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237 results about "Sodium acetrizoate" patented technology

Sodium acetrizoate (rINN, trade names Urokon, Triurol and Salpix), the sodium salt of acetrizoic acid, is a high-osmolality, water-soluble, iodine-based radiographic contrast medium no longer in clinical use.

Electrodynamic method for removing fluorine contaminant in soil

The invention discloses an electrodynamic method for removing fluorine contaminant in soil, which is as follows: an anion-exchange membrane is arranged between the anode and the contaminated soil to prevent the H+ generated by the anode from entering the electrolyzer so as to avoid the increase of the acidity of the contaminated soil; sodium acetate solution is put in an anode chamber to be used as electrolyte, deionized water is put in a cathode chamber to be used as electrolyte, and the liquid levels of the anode chamber and the cathode chamber are maintained to be parallel; in the rehabilitating process, the electrolytes circulate constantly to be stirred evenly so as to bring away the H2 and O2 which are generated by the anode and the cathode; the sodium acetate solution added in the anode chamber supplies OH- which neutralizes the H+ generated by the anode, and the surplus OH- and the OH- generated by the cathode promote the adsorbed fluorine in the soil to be desorbed to be free fluorinions; and the fluoride in the soil is removed through the electrodynamic approaches of electromigration, electroosmosis and the like. The method can effectively promote the adsorbed fluoride to be desorbed from the surface of the contaminated soil particles, remarkably improves the fluorine contaminant removal efficiency, reduces overpotential and saves energy consumption, and after the soil is rehabilitated, the pH value of the soil is basically maintained at the original state.
Owner:HENAN UNIV OF SCI & TECH

PtRu/graphene nano electro-catalyst and preparation method thereof

The invention discloses a preparation method of PtRu/graphene nano electro-catalyst, comprising the following steps of: ultrasonically dispersing oxidized nano graphite sheets into liquid polylol; then adding a chloroplatinic acid solution and a sodium acetate solution, sufficiently mixing, wherein the content of the oxidized nano graphite sheets contained in a mixture is 0.3-1.1 g/L, the concentration of chloroplatinic acid is 0.0004-0.002 mol/L, the concentration of ruthenium chloride is 0.0004-0.0013 mol/L, and the concentration of sodium acetate is 0.005-0.027 mol/L; transferring the mixture to a microwave hydro-thermal reaction kettle for microwave hydro-thermal reaction for 5-10 minutes; and filtering, washing and drying to obtain the PtRu/graphene nano electro-catalyst, wherein the mass fraction of a PtRu alloy contained in the PtRu/graphene nano electro-catalyst is 20-40 percent, the mass fraction of graphene is 80-60 percent, the atomic ratio of the PtRu alloy is Pt:Ru=1:2-1.5:1, and the liquid polylol is propanetriol or glycol. The preparation method has energy saving, fastness, simple process, and the like; and in addition, the prepared PtRu/graphene nano electro-catalyst has good electrocatalysis property for the oxidation of methanol and ethanol and is widely used as anode catalysts of direct methanol fuel cells.
Owner:ZHEJIANG UNIV

Rhodamine 6G hydrazide salicylaldehyde azomethine, synthesizing process and application in measuring content of copper ion

The present invention relates to rhodamine 6G hydrazide salicylal azomethine, a synthesization method and an application in the content determination of cupric ions, which belong to the field of the analysis and determination of cupric ions in water sample. The molecular structural formula of the rhodamine 6G hydrazide salicylal azomethine is shown on the right, and the present invention discloses the synthesization method of the rhodamine 6G hydrazide salicylal azomethine and rhodamine 6G hydrazide salicylal azomethine solution used for the content determination of a small amount of cupric ions in water sample: 0 percent to 98.99 percent of ethanol, 99.99 percent to 1 percent of acetic acid / sodium acetate buffer solution with the pH value of 5 to 9, in which the total concentration of acetic acid is 1 to 100 millimoles per litre, 0.01 percent of N, N-dimethylformamide and 1ppm to 100ppm of rhodamine 6G hydrazide salicylal azomethine, all measured in mass percentage. By a spectrophotometer, the solution can be used for the accurate quantitative determination of 0.005ppm to 0.256ppm of cupric ions in water sample as well as the semiquantitative determination of no less than 0.075ppm of cupric ions in water sample by direct naked-eye observation on the change of colors.
Owner:TSINGHUA UNIV

Production method of high-purity polyvinyl alcohol

The invention discloses a production method of high-purity polyvinyl alcohol. The production method adopts polyvinyl acetate as the material, comprises alcoholysis reaction, saponification reaction as well as neutralizing, washing, separating and drying; the production method is characterized in that the saponification reaction is carried out in the following steps of adding a semi-finished product with alcoholysis degree of 80%-92% and grain size of 1mm-10mm, which is prepared by the alcoholysis reaction, into sodium hydroxide liquor with concentration of 4g/L-60g/L to stir and react for 0.5 hour under 0 DEG C-20 DEG C, wherein a batching mass ratio of the semi-finished product to alkali liquor is (1:2)-(1:7); residual alkaline is neutralized by using acetic acid after the reaction is ended, and then washed by using desalted water; and solid-liquid separation is carried out after washing, and solid is vacuum-dried to obtain the high-purity polyvinyl alcohol with alcoholysis degree greater than 92%. The product has sodium acetate content lower than 0.3%, and volatile component lower than 0.5%, can be directly applied to high-quality industries such as medicines and optical films without being re-processed, and is convenient for downstream manufacturers to use, so that using cost is lowered.
Owner:安徽皖维先进功能膜材料研究院有限公司

Preparation method of rice bran selenoprotein powder

The invention relates to the field of selenium-rich rice byproducts, and in particular relates to a preparation method of rice bran selenoprotein powder. The method comprises the following steps of: grinding, screening and degreasing byproduct rice bran obtained after rice processing to prepare rough rice bran into degreased rice bran, mixing 60%-70% alcohol with the degreased rice bran in the material-liquid ratio of (1:3)-(1:5), stirring on a magnetic force mixing machine for a certain period of time, and centrifuging, wherein the processes are repeated for three times; and carrying out alkaline extraction with 0.02-0.1mol/L NaOH solution for 1-3 hours in the material-liquid ratio of (1:10)-(1:20) at the temperature of 30-40 DEG C, taking supernate after centrifuging, decolorizing with active carbon, adjusting an isoelectric point by utilizing a acetic acid-natrium aceticum buffer solution for acid deposition, then centrifuging, and freezing to dry after washing, thereby obtaining the rice bran selenoprotein powder with the protein extraction ratio of 60-80%, and the selenium content of 0.2-0.3mg/kg finally. The selenoprotein powder provided by the invention is natural in nutritional ingredient, is rich in trace element selenium, keeps the original nutrition ingredients in the rice bran selenoprotein powder effectively, and is suitably used as a food auxiliary material or a nutrition enhancer.
Owner:NANJING UNIV OF FINANCE & ECONOMICS +1

Method for preparing spherical super-paramagnetic ferroferric oxide nano-clusters

The invention relates to a method for preparing spherical super-paramagnetic ferroferric oxide nano-clusters. The method comprises the following steps: dissolving ferric chloride hexahydrate in ethylene glycol, wherein each millimole of the ferric chloride hexahydrate is dissolved in 1 to 40 milliliters of the ethylene glycol; stirring the mixture to obtain uniform reddish brown solution; dissolving anhydrous sodium acetate in the solution obtained by the step one; ultrasonically stirring the mixture to obtain yellowish-brown viscous solution, wherein the molar ratio of the anhydrous sodium acetate to ferric chloride is 1:1-8:1; dissolving polyacrylic acid in the solution and ultrasonically stirring the mixture to obtain uniform red viscous solution, wherein 1 milliliter of PAA is added into every 40 to 400 milliliter of ethylene glycol or solution of diethylene glycol; transferring the solution to a hydrothermal kettle inner container (made from tetrafluoroethylene) with a total volume of 50 milliliters; performing a reaction at the temperature of between 180 and 220 DEG C for 6 to 16 hours after enclosing the inner container; naturally cooling the inner container to room temperature; and extracting a sample and washing the sample with water and alcohol to obtain the spherical super-paramagnetic ferroferric oxide nano-clusters. A synthetic method only needs a one-step reaction, and a used reagent is cheap and nontoxic.
Owner:NANJING UNIV

Magnetic water-soluble fullerene, and preparation method and application thereof

The invention relates to a magnetic water-soluble fullerene, and a preparation method and application thereof. The invention effectively solves the problems of low water solubility, low compatibility and poor targeting property of the fullerene. The method comprises the following steps: dissolving fullerene in toluene, adding sodium hydride and diethyl bromomalonate, stirring in a nitrogen protective atmosphere to remove sodium hydride and toluene, adding the dried diethyl-bromomalonate-substituted fullerene into the toluene, hydrolyzing until the toluene phase becomes colorless, adding concentrated hydrochloric acid, filtering to obtain a filter cake, removing insoluble substances and methanol, drying to obtain malonic-acid-substituted fullerene, dissolving in an ethylene glycol and di-acetal mixed solvent, adding sodium acetate and ferric iron salt to react, washing, drying to obtain ferroferric-oxide-carried fullerene, carrying out ultrasonic dispersion on the ferroferric-oxide-carried fullerene, amino water-soluble substance and EDC.HCl in phosphate, reacting in a dark place, carrying out vacuum filtration, and drying to obtain the magnetic water-soluble fullerene. The magnetic water-soluble fullerene has the advantages of favorable magnetic targeting propertt, strong water dispersity, low toxicity for organisms, high physical and chemical stability, good quality and low cost.
Owner:ZHENGZHOU UNIV

Method for recycling and utilizing phosphoric acid and acetic acid from waste aluminum etching solution

The invention discloses a method for recycling and reutilizing phosphoric acid and acetic acid from a waste aluminum etching solution. The method comprises the following steps of (1) performing pressure-relief distillation on the waste aluminum etching solution, and removing acetic acid and nitric acid by a fractionation method; (2) treating by ethanol, purifying, and recycling the phosphoric acid; (3) adding sodium acetate into a nitric acid-acetic acid-water mixed solution to react, so as to obtain the acetic acid; applying a water absorbent, so as to obtain the high-concentration acetic acid. A harmless treatment and resource utilization method for recycling and reutilizing of the mixed acid is provided, and has the advantages that the resource recycling and reutilizing of the phosphoric acid and acetic acid can be furthest realized, the raw material is saved, the economic benefit is increased, the amount of wastewater is greatly reduced, and the waste of resource and the pollutionto environment are avoided; the technology process is simple, the operability is good, the effective resource utilization effect is realized, and the method is suitable for the industrial production and waste liquid treatment in the related fields.
Owner:ANQING XINXIANGRUI CHEM CO LTD

Method using acetic acid for controlled catalysis of orientational hydrolysis of xylan to prepare multicomponent xylooligosaccharide

ActiveCN104164520AAchieve controlled catalytic hydrolysisOvercome the deficiency of many toxic decomposition productsSaccharides productionSodium acetateSodium acetrizoate
The present invention discloses a method using acetic acid for controlled catalysis of orientational hydrolysis of xylan to prepare multicomponent xylooligosaccharide, and the method includes the following steps: 1) adding food grade acetic acid to a suspension reaction system containing no more than 20% of the xylan until the final concentration of the acetic acid is not more than 30%, controlling the reaction temperature at 110 to 125 DEG C for reaction for no more than 3h to obtain a xylan hydrolysate; 2) performing microfiltration and nanofiltration on the xylan hydrolysate product to obtain an entrapped xylooligosaccharide solution and an acetic acid through liquid, and recycling the acetic acid through liquid for using in the step 1); and 3) using an edible alkaline material for neutralizing the entrapped xylooligosaccharide solution to neutral and producing sodium acetate, and removing the sodium acetate by electrodialysis treatment to obtain a xylooligosaccharide product solution. The recyclable edible acetic acid is used as a catalyst for the realization of controlled hydrolysis reaction of the xylan in the mild reaction conditions for orientational catalysis of hydrolysis of the xylan to prepare a xylooligosaccharide product containing xylooligosaccharide components with the polymerization degree of 2-8, the yield is more than 30% of raw material xylooligosaccharide, the product almost contains no furan, formic acid and other decomposition products, and xylooligosaccharide green production can be achieved.
Owner:NANJING FORESTRY UNIV

Detection method of glucose related substances in acetate compound electrolyte injection

The invention provides a detection method of glucose related substances in an acetate compound electrolyte injection, related to the technical field of medicine. The detection method of glucose related substances in the acetate compound electrolyte injection comprises the following steps: preparing a system suitability solution: weighing a sodium acetate reference substance, a glucose reference substance and a glucose degradation product reference substance, placing in a 10ml volumetric flask, diluting to a mark with water, shaking well, and taking as the system suitability solution; preparinga test substance and a self reference solution: taking the sample directly for the test substance solution; measuring and taking the test substance solution, placing in a 50ml volumetric flask, diluting to the mark with water, shaking well as a contrast solution A; taking a portion of the contrast solution A, placing in a 100ml volumetric flask, diluting to the mark with water, and shaking well as a contrast solution B; and chromatographic conditions are as follows: Waters Sugar Park I column, 300mm x 6.5mm, 10[Mu]m; mobile phase, 50 mg/L aqueous solution of calcium ethylenediaminetetraacetate; flow rate, 0.3 ml/min; column temperature, 85+/-5 degrees centigrade; differential detector set temperature, 40+/-5 degrees centigrade; and injection volume, 20[Mu]l. The detection method of glucose related substances in the acetate compound electrolyte injection has the beneficial effects of effectively separating the acetate and the glucose degradation products, optimizing the process and improving the product quality and safety.
Owner:HUAREN PHARMACEUTICAL CO LTD

Preparation method of platiniridium/carbon-electro catalyst by using microwave synthesis

The invention discloses a preparation method of a platiniridium/carbon-electro catalyst by using microwave synthesis. The preparation method comprises the following steps of: evenly distributing nanometer carbon carriers in ethylene glycol solution containing both platinum metal salt and iridium metal salt at the same time, wherein the concentration of the platinum salt and the iridium salt is 0.001 to 0.01 mol/L; adding sodium acetate as a stabilizer, wherein the concentration of the sodium acetate in the resulting solution is 0.005 to 0.03 mol/L; then heating the well-distributed mixture of the nanometer carbon carriers and the metal salt ethylene glycol solution for 2 to 4 minutes by microwave radiation, and then filtering, washing and drying to obtain the platiniridium/carbon-electro catalysts. The atomic composition ratio of a platinum iridium alloy is PtxIry, wherein x is 0.1 to 1, and y is 0.1 to 1. The invention has the advantages that the nano-particles of the platinum iridium alloy, which are loaded on the surfaces of the carbon carriers, have small grain diameter averagely from 3 to 4 nm, and the grain diameter distribution is narrow, and the loading capacity of the alloy nano particles on the surface of the carbon carrier is 5% to 30%. The invention also has the advantages of high speed, simple process, high efficiency and energy saving. The platiniridium/carbon-electro catalyst is widely used in the field of electrochemical energy conversion.
Owner:赵杰 +1
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