to the technical field of adsorption materials. A modification method of a modified amorphous alumina defluorination adsorbent comprises the following steps: (1) preparation of a precursor: dissolving an aluminum salt with a solvent, adding a regulator, uniformly stirring, and carrying out solvothermal reaction in a reaction kettle with a polytetrafluoroethylene lining to obtain the precursor; (2) preparation of amorphous alumina: calcining the precursor in a muffle furnace to obtain amorphous alumina AlOx; and (3) modifying the amorphous alumina: adding the amorphous alumina into the modifier solution, stirring, standing, filtering and drying to obtain the amorphous alumina. The method is easy and convenient to operate, low in cost, suitable for large-scale production, environmentally friendly and free of pollution, and the modified aluminum oxide is higher in adsorption activity and has excellent regeneration performance.

The invention belongs to the technical field of preparation of isocyanate, and particularly discloses an isocyanate preparation method based on a rare earth upconversion material, which comprises the following steps: mixing and dissolving rare earth metal salt and ligand in absolute ethyl alcohol or anhydrous ethylene glycol, and performing solvothermal reaction to prepare rare earth nanoparticles; and calcining the prepared rare earth nanoparticles at 450-550 DEG C to obtain the rare earth up-conversion material. The preparation method comprises the following steps: adding the rare earth up-conversion material into a solution of an organic amine compound, and carrying out photocatalytic oxidation reaction under the irradiation of near-infrared light, so as to prepare the isocyanate, wherein the mass percent of the rare earth up-conversion material in the organic amine compound is 1-10%, and the mass percent of the rare earth up-conversion material in the organic amine compound is 1-10%. Through the light conversion characteristic of the rare earth upconversion material, the isocyanate reaction is smoothly carried out under the excitation of low-energy near-infrared light, and the method has the advantages of mild reaction, low equipment requirement, high efficiency and the like.

The invention belongs to the technical field of nano composite materials, and relates to a preparation method of an iron diselenide / nitrogen-sulfur co-doped carbon nanosheet composite material, which comprises the following steps: putting cellulose, sodium bicarbonate and thiourea into a mortar, uniformly grinding, putting into a tubular furnace, calcining at high temperature under the protection of inert gas, naturally cooling, centrifugally separating and collecting the calcined powder, thereby obtaining the iron diselenide / nitrogen-sulfur co-doped carbon nanosheet composite material. The nitrogen and sulfur co-doped carbon nanosheets are obtained; ultrasonically dispersing iron nitrate nonahydrate in ethanol, heating in an oil bath until the ethanol is evaporated to dryness, and carrying out heat treatment to obtain an iron-based precursor; the obtained iron-based precursor, selenium dioxide and nitrogen and sulfur co-doped carbon nanosheets are ultrasonically dispersed in benzyl alcohol, the mixture is transferred into a reaction kettle with a polytetrafluoroethylene lining, the composite material is obtained after solvothermal reaction, and the morphology of the composite material is that iron diselenide nanoparticles are evenly and densely attached to the surfaces of the nitrogen and sulfur co-doped carbon nanosheets. The method is simple and easy to implement, suitable for large-scale production, easy to implement industrially and expected to be applied to the negative electrode of the hybrid supercapacitor.